[H_(2)dab][GaB_(5)O_(10)]:an Acentric Galloborate with a 4-Connected Uninodal Framework

作     者：LIU Wenfang CHEN Chongan YANG Guoyu LIU Wenfang;CHEN Chongan;YANG Guoyu

作者机构：School of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijing102488P.R.China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2024年第40卷第4期

页      面：747-752页

核心收录：

学科分类：07[理学] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(Nos.21831001,21571016,91122028) the National Natural Science Foundation of China for Distinguished Young Scholars(No.20725101) 

主　　题：Galloborate Solvothermal synthesis Nonlinear optics Zeolitic framework 

摘      要：A new acentric galloborate(GBO)[H_(2)dab][GaB_(5)O_(10)](1,1,4-dab:1,4-diaminobutane)has been synthesized under solvothermal *** alternation of 4,4-connected GaO4 and B5O10 cluster build up the 3D[GaB_(5)O_(10)]_(n)^(2n-)uninodal framework,which contains three pairs of helical channels with 8-member ring(MR)and 7-MR apertures,*** 1 exhibits a moderate second harmonic generation(SHG)response of 1.8 times that of KH_(2)PO_(4)(KDP),indicating its potential application in UV *** acentric uninodal framework in compound 1 represents a new type of zeolitic framework in the GBOs’family.