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员工组织规避劳动合同法认知、工作不安全感与组织报复行为的关系:基于华南地区新生代员工的实证研究

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管理评论 2014年第3期26卷 113-127页

作者：朱瑜李云健马智妍王小霏暨南大学管理学院广州510632 华南理工大学工商管理学院广州510640

新劳动合同法的实施在保护广大员工利益方面发挥了重要作用,但是也对企业的制度与管理创新带来了相当大的压力,因此相当一部分企业或多或少地采取了规避劳动合同法的行为。当组织的这种行为被新生代员工所感知后,对新生代员工的心理与... 详细信息

新劳动合同法的实施在保护广大员工利益方面发挥了重要作用,但是也对企业的制度与管理创新带来了相当大的压力,因此相当一部分企业或多或少地采取了规避劳动合同法的行为。当组织的这种行为被新生代员工所感知后,对新生代员工的心理与行为会造成什么影响,是目前国内研究较少关注和本研究将要解决的重要问题。本研究以华南地区企业新生代员工为调查对象,通过两次实证调查,在系统检验员工组织劳动合同法规避认知、工作不安全感和组织报复行为测量工具有效性的基础上,建构了员工组织劳动合同法规避认知、工作不安全感和组织报复行为关系的模型并进行了验证。研究结果表明:(1)新生代员工组织劳动合同法规避认知显著正向影响员工工作不安全感;(2)新生代员工组织劳动合同法规避认知显著正向影响组织报复行为;(3)新生代员工工作不安全感显著正向影响组织报复行为;(4)新生代员工工作不安全感在组织劳动合同法规避认知与组织报复行为的关系中起完全中介作用。

关键词：新生代组织规避行为认知工作不安全感组织报复行为

Enhanced electrochemical performance of li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3) solid electrolyte by anion doping

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Nano Research 2024年第3期17卷 1465-1472页

作者： Jingrui Kang Xu Guo Rui Gu Honglei Hao Yi Tang Jiahui Wang li Jin Hongfei li Xiaoyong Wei Electronic Materials Research Laboratory Key Laboratory of the Ministry of Education&International Center for Dielectric ResearchSchool of Electronic and Information EngineeringXi’an Jiaotong UniversityXi’an 710049China School of Energy and Materials Shanghai Key Laboratory of Engineering Materials Application and EvaluationShanghai Polytechnic UniversityShanghai 201209China

Nowadays,the majority of the studies on the substitution are focused on cations(such as Y^(3+),Ti^(4+),P^(5+),etc.)in li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3)(LATP),while there are few studies on the substitution of anion O^(2-).In this work,the modified LATP with a series of liCl(LATPClx,x=0.1,0.2,0.3,0.4)additives is prepared to enhance ionic *** successful introduction of Cl-makes the length of the c axis decrease from 20.822(2)to 20.792(1)Å,and the bulk conductivity of 2.13×10^(-3) S·cm^(-1) is achieved in LATPCl_(0.3).Moreover,the Al/Ti-O1/Cl1 and Al/Ti-O_(2)/Cl_(2) distance decrease,while the li1-O_(2)/Cl_(2) distance *** ions migrate more easily in the nanochannel of *** addition,the liCl additive increases the relative density and the grain boundary conductivity of LATPClx ***,a higher ionic conductivity of 2.12×10^(–4) S·cm^(-1) and a low activation energy of 0.30 eV are obtained in LATPCl_(0.3).Correspondingly,the symmetric cell exhibits a low overpotential of±50 mV for over 200 h in LATPCl_(0.3).The solid-state li|LATPCl_(0.3)|NCM811(NCM811=liNi0.8Co0.1Mn0.1O_(2))battery exhibits high initial capacity 185.1 mAh·g^(-1) with a capacity retention rate of 95.4%after 100 cycles at 0.5 *** result suggests that liCl additive is an effective strategy to promote electrochemical properties of LATP solid electrolyte and can be considered for reference to other inorganic solid electrolytes systems.

关键词： li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3)(LATP)solid electrolyte anion doping ionic conductivity cyclic performance

Catalytic anode surface enabling in situ polymerization of gel polymer electrolyte for stable li metal batteries

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Nano Research 2024年第6期17卷 5216-5223页

作者： Guocheng li Kang liang Yuanjian li Xiangrui Duan lin Fu Zhao Cai Zhaofu Zhang Jiangnan Dai Yongming Sun Wuhan National Laboratory for Optoelectronics Huazhong University of Science and TechnologyWuhan 430074China The Institute of Technological Sciences Wuhan UniversityWuhan 430074China Faculty of Materials Science and Chemistry China University of Geoscience(Wuhan)Wuhan 430074China

Employing quasi-solid-state gel polymer electrolyte(GPE)instead of the liquid counterpart has been regarded as a promising strategy for improving the electrochemical performance of li metal ***,the poor and uneven interfacial contact between li metal anode and GPE could cause large interfacial resistance and electrochemical li stripping/plating inhomogeneity,deteriorating the electrochemical ***,we proposed that the functional component of composite anode could work as the catalyst to promote the in situ polymerization reaction,and we experimentally realized the integration of polymerized-dioxolane electrolyte and li/li_(22)Sn_(5)/liF composite electrode with low interfacial resistance and good stability by in situ catalyzation ***,the reaction kinetics and stability of metallic li anode were significantly *** a demonstration,symmetric cell using such a GPE-li/li_(22)Sn_(5)/liF integration achieved stable cycling beyond 250 cycles with small potential hysteresis of 25 mV at 1 mA·cm^(−2)and 1 mAh·cm^(−2),far outperforming the counterpart regular GPE on pure *** with liNi0.5Co0.3Mn0.2O2,the full cell with the GPE-li/li_(22)Sn_(5)/liF integration maintained 85.7%of the original capacity after 100 cycles at 0.5 C(1 C=200 mA·g^(−1)).Our research provides a promising strategy for reducing the resistance between GPE and li metal anode,and realizes li metal batteries with enhance electrochemical performance.

关键词： catalyzation polymerization interface resistance interfacial stability li metal batteries electrochemical performance

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基于LASVM-NC和***的文本分类方法

计算机工程与应用 2014年第10期50卷 136-140,265页

作者：李玉鑑李玉雄冷强奎北京工业大学计算机学院北京100124

非凸在线支持向量机(LASVM-NC)具有抗噪能力强和训练速度快的优点,而词频相关频率积(***)则是一种自适应能力很强、分类性能非常好的文本特征。通过把非凸在线支持向量机和词频相关频率积相结合,提出了一种新的文本分类方法,即LASVM-NC+... 详细信息

非凸在线支持向量机(LASVM-NC)具有抗噪能力强和训练速度快的优点,而词频相关频率积(***)则是一种自适应能力很强、分类性能非常好的文本特征。通过把非凸在线支持向量机和词频相关频率积相结合,提出了一种新的文本分类方法,即LASVM-NC+***。实验结果表明,这种方法在LASVM-NC与多种其他特征的结合中性能是最好的,且与SVM+***相比,不仅所产生的分类器具有泛化能力更强、模型表达更稀疏的优点,而且在处理含噪声的数据时具有更好的鲁棒性,在处理大规模数据时具有快得多的训练速度。

关键词：非凸在线支持向量机支持向量机特征项词频相关频率文本分类

Vinyltrimethylsilane as a novel electrolyte additive for improving interfacial stability of li-rich cathode working in high voltage

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Chinese Chemical Letters 2024年第2期35卷 534-538页

作者： Bing Jiang Hao li Bi Luo Lehao liu lihua Chu Qiaobao Zhang Meicheng li State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources School of New EnergyNorth China Electric Power UniversityBeijing 102206China State Key Laboratory of Physical Chemistry of Solid Surfaces College of MaterialsXiamen UniversityXiamen 361005China

Boosting the interfacial stability between electrolyte and li-rich cathode material at high operating voltage is vital important to enhance the cycling stability of li-rich cathode materials for high-performance li-ion *** this work,vinyltrimethylsilane as a new type of organic silicon electrolyte additive is studied to address the interfacial instability of li-rich cathode material at high operating *** cells using vinyltrimethylsilane additive shows the high capacity retention of 73.9%after 300 cycles at 1 C,whereas the cells without this kind of additive only have the capacity retention of 58.9%.The improvement of stability is mainly attributed to the additive helping to form a more stable surface film for li-rich cathode material,thus avoiding direct contact between the electrolyte and the cathode material,slowing down the dissolution of metal ions and the decomposition of the electrolyte under high operating *** findings in this work shed some light on the design of stable cycling performance of li-rich cathode toward advanced li-ion batteries.

关键词： Vinyltrimethylsilane Electrolyte additive li-rich cathode Interfacial stability Capacity retention

Congener-derived template to construct lithiophilic organic-inorganic layer/interphase for high volumetric capacity dendrite-free li metal batteries

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Chinese Chemical Letters 2024年第3期35卷 453-460页

作者： Kang Yang Long li Yuanbin Xiao Qiaoli Zhang Chenpeng Xi Borong li Yan Yu Chengkai Yang Key Laboratory of Advanced Materials Technologies International(HongKong Macao and Taiwan)Joint Laboratory on Advanced Materials TechnologiesCollege of Materials Science and EngineeringFuzhou UniversityFuzhou 350108China

The development of lithium-metal batteries(LMBs)is seriously restricted by the out-of-control dendrites growth and infinite volume ***,a pervasive organic-inorganic layer construction strategy is reported for the composite lithium metal anode with congener-derived organic-inorganic solid electrolyte interphase(SEI).In this strategy,the organic-inorganic Ag@polydopamine(Ag@PDA)layer is coated on the arbitrary substrates by a simple two-step *** thin and stable congener-derived SEI is insitu formed with fewer inorganic components and more organic components during charging/*** polydopamine with sufficient adhesion groups and lithiophilic Ag layer realize near-zero nucleation overpotential during lithium *** low interface resistance and stable lithium deposition are ***,the practical areal and volumetric capacities of the composite anode with three-dimensional copper(3DCu)as the substrate are 10 mAh/cm^(2)and 1538 mAh/cm^3(*** mass of anode).The symmetrical cell shows very low polarization voltage(10 mV)and more than 2500 h cycles life at 1 mA/cm^(2)(1 mAh/cm^(2)).The liNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)-based full cells show improved capacity retention(82%)after 100 cycles at 0.5 *** modified lithiophilic anode with congener-derived interphase provides a promising strategy to realize the next-generation dendrite-free LMBs.

关键词： lithium metal anode Congener-derived lithiophilicity Volumetric capacity Organic-inorganic interphase

Anion competition for li^(+)solvated coordination environments in poly(1,3 dioxolane)electrolyte to enable high-voltage lithium metal solid-state batteries

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Journal of Energy Chemistry 2024年第9期96卷 633-641页

作者： Qiujun Wang Yanqiang Ma Xiaomeng Jia Di Zhang Zhaojin li Huilan Sun Qujiang Sun Bo Wang li-Zhen Fan Hebei Key Laboratory of Flexible Functional Materials School of Materials Science and EngineeringHebei University of Science and TechnologyShijiazhuang 050000HebeiChina Beijing Advanced Innovation Center for Materials Genome Engineering Institute of Advanced Materials and TechnologyUniversity of Science and Technology BeijingBeijing 100083China

Gel-based polymer electrolytes are limited by the polarity of the residual solvent,which restricts the coupling-breaking behaviour during li^(+)conduction,resulting in the li^(+)transport kinetics being greatly ***,we designed anion competitive gel polymer electrolyte(ACPE)by introducing lithium difluoro(oxalato)borate(liDFOB)anion into the 1,3-dioxolane(DOL)in situ polymerisation *** enhances the ionic dipole interaction between li^(+)and the solvent molecules and synergizes with li^(+)across the solvation site of the polymer ethylene oxide(EO)unit,combination that greatly improves the li^(+)transport *** a result,ACPE exhibits 1.12 mS cm^(−1)ionic conductivity and 0.75 li^(+)transfer number at room ***,this intra-polymer solvation sheath allows preferential desolvation of DFOB−,which contributes to the formation of kinetically stable anion-derived interphase and effectively mitigates side *** results demonstrate that the assembled li||NCM622 solid-state battery exhibits lifespan of over 300 cycles with average Coulombic efficiency of 98.8%and capacity retention of 80.3%.This study introduces a novel approach for ion migration and interface design,paving the way for high-safety and high-energy-density batteries.

关键词： li-metal batteries Poly(1,3-dioxolane) In situ polymerization Solid-state polymer electrolytes Anion competition

一体化理念在郑州轨道管理信息系统集成建设中的研究与实现

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计算机应用与软件 2018年第7期35卷 173-177页

作者：李亚军李昱见吴若童郑州市轨道交通有限公司河南郑州450046 上海汉得信息技术股份有限公司上海201799

提出一种软件架构实施方式,以解决目前在一体化管理信息过程中存在的信息孤岛、处理不协调和追溯难的问题。基于提出的6大基础业务的管理需求,结合3个基础技术和3种业务贯通的应用要求,研究设计了系统的软件结构和构架模式,并给出部分... 详细信息

提出一种软件架构实施方式,以解决目前在一体化管理信息过程中存在的信息孤岛、处理不协调和追溯难的问题。基于提出的6大基础业务的管理需求,结合3个基础技术和3种业务贯通的应用要求,研究设计了系统的软件结构和构架模式,并给出部分应用分析。实践证明,系统运行后有效地提高了数据采集的实时性、数据共享使用处理的准确性、数据分析的科学性和跨部门业务处理的实效性。

关键词：一体化管理信息软件构架质量属性集成技术

Polyimide covalent organic frameworks as efficient solid-state li^(+) electrolytes

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Science China Chemistry 2024年第5期67卷 1647-1652页

作者： Xu liu Shi Wang Siqi liu Chengfang liu Xiangchun li Jian Wu Dazhi li Shihao Xu Chongyang liu Wen-Yong Lai State Key Laboratory of Organic Electronics and Information Displays(SKLOEID) Institute of Advanced Materials(IAM)School of Chemistry and Life SciencesNanjing University of Posts&TelecommunicationsNanjing 210023China

Covalent organic frameworks(COFs) are attractive porous crystalline materials with extremely high stability, easy functionalization, and open channels, which are expected to be unique ion conductors/transporters in lithium ion batteries(liBs). Despite recent advances, low ion conductivity and low transference number, resulting in low charging/discharging rate, low energy density, and short battery life, are the main issues that limit their direct application as solid electrolytes in liBs. Here, we designed and synthesized a novel polyimide COF, namely, TAPA-PDI-COF, with abundant C=O groups, which has been successfully employed as high-performance solid electrolytes by doping TAPA-PDI-COF and succinonitrile(SN). Both the well-defined nanochannels of COFs and SN confined in the well-aligned channels restricted the free migration of anions, while C=O on COFs and CN groups of SN enhanced li^(+) transport, thus achieving a high ion conductivity of 0.102 m S cm^(-1)at 80 °C and a high lithium-ion transference number of 0.855 at room temperature. According to density functional theory(DFT)calculations, li-ion migration mainly adopted in-plane transport rather than the axial pathway, which may be due to the shorter hopping distances in the planar pathway. The results suggest an effective strategy for the design and development of all-solidstate ionic conductors for achieving high-performance liBs.

关键词： lithium ion batteries(liBs) covalent organic frameworks(COFs) solid-state ion conductors solid-state electrolytes ion conductivity