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Highly active brookite TiO2-assisted photocatalytic degradation of dyes under the simulated solar-UVA radiation

Highly active brookite TiO2-assisted photocatalytic degradation of dyes under the simulated solar-UVA radiation

作     者:Huyen Tran Thi Thuong Chi Tran Thi Kim Liem Nguyen Quang Hendrik Kosslick 

作者机构:Institute of Materials Science (IMS) Vietnam Academy of Science and Technology (VAST) University of Rostock Institute of Chemistry Department of Inorganic Chemistry 

出 版 物:《Progress in Natural Science:Materials International》 (自然科学进展·国际材料(英文))

年 卷 期:2019年第29卷第6期

页      面:641-647页

核心收录:

学科分类:083002[工学-环境工程] 0830[工学-环境科学与工程(可授工学、理学、农学学位)] 081704[工学-应用化学] 081705[工学-工业催化] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基  金:supported by National Foundation for Science and Technology Development (NAFOSTED) grant 103.02-2018.28 

主  题:Brookite Anatase Dye Photocatalytic degradation Decolourization Mineralization 

摘      要:Brookite TiO2nanoparticles were synthesized by hydrothermal method and characterized by X-ray powder diffraction(XRD), diffuse reflectance UV–Visible spectroscopy(DRUV), and scanning electron microscopy(SEM). The obtained particles were spherical in shape with the diameter of about ~10 nm under the hydrothermal temperature of 175 °C. The photocatalytic performance of brookite was investigated in the photodegradation of dyes(rhodamine B and rose bengal) under UV-A radiation by low-power lamp. The activity of brookite and the photodegradation efficiency of dyes were estimated using a UV–Visible spectrophotometer and a total organic carbon(TOC) analyzer. Compared to anatase and rutile prepared by the similar synthesis procedure, brookite is highly active in terms of decolourization, aromatic ring opening, and mineralization.

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