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Bio-regeneration of p-complexation desulfurization adsorbents

science{1. Chemistry 2005年第6期48卷 538-544页

作者： li wangliang1,2. xing jianmin1,{2.,2. shan guobin1,{4., institute of process engineering, Chinese Academy of sciences, beijing 100080, china 2. Graduate School of the Chinese Academy of sciences,beijing 100039, china 1. laboratory of {1. {2. and {4. Institute of Process Engineering Chinese Academy of Sciences 100080 Beijing China 2. Graduate School of the Chinese Academy of {1. 100039 Beijing China

The coupling of adsorption desulfurization and biodesulfurization is a new approach to produce clean fuels. Sulfur compounds are firstly adsorbed on adsorbents, and then the ad-sorbents are regenerated by microbial conversion. p-Complexation adsorbent, Cu(I)-Y, was ob-tained by ion exchanging Y-type zeolite with Cu2. and then by auto-reduction in he{2.m at 4.0℃ for 3 h. Dibenzothiophene (DBT) was used as a model compound. The effects of cell concentra-tion, volume of oil phase, the ratio of aqueous phase to adsorbent on DBT desorption by a bac-terium were studied. The amounts of DBT desorbed and 2.HBP produced can be apparently increased with addition of n-octane. BDS activity can be improved by increasing cell concentra-tion and the ratio of water-to-adsorbent. 89% of DBT desorbed from the adsorbents can be converted to 2.HBP within 6 h and almost 1.0% within 2. h, when the volume ratio of oil-to-water was 1.5 mL/mL, the cell concentration was 60 g·L?1. and the ratio of adsorbent-to-oil was 0.03 g·mL?1. The amount of 2.HBP produced was strongly dependent on the volume ratio of oil-to- water, cell concentration and amount of adsorbent. Adsorption capacity of the regenerated ad-sorbent is 95% that of the fresh one after being desorbed with Pseudomonas delafieldii R-8, washed with n-octane, dried at 1.0℃ for 2. h and auto-reduced in He.

关键词： adsorption desulfurization p-complexation adsorbents bio-regeneration Pseudomonas delafieldii desorption.

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