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Catalyst-free and Reprocessable Aromatic Polydithiourethanes

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Chinese Journal of Polymer Science 2024年第10期42卷 1435-1441,I0007页

作者： Bo Yang hai-Jun Feng tian-tian Ni Xiao-Rui Zhou Tao Xie Ning Zheng State Key Laboratory of Chemical Engineering College of Chemical and Biological EngineeringZhejiang UniversityHangzhou310058China Department of Colorectal Surgery and Oncology Key Laboratory of Cancer Prevention and InterventionMinistry of EducationThe Second Affiliated HospitalZhejiang University School of MedicineHangzhou310009China

The incorporation of dynamic covalent bonds into thermosets facilitates the reprocessing of polymer networks,thereby meeting the sustainable requirements for polymer ***,the mechanical properties of many materials often decline significantly upon reprocessing due to side reactions caused by harsh processing *** this work,we find that the aromatic dithiocarbamate bond can undergo dissociation under mild conditions without the need for a catalyst,enabling the efficient reprocessing of the corresponding *** a consequence,the mechanical properties of the polydithiourethane can be largely preserved after *** discovery of this dynamic chemistry is anticipated to broaden the potential for material design in dynamic covalent polymer networks.

关键词： Reprocessing Polydithiourethane Dynamic covalent bond

Improving the Forecasts of Coastal Wind Speeds in tianjin,China Based on the WRF Model with Machine Learning Algorithms

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Journal of Meteorological Research 2024年第3期38卷 570-585页

作者： Weihang ZHANG Meng tian Shangfei hai Fei WANG Xiadong AN Wanju LI Xiaodong LI Lifang SHENG College of Oceanic and Atmospheric Sciences Ocean University of ChinaQingdao266100China tianjin Key Laboratory for Oceanic Meteorology Tianjin Institute of Meteorological ScienceTianjin300074China CMA Earth System Modeling and Prediction Centre China Meteorological Administration(CMA)Beijing100081China Qingdao Meteorological Bureau Qingdao266003China

Characterized by sudden changes in strength,complex influencing factors,and significant impacts,the wind speed in the circum-Bohai Sea area is relatively challenging to *** the western side of Bohai Bay,as the economic center of the circum-Bohai Sea,tianjin exhibits a high demand for accurate wind *** this study,three machine learning algorithms were employed and compared as post-processing methods to correct wind speed forecasts by the Weather Research and Forecast(WRF)model for *** results showed that the random forest(RF)achieved better performance in improving the forecasts because it substantially reduced the model bias at a lower computing cost,while the support vector machine(SVM)performed slightly worse(especially for stronger winds),but it required an approximately 15 times longer computing *** back propagation(BP)neural network produced an average forecast significantly closer to the observed forecast but insufficiently reduced the *** regard to wind speed frequency forecasting,the RF method commendably corrected the forecasts of the frequency of moderate(force 3)wind speeds,while the BP method showed a desirable capability for correcting the forecasts of stronger(force>6)*** addition,the 10-m u and v components of wind(u_(10)and v_(10)),2-m relative humidity(RH_(2))and temperature(T_(2)),925-hPa u(u925),sea level pressure(SLP),and 500-hPa temperature(T_(500))were identified as the main factors leading to bias in wind speed forecasting by the WRF model in tianjin,indicating the importance of local dynamical/thermodynamic processes in regulating the wind *** study demonstrates that the combination of numerical models and machine learning techniques has important implications for refined local wind forecasting.

关键词： machine learning Weather Research and Forecast(WRF)model wind speed forecasting coastal region

One-step conversion of methane and formaldehyde to ethanol over SA-FLP dual-active-site catalysts: A DFT study

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Chinese Chemical Letters 2024年第4期35卷 544-548页

作者： Tao Ban Xi-Yang Yu hai-Kuo tian Zheng-Qing Huang Chun-Ran Chang Shaanxi Key Laboratory of Energy Chemical Process Intensification School of Chemical Engineering and TechnologyXi'an Jiaotong UniversityXi'an 710049China Shaanxi Key Laboratory of Low Metamorphic Coal Clean Utilization School of Chemistry and Chemical EngineeringYulin UniversityYulin 719000China

One-step conversion of methane and formaldehyde into ethanol is a 100% atom-efficient process for carbon resources utilization and environment protection but still faces eminent challenges due to the lacking of efficient catalysts. Therefore, developing active and stable catalysts is crucial for the co-conversion of methane and formaldehyde. Herein, twelve kinds of “Single-Atom”-“Frustrated Lewis Pair”(SA-FLP)dual-active-site catalysts are designed for the direct conversion of methane and formaldehyde to ethanol based on density functional theory(DFT) calculations and microkinetic simulations. The results show that the SA-FLP dual active sites can simultaneously activate methane at the SA site and activate formaldehyde at the FLP site. Among the twelve designed SA-FLP catalysts, Fe1-FLP shows the best performance in the co-conversion of methane and formaldehyde to ethanol with the rate-determining barrier of 1.15 e *** is proved as the main product with the turnover frequency of 1.32 × 10^(-4)s^(-1)at 573 K and 3 *** work provides a universal strategy to design dual active sites on metal oxide materials and offers new insights into the effective conversion of methane and formaldehyde to desired C_(2) chemicals.

关键词： Single-atom Frustrated Lewis pairs Methane conversion Dual active sites Ethanol synthesis

Interpretation and characterization of rate of penetration intelligent prediction model

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Petroleum Science 2024年第1期21卷 582-596页

作者： Zhi-Jun Pei Xian-Zhi Song hai-Tao Wang Yi-Qi Shi Shou-Ceng tian Gen-Sheng Li College of Petroleum Engineering China University of Petroleum(Beijing)Beijing102249China State Key Laboratory of Petroleum Resources and Prospecting Beijing102249China Kunlun Digital Technology Co. Ltd.Beijing102206China

Accurate prediction of the rate of penetration(ROP)is significant for drilling *** the intelligent ROP prediction model based on fully connected neural networks(FNN)outperforms traditional ROP equations and machine learning algorithms,its lack of interpretability undermines its *** study proposes a novel interpretation and characterization method for the FNN ROP prediction model using the Rectified Linear Unit(ReLU)activation *** leveraging the derivative of the ReLU function,the FNN function calculation process is transformed into vector *** FNN model is linearly characterized through further simplification,enabling its interpretation and *** proposed method is applied in ROP prediction scenarios using drilling data from three vertical wells in the Tarim *** results demonstrate that the FNN ROP prediction model with ReLU as the activation function performs exceptionally *** relative activation frequency curve of hidden layer neurons aids in analyzing the overfitting of the FNN ROP model and determining drilling data *** the well sections with similar drilling data,averaging the weight parameters enables linear characterization of the FNN ROP prediction model,leading to the establishment of a corresponding linear representation ***,the quantitative analysis of each feature's influence on ROP facilitates the proposal of drilling parameter optimization schemes for the current well *** established linear characterization equation exhibits high precision,strong stability,and adaptability through the application and validation across multiple well sections.

关键词： Fully connected neural network Explainable artificial intelligence Rate of penetration ReLU active function Deep learning Machine learning

Visual test paper based on Au/δ-MnO_(2) hollow nanosphere oxidase-like activity regulation using hexavalent chromium as a smart switch

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Rare Metals 2024年第2期43卷 711-722页

作者： Wen-Chang Zhuang hai-Yue Zhang Zhen-Yang Chen Wen-Jing Cheng Wei-Dan Na Zhao Li Lin tian School of Materials and Chemical Engineering Xuzhou University of TechnologyXuzhou221018China School of Chemistry and Environmental Science Yili Normal UniversityYining835000China

Paper-based sensing platform is a point of need analytical toolkit for safety ***,the sensitivity,specificity,and simplicity are still ***,we report a novel strategy(Au/δ-MnO_(2) hollow nanosphere and 3,3′,5,5′-tetramethylbenzidine(TMB)induced test strips for signal-on detection)that can be utilized for hexavalent chromium(Cr^(6+))***,Cr^(6+)(CrO_(4)^(2−)) as a smart switch can remarkably enhance the oxidase-like activity of Au/δ-MnO_(2) hollow *** presence of Cr^(6+) can regulate the surface electronic redistribution of Au/δ-MnO_(2) and adjust the geometric configuration,which leads to the improvement in oxidase-like activity of Au/δ-MnO_(2).As a proof-of-concept application,a visual paper-based sensing platform of Cr^(6+) along with quantitative analysis by the test strips was successfully *** paper-based sensing platform exhibits a linear range with excellent selectivity for other interfering substances and lower limit of detection of 0.09μmol·L^(−1),providing a promising toolkit at-home Cr^(6+) measurement and environmental monitoring.

关键词： Point of need Colorimetric biosensing platform Au/δ-MnO_(2) hollow nanosphere Test strip Cr^(6+)

Development of lithium-free P2-type high-sodium content cathode materials with enhanced cycle and air stability for sodium-ion batteries

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Rare Metals 2024年第1期43卷 113-123页

作者： Jin-Lv tian Lin-Rong Wu hai-Jun Zhao Shou-Dong Xu Liang Chen Ding Zhang Xiao-Chuan Duan College of Chemical Engineering and Technology Taiyuan University of TechnologyTaiyuan 030024China College of Chemistry Taiyuan University of TechnologyTaiyuan 030024China School of Chemical Engineering and Pharmacy Wuhan Institute of TechnologyWuhan 430205China

The effect of partial substitution of Mg for Ni on a high-sodium and lithium-free layered P2-type Na_(45/54)Mg_(6)/_(54)Ni_(12/54)Mn_(34/54)O_(2) cathode with high initial Coulombic efficiency and excellent cyclic stability has been investigated in this *** on the crystal structural analysis,the Mg doping can retain the P2 structure up to 4.3 V,thus restraining the detrimental phase transformation of P2-02during the Na-ion intercalation/deintercalation ***,the obtained Mg-doped P2-type cathode exhibits a reversible specific capacity of 109 mAh·g^(-1) at 0.1C between 2.0 and 4.3 V and a retention rate of 81.5% after 200cycles at *** addition,the full cell consisting of Mg-doped P2-type cathode and hard carbon anode shows a capacity retention rate of 85.6% after 100 *** study provides new insight into the development of durable cathode materials for sodium-ion batteries.

关键词： Sodium-ion batteries Cathode material High sodium content Air stability

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经桡动脉穿刺的冠状动脉介入治疗

中国介入心脏病学杂志 2002年第3期10卷 135-137页

作者：洪涛 koh tian hai Charles Chan Lim Yean-Leng 北京大学第一医院心内科 100034 National Heart Centre of Singapore

目的　探讨经桡动脉穿刺行冠状动脉介入治疗的可行性和安全性。方法　 116例冠心病患者 (男 96例 ,女 2 0例 ,平均年龄 5 7 44± 9 40岁 )经桡动脉穿刺行冠状动脉介入治疗。结果　 5例桡动脉穿刺失败改行股动脉穿刺 ,2例桡动脉穿刺虽成... 详细信息

目的　探讨经桡动脉穿刺行冠状动脉介入治疗的可行性和安全性。方法　 116例冠心病患者 (男 96例 ,女 2 0例 ,平均年龄 5 7 44± 9 40岁 )经桡动脉穿刺行冠状动脉介入治疗。结果　 5例桡动脉穿刺失败改行股动脉穿刺 ,2例桡动脉穿刺虽成功但试行球囊扩张失败 ,其余患者均取得穿刺和介入治疗成功。共扩张病变血管 135支 (前降支 6 9支 ,回旋支 2 6支 ,右冠状动脉 39支 ,静脉桥血管1支 ) ,治疗病变 148处 (A型 15处 ,B型 10 6处 ,C型 2 7处 )。 98例患者的 10 5支血管植入支架共 110个 ,1例行旋磨术 ,1例行冠状动脉内超声检查。 2 5例患者术中须更换导引导管。术后穿刺局部大量出血需输血者 1例 ,局部较大血肿 2例 ,肘动脉分支穿孔 1例。结论　经桡动脉穿刺行冠状动脉介入治疗在临床上可行 ,但穿刺较困难 ,导引导管支撑力较差 ,应警惕局部血管损伤的可能。

关键词：经桡动脉穿刺介入治疗冠心病安全性

Effect of heat treatment on corrosion behaviors of Mg-6Gd-3Y-0.5Zr alloy

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China Foundry 2024年第5期21卷 599-612页

作者： Fei Wang Bin-guo Fu Yu-feng Wang tian-shun Dong Guo-lu Li Jin-hai Liu Hebei Key Laboratory of New Functional Materials School of Materials Science and EngineeringHebei University of TechnologyTianjin 300401China tianjin Institute of Aerospace Mechanical and Electrical Equipment Tianjin 300301China tianjin Aerospace Long March Technology and Equipment Co. Ltd.Tianjin 300462China

The microstructures and corrosion behaviors of as-cast,T4-treated,and T6-treated Mg-6Gd-3Y-0.5Zr alloys were systematically investigated by SEM,TEM,immersion test,and electrochemical corrosion *** results show that the microstructure of the as-cast alloy is composed ofα-Mg and Mg_(24)(Gd,Y)_(5)eutectic phase,and in T4-treated alloy,Mg_(24)(Gd,Y)_(5)phase dissolves into theα-Mg matrix,leading to an increase in the(Y,Gd)H_(2)*** T6 treatment,nanoscale Mg_(24)(Gd,Y)_(5)phase dispersedly precipitates from theα-Mg matrix,and exhibits a specific orientation relationship with theα-Mg:(332)Mg_((24)(Gd,Y)_(5))//(1011)_(α-Mg),[136]Mg_((24)(Gd,Y)_(5))//[1210]_(α-Mg).The corrosion resistance of the Mg-6Gd-3Y-0.5Zr alloys can be ranked in the following order:T6-treated alloy exhibits the highest corrosion resistance,followed by the T4-treated alloy,and finally,the as-cast *** corrosion products of the alloys are all composed of MgO,Mg(OH)_(2),Gd_(2)O_(3),Y_(2)O_(3),and MgCl_(2).The corrosion behavior of Mg-6Gd-3Y-0.5Zr alloy is closely related to the precipitated *** establishing the relationship between corrosion rate,hydrogen evolution rate,and corrosion potential,it is further demonstrated that during the micro galvanic corrosion process,the coarse Mg_(24)(Gd,Y)_(5)phase in the as-cast alloy undergoes extensive dissolution,and(Y,Gd)H_(2)phase promotes the dissolution of theα-Mg matrix in the T4-treated alloy,intensifying the hydrogen evolution *** T6-treated alloy,with dispersive precipitation of nanoscale Mg_(24)(Gd,Y)_(5)phase,exhibits better corrosion resistance performance.

关键词： Mg-6Gd-3Y-0.5Zr alloy heat treatment microstructure precipitated phase corrosion resistance

Accelerating Asteroidal Period and Pole Inversion from Multiple Lightcurves Using Parallel Differential Evolution and Cellinoid Shape Model

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Research in Astronomy and Astrophysics 2024年第4期24卷 271-286页

作者： Yong-Xiong Zhang Wen-Xiu Guo Xiao-Ping Lu Hua Zheng hai-Bin Zhao Jun tian Wei-Lin Wang School of Engineering Guangzhou College of Technology and BusinessGuangzhou 510850China School of Computer Science and Engineering Macao University of Science and TechnologyTaipaMacao 999078China School of Mathematics and Statistics Shaoguan UniversityShaoguan 512099China State Key Laboratory of Lunar and Planetary Sciences Macao University of Science and TechnologyMacao 999078China Key Laboratory of Planetary Sciences Purple Mountain ObservatoryCASNanjing 210023China

Determining asteroid properties provides valuable physical insights but inverting them from photometric lightcurves remains computationally *** paper presents a new approach that combines a simplified Cellinoid shape model with the Parallel Differential Evolution(PDE)algorithm to accelerate *** PDE algorithm is more efficient than the Differential Evolution algorithm,achieving an extraordinary speedup of 37.983 with 64 workers on multicore *** PDE algorithm accurately derives period and pole values from simulated *** analysis of real asteroid lightcurves validates the method’s reliability:in comparison with results published elsewhere,the PDE algorithm accurately recovers the rotational periods and,given adequate viewing geometries,closely matches the pole *** PDE approach converges to solutions within 20,000 iterations and under one hour,demonstrating its potential for large-scale data *** work provides a promising new tool for unveiling asteroid physical properties by overcoming key computational bottlenecks.

关键词： methods:numerical minor planets asteroids:general techniques:photometric astrom