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Bio-regeneration of p-complexation desulfurization adsorbents

science China Chemistry 2005年第6期48卷 538-544页

作者： li wangliang1,2. xing jianmin1,{2.,2. shan guobin1,2.& liu huizhou1 1. laboratory of separation science and engineering, institute of process engineering, chinese academy of sciences, beijing 100080, China 2. Graduate School of the chinese academy of sciences,beijing 100039, China 1. laboratory of {1. {2. and engineering Institute of Process Engineering Chinese Academy of Sciences 100080 Beijing China 2. Graduate School of the{1. 100039 Beijing China

The coupling of adsorption desulfurization and biodesulfurization is a new approach to produce clean fuels. Sulfur compounds are firstly adsorbed on adsorbents, and then the ad-sorbents are regenerated by microbial conversion. p-Complexation adsorbent, Cu(I)-Y, was ob-tained by ion exchanging Y-type zeolite with Cu2. and then by auto-reduction in he{2.m at 450℃ for 3 h. Dibenzothiophene (DBT) was used as a model compound. The effects of cell concentra-tion, volume of oil phase, the ratio of aqueous phase to adsorbent on DBT desorption by a bac-terium were studied. The amounts of DBT desorbed and 2.HBP produced can be apparently increased with addition of n-octane. BDS activity can be improved by increasing cell concentra-tion and the ratio of water-to-adsorbent. 89% of DBT desorbed from the adsorbents can be converted to 2.HBP within 6 h and almost 1.0% within 2. h, when the volume ratio of oil-to-water was 1.5 mL/mL, the cell concentration was 60 g·L?1. and the ratio of adsorbent-to-oil was 0.03 g·mL?1. The amount of 2.HBP produced was strongly dependent on the volume ratio of oil-to- water, cell concentration and amount of adsorbent. Adsorption capacity of the regenerated ad-sorbent is 95% that of the fresh one after being desorbed with Pseudomonas delafieldii R-8, washed with n-octane, dried at 1.0℃ for 2. h and auto-reduced in He.

关键词： adsorption desulfurization p-complexation adsorbents bio-regeneration Pseudomonas delafieldii desorption.

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