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Synthesis and Characterization of a New Titanium-silicate Material Containing Cage-like Polyhedral Oligosilsesquioxane

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Chemical Research in Chinese Universities 2007年第4期23卷 388-390页

作者： DING Han-ming ZHANG Da-wei li Jiang KONG ai-guo shan Yong-kui Department of Chemistry East China Normal University Shanghai 200062 P. R. China

A new titanium-silicate material was synthesized with cubic cage-like tetramethylammonium octasilicate and TiCl4 ethanol solution as precursors. The product was characterized by FTIR, ^29Si NMR, UV-Vis, and XRD. Struc-tural and ingrediental analyses suggest that this material has a layered structure with cubic cage-like polyhedral oligo-silsesquioxane as building blocks and titanium as bridging atoms.

关键词： Polyhedral oligosilsesquioxane Synthesis Titanium-silicate material

Construction of Orthogonal Arrays without Interaction Columns

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Acta Mathematicae Applicatae Sinica 2022年第1期38卷 159-168页

作者： shan-qi PANG Ya-ping WANG Ming-yao ai School of Mathematics and Information Science Henan Engineering Laboratory for Big Data Statistical Analysis and Optimal ControlHenan Normal UniversityXinxiang 453007China KLATASDS-MOE School of StatisticsEast China Normal UniversityShanghai 200062China LMAM School of Mathematical Sciences and Center for Statistical SciencePeking UniversityBeijing 100871China

In this paper a new class of orthogonal arrays(OAs),i.e.,OAs without interaction columns,are proposed which are applicable in factor screening,interaction detection and other *** the tools of difference matrices,we present some general recursive methods for constructing OAs of such *** families of OAs with high percent saturation are *** particular,for any integerλ≥3,such a two-level OA of run 4λcan always be obtained if the corresponding Hadamard matrix exists.

关键词： complex aliasing difference matrix Hadamard matrix Kronecker sum symmetric array

发芽糙米特征营养、食味品质提升及功能性评价研究进展

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食品科学 2025年第1期46卷 284-292页

作者：任传英洪滨张珊袁迪冯俊然山珊张竞一管立军李波黄文功卢淑雯黑龙江省农业科学院食品加工研究所黑龙江省食品加工重点实验室黑龙江省全谷物营养食品工程技术研究中心黑龙江哈尔滨150086 黑龙江省农业科学院农产品质量安全研究所黑龙江哈尔滨150086

发芽糙米作为一种全谷物,保留了完整的皮层和胚,集中了大部分营养素和功能性活性物质,但由于皮层纤维结构致密,蒸饭过程中阻碍了吸水速率、吸水量和淀粉糊化,与大米相比,其蒸煮性和食用品质较差,且难以同煮同熟,因此一直以来未被广大消... 详细信息

发芽糙米作为一种全谷物,保留了完整的皮层和胚,集中了大部分营养素和功能性活性物质,但由于皮层纤维结构致密,蒸饭过程中阻碍了吸水速率、吸水量和淀粉糊化,与大米相比,其蒸煮性和食用品质较差,且难以同煮同熟,因此一直以来未被广大消费者接受。本文综述糙米发芽的生理代谢反应及发芽过程中营养成分、活性成分和食味品质的变化,总结发芽糙米胁迫富集γ-氨基丁酸(γ-aminobutyric acid,GABA)技术和发芽糙米的功能特性研究现状。糙米发芽过程中,多种生物活性物质在酶促反应下富集,尤其是特征成分GABA含量显著提升。多种逆境胁迫均可通过改变Ca^(2+)、H^(+)或底物水平促进GABA富集,一些预处理技术可进一步提升发芽糙米的食味品质。GABA与其他营养成分和活性成分发挥协同作用,赋予发芽糙米抗高血脂、抗高血糖、保护心脏、改善睡眠、抗炎和抗氧化等一系列功效与作用。

关键词：发芽糙米特征营养食味品质功能性

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Surfactant-enhanced electrochemical detection of bisphenol A based on Au on ZnO/reduced graphene oxide sensor

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Rare Metals 2023年第4期42卷 1274-1282页

作者： ai-Yun Zha Qing-Bing Zha Zhi li Hong-Min Zhang Xue-Feng Ma Wen Xie Ming-shan Zhu Department of Nephrology The First Affiliated Hospital of Jinan UniversityGuangzhou510630China Department of Clinical Laboratory The Fifth Affiliated Hospital of Jinan University(Heyuan Shenhe People’s Hospital)Heyuan517000China Department of Obstetrics and Gynecology The First Affiliated Hospital of Jinan UniversityGuangzhou510630China Guangdong Key Laboratory of Environmental Pollution and Health School of EnvironmentJinan UniversityGuangzhou511443China

Bisphenol A(BPA),one of the most commonly used plastic organic monomers,is widely used in manufacturing food packaging and ***,the gradual emissions of BPA from manufacturing plastic products bring great potential in human health threats,which urgently need to develop a simple and rapid method for detecting *** bromide(CTAB),a typical surfactant,is used to enhance the electrochemical detection of trace endocrine disruptors due to the fact that it can effectively enrich and absorb hydrophobic phenolic compounds through the hydrophobicity of its long-chain *** on these,the present study reports a ternary composite of Au on zinc oxide/reduced graphene oxide nanosheets(Au/ZnO/rGO)as electrochemical sensor for detecting BP *** the addition of CTAB,the analytic performances toward BP A detection are significantly improved 3.8 times compared with those without *** pH,accumulation potential and time are ***,the electrochemical activity of CTAB/Au/ZnO/rGO sensor is also evaluated by cyclic voltammetry(CV),electrochemical impedance spectroscopy(EIS),differential pulse voltammetry(DPV)and scan *** sensor displays two linear range from 10to 1340 nmol·L^(-1)and 1340 to 10,000 nmol·L^(-1),and a low detection limit of 4.95 nmol·L^(-1).Lastly,the sensor also exhibits good reproducibility,selectivity and potential practical application for BPA detection in real samples.

关键词： Bisphenol A(BPA) Cetyltrimethylammonium bromide(TAB) Electrochemical detection(ED) Electron transmission

Carotenoid Metabolism:Biosynthesis,Regulation,and Beyond

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Journal of Integrative Plant Biology 2008年第7期50卷 778-785页

作者： shan Lu li li State Key Laboratory of Pharmaceutical Biotechnology School of Life Sciences Nanjing University Nanjing 210093 China US Department of Agriculture-Agricultural Research Service Plant Soil and Nutrition Laboratory Department of Plant Breeding and Genetics Cornell University Ithaca New York 14853 USA

Carotenoids are indispensable to plants and play a critical role in human nutrition and health. Significant progress has been made in our understanding of carotenoid metabolism in plants. The biosynthetic pathway has been extensively studied. Nearly all the genes encoding the biosynthetic enzymes have been isolated and characterized from various organisms. In recent years, there is an increasing body of work on the signaling pathways and plastid development, which might provide global control of carotenoid biosynthesis and accumulation. Herein, we will highlight recent progress on the biosynthesis, regulation, and metabolic engineering of carotenoids in plants, as well as the future research towards elucidating the regulatory mechanisms and metabolic network that control carotenoid metabolism.

关键词： carotenoids isoprenoids metabolism metabolic engineering plastid regulation.

Isotopic dependence of the yield ratios of light fragments from different projectiles and their unified neutron skin thicknesses

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Nuclear Science and Techniques 2024年第3期35卷 228-236页

作者： Ting-Zhi Yan shan li School of Energy and Power Engineering Northeast Electric Power UniversityJilin 132012China

The yield ratios of neutron-proton(R(n/p))and^(3)H-^(3)He(R(^(3)H∕^(3)He))with reduced rapidity from 0 to 0.5 were simulated at 50 MeV/u even-even ^(36−56)Ca+^(40)Ca,even-even ^(48−78)Ni+^(58)Ni,and ^(100−139)Sn(every third isotopes)+112 Sn for full reduced impact parameters using the isospin-dependent quantum molecular dynamics(IQMD)*** neutron and proton density distributions and root-mean-square radii of the reaction systems were obtained using the Skyrme-Hartree-Fock model,which was used for the phase space initialization of the projectile and target in *** defined the unified neutron skin thickness asΔRnp=^(1∕2) n−^(1∕2)p,which was negative for neutron-deficient *** unifiedΔRnp values for nuclei with the same relative neutron excess from different isotopic chains were nearly equal,except for extreme neutron-rich isotopes,which is a type of scaling *** yield ratios of the three isotopic chain-induced reactions,which depended on the reduced impact parameter and unified neutron skin thickness,were *** results showed that both R(n/p)and R(^(3)H∕^(3)He)decreased with a reduced impact parameter for extreme neutron-deficient isotopes;however,they increased with reduced impact parameters for extreme neutron-rich isotopes,and increased with theΔRnp of the projectiles for all reduced impact *** addition,a scaling phenomenon was observed betweenΔR np and the yield ratios in peripheral colli-sions from different isotopic chain projectiles(except for extreme neutron-rich isotopes).Thus,R(n/p)and R(^(3)H∕^(3)He)from peripheral collisions were suggested as experimental probes for extracting the neutron or proton skin thicknesses of non-extreme neutron-rich nuclei from different isotopic chains.

关键词： Exotic nuclei Unified neutron skin thickness Yield ratios IQMD

Synthesis of FeOOH scaly hollow tubes based on Cu_(2)O wire templates toward high-efficiency oxygen evolution reaction

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Rare Metals 2023年第6期42卷 1836-1846页

作者： Yu Zhang Xue-ai Teng Ze-Qun Ma Rong-Ming Wang Woon-Ming Lau ai-Xian shan Beijing Advanced Innovation Center for Materials Genome Engineering and Center for Green Innovation School of Mathematics and PhysicsUniversity of Science and Technology BeijingBeijing100083China Beijing Advanced Innovation Center for Materials Genome Engineering Beijing Key Laboratory for Magneto-Photoelectrical Composite and Interface ScienceSchool of Mathematics and PhysicsUniversity of Science and Technology BeijingBeijing100083China Shunde Innovation School of University of Science and Technology Beijing Foshan528000China Institute of Materials Science and Devices School of Materials Science and EngineeringSuzhou University of Science and TechnologySuzhou215009China

For catalytic materials,the characteristics of one-dimension and hollowness are the promotion factors for their full presentation of catalytic activity,and through a template-as sis ted method,both above superiorities can be fused ***,we proposed a novel strategy inspired by Pearson's principle with Cu_(2)O wires as templates,and prepared FeOOH hollow tubes,which covered by FeOOH *** applied as oxygen evolution reaction(OER)catalyst,the FeOOH scaly hollow tubes(FeOOH SHTs)showed outstanding catalytic activity with a low overpotential of 245 mV to drive a current density of10 mA·cm^(-2),excellent kinetics manifesting as a low Tafel slope of 46.9 mV·dec^(-1),and robust *** work provides a new synthesis strategy for an ideal OER catalyst,FeOOH,with high inherent activity and enhances the feasibility to broaden the design ideas of transition metalbased catalysts.

关键词： FeOOH scaly hollow tube(SHT) Cu_(2)O wire template One-dimensional(1D)hollow structure Oxygen evolution reaction(OER)

Odor representation and coding by the mitral/tufted cells in the olfactory bulb

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Journal of Zhejiang University-Science B(Biomedicine & Biotechnology) 2024年第10期25卷 824-840页

作者： Panke WANG shan li An’an li School of Biomedical Engineering Guangdong Medical UniversityDongguan 523808China Jiangsu Key Laboratory of Brain Disease and Bioinformation Research Center for Biochemistry and Molecular BiologyXuzhou Medical UniversityXuzhou 221002China

The olfactory bulb(OB)is the first relay station in the olfactory system and functions as a crucial *** can represent odor information precisely and accurately in an ever-changing *** the only output neurons in the OB,mitral/tufted cells encode information such as odor identity and ***,the neural strategies and mechanisms underlying odor representation and encoding in the OB have been investigated *** we review the main progress on this *** first review the neurons and circuits involved in odor representation,including the different cell types in the OB and the neural circuits within and beyond the *** will then discuss how two different coding strategies—spatial coding and temporal coding—work in the rodent ***,we discuss potential future directions for this research ***,this review provides a comprehensive description of our current understanding of how odor information is represented and encoded by mitral/tufted cells in the OB.

关键词： Olfactory bulb Mitral/tufted cells Odor identity Neural representation Information encoding

Global Existence and Uniqueness of Weak Solution to Nonlinear Viscoelastic Full Marguerre-von Kármán Shallow Shell Equations

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Acta Mathematica Sinica,English Series 2009年第12期25卷 2133-2156页

作者： Fu shan li School of Mathematical Sciences Qufu Normal University Qufu 273165 P. R. China

By Galerkin finite element method, we show the global existence and uniqueness of weak solution to the nonlinear viscoelastic full Marguerre-von Karman shallow shell equations.

关键词： global solution viscoelastic Marguerre-von Karman shallow shell