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Chinese Chemical Letters 2024年第4期35卷 176-180页

作者： Chao-Long Chen Rong Chen La-Sheng Long lan-sun Zheng xiang-Jian Kong Collaborative Innovation Center of Chemistry for Energy Materials State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of ChemistryCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China

Light-driven nitrogen fixation to produce ammonia is a green and economical technology of nitrogen reduction but is still quite challenging, especially in an air atmosphere without any sacrificial ***, we demonstrate efficient photocatalytic nitrogen fixation using water and air directly by loading lanthanide–transition metal(4f–3d) cluster NdCo_(3) on two-dimensional P-doped graphitic carbon nitrides(PCN) material surface. Benefiting from the increase in the number of nitrogen vacancies(NVs) and highly matched band gap structure and excellent hole trapping ability of clusters, the NdCo_(3)/PCN photocatalyst exhibits efficient nitrogen reduction activity with 371(in air) and 825 μmol h^(-1)g^(-1)(in pure nitrogen)without any sacrificial reagents. The introduction of potassium sulfate inhibits hydrogen production and promotes nitrogen reduction activation. This work suggests that anchoring precisely structured clusters on 2D materials may enhance photocatalytic nitrogen reduction under normal temperature and pressure.

关键词： Photocatalytic Nitrogen fixation 4f-3d Cluster Air atmosphere

Larger in-plane upper critical field and superconducting diode effect observed in topological superconductor candidate InNbS_(2)nanoribbons

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Nano Research 2024年第7期17卷 6686-6694页

作者： Bo Zheng Changlong Wang Xukun Feng Xiaozhen sun Shasha Wang Dawei Qiu xiang Ma Ruimin Li Guanglei Cheng lan Wang Yalin Lu Peng Li Shengyuan A.Yang Bin xiang Department of Materials Science and Engineering CAS Key Lab of Materials for Energy ConversionAnhui Laboratory of Advanced Photon Science and TechnologyUniversity of Science and Technology of ChinaHefei 230026China Research Laboratory for Quantum Materials Singapore University of Technology and DesignSingapore 487372Singapore School of Microelectronics University of Science and Technology of ChinaHefei 230052China CAS Key Laboratory of Microscale Magnetic Resonance and School of Physical Sciences University of Science and Technology of ChinaHefei 230026China Lab of Low Dimensional Magnetism and Spintronic Devices School of PhysicsHefei University of TechnologyHefei 230009China Research Laboratory for Quantum Materials IAPMEUniversity of MacaoMacaoChina

Recently,the coexistence of topology and superconductivity has garnered considerable ***,the dimensionality of these materials is crucial for the realization of topological quantum ***,the naturally grown materials,especially with one-dimensional feature that exhibits the coexistence of topology and superconductivity,still face challenges in terms of experimental realization and scalability,which hinders the fundamental research development and the potential to revolutionize quantum ***,we report the first experimental synthesis of quasi-one-dimensional InNbS_(2)nanoribbons that exhibit the coexistence of topological order and superconductivity via a chemical vapor transport ***,the inplane upper critical field of InNbS_(2)nanoribbons exceeds the Pauli paramagnetic limit by more than 2.2 times,which can be attributed to the enhanced spin-orbit coupling and the weakened interlayer interaction between the NbS_(2)layers induced by the insertion of In atoms,making InNbS_(2)exhibit spin-momentum locking similar to that of monolayer NbS_(2).Moreover,for the first time,we report the superconducting diode effect in a quasi-one-dimensional superconductor system without any inherent geometric *** measured maximum efficiency is manifested as 14%,observed atμ0H≈±60 mT,and we propose that the superconducting diode effect can potentially be attributed to the presence of the nontrivial topological *** work provides a platform for studying exotic phenomena in condensed matter physics and potential applications in quantum computing and quantum information processing.

关键词： topological order superconductivity nanoribbon superconducting anisotropy superconducting diode

Molecular solid solution of lanthanide-titanium-oxo clusters with enhanced photocatalytic hydrogen evolution

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Science China Chemistry 2024年第2期67卷 529-535页

作者： Rong Chen Chao-Long Chen Hui Zhang Zi-Han Wang Fu-Li sun Ming-Hao Du Gui-Lin Zhuang Cheng Wang La-Sheng Long lan-sun Zheng xiang-Jian Kong Collaborative Innovation Centre of Chemistry for Energy Materials State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry College of Chemistry and Chemical EngineeringXiamen UniversityXiamen361005China College of Chemical Engineering Zhejiang University of TechnologyHangzhou310032China

Molecular solid solutions of metal clusters containing different metal centers with well-defined structures can accurately regulate the HOMO-LUMO gap,but are rarely ***,a series of colorless lanthanide-titanium-oxo clusters Ln_(2)Ti_4(μ_(2)-O)_(2)(μ_(3)-O)_4(Piv)_(10)(THF)_(2)(Ln_(2)Ti_4,Ln = Eu,Gd,Tb,and Ce,HPiv = pivalic acid) were synthesized by the reaction of pivalic acid with Ln(Ac)_(3) and titanium *** light yellow crystal of cluster solid solutions Eu_(2)Ti_(4-x)Cd_(x),containing a mixture of Eu_(2)Ti_4 and Eu_(2)Ti_(3)Cd,was obtained by in situ doping Cd^(2+) and S^(2–).Eu_(2)Ti_(3.92)Cd_(0.08) displays efficient photocatalytic hydrogen evolution activity without a co-catalyst,which is up to 2.6 times that of Eu_(2)Ti_*** time-resolved transient absorption spectroscopy and spin-polarized density functional calculations showed that the enhanced photocatalytic performance of Eu_(2)Ti_(4-x)Cd_(x) can be attributed to the narrower HOMO-LUMO gap and lower LUMO position than that of Eu_(2)Ti_*** studyprovides an in situ doping method to realize the simple preparation of cluster solid solution.

关键词： molecular solid solution lanthanide-titanium-oxo clusters photocatalytic hydrogen evolution

Lacticaseibacillus rhamnosus Probio-M9 may be vertically transmitted from mother to infant during lactation based on faeces metagenomics

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Food Science and Human Wellness 2024年第2期13卷 721-728页

作者： lan Yang Lai-Yu Kwok Zhihong sun Heping Zhang Key Laboratory of Dairy Biotechnology and Engineering Ministry of EducationInner Mongolia Agricultural UniversityHohhot 010018China Key Laboratory of Dairy Products Processing Ministry of Agriculture and Rural AffairsInner Mongolia Agricultural UniversityHohhot 010018China Inner Mongolia Key Laboratory of Dairy Biotechnology and Engineering Inner Mongolia Agricultural UniversityHohhot 010018China

Probiotics exert beneficial effects on the *** study aimed to investigate whether maternally ingested Lacticaseibacillus rhamnosus Probio-M9 during pregnancy could access and colonize the infant *** study recruited one pregnant woman,who ingested Probio-M9 daily from 35 weeks of gestation to *** of the mother-infant pair were regularly collected from one month before delivery to 6 months of infant's age for metagenomic ***-M9 genomes were mappable to all infant fecal samples,suggesting the ingested probiotics could be vertically transmitted from mother to ***-or mother-specific differential metabolic pathways were found between the maternal and infant's gut microbiome,implicating apparent differences in the intestinal metagenomic potential/function between the mother and the *** conclusion,maternal ingestion of Probio-M9 during the final weeks of gestation could deliver to the infant *** findings provided novel insights into shaping infant's gut microbiota.

关键词： Metagenomic analysis Lacticaseibacillus rhamnosus Gut microbiome Mother Infant

Effect of topical application of terbinafine on fungal keratitis

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Chinese Medical Journal 2009年第16期122卷 1884-1888页

作者： LIANG Qing-feng JIN Xiu-ying WANG xiang-lan sun Xu-guang Beijing Institute of Ophthalmology Beijing Tongren Eye Center Beijing Tongren Hospital Capital Medical University Beijing 100005 China

Background Fungal keratitis is a rare but serious corneal disease that may result in loss of vision. The poor prognosis might be due to limited treatment option. This study aimed to evaluate the clinical efficacy of 0.25% terbinafine eye drops comparing with 5% natamycin suspension on fungal keratitis. Methods A retrospective clinical trial was performed on 90 patients presenting with direct smear and/or culture positive fungal keratitis at Beijing Tongren Hospital, Beijing, China from January 2006 to May 2008. Corneal ulcers were categorized as mild or severe. Forty-five patients were treated with topical terbinafine and the next 45 cases received topical natamycin hourly. Results Filamentous fungi were found in corneal scrapings among all 90 cases. Fungal cultures were positive in 64 patients （71%）. Species of Fusarium and Aspergillus were the principal isolates. Forty （89%） patients showed favorable response to terbinafine, while forty-two （93%） patients exhibited favorable response to natamycin （P 〉0.05）. The mean course of treatment was significantly showed in the terbinafine treatment group than natamycin group （（26.5±11.2） days versus （19.3±6.4） days; P 〈0.05）. In terbinafine group, twenty patients with ulcers smaller than 4 mm had favorable outcome, while 20 of 25 patients with ulcers more than 4 mm in diameter had favorable response （P 〈0.05）. Twenty-seven patients with depth of infiltration less than half of stroma thickness had favorable response to terbinafine, while 13 of 18 patients with depth of infiltration more than half of stroma responded to terbinafine. This difference was statistically significant （P 〈0.05）. Conclusions Our findings suggest that topical terbinafine is an effective antifungal drug for the management of filamentous mycotic keratitis, particularly in cases with smaller and shallower ulcers. Its mean duration of treatment was longer than natamycin.

关键词： terbinafine natamycin keratitis fungal therapy

Mechanisms of inclusion-induced pitting of stainless steels:A review

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Journal of Materials Science & Technology 2024年第1期168卷 143-156页

作者： Yangting sun Xin Tan Rulei lan Guoyong Ran Jin Li Yiming Jiang Department of Materials Science State Key Laboratory of Molecular Engineering of PolymersFudan UniversityShanghai 200438China

Pitting is a common type of localized corrosion in passive alloys that can cause rapid failure of material or *** the case of stainless steels,non-metallic inclusions have been identified as the most susceptible sites for pitting,and have therefore garnered significant *** review critically ex-amines the issue of how inclusions induce pitting,with a particular focus on three mechanisms:sponta-neous dissolution of inclusions,active dissolution of Cr-depleted regions,and propagation of microcracks at the inclusion-matrix *** researchers have made significant strides in understanding these mechanisms over the past few decades,many gaps and controversies *** such as the ini-tial driving force of inclusion dissolution and factors affecting Cr-depleted regions require further ***,some old concepts and methods need to be revised to arrive at more credible *** review aims to delve deeply into these important issues and provide inspiration for future research.

关键词： Pitting Inclusion Stainless steel Localized corrosion MnS

Multi-agent evaluation for energy management by practically scalingα-rank

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Frontiers of Information Technology & Electronic Engineering 2024年第7期25卷 1003-1016页

作者： Yiyun sun Senlin ZHANG Meiqin LIU Ronghao ZHENG Shanling DONG Xuguang lan National Key Laboratory of Industrial Control Technology Zhejiang UniversityHangzhou 310027China College of Electrical Engineering Zhejiang UniversityHangzhou 310027China National Key Laboratory of Human–Machine Hybrid Augmented Intelligence Xi’an Jiaotong UniversityXi’an 710049China

Currently,decarbonization has become an emerging trend in the power system ***,the increasing number of photovoltaic units distributed into a distribution network may result in voltage issues,providing challenges for voltage regulation across a large-scale power grid *** learning based intelligent control of smart inverters and other smart building energy management(EM)systems can be leveraged to alleviate these *** achieve the best EM strategy for building microgrids in a power system,this paper presents two large-scale multi-agent strategy evaluation methods to preserve building occupants’comfort while pursuing systemlevel *** EM problem is formulated as a general-sum game to optimize the benefits at both the system and building ***α-rank algorithm can solve the general-sum game and guarantee the ranking theoretically,but it is limited by the interaction complexity and hardly applies to the practical power system.A new evaluation algorithm(TcEval)is proposed by practically scaling theα-rank algorithm through a tensor complement to reduce the interaction ***,considering the noise prevalent in practice,a noise processing model with domain knowledge is built to calculate the strategy payoffs,and thus the TcEval-AS algorithm is proposed when noise *** evaluation algorithms developed in this paper greatly reduce the interaction complexity compared with existing approaches,including ResponseGraphUCB(RG-UCB)andαInformationGain(α-IG).Finally,the effectiveness of the proposed algorithms is verified in the EM case with realistic data.

关键词： Energy management Multi-agent deep reinforcement learning Strategy evaluation Power grid system

Increased Expression of Serum Monocyte Chemoattractant Protein-1,Chemokine(C-C motif)Ligand 3,and Interleukins in Patients With Vitiligo

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International Journal of Dermatology and Venereology 2024年第1期7卷 40-43页

作者： Xiao-Ling Zhao Ya-lan Li Zi-Han Li Xiao-Chong Zhang Li-Hui An Yu-Jiao sun Deng-xiang Liu Fang Cheng Cancer Laboratory Xingtai People’s HospitalXingtaiHebei 054001China Endocrine Department Xingtai People’s HospitalXingtaiHebei 130500China Dermatological Department Xingtai People’s HospitalXingtaiHebei 054001China

Objective:Vitiligo is a chronic,acquired depigmentation of the skin,which can be divided into active and stable *** stable and active stages are not immutable and often *** of internal markers would help to diagnose the active stage of vitiligo,and the purpose of this study was to find potential active markers in the progression of ***:We compared 30 healthy controls to 60 patients with vitiligo(30 with active disease and 30 with stable disease)regarding the expression of serum monocyte chemoattractant protein(MCP)-1,chemokine(C-C motif)ligand(CCL)3,CCL5,CCL21,interleukin(IL)-6,and *** were collected from May 2017 to December *** detection was carried out by enzyme-linked immunosorbent *** difference between groups was compared by Kruskal-Wallis H test and Mann-Whitney U ***:We found that the serum levels of MCP-1,CCL3,IL-6,and IL-17 were significantly higher in patients with vitiligo than in healthy controls(P<0.01)and that IL-17 was higher in patients with active vitiligo than in those with stable vitiligo(P<0.01).After 3months of treatment,the serum IL-17 level of patients with active vitiligo was not significantly different from that before treatment(P=0.526);after 6months of treatment,however,the serum IL-17 level had significantly decreased(P<0.01).Conclusion:These findings suggest that the serum IL-17 level can be used as a marker of vitiligo disease activity giving it certain guiding significance for clinical treatment.

关键词： clinical marker serum cytokines vitiligo

Lateral root elongation in maize is related to auxin synthesis and transportation mediated by N metabolism under a mixed NO_(3)^(–) and NH_(4)^(+) supply

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Journal of Integrative Agriculture 2024年第3期23卷 1048-1060页

作者： Peng Wang lan Yang Xichao sun Wenjun Shi Rui Dong Yuanhua Wu Guohua Mi Key Laboratory of Tobacco Biology and Processing of Ministry of Agriculture and Rural Affairs Tobacco Research InstituteChineseAcademy of Agricultural SciencesQingdao 266101China Department of Plant Nutrition College of Resources and Environmental SciencesChina Agricultural UniversityBeijing 100193China College of Resources Hunan Agricultural UniversityChangsha 410128China Agro-Environmental Protection Institute Ministry of Agriculture and Rural AffairsTianjin 300191China

A mixed nitrate (NO_(3)^(–)) and ammonium (NH_(4)^(+)) supply can promote root growth in maize (Zea mays),however,the changes in root morphology and the related physiological mechanism under different N forms are still ***,maize seedlings were grown hydroponically with three N supplied in three different forms (NO_(3)^(–)only,75/25 NO_(3)^(–)/NH_(4)^(+)and NH_(4)^(+)only).Compared with sole NO_(3)^(–)or NH_(4)^(+),the mixed N supply increased the total root length of maize but did not affect the number of axial *** main reason was the increased total lateral root length,while the average lateral root (LR) length in each axle was only slightly *** addition,the average LR density of 2nd whorl crown root under mixed N was also *** with sole nitrate,mixed N could improve the N metabolism of roots (such as the N influx rate,nitrate reductase (NR) and glutamine synthase (GS)enzyme activities and total amino content of the roots).Experiments with exogenously added NR and GS inhibitors suggested that the increase in the average LR length under mixed N was related to the process of N assimilation,and whether the NR mediated NO synthesis participates in this process needs further ***,an investigation of the changes in root-shoot ratio and carbon (C) concentration showed that C transportation from shoots to roots may not be the key factor in mediating lateral root elongation,and the changes in the sugar concentration in roots further proved this ***,the synthesis and transportation of auxin in axial roots may play a key role in lateral root elongation,in which the expression of ZmPIN1B and ZmPIN9 may be involved in this *** study preliminarily clarified the changes in root morphology and explored the possible physiological mechanism under a mixed N supply in maize,which may provide some theoretical basis for the cultivation of crop varieties with high N efficiency.

关键词： maize NO_(3)^(–)/NH_(4)^(+)ratio lateral root elongation N assimilation indole-3-acetic acid

Self-assembly tungsten selenide hybrid ternary MOF derived magnetic alloys via multi-polarization to boost microwave absorption

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Nano Research 2024年第3期17卷 1625-1635页

作者： Tianbao Zhao Tingting Zheng Di lan Yan Zhang Zhengshuo sun Chao Wang Zirui Jia Guanglei Wu Institute of Materials for Energy and Environment State Key Laboratory of Bio-fibers and Eco-textilesCollege of Materials Science and EngineeringQingdao UniversityQingdao 266071China School of Materials Science and Engineering Hubei University of Automotive TechnologyShiyan 442002China College of Chemistry and Chemical Engineering Qingdao UniversityQingdao 266071China

Confronted with severe electromagnetic wave pollution,the development of high-performance electromagnetic wave shielding or absorbing materials is an effective way to deal with ***,double transition metal alloys and transition metal dichalcogenides have attracted extensive attention in electromagnetic wave absorption,but few reports have studied the effects of these two materials on electromagnetic wave absorption at the same *** this work,cobalt-based alloy with magnetic loss mechanism was selected for composition *** ternary metal-organic framework was prepared by the one-step method,and then CoCu/C was prepared by high temperature ***,in the hydrothermal process,ultra-thin tungsten selenide nanosheets were coated on the surface of magnetic component,and the final polyhedral WSe_(2)/CoCu/C composites with multiple heterogeneous interfaces were *** synergistic effect of dielectric and magnetic components optimizes impedance matching and allows more electromagnetic waves to enter the ***,through the conduction loss of high conductivity graphitized carbon,interfacial polarization,and dipole polarization of heterogeneous interfaces between the components,the magnetic loss provided by CoCu alloy can work together to maximize the attenuation ability of electromagnetic ***,the minimum reflection loss(RLmin)value of the composite reaches-53.43 dB when the matched thickness is 2.1 mm,while the maximum effective absorption bandwidth(EABmax)reaches 6.0 GHz at a thin thickness of 1.8 *** work provides some support and reference for the design of novel electromagnetic wave absorbing materials via the dielectric/magnetic loss synergistic mechanism.

关键词： metal-organic framework dielectric/magnetic loss transition metal dichalcogenide electromagnetic wave absorption