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hierarchical FeO_(χ)h_(y)@Ni_(3)B hybrid for efficient alkaline oxygen evolution at high current density

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Journal of Energy Chemistry 2024年第7期94卷 599-607页

作者： Fuxi liu Qing Liang Zhenyu Li Meiqi liu Nailin yue Zizhun Wang Xu Zou Wei Zhang Key Laboratory of Automobile Materials Ministry of Education School of Materials Science&EngineeringElectron Microscopy CenterInternational Center of Future ScienceJilin Provincial International Cooperation Key Laboratory of High-Efficiency Clean Energy MaterialsJilin UniversityChangchun 130012JilinChina

Electrocatalysts with high activity and long-term durability are vital toward large-scale hydrogen pro-duction from electrocatalytic water ***,the self-supported electrode(FeO_(χ)h_(y)@Ni_(3)B/NF)with hierarchical heterostructure was simply prepared by using Ni_(3)B chunks grown on nickel foam as sub-strate to in situ form vertical FeO_(χ)h_(y)*** hybrid shows efficient oxygen evolution reaction activity with overpotentials as low as 267 and 249 mV at 100 mA cm^(-2)in 1 M KOh solution and 30 wt%KOh solution,***,it also exhibits excellent catalytic stability,sustaining catalysis at 500 mA cm^(-2)in 1 M KOh solution for 200 h,and even for 200 h at 1000 mA cm^(-2)in 30 wt%KOh *** experimental results reveal that the FeO_(χ)h_(y)@Ni_(3)B/NF is endowed with superhydrophilic and superaerophobic surface properties,which not only provide more mass transport channels,as well as facilitated the diffusion of reaction intermediates and gas ***,it holds faster reaction kinetics,more accessible active sites and accelerated electron transfer rates due to strong synergistic interactions attheheterogeneous interface.

关键词： FeO_(χ)h_(y)@Ni_(3)B/NF hybrid heterostructure Oxygen evolution reaction Electrocatalytic

Study on real-gas state equations of hydrogen

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Study on real-gas state equations of hydrogen

[h_(2)dab][GaB_(5)O_(10)]:an Acentric Galloborate with a 4-Connected Uninodal Framework

第九届全国氢能学术会议

作者： h.G.Chen,J.y Zheng,P Xu,L.Li,y.L.liu,h.y.Bie Zhejiang University,China

＜正＞Currently,high pressure hydrogen storage has been an important transportation channel in areas of new energy development and *** hydrogen demonstrations require to explore the physical and chemical properties in detail before the practical employment,which is completely different from the ideal gas under high pressure ***,the

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来源： cnki会议评论

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Chemical Research in Chinese Universities 2024年第4期40卷 747-752页

作者： liu Wenfang ChEN Chongan yANG Guoyu School of Chemistry and Chemical Engineering Beijing Institute of TechnologyBeijing102488P.R.China

A new acentric galloborate(GBO)[h_(2)dab][GaB_(5)O_(10)](1,1,4-dab:1,4-diaminobutane)has been synthesized under solvothermal *** alternation of 4,4-connected GaO4 and B5O10 cluster build up the 3D[GaB_(5)O_(10)]_(n)^(2n-)uninodal framework,which contains three pairs of helical channels with 8-member ring(MR)and 7-MR apertures,*** 1 exhibits a moderate second harmonic generation(ShG)response of 1.8 times that of Kh_(2)PO_(4)(KDP),indicating its potential application in UV *** acentric uninodal framework in compound 1 represents a new type of zeolitic framework in the GBOs’family.

关键词： Galloborate Solvothermal synthesis Nonlinear optics Zeolitic framework

二次离子质谱技术在季节分辨石笋δ^(18)O分析中的应用

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中国科学：地球科学 2015年第10期45卷 1316-1323页

作者：刘浴辉唐国强凌潇潇胡超涌李献华中国地质大学生物地质与环境地质国家重点实验室武汉430074 中国地质大学材料与化学学院武汉430074 中国科学院地质与地球物理研究所岩石圈演化国家重点实验室北京100029

尝试利用二次离子质谱(SIMS)技术,采用国家一级标样(GBW04481)Oka方解石和美国威斯康星大学标样UWC-3方解石,对长江中游清江和尚洞洞穴碳酸盐沉积物hS4石笋的8.3ka BP时段(236.3~235.6 cm)进行了季节分辨率的?18O原位分析,探讨了利用季... 详细信息

尝试利用二次离子质谱(SIMS)技术,采用国家一级标样(GBW04481)Oka方解石和美国威斯康星大学标样UWC-3方解石,对长江中游清江和尚洞洞穴碳酸盐沉积物hS4石笋的8.3ka BP时段(236.3~235.6 cm)进行了季节分辨率的?18O原位分析,探讨了利用季节分辨SIMS?18O所呈现出的年际旋回对石笋进行相对定年的可能性;并通过SIMS法与常规法?18O值的比较,分析了两者间偏差产生的可能原因.以Oka作外标,利用Cameca IMS 1280离子探针在3个工作日内对UWC-3进行了氧同位素分析,获得的测量结果(?18OVPDB=?17.85‰±0.22‰,1SD)与其推荐值(?18OVPDB=?17.83‰?0.08‰)在误差范围内一致,说明仪器稳定性良好、测试方法可靠.用SIMS法获得的hS4石笋?18O季节分辨率记录,则呈现出较为显著的年际旋回特征,其旋回总数与同段石笋Mg/Ca比及石笋反光微层图像中所呈现出的年层总数一致,有望为不具备清晰年纹层石笋的相对定年提供一个新的方法.与常规法?18O分析结果相比,hS4石笋SIMS法?18O值系统偏负0.90‰,且季节性差异增大,其主要原因可能是缘于样品中细微裂隙、孔洞和包裹体的存在,同时亦不排除石笋中有机质的存在对SIMS?18O值可能造成的影响,说明要获得与常规法?18O值相符的SIMS?18O值记录,石笋样品的致密度和纯净度均至关重要.

关键词： SIMS 石笋 δ^18O 季节分辨率

Trial characteristics and treatment effect estimates in randomized controlled trials of Chinese herbal medicine: A meta-epidemiological study

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Journal of Integrative Medicine 2024年第3期22卷 223-234页

作者： Betty h.Wang ya-li Lin yin-yan Gao Jin-lu Song Lang Qin Ling-qi Li Wen-qi liu Claire C.W.Zhong Mary y.Jiang Chen Mao Xiao-bo yang Vincent C.h.Chung Irene X.y.Wu Jockey Club School of Public health and Primary Care the Chinese University of Hong KongHong Kong 999077China Xiangya School of Public health Central South UniversityChangsha 410006Hunan ProvinceChina School of Chinese Medicine the Chinese University of Hong KongHong Kong 999077China School of Public health Southern Medical UniversityGuangzhou 510080Guangdong ProvinceChina State Key Laboratory of Dampness Syndrome of Chinese Medicine the Second Affiliated Hospital of Guangzhou University of Chinese MedicineGuangzhou 510120Guangdong ProvinceChina Chinese Medicine Syndrome Research Team the Second Affiliated HospitalGuangzhou University of Chinese MedicineGuangzhou 510120Guangdong ProvinceChina Guangdong Provincial Key Laboratory of Clinical Research on Traditional Chinese Medicine Syndrome Guangzhou 510120Guangdong ProvinceChina hunan Provincial Key Laboratory of Clinical Epidemiology Central South UniversityChangsha 410006Hunan ProvinceChina

Background:Previously published meta-epidemiological studies focused on Western medicine have identified some trial characteristics that impact the treatment effect of randomized controlled trials(RCTs).Nevertheless,it remains unclear if similar associations exist in RCTs on Chinese herbal medicine(ChM).Further,Chinese medicine-related characteristics have not been explored ***:To investigate trial characteristics related to treatment effect estimates on ChM *** strategy:This meta-epidemiological study searched 5 databases for systematic reviews on ChM treatment published between January 2011 and July *** criteria:An eligible systematic review should only include RCTs of ChM and conduct at least one *** extraction and analysis:Two reviewers independently conducted data extraction on general characteristics of systematic reviews,meta-analyses and included *** also assessed the risk of bias of RCTs using the Cochrane risk of bias tool.A two-step approach was used for data *** ratio of odds ratios(ROR) and difference in standardized mean differences (dSMD) with 95%confidence interval (CI) were applied to present the difference in effect estimates for binary and continuous outcomes,***:Ninety-one systematic reviews,comprising 1338 RCTs were *** binary outcomes,RCTs incorporated with syndrome differentiation (ROR:1.23;95%CI:[1.07,1.39]),adopting Chinese medicine formula (ROR:1.19;95%CI:[1.03,1.34]),with low risk of bias on incomplete outcome data (ROR:1.29;95%CI:[1.06,1.52]) and selective outcome reporting (ROR:1.12;95%CI:[1.01,1.24]),as well as a trial size≥100 (ROR:1.23;95%CI:[1.04,1.42]) preferred to show larger effect *** for continuous outcomes,RCTs with Chinese medicine diagnostic criteria (dSMD:0.23;95%CI:[0.06,0.41]),judged as high/unclear risk of bias on allocation concealment (dSMD:-0.70;95%CI:[-0.99,-0.42]),with low risk of bias on incomplete outcome data (dSMD:0.30

关键词： Chinese herbal medicine Randomized controlled trial Risk of bias Meta-epidemiological study Effect estimates

Implicit Function Based Open-loop Analysis Method for Detecting the SSR Using Identified System Parameters

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CSEE Journal of Power and Energy Systems 2024年第5期10卷 2016-2026页

作者： Luonan Qiu Tianhao Wen yang liu Q.h.Wu School of Electric Power Engineering South China University of TechnologyGuangzhou 510640China

This paper proposes an implicit function based open-loop analysis method to detect the subsynchronous resonance(SSR),including asymmetric subsynchronous modal attraction(ASSMA)and asymmetric subsynchronous modal repulsion(ASSMR),of doubly-fed induction generator based wind farms(DFIG-WFs)penetrated power *** some important parameters of DFIG-WF are difficult to obtain,reinforcement learning and least squares method are applied to identify those important *** predicting the location of closed-loop subsynchronous oscillation(SSO)modes based on the calculation of partial differentials of characteristic equation,both ASSMA and ASSMR can be *** proposed method in this paper can select SSO modes which move to the right half complex planes as control parameters ***,the proposed open-loop analysis method is adaptive to parameter *** studies are carried out on the 4-machine 11-bus power system to verify properties of the proposed method.

关键词： Open-loop modal analysis reinforcement learning based parameter identification subsynchronous resonance

Adsorption behavior of CO2/h2S mixtures in calcite slit nanopores for CO2 storage:An insight from molecular perspective

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Petroleum Science 2024年第4期21卷 2444-2456页

作者： Cheng Qian Zhen-hua Rui yue-Liang liu Kai Du Chen liu yang Zhao Xiao-Min Ma State Key Laboratory of Petroleum Resources and Engineering China University of Petroleum College of Petroleum Engineering China University of Petroleum College of Carbon Neutrality Future Technology China University of Petroleum College of Petroleum China University of Petroleum-Beijing at Karamay College of Mining Engineering Taiyuan University of Technology

It is acknowledged that injecting CO2into oil reservoirs and saline aquifers for storage is a practical and affordable method for *** CO2produced from industrial exhaust contains impurity gases such as h2S that might impact CO2sequestration due to competitive *** study makes a commendable effort to explore the adsorption behavior of CO2/h2S mixtures in calcite slit *** Canonical Monte Carlo（GCMC） simulation is employed to reveal the adsorption of CO2,h2S as well as their binary mixtures in calcite *** show that the increase in pressure and temperature can promote and inhibit the adsorption capacity of CO2and h2S in calcite nanopores,***2exhibits stronger adsorption on calcite surface than *** energy plays the dominating role in the adsorption *** energy accounts for 97.11% of the CO2-calcite interaction energy and 56.33% of the h2S-calcite interaction energy at 10 MPa and 323.15 *** presence of h2S inhibits the CO2adsorption in calcite nanopores due to competitive adsorption,and a higher mole fraction of h2S leads to less *** quantity of CO2adsorbed is lessened by approximately 33% when the mole fraction of h2S reaches ***2molecules preferentially occupy the regions near the po re wall and h2S molecules tend to reside at the center of nanopore even when the molar ratio of CO2is low,indicating that CO2has an adsorption priority on the calcite surface over *** addition,moisture can weaken the adsorption of both CO2and h2S,while CO2is more *** interestingly,we find that pure CO2is more suitable to be sequestrated in the shallower formations,i.e.,500-1500 m,whereas CO2with h2S impurity should be settled in the deeper reservoirs.

关键词： Adsorption behavior CO 2 /h 2 S binary mixtures Molecular perspective Calcite slit nanopores CO 2 sequestration

Expanding Annular Domain Algorithm to Estimate Domains of Attraction for Power System Stability Analysis

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CSEE Journal of Power and Energy Systems 2024年第5期10卷 1925-1934页

作者： yuqing Lin Tianhao Wen yang liu Q.h.Wu School of Electric Power Engineering South China University of TechnologyGuangzhou 510640China

This paper presents an Expanding Annular Domain(EAD)algorithm combined with Sum of Squares(SOS)programming to estimate and maximize the domain of attraction(DA)of power *** proposed algorithm can systematically construct polynomial Lyapunov functions for power systems with transfer conductance and reliably determine a less conservative approximated DA,which are quite difficult to achieve with traditional *** linear SOS programming,we begin from an initial estimated DA,then enlarge it by iteratively determining a series of so-called annular domains of attraction,each of which is characterized by level sets of two successively obtained Lyapunov ***,the EAD algorithm is theoretically analyzed in detail and its validity and convergence are shown under certain *** the end,our method is tested on two classical power system cases and is demonstrated to be superior to existing methods in terms of computational speed and conservativeness of results.

关键词： Domain of attraction Lyapunov functions power system transient stability sum of squares programming

A functionalized activated carbon adsorbent prepared from waste amidoxime resin by modifying with h_(3)PO_(4) and ZnCl_(2) and its excellent Cr(Ⅵ)adsorption

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International Journal of Minerals,Metallurgy and Materials 2024年第3期31卷 585-598页

作者： Chunlin he yun liu Mingwei Qi Zunzhang liu yuezhou Wei Toyohisa Fujita Guifang Wang Shaojian Ma Wenchao yang School of Resources Environment and MaterialsGuangxi UniversityNanning 530004China State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures Guangxi UniversityNanning 530004China School of Nuclear Science and Technology University of South ChinaHengyang 421000China School of Nuclear Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240China Key Laboratory of New Low-carbon Green Chemical Technology Education Department of Guangxi Zhuang Autonomous RegionNanning 530004China

With the application of resins in various fields, numerous waste resins that are difficult to treat have been produced. The industrial wastewater containing Cr(Ⅵ) has severely polluted soil and groundwater environments, thereby endangering human health. Therefore, in this paper, a novel functionalized mesoporous adsorbent PPR-Z was synthesized from waste amidoxime resin for adsorbing Cr(Ⅵ). The waste amidoxime resin was first modified with h3PO4 and ZnCl_(2), and subsequently, it was carbonized through slow thermal decomposition. The static adsorption of PPR-Z conforms to the pseudo-second-order kinetic model and Langmuir isotherm, indicating that the Cr(Ⅵ) adsorption by PPR-Z is mostly chemical adsorption and exhibits single-layer adsorption. The saturated adsorption capacity of the adsorbent for Cr(Ⅵ) could reach 255.86 mg/g. The adsorbent could effectively reduce Cr(Ⅵ) to Cr(Ⅲ) and decrease the toxicity of Cr(Ⅵ) during adsorption. PPR-Z exhibited Cr(Ⅵ) selectivity in electroplating wastewater. The main mechanisms involved in the Cr(Ⅵ) adsorption are the chemical reduction of Cr(Ⅵ) into Cr(Ⅲ) and electrostatic and coordination interactions. Preparation of PPR-Z not only solves the problem of waste resin treatment but also effectively controls Cr(Ⅵ) pollution and realizes the concept of “treating waste with waste”.

关键词： waste amidoxime resin mesoporous adsorbent h_(3)PO_(4)and ZnCl_(2)processing Cr(VI)adsorption electroplating wastewater