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Tungsten-based nanocatalysts with different structures for visible light responsive photocatalytic degradation of bisphenol A

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Journal of Environmental Sciences 2024年第5期139卷 569-588页

作者： Hai Bang Truong Thi Thu Loan Doan Nguyen Tien Hoang Nguyen Van Tam Minh kim Nguyen Le Gia Trung Jin Seog Gwag Nguyen Tien tran Optical Materials Research Group Science and Technology Advanced InstituteVan Lang UniversityHo Chi Minh CityViet Nam Faculty of Applied Technology School of TechnologyVan Lang UniversityHo Chi Minh CityViet Nam The University of Da Nang University of Science and Technology54 Nguyen Luong BangDa NangViet Nam The University of Da Nang University of Science and Education459 Ton Duc Thang St.Lien ChieuDa Nang 550000Viet Nam Institute of Veterinary Science and Technology 31ha zoneTrau QuyGia LamHa Noi 12400Viet Nam Department of Physics Yeungnam UniversityGyeongsanGyeongbuk 38541Republic of Korea Center for Advanced Chemistry Institute of Research and DevelopmentDuy Tan University03 Quang TrungDa Nang 550000Viet Nam Faculty of Natural Sciences Duy Tan University03 Quang TrungDa Nang 550000Viet Nam

Environmental pollution,such as water contamination,is a critical issue that must be absolutely ***,three different morphologies of tungsten-based photocatalysts(WO_(3)nanorods,WO_(3)/WS_(2)nanobricks,WO_(3)/WS_(2)nanorods)are made using a simple hydrothermal method by changing the solvents(H_(2)O,DMF,aqueous HCl solution).The as-prepared nanocatalysts have excellent thermal stability,large porosity,and high *** results show all materials have good photocatalytic activity in aqueous media,with WO_(3)/WS_(2)nanorods(NRs)having the best activity in the photodegradation of bisphenol A(BPA)under visible-light *** may originate from increased migration of charge carriers and effective prevention of electron–hole recombination in WO_(3)/WS_(2)NRs,whereby this photocatalyst is able to generate more reactive·OH and·O_(2)^(–)species,leading to greater photocatalytic *** 99.6% of BPA is photodegraded within 60 min when using 1.5 g/L WO_(3)/WS_(2)NRs and 5.0 mg/L BPA at pH ***,the optimal conditions(pH,catalyst dosage,initial BPA concentration)for WO_(3)/WS_(2)NRs are also elaborately *** rod-like heterostructures are expressed as potential catalysts with excellent photostability,efficient reusability,and highly active effectivity in different types of *** particular,the removal efficiency of BPA by WO_(3)/WS_(2)NRs reduces by only 1.5% after five recycling runs and even reaches 89.1%in contaminated lake *** study provides promising insights for the nearly complete removal of BPA from wastewater or different water resources,which is advantageous to various applications in environmental remediation.

关键词： Photodegradation Bisphenol A Tungsten-based nanocatalyst Structure Nanorod

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Stable operation of highly loaded pure Si-Fe anode under ambient pressure via carboxy silane-directed robust solid electrolyte interphase

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Journal of Energy Chemistry 2024年第7期94卷 568-576页

作者： Guntae Lim Dong Guk Kang Hyeon Gyu Lee Yen Hai Thi tran Kihun An Junghyun Choi Kwang Chul Roh Do Youb kim Seung-Wan Song Department of Chemical Engineering&Applied Chemistry Chungnam National University Daejeon 34134Republic of Korea Energy Storage Materials Center Korea Institute of Ceramic Engineering&TechnologyJinju 52851Republic of Korea Advanced Energy Materials Research Center Korea Research Institute of Chemical TechnologyDaejeon 34114Republic of Korea

Incorporation of higher content Si anode material beyond 5 wt% to Li-ion batteries(LIBs)is challenging,owing to large volume change,swelling,and solid electrolyte interphase(SEI)instability ***,a strategy of diacetoxydimethylsilane(DAMS)additive-directed SEI stabilization is proposed for a stable operation of Si-0.33FeSi_(2)(named as Si-Fe)anode without graphite,which provides siloxane inorganics and organics enrichment that compensate insufficient passivation of fluoroethylene carbonate(FEC)additive and reduce a dependence on *** stable cycling performance of highly loaded(3.5 mA h cm^(-2))pure Si-Fe anode is achieved with 2 wt%DAMS combined with 9 wt%FEC additives under ambient pressure,yielding high capacity 1270 mA h g^(-1)at 0.5 C and significantly improved capacity retention of 81% after 100 cycles,whereas short circuit and rapid capacity fade occur with FEC only ***-directed robust SEI layer dramatically suppresses swelling and particles crossover through separator,and therefore prevents short circuit,demonstrating a possible operation of pure Si or Sidominant anodes in the next-generation high-energy-density and safe LIBs.

关键词： High-energy Li-ion battery Pure Si-Fe anode without graphite Silane additive SEI layer Suppressed swelling

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Liquid Metal Grid Patterned Thin Film Devices Toward Absorption‑Dominant and Strain‑Tunable Electromagnetic Interference Shielding

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Nano-Micro Letters 2024年第11期16卷 541-553页

作者： Yuwen Wei Priyanuj Bhuyan Suk Jin Kwon Sihyun kim Yejin Bae Mukesh Singh Duy Thanh tran Minjeong Ha Kwang‑Un Jeong Xing Ma Byeongjin Park Sungjune Park Department of Polymer‑Nano Science and Technology Department of Nano Convergence EngineeringJeonbuk National UniversityJeonju 54896Republic of Korea School of Chemical Engineering Sungkyunkwan University(SKKU)Suwon 16419Republic of Korea Composites Research Division Korea Institute of Materials ScienceChangwon 51508Republic of Korea School of Materials Science and Engineering Gwangju Institute of Science and TechnologyGwangju 61005Republic of Korea School of Materials Science and Engineering and Sauvage Laboratory for Smart MaterialsHarbin Institute of Technology(Shenzhen)ShenzhenGuangdong 518055People’s Republic of China

The demand of high-performance thin-film-shaped deformable electromagnetic interference(EMI)shielding devices is increasing for the next generation of wearable and miniaturized soft *** highly reflective conductive materials can effectively shield EMI,they prevent deformation of the devices owing to rigidity and generate secondary electromagnetic pollution ***,soft and stretchable EMI shielding thin film devices with absorption-dominant EMI shielding behavior is *** devices consist of liquid metal(LM)layer and LM grid-patterned layer separated by a thin elastomeric film,fabricated by leveraging superior adhesion of aerosol-deposited LM on *** devices demonstrate high electromagnetic shielding effectiveness(SE)(SE_(T) of up to 75 dB)with low reflectance(SER of 1.5 dB at the resonant frequency)owing to EMI absorption induced by multiple internal reflection generated in the LM grid ***,the excellent stretchability of the LM-based devices facilitates tunable EMI shielding abilities through grid space adjustment upon strain(resonant frequency shift from 81.3 to 71.3 GHz@33%strain)and is also capable of retaining shielding effectiveness even after multiple strain *** newly explored device presents an advanced paradigm for powerful EMI shielding performance for next-generation smart electronics.

关键词： Absorption-dominant electromagnetic interference shielding Liquid metals Soft and stretchable electronics Thin film devices Tunable electromagnetic interference shielding

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Highly enhanced UV absorption and light emission of monolayer WS_(2)through hybridization with Ti_(2)N MXene quantum dots and g-C_(3)N_(4)quantum dots

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Opto-Electronic Advances 2024年第6期7卷 31-39页

作者： Anir S.Sharbirin Rebekah E.Kong Wendy B.Mato trang Thu tran Eunji Lee Jolene W.P.Khor Afrizal L.Fadli Jeongyong kim Department of Energy Science Sungkyunkwan UniversitySuwon 16419Republic of Korea

Two-dimensional(2D)transition metal dichalcogenides(TMD)are atomically thin semiconductors with promising optoelectronic applications across the visible ***,their intrinsically weak light absorption and the low photoluminescence quantum yield(PLQY)restrict their performance and potential use,especially in ultraviolet(UV)wavelength light *** dots(QD)derived from 2D materials(2D/QD)provide efficient light absorption and emission of which energy can be tuned for desirable light *** this study,we greatly enhanced the photon absorption and PLQY of monolayer(1L)tungsten disulfide(WS_(2))in the UV range via hybridization with 2D/QD,particularly titanium nitride MXene QD(Ti_(2)N MQD)and graphitic carbon nitride QD(GCNQD).With the hybridization of MQD or GCNQD,1LWS_(2)showed a maximum PL enhancement by 15 times with 300 nm wavelength excitation,while no noticeable enhancement was observed when the excitation photon energy was less than the bandgap of the QD,indicating that UV absorption by the QD played a crucial role in enhancing the light emission of 1L-WS_(2)in our 0D/2D hybrid *** findings present a convenient method for enhancing the photo-response of 1L-WS_(2)to UV light and offer exciting possibilities for harvesting UV energy using 1L-TMD.

关键词： monolayer TMD WS_(2) 2D-derived quantum dots UV absorption energy transfer

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Epidemiology and Clonal Spread Evidence of Carbapenem-Resistant Organisms in the Center of Care and Protection of Orphaned Children, Vietnam

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Open Journal of Medical Microbiology 2024年第3期14卷 165-189页

作者： Van kim Nguyen Pirom Noisumdaeng Pol. Maj. Katiya Ivanovitch Stephen Baker Eugene Athan Stephanie Jones Le Thi Lan Larry Croft Yin Peng Lee Tara Cassidy Van Hung tran Thi Hang Phan Huu Tinh Ho Faculty of Public Health Thammasat University Bangkok Thailand Department of Prevention and Infection Control Hung Vuong Hospital HCM City Vietnam Microbiology of Faculty of Public Health Thammasat University Bangkok Thailand Thammasat University Research Unit in Modern Microbiology and Public Health Genomics Thammasat University Bangkok Thailand National Heart & Lung Institute (NHLI) University of Cambridge Cambridge UK Barwon South West Public Health Unit Geelong Australia Center for Innovation in Infectious Disease and Immunology Research (CIIDIR) Geelong Australia School of Medicine Deakin University Burwood Australia Monash Health Berwick Australia Center of Care and Protection of Orphaned Children HCM City Vietnam Charles River Laboratories Microbial Solutions Melbourne Australia Personnel Department of Nhan Dan Gia Dinh Hospital HCM City Vietnam Hung Vuong Hospital HCM City Vietnam Department of Epidemiology Institute of Public Health HCM City Vietnam

Objective: To determine the prevalence of colonization and transmission of carbapenem-resistant Gram-negative organisms in order to develop of an effective infection prevention program. Design: Cross-sectional study with carbapenem-resistant organisms (CRO) colonization detection from the fecal specimens of 20 Health Care Workers (HCWs) and 67 residents and 175 random environment specimens from September 2022 to September 2023. Setting: A Care and Protection Centre of Orphaned Children in South of HCM City. Participants: It included 20 HCWs, 67 residents, and 175 randomly collected environmental specimens. Method: Rectal and environmental swabs were collected from 20 HCWs, 67 residents (most of them were children), and 175 environmental specimens. MELAB Chromogenic CARBA agar plates, Card NID, and NMIC-500 CPO of the BD Phoenix TM Automated Microbiology System and whole genome sequencing (WGS) were the tests to screen, confirm CROs, respectively and determine CRO colonization and transmission between HCWs, residents, and the environment. Result: We detected 36 CRO isolates, including 6, 11 and 19 CROs found in 6 HCWs, 10 residents and 19 environments. The prevalence of detectable CRO was 30% (6/20) in HCWs, 14.92% (10/67) in residents, and 10.86% (19/175) in environmental swabs in our study. WGS demonstrated CRO colonization and transmission with the clonal spread of E. coli and A. nosocomialis, among HCWs and residents (children). Conclusion: Significant CRO colonization and transmission was evident in HCWs, residents, and the center environment. Cleaning and disinfection of the environment and performing regular hand hygiene are priorities to reduce the risk of CRO colonization and transmission.

关键词： Carbapenem-Resistant Organisms Contamination Hand Hygiene Whole Genome Sequencing Infection Prevention

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Synthesis and characterization of core/shell structured nanophosphors CePO_4:Tb@LaPO_4 by solvothermal method

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Journal of Rare Earths 2011年第12期29卷 1147-1151页

作者： Dinh Xuan Loc tran Thi kim Chi tran Thu Huong Nguyen Vu tran kim Anh Wieslaw Strek Le Quoc Minh Institute of Materials Science Vietnam Academy of Science and Technology Institute of Low Temperature and Structure Research Polish Academy of Sciences(PAN) University of Engineering and Technology

Core/shell structured CePO4：Tb（Ⅲ）@LaPO4 and CePOa：Tb（Ⅲ） were successfully synthesized in tris（2-ethylhexyl） phosphate （TEHP） and diethylene glycol （DEG） solvents for comparison of the two techniques in open air and closed reaction vessel. Morphology and crystal structure of the core/shell nanophosphors were determined by using X-ray diffraction （XRD） and transmission electron microscopy （TEM）, which showed that nanophosphors had diameter of about 5-10 nm with the monoclinic monazite phase. The nanophosphors obtained by close vessel procedure showed smaller size, more homogeneity and pure crystallite. The luminescent measurements were done upon the different excitation wavelengths in ultraviolet region and at room temperatm＇e to elucidate the influences of the used solvents and the reaction temperatures. It was found that CePO4：Tb@LaPO4 preparedby the close vessel synthesis showed the intensity of green band of the transfer from 5D4 to 7F5 energy level, which was strongly increased, and the luminescent decay time was 3.2 ms, which was longer than that of naked CePO4：Tb phosphor.

关键词： solvothermal synthesis luminescence CePOn:Tb CePOa:Tb@LaPO4 rare earths

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Highly active brookite TiO2-assisted photocatalytic degradation of dyes under the simulated solar-UVA radiation

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Progress in Natural Science:Materials International 2019年第6期29卷 641-647页

作者： Huyen tran Thi Thuong Chi tran Thi kim Liem Nguyen Quang Hendrik Kosslick Institute of Materials Science (IMS) Vietnam Academy of Science and Technology (VAST) University of Rostock Institute of Chemistry Department of Inorganic Chemistry

Brookite TiO2nanoparticles were synthesized by hydrothermal method and characterized by X-ray powder diffraction(XRD), diffuse reflectance UV–Visible spectroscopy(DRUV), and scanning electron microscopy(SEM). The obtained particles were spherical in shape with the diameter of about ～10 nm under the hydrothermal temperature of 175 °C. The photocatalytic performance of brookite was investigated in the photodegradation of dyes(rhodamine B and rose bengal) under UV-A radiation by low-power lamp. The activity of brookite and the photodegradation efficiency of dyes were estimated using a UV–Visible spectrophotometer and a total organic carbon(TOC) analyzer. Compared to anatase and rutile prepared by the similar synthesis procedure, brookite is highly active in terms of decolourization, aromatic ring opening, and mineralization.

关键词： Brookite Anatase Dye Photocatalytic degradation Decolourization Mineralization

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Fabrication and characterization of YVO_4:Eu^(3+) nanomaterials by the microwave technique

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Journal of Rare Earths 2011年第12期29卷 1137-1141页

作者： tran Thu Huong Vu Duc Tu tran kim Anh Le Thi Vinh Le Quoc Minh Institute of Materials Science Vietnamese Academy of Science and Technology University of Engineering and Technology National University Hanoi Departments of Chemistry Hanoi University of Mining and Geology

Fabrication and characterization of YVO4：Eu^3＋ nanophosphors prepared by microwave （MW） irradiation assisted soft template synthesis were reported. The effects of synthesis conditions such as different powers of MW irradiation, pH values and concentration of reac- tion materials on properties of nanophosphor were also investigated to obtain the controllable size, morphology and high luminescence efficiency. Morphology, crystalline structure, and optical properties were characterized by field emission scanning electron microscopy （FE-SEM）, X-ray diffraction （XRD） and fluorescence spectroscopy, respectively. The results showed that YVOa：Eu^3＋ nanophosphors were obtained by using diethyleneglycol （DEG） as soft template, with pH values in the range of 4 to 12, upon microwave irradiation from 300 to 900 W, at temperature of 80 ℃. The high fluorescent YVOa：Eu^3＋ nanocrystals obtained with size from 15 nm down to 8 nm are more effective to develop an ultrahigh sensitive fluorescent label for biomolecule, cell and tissue.

关键词： microwave synthesis method DEG soft template YVO4:Eu^3+ nanophosphor luminescence rare earths

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Monte Carlo simulation of a cone-beam CT system for lightweight casts

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Radiation Detection Technology and Methods 2021年第4期5卷 504-512页

作者： Thuy Duong tran Ngoc Ha Bui kim tua. tran Ngoc Toan tran Department of Nuclear Engineering and Environmental Physics School of Engineering PhysicsHanoi University of Science and Technology01 Dai Co VietHai Ba TrungHanoiVietnam Vietnam Atomic Energy Institute 59 Ly Thuong KietHoan KiemHanoiVietnam

Cone-beam computed tomography(CBCT),a modern technique with many applications,is becoming increasingly important and essential in many areas of economics and *** equipment has been commercialized in both hardware and ***,having a device system suitable for a specific group of objects will be the *** work used Monte Carlo simulation to optimize the design of a Cone-beam Computed Tomography(CBCT)for lightweight and small-size *** affecting image quality such as radiation-source,flat-panel detector,and geometrical distance were *** results indicate that an X-ray generator with a focal spot size of 4×4µm^(2),high voltage of 240 kV,and a radiation intensity of 10^(13) photon/s with a flat panel CsI(Tl)detector of 0.3 mm thickness and a pixel size of 0.1–0.2 mm,is suitable for a CBCT to inspect small objects in *** Monte Carlo model was validated against experiments and to evaluate some characteristics of the existing system.

关键词： Cone-beam computed technology Monte Carlo simulation Lightweight casts in industry Applied radiation

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奉祀天后圣母的研究--以越南芹苴市华人的天后圣母信仰为例

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妈祖文化研究 2024年第1期 25-33页

作者： [越南]阮福才陈氏金黄 FPT大学越南芹苴26132 坚江师范学院越南坚江83000

本文以芹苴市华人奉祀天后圣母为研究对象,探讨了这一文化的特征、形成原因和社会意义,分析了芹苴市华人奉祀天后圣母的组成要素、内在逻辑和外在表现发现,这一文化是华人社区对中国传统文化的继承和创新,也是对越南多元文化的融入和贡... 详细信息

本文以芹苴市华人奉祀天后圣母为研究对象,探讨了这一文化的特征、形成原因和社会意义,分析了芹苴市华人奉祀天后圣母的组成要素、内在逻辑和外在表现发现,这一文化是华人社区对中国传统文化的继承和创新,也是对越南多元文化的融入和贡献。本文认为,芹苴市华人奉祀天后圣母是华人社会意识的反映,也是华人社会实践的指导,体现了华人对生存环境的适应和改造。同时指出,天后圣母的当地信仰满足了华人的精神需求,增强了华人的社会凝聚力,促进了华人与越南社会的和谐共处。

关键词：越南华人妈祖文化跨文化交流

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