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Cyclization mechanism of monoterpenes catalyzed by monoterpene synthases in dipterocarpaceae

Synthetic and Systems Biotechnology 2024年第1期9卷 11-18页

作者： Xiaoyun Lu Jie bai Zunzhe Tian Congyu Li Nida Ahmed Xiaonan liu Jian {2. Lina Lu Jing Cai Huifeng Jiang Wen Wang School of Ecology and Environment Northwestern Polytechnical UniversityXi’anShanxi710072China key laboratory of Engineering Biology for Low-Carbon {2. Tianjin Institute of Industrial BiotechnologyChinese Academy of SciencesTianjin300308China

Monoterpenoids are typically present in the secretory tissues of higher plants,and their biosynthesis is catalyzed by the action of monoterpene synthases(MTSs).However,the knowledge about these enzymes is restricted in a few plant *** are responsible for the complex cyclization of monoterpene precursors,resulting in the production of diverse monoterpene *** enzymatic reactions are considered exceptionally complex in ***,it is crucial to understand the catalytic mechanism of MTSs to elucidate their ability to produce diverse or specific monoterpenoid *** our study,we analyzed thirteen genomes of Dipterocarpaceae and identified 38 MTSs that generate a variety of monoterpene *** focusing on four MTSs with different product spectra and analyzing the formation mechanism of acyclic,monocyclic and bicyclic products in MTSs,we observed that even a single amino acid mutation can change the specificity and diversity of MTS products,which is due to the synergistic effect between the shape of the active cavity and the stabilization of carbon-positive intermediates that the mutation ***,residues N340,I448,and phosphoric acid groups were found to be significant contributors to the stabilization of intermediate terpinyl and pinene *** in these residues,either directly or indirectly,can impact the synthesis of single monoterpenes or their *** revealing the role of key residues in the catalytic process and establishing the interaction model between specific residues and complex monoterpenes in MTSs,it will be possible to reasonably design and engineer different catalytic activities into existing MTSs,laying a foundation for the artificial design and industrial application of MTSs.

关键词： Cyclization Monoterpene synthases Intermediate stabilization

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Development of sustainable and efficient recycling technology for spent Li-ion batteries: Traditional and transformation go hand in hand

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Green Energy & Environment 2024年第5期9卷 802-830页

作者： Zejian liu Gongqi liu Leilei {2. Jing Gu Haoran Yuan Yong Chen Yufeng Wu Guangzhou Institute of Energy Conversion Chinese Academy of Sciences(CAS)Guangzhou510640China School of Engineering Science University of Science and Technology of ChinaHefei230026China Guangdong Provincial key laboratory of New and Renewable Energy Research and Development Guangzhou510640China Faculty of materials and manufacturing Beijing University of TechnologyBeijing100124China

Clean and efﬁcient recycling of spent lithium-ion batteries(LIBs)has become an urgent need to promote sustainable and rapid development of human ***,we provide a critical and comprehensive overview of the various technologies for recycling spent LIBs,starting with lithium-ion power *** research on raw material collection,metallurgical recovery,separation and puriﬁcation is highlighted,particularly in terms of all aspects of economic efﬁciency,energy consumption,technology transformation and policy *** and pathways for transformative full-component recovery of spent LIBs are explored,revealing a clean and efﬁcient closed-loop recovery *** methods are proposed for future recycling technologies,with a focus on how future research directions can be ***,based on life-cycle assessment,the challenges of future recycling are revealed from the LIBs supply chain and stability of the supply chain of the new energy battery industry to provide an outlook on clean and efﬁcient short process recycling *** work is designed to support the sustainable development of the new energy power industry,to help meet the needs of global decarbonization strategies and to respond to the major needs of industrialized recycling.

关键词： Spent LIBs Transformative recycling LCA analysis Policy guidance High value utilization

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Effect of Preload Force on Heat Generation of Li(Ni_(0.8)Co_(0.1)Mn_(0.1))O_(2./SiO_(x)-C System Batteries:The Discharge Process

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Journal of Thermal Science 2024年第5期33卷 1809-1825页

作者： LIN Chunjing LAI Zhenxing bai Guangli MA Biao WEI Zhen QI Chuang liu Shiqiang key laboratory of Advanced {2. technology for Automobile Parts Ministry of EducationChongqing University of TechnologyChongqing 400054China China Auto Research New Energy Vehicle Inspection Center(Tianjin)Co Tianjin 300300China

Lithium-ion batteries(LIBs)undergo various degradation phenomena such as material decomposition,structural change and uneven lithium ion distribution during long-term cycles,which would affect their performance and *** order to improve the performance of the LIBs during their life cycle,preload force is preset when the batteries are *** preload forces will in turn affect the cycle life and heat generation of the *** order to address this issue,this work carries out charge/discharge cycle tests on a NCM811 battery under different preload *** calorimetry tests are performed to investigate the battery heat generation under different states of health(SOHs)and preload *** on the test results,an empirical prediction model for heat generation power as a function of SOH is *** show that when the preload force is 5 N·m,the battery capacity decreases in the slowest rate and the average heat generation power is the *** in peaks of the incremental capacity curve can be used to characterize the loss of lithium at the electrode,which in turn characterizes the change of heat generation power of the *** average heat generation power is mainly affected by the SOH,going through a period of trough with the decrease of the SOH and continuing to increase after crossing the critical *** general,these findings emphasize the relationship between preload force,SOH and heat generation power,which is helpful for the judgment of optimal preload to improve the efficiency of LIBs.

关键词： lithium ion battery cyclic aging preload force heat generation characteristic

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Toughening additive manufactured Zr-based bulk metallic glass composites by martensite phase transformation

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Journal of materials Science & technology 2024年第3期170卷 95-102页

作者： Pengcheng Zhang cheng Zhang Jie Pan Di Ouyang Lin {2. State key laboratory of {2. processing and Die&Mould technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China

Additive manufacturing technology based on laser powder bed fusion(LPBF)offers a novel approach for fabricating bulk metallic glass(BMG)products without restriction in size and ***,the BMGs prepared by LPBF usually suffered from less plasticity and poorer fracture toughness as compared to their cast counterparts due to partial crystallization in heat-affected zones(HAZs).Since crystallization in HAZs is hard to avoid completely in LPBF BMGs,it is desirable to design a suitable alloy system,in which only ductile crystalline phase,instead of brittle intermetallics,is formed in *** unique structure could effectively increase the toughness/plasticity of the LPBF *** achieve this goal,a quaternary BMG system with a composition of Zr_(47.5)Cu_(45.5)Al_(5)Co_(2.is adopted and subjected to *** is found that nearly a single phase of B_(2.-ZrCu is precipitated in HAZs,while a fully amorphous phase is formed in molten pools(MPs).This B_(2.phase reinforced BMG composite exhibits excellent mechanical properties with enhanced plasticity and ***,it is easy to modulate the mechanical properties by altering the amount of the B_(2.phase via adjusting the laser energy ***,the best combination of strength,plasticity,and notch toughness is obtained in the BMG composite containing 2..4%B_(2.phase and 72.6%amorphous phase,which exhibits yield strength(σ_(s))of 142. MPa,plastic strain(ε_(p))of 4.65%,and notch toughness(K_(q))of 53.9 MPa m 1/***,a notable strain-hardening is also *** improvement of plasticity/toughness and appearance of strain-hardening behavior are mainly due to the martensite phase transformation from the B_(2.phase to the Cm phase during plastic deformation(i.e.,the phase transformation-induced plasticity effect).The current work provides a guide for making advanced BMGs and BMG composites by additive manufacturing.

关键词： Laser powder bed fusion Bulk metallic glass composites Phase transformation-induced plasticity Deformation mechanism

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Defects in the grain interiors of 3 mol%yttria-stabilized tetragonal zirconia polycrystal ceramics with 0.2. wt%alumina

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Journal of Advanced Ceramics 2024年第4期13卷 469-477页

作者： Yan Xiong Lian Luo Yao cheng Zhi liu Qi liu Weimin Wang Wei Ji School of materials&Chemical Engineering Hubei Province Key Laboratory of Green Materials for Light IndustryHubei University of TechnologyWuhan 430068China Fujian Institute of Research on the Structure of Mater Chinese Academy of SciencesFuzhou 350002China Jiangxi Provincial Engineering Research Center for Multifunction Zirconia materials Jiangxi Size Materials Co.Ltd.Jiujiang 332500China State key laboratory of Advance {2. for materials Synthesis and processing Wuhan University of TechnologyWuhan 430070China

The presence of high-density defects is rarely observed in bulk 3 mol%yttria-stabilized tetragonal zirconia polycrystal(3Y-TZP)ceramics obtained through conventional pressureless *** the present work,fine-grained dense 147 nm 3Y-TZP ceramics were prepared by pressureless sintering of commercial 0.2. wt%alumina-doped zirconia powders at 1300℃.A novel discovery was reported in which large amounts of defects were present in the grain interiors of the *** phenomenon was further examined using three types of powder samples,and the reasons for defect formation were investigated by microstructural characterization using high-resolution transmission electron microscopy(HRTEM)analysis and Rietveld *** results confirmed the essential dependence of the defect formation on the alumina *** authors attributed the defect formation to the significant difference in ionic radii of the solvent and solute during the dissolution of alumina into the zirconia *** sintering kinetics were proposed to be enhanced by the presence of substantial defects,which consequently favored the low-temperature sintering of the alumina-doped zirconia ceramics.

关键词： 3 mol%yttria-stabilized tetragonal zirconia polycrystal(3Y-TzP)ceramics alumina addition microstructure defect

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BaCe_(0.8)Fe_(0.1)Ni_(0.1)O_(3−δ)-impregnated Ni-GDC by phase-inversion as an anode of solid oxide fuel cells with on-cell dry methane reforming

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Journal of Advanced Ceramics 2024年第6期13卷 834-841页

作者： Yanya liu Jun Luo cheng Li Bo liu Dong Yan Jian Li Lichao Jia School of materials Science and Engineering State Key Laboratory of Materials Processing and Die&Mould TechnologyHuazhong University of Science and TechnologyWuhan 430074China

BaCe_(0.8)Fe_(0.1)Ni_(0.1)O_(3−δ)(BCFN)in a perovskite structure is impregnated consecutively by BCFN solution and BCFN suspension into a phase-inversion prepared NiO–Gd_(0.1)Ce_(0.9)O_(2.δ)(GDC)scaffold as an anode for solid oxide fuel cells(SOFCs)with on-cell dry reforming of methane(DRM).The whole pore surface of the scaffold is covered by small BCFN particles formed by BCFN solution impregnation;the large pores near the scaffold surface are filled by BCFN aerogels with a high specific surface area produced by BCFN suspension impregnation,which act as a catalytic layer for on-cell *** reduction,the anode consists of a Ni–GDC scaffold and BCFN particles with exsolved FeNi3 *** BCFN-impregnated Ni–GDC anode has higher electrical conductivity,electrochemical activity,and resistance to carbon deposition,with which the cell shows maximum power densities between 1.44 and 0.92.W·cm^(−2. when using H_(2. and between 1.09 and 0.50 W·cm^(−2. when using CO_(2.–CH_(4) at temperatures ranging from 750 to 600℃.A stable performance at 400 mA·cm^(−2. and 700℃is achieved using 45%CO_(2.–45%CH_(4)–10%N_(2. for more than 400 h without carbon deposition,benefiting from the impregnated BCFN aerogel with a high specific surface area and water adsorbability.

关键词： aerogel solid oxide fuel cells(SOFCs) phase-inversion dry reforming of methane(DRM) carbon resistance

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Food nutrition and toxicology targeting on specific organs in the era of single-cell sequencing

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Food Science and Human Wellness 2024年第1期13卷 75-89页

作者： Xiaofei Wang Xiaowen cheng Huiling liu Xiaohuan Mu Hao Zheng National Engineering technology Research Center for Fruit and Vegetable processing Key Open Laboratory of Fruit and Vegetable ProcessingMinistry of Agriculture and Rural AffairsBeijing Key Laboratory of Food Non-Thermal ProcessingCollege of Food Science and Nutritional EngineeringChina Agricultural UniversityBeijing 100083China

Due to the complex natures of dietary food components,it is difficult to elucidate how the compounds affect host *** food often selectively presents its mechanism of action on different cell types,and participates in the modulation of targeted cells and their microenvironments within ***,the limitations of traditional in vitro assays or in vivo animal experiments cannot comprehensively examine cellular heterogeneity and the tissue-biased ***-cell RNA sequencing(sc RNA-seq)has emerged as an indispensable methodology to decompose tissues into different cell types for the demonstration of transcriptional profiles of individual *** RNA-seq applications has been summarized on three typical organs(brain,liver,kidney),and two representative immune-and tumor related health *** everincreasing role of sc RNA-seq in dietary food research with further improvement can provide sub-cellular information and the coupling between other cellular *** this review,we propose utilizing sc RNAseq to more effectively capture the subtle and complex effects of food chemicals,and how they may lead to health problems at single-cell *** novel technique will be valuable to elucidate the underlying mechanism of both the health benefits of food nutrients and the detrimental consequences food toxicants at the cellular level.

关键词： Dietary food Cellular heterogeneity Single-cell RNA sequencing Food nutrients Food toxicants

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Precise regulation of the phase transformation for pyrolusite during the reduction roasting process

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International Journal of Minerals,Metallurgy and materials 2024年第1期31卷 81-90页

作者： Ruofeng Wang Peng Gao Shuai Yuan Yanjun Li Yingzhi liu cheng Huang School of Resources and Civil Engineering Northeastern UniversityShenyang 110819China National-Local Joint Engineering Research Center of High-efficient Exploitation technology for Refractory Iron Ore Resources Shenyang 110819China

The mechanism involved in the phase transformation process of pyrolusite (MnO_(2.) during roasting in a reducing atmosphere was systematically elucidated in this study,with the aim of effectively using low-grade complex manganese ore *** to single-factor experiment results,the roasted product with a divalent manganese (Mn^(2.)) distribution rate of 95.30% was obtained at a roasting time of 2. min,a roasting temperature of 700℃,a CO concentration of 2.at%,and a total gas volume of 500 mL·min^(-1),in which the manganese was mainly in the form of manganosite (MnO).Scanning electron microscopy and Brunauer–Emmett–Teller theory demonstrated the microstructural evolution of the roasted product and the gradual reduction in the pyrolusite ore from the surface to the core Thermodynamic calculations,X-ray photoelectron spectroscopy,and X-ray diffractometry analyses determined that the phase transformation of pyrolusite followed the order of MnO_(2.→Mn_(2.O_(3)→Mn_(3)O_(4)→MnO phase by phase,and the reduction of manganese oxides in each valence state proceeded simultaneously.

关键词： pyrolusite phase transformation reduction roasting microstructural evolution reaction mechanism

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Modulating charge separation and transfer for high-performance photoelectrodes via built-in electric field

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International Journal of Minerals,Metallurgy and materials 2024年第5期31卷 1126-1146页

作者： Houyan cheng Peng liu Yuntao Cui Ru Ya Yuxiang Hu Jinshu Wang key laboratory of Advanced Functional {2. of Education Ministry of China Faculty of Engineering and ManufacturingBeijing University of TechnologyBeijing 100124China key laboratory of Cryogenic Science and {2. and Beijing key Lab of Cryo-Biomedical Engineering Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China Inner Mongolia Academy of Science and technology Hohhot 010020China

Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical ***,considerable efforts have been devoted to this *** review systematically summarizes the impact of built-in electric fields on enhancing charge separation and transfer mechanisms,focusing on the modulation of built-in electric fields in terms of depth and ***,mechanisms and tuning strategies for built-in electric fields are ***,the state-of-the-art works regarding built-in electric fields for modulating charge separation and transfer are summarized and categorized according to surface and interface ***,current strategies for constructing bulk built-in electric fields in photoelectrodes are explored,and insights into future developments for enhancing charge separation and transfer in high-performance photoelectrochemical applications are provided.

关键词： photoelectrochemical water splitting bulk built-in electric field cation intercalation charge separation and transfer

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Intelligent representation method of image flatness for cold rolled strip

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Journal of Iron and Steel Research International 2024年第5期31卷 1177-1195页

作者： Yang-huan Xu Dong-cheng Wang Hong-min liu Bo-wei Duan National Engineering Research Center for Equipment and technology of Cold Strip Rolling Yanshan UniversityQinhuangdao066004HebeiChina National key laboratory of Metal Forming {2. and Heavy Equipment China National Heavy Machinery Research Institute Co.Ltd.Xi’an710018ShaanxiChina State key laboratory of Metastable {2. Science and technology Yanshan UniversityQinhuangdao066004HebeiChina

Real flatness images are the bases for flatness detection based on machine vision of cold rolled *** characteristics of a real flatness image are analyzed,and a lightweight strip location detection(SLD)model with deep semantic segmentation networks is *** interference areas in the real flatness image can be eliminated by the SLD model,and valid information can be *** this basis,the concept of image flatness is proposed for the first *** image flatness representation(IFAR)model is established on the basis of an autoencoder with a new *** optimal structure of the bottleneck layer is 16×16×4,and the IFAR model exhibits a good representation ***,interpretability analysis of the representation factors is carried out,and the difference and physical meaning of the representation factors for image flatness with different categories are *** flatness with new defect morphologies(bilateral quarter waves and large middle waves)that are not present in the original dataset are generated by modifying the representation factors of the no wave ***,the SLD and IFAR models are used to detect and represent all the real flatness images on the test *** average processing time for a single image is 11.42.ms,which is suitable for industrial *** research results provide effective methods and ideas for intelligent flatness detection technology based on machine vision.

关键词： Cold rolled strip Image flatness Location detection Representation learning Bottleneck layer

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