Complete kinetic model for esterification reaction of lauric acid with glycerol to synthesize glycerol monolaurate
作者机构：Research Center of the Ministry of Education for High Gravity Engineering and TechnologyBeijing University of Chemical TechnologyBeijing 100029China State Key Laboratory of Organic-Inorganic CompositesBeijing University of Chemical TechnologyBeijing 100029China Petrochemical Research InstituteChina National Petroleum CorporationBeijing 102206China
出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报（英文版）)
年 卷 期：2024年第70卷第6期
页 面：211-221页
核心收录：
学科分类：081702[工学-化学工艺] 080103[工学-流体力学] 0817[工学-化学工程与技术] 08[工学] 0807[工学-动力工程及工程热物理] 0703[理学-化学] 0701[理学-数学] 0702[理学-物理学] 0801[工学-力学（可授工学、理学学位）]
基 金：supported by the National Research and Development Program of China(2021YFC3001100) the National Natural Science Foundation of China(22288102)
主 题：Glycerol monolaurate p-Toluenesulfonic acid Esterification Kinetics Mass transfer
摘 要：Glycerol monolaurate(GML)is a widely used industrial chemical with excellent emulsification and antibacterial *** direct esterification of glycerol with lauric acid is the main method to synthesize *** this work,the kinetic process of direct esterification was systematically studied using p-toluenesulfonic acid as catalyst.A complete kinetic model of consecutive esterification reaction has been established,and the kinetic equation of acid catalysis was *** isomerization reactions of GML and glycerol dilaurate were *** was found that the reaction was an equilibrium reaction and the reaction rate was faster than the esterification *** kinetic equations of the consecutive esterification reaction were obtained by experiments as k_(1)=(276+92261Xcat)exp(-37720/RT)and k_(2)=(80+4413Xcat)exp(-32240/RT).The kinetic results are beneficial to the optimization of operating conditions and reactor design in GML production process.
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