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Potential Oscillations of a Stainless Steel Electrode during Galvanostatic Polarization in a Mixed Solution of Sulfuric and Chromic Acids

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International Journal of Minerals,Metallurgy and Materials 1998年第3期12卷 134-139页

作者： k Ogura W Lou M Nakayama T Fukume(Department of Applied Chemistry, yamaguchi University, Ube 755, Japan Department of Applied Chemistry Yamaguchi University Ube 755 Japan

Potential oscillations of a stainless steel electrode galvanostatically anodized have been observed in amixture of chromic and sulfuric acids. The potential regularly oscillated between 1.6 V vs. SCE (lower) and 2.1V(upper) with a certain frequency. The potential values are affected neither by the composition of chromic and sulfu-ric acids nor by the magnitude of applied current density although the potential frequency is very sensitive to theseparameters. This phenomenon is interpreted in terms of the repeated formation and disappearance of the saturatedlayer of dichromate ions on the electrode surface. Such scheme is consistent with the in situ FTIR spectroscopicresult that the concentration of Cr2O ions on the electrode surface increased with time during the polarization atthe lower potential but the change in concenetion of Cr2O ions was negligible at the higher potential.

关键词： stainless steel electrode potential galvanostatic polarization

Photocatalytic dry reforming of methane by rhodium supported monoclinic TiO_(2)-B nanobelts

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Journal of Energy Chemistry 2022年第8期31卷 562-571,I0015页

作者： Masaru kushida Akira yamaguchi Masahiro Miyauchi School of Materials and Chemical Technology Tokyo Institute of Technology2-12-1 OokayamaMeguro-kuTokyo 152-8552Japan

The conversion of methane and carbon dioxide into syngas(dry reforming of methane;DRM)has attracted attention owing to the potential to reuse greenhouse *** dioxide(TiO_(2))-based photocatalysts,which have been widely commercialized owing to their high efficiency,non-toxicity,and low cost,are strongly desired in ***,we report a monoclinic-phase TiO_(2)-B nanobelts-supported rhodium(Rh/TiO_(2)-B nanobelts)catalyst that efficiently promotes DRM under ultraviolet light irradiation at low *** holes in the TiO_(2)-B nanobelts were used to oxidize methane,while the electrons were trapped in rhodium to reduce carbon ***/TiO_(2)-B nanobelts exhibited considerably higher durability and activity than Rh-loaded conventional TiO_(2)(anatase and rutile),owing to the lattice and/or surface oxygen reactivity in TiO_(2)-B nanobelts,which was suggested by X-ray photoelectron spectroscopy measurements and photocatalytic performance tests under an atmosphere of methane *** study paves the path for the effective utilization of methane by constructing active TiO_(2)-based nanometal photocatalysts.

关键词： Photocatalysis Dry reforming of methane Greenhouse gas conversion Gas-phase reaction Titanium dioxide TiO_(2)-B

pH-controlled hydrothermal synthesis of titanium phosphates and their powder properties

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Journal of Advanced Ceramics 2014年第4期3卷 326-331页

作者： Hiroaki ONODA Taisuke yamaguchi Department of Informatics and Environmental Sciences Kyoto Prefectural University1-5Shimogamo Nakaragi-cyoSakyo-kuKyoto 606-8522Japan

Titanium phosphates were prepared from titanium chloride and sodium pyrophosphate at various pH in hydrothermal process as a novel white pigment for *** chemical composition,powder properties,photo catalytic activity,colour phase and smoothness were *** obtained materials had a higher Ti/P ratio than that used in preparation conditions because of the formation of titanium oxide and *** samples prepared at pH=4 had particles smaller than 100μ*** phosphates had less photo catalytic activity to protect the sebum on the *** obtained materials in hydrothermal process and their thermal products at 100℃showed high reflectance in the range of visible light.

关键词： titanium phosphates pyrophosphate pH photo catalytic activity smoothness

Estimating reflectance and shape of objects from a single cartoon-shaded image

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Computational Visual Media 2017年第1期3卷 21-31页

作者： Hideki Todo Yasushi yamaguchi Tokyo University of Technology The University of Tokyo

Although many photorealistic relighting methods provide a way to change the illumination of objects in a digital photograph, it is currently difficult to relight digital illustrations having a cartoon shading style. The main difference between photorealistic and cartoon shading styles is that cartoon shading is characterized by soft color quantization and nonlinear color variations that cause noticeable reconstruction errors under a physical reflectance assumption, such as Lambertian reflection. To handle this non-photorealistic shading property, we focus on shading analysis of the most fundamental cartoon shading technique. Based on the color map shading representation, we propose a simple method to determine the input shading as that of a smooth shape with a nonlinear reflectance property. We have conducted simple ground-truth evaluations to compare our results to those obtained by other approaches.

关键词： non-photorealistic rendering cartoon shading relighting quantization

Study on multimers and their structures in molecular association mixture

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Science China Chemistry 2007年第1期50卷 23-31页

作者： yamaguchi Yoshinori OZAkI Yukihiro Consolidated Research Institute for Advanced Science and Medical Care Waseda UniversityJapan Department of Chemistry School of Science and TechnologyKwansei-Gakuin UniversitySandaHyogo 669-1337Japan

Self-association system of(R)-1,3-butanediol in dilute carbon tetrachloride(CCl4)solution is studied as a model of molecular association *** methods including FSMWEFA(fixed-size moving window evolving factor analysis)combined with PCA(principal component analysis),SIMPLISMA (simple-to-use interactive self-modeling mixture analysis),and ITTFA(iterative target transformation factor analysis)are adopted to resolve infrared spectra of(R)-1,3-butanediol *** number and equilibrium constant are computed.(R)-1,3-butanediol in dilute inert solution is determined as a monomer-trimer equilibrium *** investigation of trimer structures is carried out with DFT(density functional theory),and structural factors are analyzed.

关键词： (R)-1 3-butanediol multimer chemometrics density functional theory

Network-Based Predictions and Simulations by Biological State Space Models: Search for Drug Mode of Action

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Journal of Computer Science & Technology 2010年第1期25卷 131-153页

作者： Rui yamaguchi Seiya Imoto Satoru Miyano Human Genome Center Institute of Medical Science University of Tokyo

Since time-course microarrav data are short but contain a large number of genes, most of statistical models should be extended so that they can handle such statistically irregular situations. We introduce biological state space models that are established as suitable computational models for constructing gene networks from microarray gene expression data. This chapter elucidates theory and methodology of our biological state space models together with some representative analyses including discovery of drug mode of action. Through the applications we show the whole strategy of biological state space model analysis involving experimental design of time-course data, model building and analysis of the estimated networks.

关键词： gene networks state space models time-course gene expression data

Microstructure and Wear Behavior of Cermet/Iron Alloy Cladding Layers on A6061 Alloy Coated by Resistance Seam Welding Method

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Acta Metallurgica Sinica(English Letters) 2015年第4期28卷 414-423页

作者： Wen-Qin Wang Tomiko yamaguchi kazumasa Nishio Faculty of Engineering Kyushu Institute of Technology Nishinippon Institute of Technology

Cermet/iron alloy cladding layers were coated on the surface of Al-Mg-Si alloy （A6061） plates by resistance seam welding method with tungsten carbide （WC） and high-carbon iron alloy （SHA） powders. The cladding layer consisted of WC reinforcement, SHA binder, A6061 and FeAl3. The effect of WC ratio （30 wt%, 50 wt% and 70 wt%） on the microstructure and wear behavior of the cladding layers was investigated in detail. Abrasive wear test was performed under two kinds of load condition by using a rubber wheel apparatus to evaluate wear resistance. The results showed that the wear resistance of the cladding layer was improved by 3.5-5 times than that of the substrate. At lower load, the wear resistances of the samples 30% and 70% WC were nearly the same, which suggested that FeAl3 played an important role in improvement of the wear resistance instead of WC. While at higher load, the amount of WC determined the wear resistance of the cladding layer. Furthermore, wear behavior of these cladding layers was explained with reference to the observed microstructure of the worn surface.

关键词： Resistance seam welding A6061 WC Cladding layer Wear resistance

Real-time rendering of layered materials with anisotropic normal distributions

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Computational Visual Media 2020年第1期6卷 29-36页

作者： Tomoya yamaguchi Tatsuya Yatagawa Yusuke Tokuyoshi Shigeo Morishima Waseda University Tokyo155-8885Japan The University of Tokyo Tokyo153-8656Japan Intel Corporation CA95054USA

This paper proposes a lightweight bidirectional scattering distribution function(BSDF)model for layered materials with anisotropic reflection and refraction *** our method,each layer of the materials can be described by a microfacet BSDF using an anisotropic normal distribution function(NDF).Furthermore,the NDFs of layers can be defined on tangent vector fields,which differ from layer to *** method is based on a previous study in which isotropic BSDFs are approximated by projecting them onto base ***,the adequateness of this previous work has not been well investigated for anisotropic *** this paper,we demonstrate that the projection is also applicable to anisotropic BSDFs and that the BSDFs are approximated by elliptical distributions using covariance matrices.

关键词： layered materials microfacet BSDF reflection modeling real-time rendering

Hybrid image of three contents

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Visual Computing for Industry,Biomedicine,and Art 2020年第1期3卷 31-38页

作者： Peeraya Sripian Yasushi yamaguchi SIT Research Laboratory Shibaura Institute of TechnologyRoom#04R313-7-5 ToyosuKoto-kuTokyo 135-8548Japan The University of Tokyo Bldg.#15Room#505A3-8-1KomabaMeguro-kuTokyo 153-8902Japan

A hybrid image allows multiple image interpretations to be modulated by the viewing ***,it can be constructed by combining the low and high spatial frequencies of two different *** original hybrid image synthesis was limited to similar shapes of source images that were aligned in the edges,e.g.,faces with a different expression,to produce an effective double image *** our previous work,we proposed a noiseinserted method for synthesizing a hybrid image from dissimilar shape images or unaligned *** this work,we propose a novel method for adding an image to be seen from a middle viewing *** middlefrequency(MF)image is extracted by a special bandpass filter,which generates ringing while extracting only specified frequency *** this method,the middle frequency should be perceived as a meaningless pattern when viewed from a far distance and close up.A parameter tuning experiment was performed to determine the suitable cutoff frequencies for designing the filter for the MF *** found that ringings of a suitable size could be used to make the middle frequency less noticeable when seen from far away.

关键词： Hybrid image Contrast sensitivity Frequency filtering Scale-space