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Complete kinetic model for esterification reaction of lauric acid with glycerol to synthesize glycerol monolaurate

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Chinese Journal of Chemical Engineering 2024年第6期70卷 211-221页

作者： Han-Qiao Hu Yue Zhang Ming Fan Yong Cai Guang-Wen Chu liang-liang Zhang Research Center of the Ministry of Education for High Gravity Engineering and Technology Beijing University of Chemical TechnologyBeijing 100029China State Key Laboratory of Organic-Inorganic Composites Beijing University of Chemical TechnologyBeijing 100029China Petrochemical Research Institute China National Petroleum CorporationBeijing 102206China

Glycerol monolaurate(GML)is a widely used industrial chemical with excellent emulsification and antibacterial *** direct esterification of glycerol with lauric acid is the main method to synthesize *** this work,the kinetic process of direct esterification was systematically studied using p-toluenesulfonic acid as catalyst.A complete kinetic model of consecutive esterification reaction has been established,and the kinetic equation of acid catalysis was *** isomerization reactions of GML and glycerol dilaurate were *** was found that the reaction was an equilibrium reaction and the reaction rate was faster than the esterification *** kinetic equations of the consecutive esterification reaction were obtained by experiments as k_(1)=(276+92261Xcat)exp(-37720/RT)and k_(2)=(80+4413Xcat)exp(-32240/RT).The kinetic results are beneficial to the optimization of operating conditions and reactor design in GML production process.

关键词： Glycerol monolaurate p-Toluenesulfonic acid Esterification Kinetics Mass transfer

The chlorine evolution reaction promoted by organocatalysts with amide functional groups

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Science China Chemistry 2024年第3期67卷 749-750页

作者： Lan Zhao liang-Nian He State Key Laboratory and Institute of Elemento-Organic Chemistry College of ChemistryNankai UniversityTianjin 300071China

Since the nineteenth century, the chlor-alkali process entails the electrochemical oxidation of sodium chloride solutions to Cl_(2) by the chlorine evolution reaction(CER) and the simultaneous production of sodium hyd... 详细信息

关键词： chlorine hydroxide promoted

Big Theta Equals Small Theta Generically

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Acta Mathematica Sinica,English Series 2024年第3期40卷 717-730页

作者： Rui CHEN Jia liang ZOU Institute for Advanced Study in Mathmatics Zhejiang UniversityHangzhou 310058P.R.China Department of Mathematics University of Michigan530 Church StAnn ArborMI 48109USA

In this paper we consider the theta correspondence over a non-Archimedean local *** the homological method and the theory of derivatives,we show that under a mild condition the bigtheta lift is irreducible.

关键词： Theta correspondence derivatives

Theoretical and experimental study on multiscale coupled Mohr-Coulomb shear strength criterion of fibre-reinforced sand

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Underground Space 2024年第1期14卷 53-69页

作者： Deluan Feng Yuxin Wang Shihua liang School of Civil and Transportation Engineering Guangdong University of TechnologyGuangzhou 510006China

Fibre-reinforced sand(FRS)is a multiphase and multiscale geo-material,which is widely used in geotechnical engineering as supporting structure of excavation of underground space and reinforcement of foundation of underground structures,and its strength is determined by the properties of the heterogeneous substances of the FRS and their coupling mechanical *** order to investigate the influence of fibre characteristics and mechanical properties on the shear strength of the FRS,according to the microscopic interface slip effect generated by the interaction between sand particles and the interaction between these particles and fibre,the material phase of the FRS is divided to conceptualize a micro cell element of the FRS that is capable of reflecting the internal material characteristic information of the ***,based on the coordinated deformation condition between fibres and sand particles at the microscale and the couple stress theory that is capable of effectively describing the discontinuous mechanical responses at the sand-fibre interface,a mesomechanism-based multiscale Mohr–Coulomb shear strength criterion of the FRS is derived,and the yield locus of the FRS is also drawn on the p ***,a series of FRS samples with different fibre content and fibre length were prepared by adopting the freezing method,and consolidated and drained triaxial compression tests were conducted on these samples to validate the proposed multiscale coupled Mohr–Coulomb shear strength *** show that the multiscale coupled Mohr–Coulomb shear strength criterion is capable of effectively reproducing and predicting the yield strength of the *** yield locus of the FRS extends outwards as fibre content and fibre length *** yield stress of the FRS predicted by the proposed multiscale coupled Mohr–Coulomb shear strength criterion is in good agreement with that of the test result.

关键词： Multiscale coupling Fibre-reinforced sand(FRS) Interface slip effect Physical mechanism Shear strength criterion

Event-triggered predefined-time control for full-state constrained nonlinear systems: A novel command filtering error compensation method

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Science China(Technological Sciences) 2024年第9期67卷 2867-2880页

作者： PAN YingNan CHEN YiLin liang HongJing College of Control Science and Engineering Bohai UniversityJinzhou 121013China School of Automation Engineering University of Electronic Science and Technology of ChinaChengdu 611731China Laboratory of Electromagnetic Space Cognition and Intelligent Control Beijing 100089China

In this paper, a command filter-based adaptive fuzzy predefined-time event-triggered tracking control problem is investigated for uncertain nonlinear systems with time-varying full-state constraints. By designing a sliding mode differentiator, the inherent computational complexity problem within the predefined-time backstepping framework is solved. Different from the existing command filter-based finite-time and fixed-time control strategies that the convergence time of the filtering error is adjusted through the system initial value or numerous parameters, a novel command filtering error compensation method is presented,which tunes one control parameter to make the filtering error converge in the predefined time, thereby reducing the complexity of design and analysis of processing the filtering error. Then, an improved event-triggered mechanism(ETM) that builds upon the switching threshold strategy, in which an inverse cotangent function is designed to replace the residual term of the ETM,is proposed to gradually release the controller's dependence on the residual term with increasing time. Furthermore, a tan-type nonlinear mapping technique is applied to tackle the time-varying full-state constraints problem. By the predefined-time stability theory, all signals in the uncertain nonlinear systems exhibit predefined-time stability. Finally, the feasibility of the proposed algorithm is substantiated through two simulation results.

关键词： predefined-time control command filtering error compensation method event-triggered mechanism time-varying full-state constraints uncertain nonlinear systems

The higher-order topological pumping explored in the 2D acoustic crystal

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Science China(Physics,Mechanics & Astronomy) 2024年第2期67卷 127-133页

作者： Yanqiu Wang Bin liang Jianchun Cheng Key Laboratory of Modern Acoustics Ministry of EducationInstitute of AcousticsDepartment of PhysicsNanjing UniversityNanjing 210093China Collaborative Innovation Center of Advanced Microstructures Nanjing UniversityNanjing 210093China

The topological pumping has been instrumental in advancing our understanding of topological phase transitions in various physical systems,which can be extended to uncover intriguing higher-order topological phases in the lower-dimensional ***,we propose a theoretical exploration of topological dipole pumping on an acoustic square superlattice by cyclically modulating intracell couplings,which shares the topological nature of an extended three-dimensional system with chiral hinge *** the multipole chiral numbers,we characterize the higher-order topological phases that arise during the *** evolution of topological phase transitions is verified by numerical simulations and shows corner states are transferred across the *** findings can inspire the construction of chiral hinge states in artificial crystals,opening up new possibilities for the design of devices allowing the unidirectional propagation of sound.

关键词： topological phases of matter Thouless pumping acoustic metamaterial

Nash-equilibrium strategies of orbital TargetAttacker-Defender game with a non-maneuvering target

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Chinese Journal of Aeronautics 2024年第10期37卷 365-379页

作者： Yifeng LI Xi liang Zhaohui DANG School of Astronautics Northwestern Polytechnical UniversityXi’an 710072China Beijing Institute of Astronautical Systems Engineering Beijing 100076China

This study investigates the orbital Target-Attacker-Defender(TAD)game problem in the context of space *** this game,the Attacker and the Defender compete for a Target that is unable to maneuver due to its original mission *** paper establishes three TAD game models based on the thrust output capabilities:unconstrained thrust output,thrust constrained by an upper bound,and fixed thrust *** models are then solved using differential game theory to obtain Nash equilibrium solutions for the game problems,and the correctness and effectiveness of the solution methods are verified through ***,an analysis of the winning mechanisms of the game is conducted,identifying key factors that influence the game’s outcomes,including weight coefficients in payoffs,the maximum thrust acceleration limit,and the initial game *** the unique characteristics of space missions,a specific focus is given to the analysis of the Defender’s initial states in the hovering formation and in-plane circling formation,revealing overall success patterns for defense strategies from these two *** summary,this study provides valuable insights into the control strategies and winning mechanisms of orbital TAD games,deepening our understanding of these games and offering practical guidance to improve success rates in real-world scenarios.

关键词： Target-Attacker-Defender problem Differential game TPBVP Continuous thrust Orbital game

Polyelectrolyte Complexes and Coacervates Formed by De novo-Designed Peptides and Oligonucleotide

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Chinese Journal of Polymer Science 2024年第9期42卷 1333-1340,I0007页

作者： Tian-Hao Ren De-Hai liang Beijing National Laboratory for Molecular Sciences Department of Polymer Science and Engineering and the Key Laboratory of Polymer Chemistry and Physics of the Ministry of EducationCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing100871China

The liquid-liquid phase separation of biopolymers in living cells contains multiple interactions and occurs in a dynamic *** the regulation mechanism is still a *** this work,we designed a series of peptides(XXLY)_(6)SSSGSS and studied their complexation and coacervation behavior with single-stranded ***“X”and“Y”are varied to combine known amounts of charged and non-charged amino acids,together with the introduction of secondary structures and pH *** show that the electrostatic interaction,which is described as charge density,controls both the strength of complexation and the degree of chain relaxation,and thus determines the growth and size of the *** hydrophobic interaction is prominent when the charges are ***,the secondary structures of peptides exhibit profound effect on the morphology of the phases,such as solid phase to liquid phase *** study gains insight into the phase separation under physiological *** is also helpful to create coacervates with desirable structures and functions.

关键词： Polyelectrolyte complex Coacervate Peptides Secondary structure Electrostatic interaction

A Fully-Integrated Memristor Chip for Edge Learning

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Nano-Micro Letters 2024年第9期16卷 123-127页

作者： Yanhong Zhang liang Chu Wenjun Li School of Electronics and Information Hangzhou Dianzi UniversityHangzhou 310018People’s Republic of China

It is still challenging to fully integrate computing in memory chip as edge learning *** recent work published on Science,a fully-integrated chip based on neuromorphic memristors was developed for edge learning as artificial neural networks with functionality of synapses,dendrites,and somas.A crossbar-array memristor chip facilitated edge learning including hardware realization,learning algorithm,and cycle-parallel sign-and threshold-based learning(STELLAR)*** motion control and demonstration platforms were executed to improve the edge learning ability for adapting to new scenarios.

关键词： Computing in memory Edge learning Fully-integrated chip