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Influence of Humic Acid on Interaction of Ammonium and Potassium Ions on Clay Minerals

Pedosphere 2013年第4期23卷 493-502页

作者： ZHANG Wen-Zhao CHEN Xiao-Qin ZHOU Jian-Min liu dai-huan WANG Huo-Yan DU Chang-Wen State Key Laboratory of Soil and Sustainable Agriculture Institute of Soil Science Chinese Academy of Sciences Key Laboratory of Agro-Ecological Processes in Subtropical Region Institue of Subtropical Agriculture Chinese Academy of Sciences

Interaction of ammonium (NH+4) and potassium (K+) is typical in field soils. However, the effects of organic matter on interaction of NH+4 and K+have not been thoroughly investigated. In this study, we examined the changes in major physicochemical properties of three clay minerals (kaolinite, illite, and montmorillonite) after humic acid (HA) coating and evaluated the influences of these changes on the interaction of NH+4 and K+on clay minerals using batch experiments. After HA coating, the cation exchange capacity (CEC) and specific surface area (SSA) of montmorillonite decreased significantly, while little decrease in CEC and SSA occurred in illite and only a slight increase in CEC was found in kaolinite. Humic acid coating significantly increased cation adsorption and preference for NH+4, and this effect was more obvious on clay minerals with a lower CEC. Results of Fourier transform infrared spectrometry analysis showed that HA coating promoted the formation of H-bonds between the adsorbed NH+4 and the organo-mineral complexes. HA coating increased cation fixation capacity on montmorillonite and kaolinite, but the opposite occurred on illite. In addition, HA coating increased the competitiveness of NH+4 on fixation sites. These results showed that HA coating affected both the nature of clay mineral surfaces and the reactions of NH+4 and K+with clay minerals, which might influence the availability of nutrient cations to plants in field soils amended with organic matter.

关键词： adsorption illite kaolinite montmorillonite organo-mineral complex

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Modified conditioning regimen busulfan-cyclophosphamide followed by allogeneic stem cell transplantation in patients with multiple myeloma

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Chinese Medical Journal 2007年第6期120卷 463-468页

作者： ZHANG Xiao-hui huanG Xiao-jun liu Kai-yan XU Lan-ping liu dai-hong CHEN huan CHEN Yu-hong WANG Jing-zhi HAN Wei LU Dao-pei Institute of Hematology Peking University People＇s Hospital Beijing 100044 China

Background Allogeneic stem cell transplantation is a potential curative approach in patients with multiple myeloma. The very high transplant related mortality associated with standard allogeneic stem cell transplantation is currently the major limitation to wider use of this potentially curative treatment modality. The challenge for clinical investigators is to reduce the incidence of post-transplant complications for patients receiving autologous hematopoietic stem cell transplantion for multiple myeloma. In this study the toxicity and efficacy of modified myeloablative conditioning regimen followed by allogeneic stem cell transplantation was investigated in patients with multiple myeloma. Methods The conditioning regimen consisted of hydroxyurea, cytarabine, busulfan, cyclophosphamide, and semustine. Ten patients underwent allogeneic transplantation among them hydroxyurea （40 mg/kg） was administered twice on day -10 and cytarabine （2 g/ms） was given on day -9, busulfan was administered orally in four divided doses daily for 3 days （days -8 to -6）. The dose of busulfan was 12 mg/kg in the protocol followed by cyclophosphamide intravenously over 1 hour on days -5 and -4 （1.8 g/m^2）, and with semustine （Me-CCNU） 250 mg/m^2 on day -3. Results Chimerism data were available on all patients and all patients achieved full donor chimerism without graft failure. Six patients had not acute graft-versus-host disease （GVHD, 36.4%; 95% CI： 13.9%-38.6%）. Two patients （18.2%） developed grade Ⅰ acute GVHD （95% CI： 10.9%-35.9%） and grade Ⅱ acute GVHD occurred in one patient （9.1%; 95% Cl. 8.4%-32.3%）. Severe grade IVa GVHD was seen in one patient, who died from acute GVHD. The incidence of chronic GVHD was 22.2% （95% Cl： 11.7%-36.7%）, among them one died of severe grade IV GVHD and one developed multiorgan failure on day ＋170; the treatment-related mortality was 22.0% （95% Cl： 10.3%-34.1%）. The overall 4-year survival rate was 67.8% （95% Cl： 16.3%-46.7%）. The estimated 4-year progr

关键词： multiple myeloma stem cell transplantation modified conditioning regimen

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Monitoring the source of mesenchymal stem cells in patients after transplantation of mismatched-sex hematopoietic stem cells plus thirdparty cells

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Chinese Medical Journal 2013年第22期126卷 4254-4259页

作者： WANG Jing huanG Xiao-jun XU Lan-ping liu dai-hong CHEN huan CHEN Yu-hong LAI Yue-yun HOU Rui-qin QIN Xiao-ying liu Kai-yan Peking University Institute of Hematology Peking University People's Hospital Beijing 100044 China

Background In bone marrow transplant patients, the microenvironment in bone marrow is damaged after chemotherapy or radiotherapy. Subsequent to allogenic hematopoietic stem cell transplantation in patients with clinically successful engraftments, the source of mesenchymal stem cells （MSCs） remains controversial. To further verify the stimulatory effect of the simultaneous transplantation of cells from second donors on engraftment success for hematopoietic stem cell transplantation in support of donor MSCs engraftments, the aim of this study is to monitor the dynamics of the engraftment of bone marrow-derived MSCs in patients after transplantation with mismatched-sex hematopoietic stem and third-party cells. Methods In this study, the hematopoietic stem cells from 32 clinical donors of different sexes that resulted in successful engraftments were selected for transplantation and were classified into three groups for research purposes： group A consisted of 14 cases of transplantation with bone marrow and recruited peripheral hematopoietic stem cell transplantation, group B contained 8 cases of simultaneous re-transfusion of MSCs from the second donor, and group C contained 10 cases of simultaneous re-transfusion of umbilical blood from the second donor. The bone marrow from 32 patients with successful engraftments of hematopoietic transplantation were selected and sub-cultured with MSCs. Flow cytometry （FCM） was used to measure the expression of surface antigens on MSCs. Denaturing high-performance liquid chromatography （DHPLC） in combination with polymerase chain reaction amplification of short tandem repeats （STR- PCR） was used to measure the engraftment status of fifth-generation MSCs in patients. Fluorescence in situ hybridization （FISH） revealed the sex origin of the fifth-generation MSCs in 32 patients. Dynamic examinations were performed on patients receiving donor transplantations. Results The progenies of fifth-generation MSCs were successfully cultured in 32

关键词： hematopoietic stem cell transplantation mesenchymal stem cells source of engraftment

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Idiopathic inflammatory demyelinating diseases of the central nervous system in patients following allogeneic hematopoietic stem cell transplantation： a retrospective analysis of incidence, risk factors and survival

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Chinese Medical Journal 2013年第6期126卷 1096-1102页

作者： ZHANG Xiao-hui huanG Xiao-jun liu Kai-yan XU Lan-ping liu dai-hong CHEN huan HAN Wei CHEN Yu-hong WANG Feng-rong WANG Jing-zhi WANG Yu ZHAO Ting CHEN Yao FU Hai-xia WANG Min Peking University People's Hospital Peking University Institute of Hematology Beijing 100044 China

Background AIIogeneic hematopoietic stem cell transplantation （allo-HSCT） is a curative therapy for many hematological diseases, but there are many complications following alIo-HSCT, among which neurological complications （NC） are one of the most commonly described ones. However, little is known about idiopathic inflammatory demyelinating diseases （IIDDs） of the central nervous system （CNS） in patients following alIo-HSCT. Methods A nested case-control study was conducted in a large cohort of 1365 patients, who underwent alIo-HSCT at the Institute of Hematology and Peking University People＇s Hospital, between January 2004 and December 2009, 36 patients of whom developed CNS IIDDs. Kaplan-Meier method, univariate and multivariate Cox regression were applied in our statistical analysis using SPSS 16.0. Results The cumulative incidence of all cases of IIDDs at 6 years posttransplantation was 3.6%. Thirty-five patients （97.2%） suffered IIDDs after transplantation, 16 patients （44.4%） between day 0 to day 100 post-transplantation, 10 patients （27.8%） between day 100 to 1 year post-transplantation, and 9 patients （25.0%） 1 year post-transplantation. Multivariate regression analysis identified donor type （P=0.031）, infection （P=0.009）, and acute lymphatic leukemia （P=0.017） as independent risk factors for posttransplantation IIDDs. The median survival time of patients with IIDDs was 514 days after transplantation （95% CI： 223-805）. Survival at 6 years was significantly lower in patients who developed the diseases compared to those who did not （26.6% vs. 73.5%, P 〈0.001）. Of the 36 patients experiencing IIDDs, 58.3% （n=21） died. The causes of death were graft-versus-host disease （GVHD）（n=4）, underlying disease relapse （n=3）, infections （n=12）, and other causes （n=2）. Conclusions IIDDs is an uncommon but serious complication of alIo-HSCT, especially in patients with a primary diagnosis of acute lymphatic leukemia, mismatched transplants, and infections. Our study results in

关键词： hematopoietic stem cell transplantation idiopathic inflammatory demyelinating diseases central nervous system risk factors survival

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Research status and prospects of the fractal analysis of metal material surfaces and interfaces

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 20-38页

作者： Qinjin dai Xuefeng liu Xin Ma Shaojie Tian Qinghe Cui Beijing Advanced Innovation Center for Materials Genome Engineering University of Science and Technology BeijingBeijing 100083China Beijing Laboratory of Metallic Materials and Processing for Modern Transportation University of Science and Technology BeijingBeijing 100083China Laboratory for Advanced Materials Processing of Ministry of Education University of Science and Technology BeijingBeijing 100083China School of Mechanical and Electrical Engineering Xinjiang Institute of EngineeringUrumqi 830023China

As a mathematical analysis method,fractal analysis can be used to quantitatively describe irregular shapes with self-similar or self-affine *** analysis has been used to characterize the shapes of metal materials at various scales and *** methods make it difficult to quantitatively describe the relationship between the regular characteristics and properties of metal material surfaces and ***,fractal analysis can be used to quantitatively describe the shape characteristics of metal materials and to establish the quantitative relationships between the shape characteristics and various properties of metal *** the perspective of two-dimensional planes and three-dimensional curved surfaces,this paper reviews the current research status of the fractal analysis of metal precipitate interfaces,metal grain boundary interfaces,metal-deposited film surfaces,metal fracture surfaces,metal machined surfaces,and metal wear *** relationship between the fractal dimensions and properties of metal material surfaces and interfaces is *** from three perspectives of fractal analysis,namely,research scope,image acquisition methods,and calculation methods,this paper identifies the direction of research on fractal analysis of metal material surfaces and interfaces that need to be *** is believed that revealing the deep influence mechanism between the fractal dimensions and properties of metal material surfaces and interfaces will be the key research direction of the fractal analysis of metal materials in the future.

关键词： metal material surfaces and interfaces fractal analysis fractal dimension homogeneity

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长期定位施肥对蔬菜保护地土壤钾素Q/I特性的影响

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湖南农业大学学报（自然科学版） 2009年第1期35卷 43-47页

作者：刘代欢杜立宇梁成华刘学刘丽沈阳农业大学土地与环境学院辽宁沈阳110161

研究蔬菜保护地18个长期定位施肥处理的土壤钾素Q/I曲线特性,结果表明,不同长期定位施肥蔬菜保护地土壤供钾容量(-?K0即QK)、供钾强度(AReK即IK)和缓冲能力PBCK差异明显,土壤基本理化性质的差异是其存在差异的根本原因;土壤CEC、速效钾... 详细信息

研究蔬菜保护地18个长期定位施肥处理的土壤钾素Q/I曲线特性,结果表明,不同长期定位施肥蔬菜保护地土壤供钾容量(-?K0即QK)、供钾强度(AReK即IK)和缓冲能力PBCK差异明显,土壤基本理化性质的差异是其存在差异的根本原因;土壤CEC、速效钾、粘粒、有机质含量越高,土壤-?K0、AReK值越大,PBCK值越小.影响各处理Q/I曲线特性的主要原因各异,施有机肥的各处理主要因为CEC和速效钾含量高,从而-?K0和AReK值较高,PBCK值较低;施钾肥的各处理主要因为速效钾含量高,具有较高的-?K0和AReK值和较低的PBCK值;施高量氮肥的处理有较低的-?K0值和PBCK值和较高的AReK值,这或许与NH4+浓度大有关.

关键词：长期定位施肥蔬菜保护地钾 Q/I曲线

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黏土矿物在土壤重金属污染中的应用研究进展

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土壤通报 2018年第2期49卷 499-504页

作者：朱维刘代欢陈建清戴青云符云聪湖南永清环保研究院有限责任公司湖南长沙410330

黏土矿物作为土壤的重要组成成分之一,因其自身的组成和结构特性在土壤重金属污染钝化修复中有较为广泛的应用。目前常见的黏土矿物包括高岭石、蒙脱石、沸石、海泡石等。详细介绍了各类黏土矿物在重金属钝化修复治理中的应用,阐述了黏... 详细信息

黏土矿物作为土壤的重要组成成分之一,因其自身的组成和结构特性在土壤重金属污染钝化修复中有较为广泛的应用。目前常见的黏土矿物包括高岭石、蒙脱石、沸石、海泡石等。详细介绍了各类黏土矿物在重金属钝化修复治理中的应用,阐述了黏土矿物对土壤重金属污染的修复机理,包括离子交换、共沉淀和配合反应等。此外还探讨了黏土矿物钝化修复的影响因素,包括重金属种类、黏土矿物类型、土壤性质等。从修复实际出发,展望了黏土矿物在土壤修复应用中的未来发展,今后应多关注黏土矿物对土壤-作物系统的潜在环境风险和黏土矿物修复效果的田间长期稳定性。

关键词：重金属土壤修复黏土矿物应用研究

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模拟酸雨淋溶下海泡石复合材料对污染土壤镉释放的影响

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生态与农村环境学报 2019年第2期35卷 242-247页

作者：符云聪赵瑰施张义刘晨李鹏祥黎红亮刘代欢湖南永清环保研究院有限责任公司湖南长沙410330 永清环保股份有限公司湖南长沙410330

为了探究改性海泡石材料对土壤中重金属的钝化效果,采用土柱模拟酸雨淋溶方法研究了天然海泡石(SEP)、二乙基二硫代氨基甲酸钠改性海泡石(SEP-DDTC)、3-巯丙基三乙氧基硅烷改性海泡石(SEP-MPTES)对污染土壤中Cd的淋溶效应。结果表明:p H... 详细信息

为了探究改性海泡石材料对土壤中重金属的钝化效果,采用土柱模拟酸雨淋溶方法研究了天然海泡石(SEP)、二乙基二硫代氨基甲酸钠改性海泡石(SEP-DDTC)、3-巯丙基三乙氧基硅烷改性海泡石(SEP-MPTES)对污染土壤中Cd的淋溶效应。结果表明:p H=4. 0的酸雨淋溶后土壤p H值上升了0. 80～0. 99个单位,淋出液的p H值也明显上升。SEP和SEP-MPTES处理Cd的累积淋溶量分别增加66. 45%和11. 49%,SEP-DDTC处理显著减少45. 98%。SEP-DDTC和SEP-MPTES处理酸雨淋溶后3层土壤有效态Cd含量均低于对照,SEP-DDTC处理比SEP-MPTES处理平均低0. 054 mg·kg-1,表明SEP-DDTC是一种潜在的土壤重金属Cd修复材料。

关键词：酸雨淋溶改性海泡石 Cd 钝化

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Pancreatic stent improves the success rate of needle-knife papillotomy in patients with difficult biliary cannulation

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World Journal of Gastroenterology 2025年第1期31卷 58-67页

作者： Mu-Hsien Lee Cheng-Hui Lin Chi-huan Wu Yung-Kuan Tsou Kai-Feng Sung Sheng-Fu Wang Nai-Jen liu Department of Gastroenterology and Hepatology Chang Gung Memorial Hospital and Chang Gung University College of MedicineTaoyuan 33305Taiwan School of Medicine Chang Gung UniversityTaoyuan 33305Taiwan

BACKGROUND Needle-knife precut papillotomy(NKP)is typically performed ***,it remains unclear whether pancreatic stent(PS)placement can improve the outcomes of *** To explore whether PS placement improves the success rate of NKP in patients with difficult biliary *** This single-center retrospective study included 190 patients who underwent NKP between January 2017 and December 2021 after failed conventional biliary *** cases with incidental pancreatic duct cannulation during conventional biliary cannulation,the decision for pre-NKP PS placement was made at the endoscopist's *** primary outcome was the difference in the NKP success rate between patients with and without PS placement;the secondary outcome was the adverse event *** Among the 190 participants,82 received pre-NKP PS(PS-NKP group)whereas 108 did not[freehand or freehand NKP(FH-NKP)group].Post-NKP selective biliary cannulation was successful in 167(87.9%)patients,and the PS-NKP had a significantly higher success rate than the FH-NKP group(93.9%vs 83.3%,P=0.027).The overall adverse event rates were 7.3%and 11.1%in the PS-NKP and FH-NKP groups,respectively(P=0.493).A periampullary diverticulum(PAD)and significant intraoperative bleeding during NKP were independently associated with NKP failure;however,a pre-NKP PS was the only predictor of NKP *** the 44 participants with PADs,the PS-NKP group had a non-significantly higher NKP success rate than the FH-NKP group(87.5%and 65%,respectively;P=0.076).CONCLUSION PS significantly improved the success rate of NKP in patients with difficult biliary cannulation.

关键词： Difficult biliary cannulation Endoscopic retrograde cholangiopancreatography Needle-knife papillotomy Pancreatic stent Selective biliary cannulation

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Gut microbiota-astrocyte axis: new insights into age-related cognitive decline

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Neural Regeneration Research 2025年第4期20卷 990-1008页

作者： Lan Zhang Jingge Wei Xilei liu dai Li Xiaoqi Pang Fanglian Chen Hailong Cao Ping Lei Haihe Laboratory of Cell Ecosystem Department of GeriatricsTianjin Medical University General HospitalTianjinChina Tianjin Geriatrics Institute Tianjin Medical University General HospitalTianjinChina Department of Gastroenterology and Hepatology Tianjin Medical University General HospitalNational Key Clinical SpecialtyTianjin Institute of Digestive DiseasesTianjin Key Laboratory of Digestive DiseasesTianjinChina Department of Urology Tianjin Medical University General HospitalTianjinChina Tianjin Neurological Institution Tianjin Medical University General HospitalTianjinChina

With the rapidly aging human population,age-related cognitive decline and dementia are becoming increasingly prevalent *** is considered the main risk factor for cognitive decline and acts through alterations in the composition of the gut microbiota,microbial metabolites,and the functions of *** microbiota–gut–brain axis has been the focus of multiple studies and is closely associated with cognitive *** article provides a comprehensive review of the specific changes that occur in the composition of the gut microbiota and microbial metabolites in older individuals and discusses how the aging of astrocytes and reactive astrocytosis are closely related to age-related cognitive decline and neurodegenerative *** article also summarizes the gut microbiota components that affect astrocyte function,mainly through the vagus nerve,immune responses,circadian rhythms,and microbial ***,this article summarizes the mechanism by which the gut microbiota–astrocyte axis plays a role in Alzheimer’s and Parkinson’s *** findings have revealed the critical role of the microbiota–astrocyte axis in age-related cognitive decline,aiding in a deeper understanding of potential gut microbiome-based adjuvant therapy strategies for this condition.

关键词： age aging Alzheimer’s disease astrocytes cognitive decline dementia gut microbiota gut–brain axis microbial metabolites neuroinflammation Parkinson’s disease

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