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Vinyltrimethylsilane as a novel electrolyte additive for improving interfacial stability of Li-rich cathode working in high voltage

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Chinese Chemical Letters 2024年第2期35卷 534-538页

作者： bing Jiang Hao Li Bi luo Lehao Liu Lihua Chu Qiaobao Zhang Meicheng Li State key Laboratory of Alternate Electrical Power System with Renewable Energy Sources School of New EnergyNorth China Electric Power UniversityBeijing 102206China State key Laboratory of Physical Chemistry of Solid Surfaces College of MaterialsXiamen UniversityXiamen 361005China

Boosting the interfacial stability between electrolyte and Li-rich cathode material at high operating voltage is vital important to enhance the cycling stability of Li-rich cathode materials for high-performance Li-ion *** this work,vinyltrimethylsilane as a new type of organic silicon electrolyte additive is studied to address the interfacial instability of Li-rich cathode material at high operating *** cells using vinyltrimethylsilane additive shows the high capacity retention of 73.9%after 300 cycles at 1 C,whereas the cells without this kind of additive only have the capacity retention of 58.9%.The improvement of stability is mainly attributed to the additive helping to form a more stable surface film for Li-rich cathode material,thus avoiding direct contact between the electrolyte and the cathode material,slowing down the dissolution of metal ions and the decomposition of the electrolyte under high operating *** findings in this work shed some light on the design of stable cycling performance of Li-rich cathode toward advanced Li-ion batteries.

关键词： Vinyltrimethylsilane Electrolyte additive Li-rich cathode Interfacial stability Capacity retention

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Retinoic acid alleviates rotavirus-induced intestinal damage by regulating redox homeostasis and autophagic flux in piglets

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Animal Nutrition 2024年第1期16卷 409-421页

作者： Xin Lai Aimin Wu bing Yu Hui Yan Junqiu luo Ping Zheng Jie Yu Daiwen Chen Institute of Animal Nutrition Sichuan Agricultural University key Laboratory for Animal Disease-resistance Nutrition of China Ministry of Education Sichuan Agricultural University

Rotaviruses(RV) are a major cause of severe gastroenteritis, particularly in neonatal piglets. Despite the availability of effective vaccines, the development of antiviral therapies for RV remains an ongoing challenge. Retinoic acid(RA), a metabolite of vitamin A, has been shown to have anti-oxidative and antiviral properties. However, the mechanism by which RA exerts its intestinal-protective and antiviral effects on RV infection is not fully understood. The study investigates the effects of RA supplementation in Duroc × Landrace × Yorkshire(DLY) piglets challenged with RV. Thirty-six DLY piglets were assigned into six treatments, including a control group, RA treatment group with two concentration gradients(5and 15 mg/d), RV treatment group, and RV treatment group with the addition of different concentration gradients of RA(5 and 15 mg/d). Our study revealed that RV infection led to extensive intestinal architecture damage, which was mitigated by RA treatment at lower concentrations by increasing the villus height and villus height/crypt depth ratio(P < 0.05), enhancing intestinal stem cell signaling and promoting intestinal barrier functions. In addition, 15 mg/d RA supplementation significantly increased NRF2 and HO-1 protein expression(P < 0.05) and GSH content(P < 0.05), indicating that RA supplementation can enhance anti-oxidative signaling and redox homeostasis after RV challenge. Additionally,the research demonstrated that RA exerts a dual impact on the regulation of autophagy, both stimulating the initiation of autophagy and hindering the flow of autophagic flux. Through the modulation of autophagic flux, RA influence the progression of RV infection. These findings provide new insights into the regulation of redox hemostasis and autophagy by RA and its potential therapeutic application in RV infection.

关键词： Rotavirus Piglet Retinoic acid Intestinal barrier Redox hemostasis Autophagic flux

Low friction under ultrahigh contact pressure enabled by self-assembled fluorinated azobenzene layers

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Friction 2024年第7期12卷 1434-1448页

作者： Dandan XUE Zhi XU Linyuan GUO Wendi luo Liran MA Yu TIAN Ming MA Qingdao ZENG ke DENG Wenjing ZHANG Yichun XIA Shizhu WEN Jianbin luo State key Laboratory of Tribology in Advanced Equipment Tsinghua UniversityBeijing 100084China National Center for Nanoscience and Technology Beijing 100190China

Extensive efforts have been made to pursue a low-friction state with promising applications in many fields,such as mechanical and biomedical *** which,the load capacity of the low-friction state has been considered to be crucial for industrial ***,we report a low friction under ultrahigh contact pressure by building a novel self-assembled fluorinated azobenzene layer on an atomically smooth highly-oriented pyrolytic graphite(HOPG)*** friction coefficients could be as low as 0.0005 or even lower under a contact pressure of up to 4 *** demonstrates that the low friction under ultrahigh contact pressure is attributed to molecular *** fluorination leads to effective and robust lubrication between the tip and the self-assembled layer and enhances tighter rigidity which can reduce the stress concentration in the substrate,which was verified by density functional theory(DFT)and molecular dynamics(MD)*** work provides a new approach to avoid the failure of ultralow friction coefficient under relatively high contact pressure,which has promising potential application value in the future.

关键词： ultrahigh contact pressure self-assembled layer fluorination robust lubrication

Secondary bile acids are associated with body lipid accumulation in obese pigs

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Animal Nutrition 2024年第3期18卷 246-256页

作者： Yaolian Hu Aimin Wu Hui Yan Junning Pu Junqiu luo Ping Zheng Yuheng luo Jie Yu Jun He bing Yu Daiwen Chen key Laboratory of Animal Disease-Resistant Nutrition Ministry of EducationAnimal Nutrition InstituteSichuan Agricultural UniversityYa'an 625014China

The aim of this study was to investigate the reasons for the differences in lipid accumulation between lean and obese *** bile acids with varying levels within two types of pigs were found and then in vitro experiments were conducted to identify whether these bile acids can directly affect lipid *** pigs,including seven lean and seven obese pigs with body weights of approximately 80 kg,were fed the same diet at an amount approximately equivalent to 3%of their respective body weights daily for 42 *** vitro,3T3-L1 preadipocytes were cultured in medium with high glucose levels and were differentiated into mature adipocytes using differentiation ***,bile acids were added to mature adipocytes for 4 *** results showed that there was a difference in body lipids levels and gut microbiota composition between obese and lean pigs(P<0.05).According to the results of gut microbial function prediction,the bile acid biosynthesis in colonic digesta of obese pigs were different from that in lean ***-five bile acids were further screened by metabolomics,of which 4 were upregulated(P<0.05)and 2 were downregulated(P<0.05)in obese pigs compared to lean *** results of the correlation analysis demonstrated that chenodeoxycholic acid-3-β-D-glucuronide(CDCA-3Gln)andω-muricholic acid(ω-MCA)had a negative correlation with abdominal fat weight and abdominal fat rate,while isoallolithocholic acid(IALCA)was positively associated with crude fat in the liver and abdominal fat *** was a positive correlation between loin muscle area and CDCA-3Gln andω-MCA(P<0.05),however,IALCA and 3-oxodeoxycholic acid(3-oxo-DCA)were negatively associated with loin eye muscle area(P<0.05).Isoallolithocholic acid increased the gene expression of peroxisome proliferator-activated receptor gamma(PPARG)and the number of lipid droplets(P<0.05),promoting the lipid storage when IALCA was added to 3T3-L1 mature adipocytes in *** conclusion,the concentration of bile ac

关键词： Lean or obese pig Lipid accumulation Bile acid profile Gut microbiota

Substantial increase of heat-induced labor and economic loss in China under rapid economic and environmental temperature growth

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Advances in Climate Change Research 2024年第4期15卷 708-716页

作者： Bo-Wen CHU Jian-Feng luo ke-Xin WANG Zhen-Cheng XING Hai-Kun WANG Joint International Research Laboratory of Atmospheric and Earth System Sciences School of Atmospheric SciencesNanjing UniversityNanjing 210023China Collaborative Innovation Center of Climate Change Jiangsu ProvinceNanjing 210023China Frontiers Science Center for Critical Earth Material Cycling Nanjing UniversityNanjing 210023China Nanjin-Helski Insiute in Amosperc and Earth System Sciences Nanjing UniversityNanjing 210023China

Exposure to heat stress causes diminished work performance and leads to economic *** the last two decades,China has experienced both rapid economic development and environmental warming;however,the spatiotemporal variations of association between environmental heat and labor loss have been rarely investigated behind this double ***,we evaluated the variation in China's heat-induced labor productivity loss and related economic cost from 2001 to 2019 and investigated the effect of economic development and regional *** found that decline in labor productivity because of heat stress increased significantly(p<0.05 for heavy-intensity work),and the corresponding economic loss also exhibited a drastic increase by 6-to *** relative economic loss showed a slight but nonsignificant increase with an average value of 0.54%of the annual total *** the sub-regional and sectoral level,adverse effects were more prominent in the southeast region,and the secondary industry sectors,such as construction and manufacturing,contributed to larger proportions of economic *** transformation of industrial structure made economic sectors more vulnerable to heat exposure,and increasingly preventive effects of air-conditioning use were noted on economic damage due to heat-induced productivity decline(36.0%relative economic benefits in 2019 compared to 9.7%in 2001).Our findings could provide a deep insight into heat burden on occupational health and heat adaptation strategies regionally under climate change,especially in developing areas with higher temperature and humidity environment.

关键词： Heat stress Labor loss Wet bulb globe temperature China Economic impact

Two sandwich-type uranyl-containing polytungstates catalyze aerobic synthesis of benzimidazoles

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Rare Metals 2024年第3期43卷 1316-1322页

作者： Yu-Feng Liu Qi-Long Hu Xue-Jiao Chen ke Li Pei luo Guo-Ping Yang School of Chemistry and Material Science Jiangxi Province Key Laboratory of Synthetic ChemistryJiangxi Key Laboratory for Mass Spectrometry and InstrumentationEast China University of TechnologyNanchang330013China School of Environmental Science and Engineering Southern University of Science and TechnologyShenzhen518055China

Diversified synthetic strategies are extremely important for the structural diversity of uranium-containing polyoxometalates(U-POMs)and their functional ***,two sandwich-type U-POMs were reported,which are Na_(5.6)K_(6.4)[(UO_(2))(H_(2)O)(TeW_(9)O_(33))]_(2)·21H_(2)O(UTeW_(9))and Na_(8.9)K_(2.7)H_(1.19)[K_(0.79)(UO_(2))_(2.21)(PW_(9)O_(34))_(2)]·12H_(2)O(UPW_9)using in-situ strategy and lacunary precursor strategy,***_9 shows a typical keggin-typeopen or half-sandwich configuration.

关键词： configuration expansion sandwich

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Rh(Ⅱ)-catalyzed intermolecular carboamination of pyridines via double Csp^(2)-H bond activations

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Science China Chemistry 2024年第1期67卷 374-382页

作者： Zhongfeng luo Jingxing Jiang Lifang Zou Xiaoyu Zhou Junshan Liu Zhuofeng ke Fengjuan Chen Huanfeng Jiang Wei Zeng key Laboratory of Functional Molecular Engineering of Guangdong Province School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou 510641China School of Materials Science and Engineering PCFM LabSun Yat-sen UniversityGuangzhou 510275China Guangdong Provincial key Laboratory of Chinese Medicine Pharmaceutics School of Traditional Chinese MedicineSouthern Medical UniversityGuangzhou 510515China

We disclose the development of the Rh-catalyzed amine-directed remote 5,6-carboamination protocol of pyridines via dual Csp^(2)-H functionalizations.A variety of readily available 2-aminopyridines and 1,2,3-triazoles are allowed for coupling cyclization to access polyfunctionalized *** studies including DFT calculations unveil that relay carbenoidelectrophilic addition to pyridines and the sequential pyridyl Csp^(2)-H amination are involved in this *** postsynthetic utility of this methodology is showcased by versatile and site-selective modification of azaindoles.

关键词： Rh-catalysis azaindoles pyridyl Csp^(2)-H bond carboamination coupling-cyclization

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Improving high-field strain and temperature stability on KNN-based ceramics sintered in reducing atmosphere via defect engineering

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Journal of Materiomics 2024年第6期10卷 1165-1175页

作者： Zhenyong Cen Meiyi Feng Fuzhi Cao Yuqi Jiang Ze Xu Changrong Zhou ke Wang Nengneng luo State key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures MOE Key Laboratory of New Proce sing Technology for Nonferrous Metals and MaterialsSchool of ResourcesEnvironment and MaterialsGuangxi Univers ityNanning530004China Guangexi key Laboratory of Information Materials Guilin University of Electronic TechnologyGuilin541004China State key Laboratory of New Ceramics and Fine Processing School of Materials Science and Engineering Tsinghua UniversityBeijing 100084China

High-field strain and its temperature stability of(1-x)K_(0.48)Na_(0.52)Nb_(0.96)Ta_(0.04)O_(3)-xBaZrO_(3)+8%MnO+3%ZrO_(2)(in mole,KNNT-xBZ+8Mn)ceramics sintered in reducing atmosphere are improved simultaneously via defect design in A and B *** is a conducting type transition from n-type to p-type at x=*** BaZrO_(3) dopant not only induces the increase of defects(Zr′_(Nb),Ba_(Na),Ba_(K))concentration,but also results in the increase of defect(Mn″_(Nb))concentration,because more Mn ions as+2 oxidation state in ceramics is triggered by BaZrO3 doping *** dipoles(Mn″_(Nb)-V_(o),Zr′_(Nb)-V_(o),Ba_(Na)-V′_(Na),Ba_(Na)-V′_(Na))in poled and aged ceramics enhance the reversibility of the non-180°domains switching,which increases the high-field strain of KNNT-xBZ+8Mn *** reversibility of non-180°domain switching can be preserved to high temperature due to stable defect dipoles(Ba_(Na)-V′_(Na),Ba_(K)-V′_(K))in *** KNNT-xBZ+8Mn ceramics at x=0.07 show the largest high-field strain coefficient(543 pm/V@20 kV/cm)and the highest temperature stability(125℃).The KNNT-xBZ+8Mn ceramic is a lead-free material with great potential to be applied in the fabrication of multilayer ceramic actuators with Ni inner electrodes in the future.

关键词： Lead-free ceramics Piezoelectric materials Reducing atmosphere Defects

Design strategy of porous elastomer substrate and encapsulation forinorganic stretchableelectronics

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International Journal of Smart and Nano Materials 2024年第2期15卷 330-347页

作者： Jiaxin Li Xianhong Meng Yunfei Shen Junlin Gu Guoquan luo ke Bai Hailong Li Zhaoguo Xue National key Laboratory of Strength and Structural Integrity Institute of Solid MechanicsSchool of Aeronautic Science and EngineeringBeihang UniversityBeijingP.R.China Applied Mechanics Laboratory Department of Engineering MechanicsTsinghua UniversityBeijingP.R.China

The emergence of stretchable electronic technology has led to the development of many industries and facilitated many unprecedented applications,owing to its ability to bear var-ious ***,conventional solid elastomer sub-strates and encapsulation can severely restrict the free motion and deformation of patterned interconnects,leading to poten-tial mechanical failures and electrical *** address this issue,we propose a design strategy of porous elastomer substrate and encapsulation to improve the stretchability of serpentine interconnects in island-bridge *** ser-pentine interconnects are fully bonded to the elastomer sub-strate,while segments above circular pores remain suspended,allowing for free deformation and a substantial improvement in elastic stretchability compared to the solid *** pores ensure unimpeded interconnect deformations,and mod-erate porosity provides support while maintaining the initial planar *** to conventional solid configurations,finite element analysis(FEA)demonstrates a substantial enhancement of elastic stretchability(e.g.=9 times without encapsulation and=7 times with encapsulation).Uniaxial cyc-lic loading fatigue experiments validate the enhanced elastic stretchability,indicating the mechanical stability of the porous *** its intrinsic advantages in permeability,the pro-posed strategy has the potential to offer insightful inspiration and novel concepts for advancing the field of stretchable inorganic electronics.

关键词： Stretchable inorganic electronics Island-bridge structures porous elastomer substrate encapsulation design serpentine interconnects