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Synergistic regulation of hydrophobicity and basicity for copper hydroxide-derived copper to promote the CO_(2)electroreduction reaction

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Carbon Energy 2023年第6期5卷 72-81页

作者： limin zhou Chenghang Li Jing-Jing Lv Wei Wang Shaojun Zhu Jun Li Yifei Yuan Zheng-Jun Wang Qingcheng Zhang Huile Jin Shun Wang Wenzhou Key Lab of Advanced Energy Storage and Conversion Zhejiang Province Key Lab of Leather EngineeringCollege of Chemistry and Materials EngineeringWenzhou UniversityWenzhouZhejiangChina Zhejiang Engineering Research Center for Electrochemical Energy Materials and Devices Institute of New Materials and Industrial TechnologiesWenzhou UniversityWenzhouZhejiangChina

A simple method was proposed to activate alkaline Cu(OH)_(2)with an acidic ionomer,Nafion,to regulate its surface microenvironment,including hydrophobicity and local basicity.In particular,the direct complete neutralization reaction between Cu(OH)_(2)and Nafion in aqueous solution induces the exposing of vast anions which can exclude the in-situ-formed hydroxides and raise the local basicity.Remarkably,the optimal Nafionactivated Cu(OH)_(2)-derived Cu can efficiently suppress the hydrogen evolution reaction(HER)and improve the selectivity for multi-carbon products in the CO_(2)electroreduction reaction(eCO_(2)RR).The H2 Faradaic efficiency(FE)decreased to 11%at a current density of 300 mA/cm2(−0.76 V vs.RHE)in a flow cell,while the bare one with H2 had an FE of 40%.The total eCO_(2)RR FE reaches as high as 83%,along with an evidently increased C2H4 FE of 44%as compared with the bare one(24%),and good stability(8000 s),surpassing that of most of the reported Cu(OH)_(2)-derived Cu.The experimental and theoretical results both show that the strong hydrophobicity and high local basicity jointly boosted the eCO_(2)RR as acquired by felicitously introducing ionomer on the Cu(OH)_(2)-derived Cu surface.

关键词： CO_(2)electroreduction reaction Cu(OH)_(2)@Nafion flow cell ionomers multi-carbon products

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Dynamics of arsenic in salt marsh sediments from Dongtan wetland of the Yangtze River estuary,China

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Journal of Environmental Sciences 2012年第12期24卷 2113-2121页

作者： Yongjie Wang limin zhou Xiangmin Zheng Peng Qian Yonghong Wu Department of Geography College of Resources and Environmental SciencesEast China Normal UniversityShanghai 200062China School of Geography Nantong UniversityNantong 226019China Department of Gography Minfiang UniversityFuzhou 350108China

The mobility and transformation of arsenic （As） in salt marsh sediments were investigated in Dongtan wetland of the Yangtze River estuary, China. As in surface water, pore water and the rhizosphere sediments were quantified. The microcosm incubation experiments were conducted during the flooding of the sediments to examine As dynamics that occurred during changing redox conditions. The concentrations of dissolved As in pore water （0.04--0.95 ixmol/L） were significantly greater than that in surface water （0.03-0.06 lunol/L）. Under anoxic conditions, the reactive As could be initially mobilized by the reductive dissolution of Fe（III）（hydr）oxides. Subsequently, most of the dissolved As was likely to be associated with secondary iron （hydr）oxide phases and remained in solid phases. The seasonal variability of acid volatile sulfide concentrations suggest the anoxic conditions are enhanced during summer by Spartina alterniflora compared to Phragmites australis and Scirpus mariqueter, causing a notable increase in As mobility. Generally, there was a typical variation in redox conditions with season in salt marsh sediments of Dongtan wetland, in which the dynamics of As mobility and transformation possibly were controlled by iron, and all of this could be significantly influenced by the rapid spread of S. alterniflora.

关键词： Arsenic iron （hydr）oxides salt marsh sediment Spartina alterniflora Yangtze River estuary

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6-Phosphogluconate dehydrogenase 2 bridges the OPP and shikimate pathways to enhance aromatic amino acid production in plants

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Science China Life Sciences 2024年

作者： Qian Tang Yuxin Huang Zhuanglin Shen Linhui Sun Yang Gu Huiqing He Yanhong Chen Jiahai zhou limin Zhang Cuihuan Zhao Shisong Ma Yunhai Li Jie Wu Qiao Zhao Shenzhen Key Laboratory of Synthetic Genomics Guangdong Provincial Key Laboratory of Synthetic Genomics Key Laboratory of Quantitative Synthetic Biology Shenzhen Institute of Synthetic BiologyShenzhen Institute of Advanced Technology Chinese Academy of Sciences University of Chinese Academy of Sciences CAS Key Laboratory for Quantitative Engineering Biology Shenzhen Institute of Synthetic Biology Shenzhen Institute of Advanced Technology Chinese Academy of Sciences Key Laboratory of Quantitative Synthetic Biology Shenzhen Institute of Synthetic Biology Shenzhen Institute of Advanced Technology Chinese Academy of Sciences Key Laboratory of Agricultural Microbiology of Heilongjiang Province Northeast Agricultural University Center for Plant Biology School of Life Sciences Tsinghua University State Key Laboratory of Plant Cell and Chromosome Engineering CAS Centre for Excellence in Molecular Plant Biology Institute of Genetics and Developmental Biology The Innovative Academy of Seed Design Chinese Academy of Sciences MOE Key Laboratory for Membraneless Organelles and Cellular Dynamics School of Life Sciences University of Science and Technology of China Innovation Academy for Seed Design Chinese Academy of Sciences

The oxidative pentose phosphate(OPP) pathway provides metabolic intermediates for the shikimate pathway and directs carbon flow to the biosynthesis of aromatic amino acids(AAAs), which serve as basic protein building blocks and precursors of numerous metabolites essential for plant growth. However, genetic evidence linking the two pathways is largely unclear. In this study, we identified 6-phosphogluconate dehydrogenase 2(PGD2), the rate-limiting enzyme of the cytosolic OPP pathway, through suppressor screening of arogenate dehydrogenase 2(adh2) in Arabidopsis. Our data indicated that a single amino acid substitution at position 63(glutamic acid to lysine) of PGD2 enhanced its enzyme activity by facilitating the dissociation of products from the active site of PGD2, thus increasing the accumulation of AAAs and partially restoring the defective phenotype of adh2. Phylogenetic analysis indicated that the point mutation occurred in a well-conserved amino acid residue. Plants with different amino acids at this conserved site of PGDs confer diverse catalytic activities, thus exhibiting distinct AAAs producing capability. These findings uncover the genetic link between the OPP pathway and AAAs biosynthesis through PGD2. The gain-of-function point mutation of PGD2 identified here could be considered as a potential engineering target to alter the metabolic flux for the production of AAAs and downstream compounds.

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Long noncoding RNA LINC02568 sequesters microRNA-874-3p to facilitate malignancy in breast cancer cells via cyclin E1 overexpression

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Oncology Research 2021年第4期29卷 291-303页

作者： YI DONG LIANBO ZHANG XIN GUAN TAO LIU limin zhou Department of Second Breast Surgery Jilin Cancer HospitalJilin130012China Department of Medical Insurance Guarantee Office Jilin Cancer HospitalJilin130012China Department of Breast Surgery The First Hospital of Jilin UniversityJilin130061China

Increasing numbers of long noncoding RNAs(lncRNAs)are implicated in breast cancer oncogenicity.However,the contribution of LINC02568 toward breast cancer progression remains unclear and requires further investigation.Herein,we evaluated LINC02568 expression in breast cancer and clariﬁed its effect on disease malignancy.We also investigated the mechanisms underlying the pro-oncogenic role of LINC02568.Consequently,LINC02568 was upregulated in breast cancer samples,with a notable association with worse overall survival.Functionally,depleted LINC02568 suppressed cell proliferation,colony formation,and metastasis,whereas LINC02568 overexpression exerted the opposite effects.Our mechanistic investigations suggested that LINC02568 was physically bound to and sequestered microRNA-874-3p(miR-874-3p).Furthermore,miR-874-3p mediated suppressive effects in breast cancer cells by targeting cyclin E1(CCNE1).LINC02568 positively controlled CCNE1 expression by sequestering miR-874-3p.Rescue experiments revealed that increased miR-874-3p or decreased CCNE1 expression recovered cell growth and motility functions induced by LINC02568 in breast cancer cells.In conclusion,the tumor-promoting functions of LINC02568 in breast cancer cells were enhanced by sequestering miR-874-3p and consequently over-expressing CCNE1.Our data may facilitate the identiﬁcation of novel therapeutic targets in clinical settings.

关键词： Long noncoding RNA ceRNA Therapeutic intervention microRNA

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Sulfur-linked carbonyl polymer as a robust organic cathode for rapid and durable aluminum batteries

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Journal of Energy Chemistry 2021年第12期30卷 320-327,I0007页

作者： Liang Fang limin zhou Lianmeng Cui Peixin Jiao Qinyou An Kai Zhang Department of Energy and Materials Engineering Dongguk University-SeoulSeoul 04620Republic of Korea Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Engineering Research Center of High-efficiency Energy Storage(Ministry of Education)Renewable Energy Conversion and Storage Center(RECAST)College of ChemistryNankai UniversityTianjin 300071China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Foshan 528200GuangdongChina

Rechargeable aluminum batteries are believed as a promising next-generation energy-storage system due to abundant low-cost Al sources and high volumetric specific capacity.The Al-storage cathodes,however,are plagued by strong electrostatic interaction between host materials and carrier ions,leading to large overpotential and undesired cycling stability as well as sluggish ion diffusion kinetics.Herein,sulfur-linked carbonyl polymer based on perylene-3,4,9,10-tetracarboxylic dianhydride(PTCDA) as the cathode materials for ABs is proposed,which demonstrates a small voltage polarization(135 mV),a reversible capacity of 110 mAh g^(-1) at 100 mA g^(-1) even after 1200 cycles,and rapid Al-storage kinetics.Compared with PTCDA,the sulfide polymer possesses higher working voltage because of its lower LUMO energy level according to theoretical calculation.The ordered carbonyl active sites in sulfide polymer contribute to the maximized material utilization and rapid ion coordination and dissociation,resulting in superior rate capability.Besides,the bridged thioether bonds endow the polysulfide with robust and flexible structure,which inhibits the dissolution of active materials and improves cycling stability.This work implies the importance of ordered arrangement of redox active moieties for organic electrode,which provides the theoretical direction for the structural design of organic materials applied in multivalent-ion batteries.

关键词： Aluminum batteries Organic materials Carbonyl polymer Electrochemical active sites Ordered arrangement

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多采样率双通道有源噪声反馈控制系统的研究

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华东理工大学学报（自然科学版） 2024年第2期50卷 301-309页

作者：杨丽民周邵萍李锦良邢改兰华东理工大学承压系统与安全教育部重点实验室上海200237

传统有源噪声控制系统中的音频编解码器只能使用高速率的单一采样率,因此系统中的建模滤波器和自适应滤波器需要的长度较长,而且预留给每次迭代计算的时间很短,这导致了计算量大、难以实现实时在线计算的问题。针对以上困难,首先提出一... 详细信息

传统有源噪声控制系统中的音频编解码器只能使用高速率的单一采样率,因此系统中的建模滤波器和自适应滤波器需要的长度较长,而且预留给每次迭代计算的时间很短,这导致了计算量大、难以实现实时在线计算的问题。针对以上困难,首先提出一种多采样率的方法,即采用抽取和插值的方法为有源噪声控制系统提供更低的采样率,从而在减少计算量的同时增加可用于迭代计算的时间,并基于最小均方算法对次级声通道进行建模,推演多采样率双通道反馈有源噪声控制系统模型;其次搭建基于座椅头靠和数字信号处理器的实验平台,对多采样率的双通道有源噪声反馈控制系统的有效性进行实验验证。验证结果表明,针对低频噪声,在相应的频段上本文降噪系统可以达到约15 dB的降噪量,降噪效果明显。

关键词：有源噪声控制多采样率双通道反馈控制低频噪声

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Emission of organic carbon, elemental carbon and water-soluble ions from crop straw burning under flaming and smoldering conditions

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Particuology 2017年第2期15卷 181-190页

作者： Lei Hong Gang Liu limin zhou Jiuhai Li Hui Xu Dan Wu fiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology ( CICAEET) School of Environmental Science and Engineering Nanjing University o fin formation Science & Technology Nanjing 210044 China

Emissions from major agricultural residues were measured using a self-designed combustion system. Emission factors （EFs） of organic carbon （OC）, elemental carbon （EC）, and water-soluble ions （WSIs）（K＋, NH4＋, Na＋, Mg2＋, Ca2＋, Cl-, NO3-, SO42–） in smoke from wheat and rice straw were measured under flaming and smoldering conditions. The OC1/TC （total carbon） was highest （45.8% flaming, 57.7% smoldering） among carbon fractions. The mean EFs for OC （EFOC） and EC （EFEC） were 9.2 ± 3.9 and 2.2 ± 0.7 g/kg for wheat straw and 6.4 ± 1.9 and 1.1 ± 0.3 g/kg for rice straw under flaming conditions, while they were 40.8 ± 5.6 and 5.8 ± 1.0 g/kg and 37.6 ± 6.3 and 5.0 ± 1.4 g/kg under smoldering conditions, respectively. Higher EC ratios were observed in particulate matter （PM） mass under flaming conditions. The OC and EC for the two combustion patterns were significantly correlated （p 〈 0.01, R = 0.95 for wheat straw; p 〈 0.01, R = 0.97 for rice straw）, and a higher positive correlation between OC3 and EC was observed under both combustion conditions. WSIs emitted from flaming smoke were dominated by Cl- and K＋, which contributed 3.4% and 2.4% of the PM mass for rice straw and 2.2% and 1.0% for wheat straw, respectively. The EFs of Cl- and K＋ were 0.73 ± 0.16 and 0.51 ± 0.14 g/kg for wheat straw and 0.25 ± 0.15 and 0.12 ± 0.05 g/kg for rice straw under flaming conditions, while they were 0.42 ± 0.28 and 0.12 ± 0.06 g/kg and 0.30 ± 0.27 and 0.05 ± 0.03 g/kg under smoldering conditions, respectively. Na＋, Mg2＋, and NH4＋ were vital components in PM, comprising from 0.8% （smoldering） to 3.1% （flaming） of the mass. Strong correlations of Cl- with K＋, NH4＋, and Na＋ ions were observed in rice straw and the calculated diagnostic ratios of OC/EC, K＋/Na＋ and Cl-/Na＋ could be useful to distinguishing crop straw burning from other sources of atmospheric pollution.

关键词： Biomass combustion Organic carbon Elemental carbon Water-soluble ion

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Besshi-type mineral systems in the Palaeoproterozoic Bryah Rift-Basin, Capricorn Orogen, Western Australia： Implications for tectonic setting and geodynamic evolution

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Geoscience Frontiers 2016年第3期7卷 345-357页

作者： Franco Pirajno Yanjing Chen Nuo Li Chao Li limin zhou Centre for Exploration Targeting University of Western Australia 35 Stirling Highway Crawley WA 6009 Australia Key Laboratory of Orogen and Crust Evolution Peking University Beijing 100871 China Xinjiang Research Center for Mineral Resources Xinjiang Institute of Ecology and Geography Chinese Academy of Sciences Urumcli 830011 China National Research Center for Geoanalysis Beijing 100037 China

In this contribution we use VMS mineral systems in the Bryah rift-basin to constrain the tectonic setting of the widespread mafic and ultramafic magmatism that characterises the rift-basin in question.Two distinct,but temporally closely associated,lithostratigraphic sequences,Narracoota and Karalundi Formations,are discussed.The Karalundi Formation is the main host of VMS mineral systems in the region.The Karalundi Formation consists of turbiditic and immature clastic sediments,which are locally intercalated with basaltic hyaloclastites,dolerites and banded jaspilites.We propose that the basaltic hyaloclastites,dolerites and elastics and jaspilites rocks,form a distinct unit of the Karalundi Formation,named Noonyereena Member.The VMS mineral systems occur near the north-east trendingJenkin Fault and comprise the giant and world-class DeCrussa and the Red Bore deposits.The nature of these deposits and their intimate association with terrigenous clastic rocks and dominantly marine mafic volcanic and subvolcanic rocks,as well as the common development of peperitic margins,are considered indicative of a Besshi-type environment,similar to that of present-day Gulf of California.Our Re-Os age data from a primary pyrite yielded a mean model age of 2012 ± 48 Ma,which coincides（within error） with recent published Re-Os data（Hawke et al.,2015） and confirms the timing of the proposed geodynamic evolution.We propose a geodynamic model that attempts to explain the presence of the Narracoota and Karalundi Formations as the result of mantle plume activity,which began with early uplift of continental crust with intraplate volcanism,followed by early stages of rifting with the deposition of the Karalundi Formation（and Noonyereena Member）,which led to the formation of Besshi-type VMS deposits.With on-going mantle plume activity and early stages of continental separation,an oceanic plateau was formed and is now represented by mafic-ultramafic rocks of the Narracoota Formation.

关键词： Bryah rift-basin DeGrussa VMS Narracoota and Karalundi Formations Besshi-type deposit Geodynamic model

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泡沫轻质土回填管道沟槽路面表层动力响应研究

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铁道科学与工程学报 2024年第2期21卷 659-668页

作者：阮波田江魏丽敏何群徐长红周宏中南大学土木工程学院湖南长沙410075 中国电建集团昆明勘测设计研究院有限公司云南昆明650051 湖南省交通规划勘察设计院有限公司湖南长沙410200

市政道路下伏管道沟槽常采用土、砂子、碎石等传统散体材料回填,由于沟槽空间受限,压实度难以满足设计要求,管道破损渗漏或交通荷载作用下,容易造成路面开裂,甚至塌陷。泡沫轻质土具有轻质、高强、自密实、抗渗漏等特性,可以将其应用于... 详细信息

市政道路下伏管道沟槽常采用土、砂子、碎石等传统散体材料回填,由于沟槽空间受限,压实度难以满足设计要求,管道破损渗漏或交通荷载作用下,容易造成路面开裂,甚至塌陷。泡沫轻质土具有轻质、高强、自密实、抗渗漏等特性,可以将其应用于管道沟槽回填工程。为了研究泡沫轻质土回填管道沟槽的路面动力响应特性,以振动加速度和动位移为动力响应指标,开展泡沫轻质土回填段和中砂回填段的路面动力响应现场试验。试验车速分别为20,40和60 km/h,车重分别为空载、半载、满载,共9种试验工况。研究结果表明,泡沫轻质土回填区段测点振动加速度最大值、动位移最大值分别为31.93 mm/s^(2)、6.23μm,而中砂回填区段分别为35.79 mm/s^(2)、6.90μm。振动加速度峰值、动位移峰值均随车重、车速的增加而增大。车重由空载变为满载时,泡沫轻质土回填区段测点动位移峰值变化幅度仅为中砂回填区段测点的15.2%~51.0%;车速由20 km/h增加至60 km/h时,动位移峰值变化幅度为中砂回填区段测点的16.8%~66.8%。泡沫轻质土回填区段振动加速度峰值衰减率、动位移峰值衰减率分别为中砂回填区段的1.16~1.38倍及1.15~1.33倍,削减了沟槽回填区段路面测点振动的高频和低频成分,泡沫轻质土回填区段整体刚度较好,减振效果良好。研究成果可为泡沫轻质土回填管道沟槽的设计施工提供参考。

关键词：管道沟槽回填泡沫轻质土中砂振动加速度动位移

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警察类高职院校教师党支部书记“双带头人”培育实证研究——以Z学院为例

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职业技术 2024年第2期23卷 9-15页

作者：周立民浙江警官职业学院杭州310018

高校教师党支部书记“双带头人”培育应主要探讨两个问题:一是选任的教师党支部书记的学术水平是否符合“双带头人”标准;二是教师党支部书记是否有一个培育的过程。以某司法警官职业学院为对象,以定量研究为方法,发现该学院近三届各系... 详细信息

高校教师党支部书记“双带头人”培育应主要探讨两个问题:一是选任的教师党支部书记的学术水平是否符合“双带头人”标准;二是教师党支部书记是否有一个培育的过程。以某司法警官职业学院为对象,以定量研究为方法,发现该学院近三届各系教工党支部书记学术水平连续提高,年轻化趋势加快,党支部书记后备人才培养情况较好。这表明近年来该学院教师党支部书记“双带头人”培育工程成效显著。其主要经验有四方面:加强制度建设,强化组织领导;以项目为抓手,以成绩来考核;严格选任党支部书记,并注重选拔年轻干部;党支部书记参与本部门重要事项讨论决策,并优先提拔或重用。

关键词：警察院校教师党支部书记 “双带头人” 培育实证研究

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