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Selective immobilization of Pb(Ⅱ)by biogenic whewellite and its mechanism

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Journal of Environmental Sciences 2024年第3期137卷 664-676页

作者： Xingxing Wang Kaiyan Ren Kairui jiao Wenjun Nie Xiaochi An Bin Lian College of Life Sciences College of Marine Science and EngineeringNanjing Normal UniversityNanjing 210023China

The development of bio-adsorbents with highly selective immobilization properties for specific heavy metals is a great challenge,but has important application *** whewellite(BW)with high selectivity for Pb(Ⅱ)was synthesized by mineral microbial *** selective immobilization properties and mechanism of BW for Pb(Ⅱ)were analyzed by combining mineral characterization technology and batch adsorption research *** results indicated that BW can efficiently and selectively immobilize Pb(Ⅱ)in single or composite heavy metal adsorption solutions,and the immobilized Pb(Ⅱ)is difficult to *** undergoes monolayer adsorption on Pb(Ⅱ),Qmax≈1073.17 mg/*** immobilization of Pb(Ⅱ)by BW is a physico-chemical adsorption process with spontaneous heat absorption and an accompanying increase in *** addition,the sequestration of Pb(Ⅱ)by BW remains around 756.99 mg/g even at p H=*** excellent selective immobilization properties of BW for Pb(Ⅱ)are closely related to its smaller Ksp,electrostatic repulsion effect,organic-inorganic composite structure,acid resistance and the formation of Pb(Ⅱ)*** study provides beneficial information about the recycling of lead in acidic lead-containing wastewater and composite heavy metal contaminated water bodies.

关键词： Aspergillus niger Biogenic whewellite Pb(Ⅱ) Selective adsorption Immobilization mechanism

Achieving an ion-homogenizing and corrosion-resisting interface through nitro-coordination chemistry for stable zinc metal anodes

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Journal of Energy Chemistry 2024年第7期94卷 10-18页

作者： Jizhen Wang long jiao Qiaoyun Liu Wei Xin Yechen Lei Tian Zhang Leixin Yang Dengkun Shu Shuo Yang Kaihua Li Chenyang Li Chao Yi Hongyuan Bai Yuchao Ma Huan Li Wenjun Zhang Bowen'Cheng schoolof Light Industry Science and Engineering State Key Laboratory of Biobased Fiber Manufacturing TechnologyTianjin Key Laboratory of Pulp and PaperChina Light Industry Key Laboratory of Papermaking and BiorefineryTianjin University of Science&TechnologyTianjin 300457China Department of Materials Science and Engineering &Center of Super-Diamond and Advanced FilmsCity University of Hong Kong83 Tat Chee AvenueHong Kong 999077China School of Chemical Engineering and Advanced Materials The University of AdelaideAdelaideSA 5005Australia

Suppression of uncontrollable dendrite growth and water-induced side reactions of Zn metal anodes is crucial for achieving long-lasting cycling stability and facilitating the practical implementations of aqueous Zn-metal *** address these challenges,we report in this study a functional nitro-cellulose interfacial layer(NCIL)on the surface of Zn anodes enlightened by a nitro-coordination chemistry *** NCIL exhibits strong zincophilicity and superior coordination capability with Zn^(2+)due to the highly electronegative and highly nucleophilic nature of the nitro functional *** characteristic facilitates a rapid Zn-ion desolvation process and homogeneous Zn plating,effectively preventing H_(2) evolution and dendrite ***,the negatively charged surface of NCIL acts as a shield,repelling SO_(4)^(2-)anions and inhibiting corrosive reactions on the Zn ***,reversible and stable Zn plating/stripping is achieved for over 5100 h at a current density of 1 mA cm^(-2),which is nearly 30 times longer than that of bare Zn ***,the Zn/V_(2)O_(5) full cells with the functional interface layer deliver a high-capacity retention of 80.3%for over 10,000 cycles at 5 A g^(-1).This research offers valuable insights for the rational development of advanced protective interface layers in order to achieve ultra-long-lifeZnmetal batteries.

关键词： Zinc metal anode Nitro-cellulose interfacial layer Coordination capability Dendrite-free deposition long-term cycling

A PDGFRβ-targeting nanodrill system for pancreatic fibrosis therapy

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Chinese Chemical Letters 2024年第10期35卷 379-385页

作者： Han Han Bi-Te Chen Jia-Rong Ding jin-Ming Si Tian-jiao Zhou Yi Wang Lei Xing Hu-Lin Jiang State Key Laboratory of Natural Medicines Department of Pharmaceutics China Pharmaceutical University Department of Nephrology Changhai Hospital Naval Medical University College of Pharmacy Yanbian University

Activated pancreatic stellate cells(PSCs) are the main source of collagen layer deposition and the key target in pancreatic fibrosis. However, no effective treatment specific to pancreatic fibrosis clinically, owing to the drug accumulation blocked by the collagen barrier and thus it is difficult to inhibit activated PSCs precisely. Herein, a PSCs-targeting nano-system based on “nanodrill” strategy(LA-PC) was designed to enhance the accumulation of all-trans retinoic acid(ATRA) in PSCs, relying on the platelet-derived growth factor receptor beta(PDGFRβ)-targeting peptide(p PB: C*SRNLIDC*) and collagenase(Col). After being injected into fibrotic mice via tail vein, the Col modified on LA-PC can remove the excess collagen layer,and the drug delivery efficiency through pPB targeting peptide was more than 5 times higher than that of free ATRA, as well as the degree of fibrosis significantly reduced. Notably, this nano-system effectively inhibited platelet-derived growth factor subunit B(PDGF-BB)/PDGFRβ axis on PSCs via a down-regulated extracellular signal-regulated protein kinase(ERK) pathway, and accordingly reduced the level of PDGFBB. Thus, the smart platform provided a promising strategy for the treatment of pancreatic fibrosis to achieve the precise regulation of PSCs.

关键词： Liposome Pancreatic fibrosis Pancreatic stellate cells PDGFRβ pPB peptide

Milestone progress of the HEPS booster commissioning

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Nuclear Science and Techniques 2024年第1期35卷 170-177页

作者： Yue-Mei Peng Jian-She Cao jin-Hui Chen Hai-Yi Dong Ping He Yi jiao Ling Kang Wen Kang Jian Li jing-Yi Li Guo-Ping Lin Fang Liu Feng-Li long Cai Meng Xin Qi Hua-Min Qu Yan-Feng Sui Sheng Wang Gang Xu Qiang Ye jing Zhang Pei Zhang Wei-Min Pan Key Laboratory of Particle Acceleration Physics and Technology Institute of High Energy PhysicsChinese Academy of Sciences19B Yuquan RoadShijingshan DistrictBeijing 100049China University of the Chinese Academy of Sciences 19A Yuquan RoadShijingshan DistrictBeijing 100049China

The high-energy photon source(HEPS)is the first fourth-generation synchrotron light source facility in *** HEPS injector consists of a linear accelerator(Linac)and a full energy *** booster captures the electron beam from the Linac and increases its energy to the value required for the storage *** full-energy beam could be injected to the storage ring directly or after“high-energy accumulation.”On November 17,2023,the key booster parameters successfully reached their corresponding target *** milestone results were achieved based on numerous contributions,including nearly a decade of physical design,years of equipment development and installation,and months of beam *** measured at the extraction energy of 6 GeV,the averaged beam current and emittance reached 8.57 mA with 5 bunches and 30.37 nm rad with a single-bunch charge of 5.58 nC,compared with the corresponding target values of 6.6 mA and 35 nm rad,*** paper presents the physical design,equipment development,installation,and commissioning process of the HEPS booster.

关键词： High energy photon source Booster Beam commissioning

Al-containing Ge-rich IWV:rapid synthesis via interzeolite transformation and application in Baeyer-Villiger oxidation

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Science China Chemistry 2024年第7期67卷 2282-2291页

作者： Meichen jiao Chunmin Jia Hao Xu Peng Wu Xian-Ming Zhang School of Chemistry&Material Science Shanxi Normal UniversityTaiyuan 030006China Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular EngineeringEast China Normal UniversityShanghai 200062China School of Chemistry Taiyuan University of TechnologyTaiyuan 030024China

Ge-containing Lewis acidic zeolites are typically synthesized using a conventional hydrothermal strategy from amorphous silica sources,through a long time-and energy-consuming approach limiting their wide *** study reports a rapid synthesis strategy for a series of IWV aluminogermanosilicate zeolites(T-x-Al)with a wide range of Si/Ge molar ratios(5–15)by interzeolite transformation of dealuminated FAU(DA-FAU).Notably,Ge-rich IWV could be obtained with crystallization time as short as one day by the equimolecular Si/Ge ratio *** effect of synthetic parameters was investigated and the obtained T-x-Al samples were characterized by XRD,SEM,EDS,ICP,^(29)Si and^(27)Al MAS NMR,FTIR,and N_(2)physisorption *** with a previously reported IWV germanosilicate(H-3),T-x-Al displayed a better catalytic activity in Baeyer-Villiger(BV)oxidation,attributed to the presence of the active framework Ge sites with the assistance of the extraframework Al *** cyclic catalysis tests revealed that the presence of framework Al species contributed to the stability of the ***,T-x-Al,with 14-membered ring(MR)supercages,outperformed the typical 12-MR Sn-beta catalyst in the BV oxidation of large ketone-like 2-admantanone,indicating a promising potential application in the macromolecular catalytic process.

关键词： Ge-rich IWV interzeolite transformation Al assistance Baeyer-Villiger oxidation

Electron vortex generations in photoionization of hydrogen atoms by circularly-polarized chirped attosecond pulses

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Communications in Theoretical Physics 2024年第1期76卷 111-118页

作者： Bingshuang Zhang Xiaoyu Liu Fengzheng Zhu Liguang jiao Aihua Liu Institute of Atomic and Molecular Physics Jilin UniversityChangchun 130012China School of Mathematics and Physics Hubei Polytechnic UniversityHuangshi 435003China College of Physics Jilin UniversityChangchun 130012China Helmholtz-Institut Jena D-07743 JenaGermany State Key Laboratory of Transient Optics and Photonics Chinese Academy of SciencesXi'an 710119China

By numerically solving the time-dependent Schr?dinger equation and employing the analytical perturbative model,we investigated the chirp-induced electron vortex in the photoionization of hydrogen atoms by a pair of counter-rotating circularly polarized chirped attosecond extremely ultraviolet *** demonstrated that single-photon ionization of hydrogen atoms generates photoelectron momentum distributions(PMDs)with distinct helical vortex structures either with or without a time delay between two counter-rotating circularly polarized laser *** structures are highly sensitive to both the time delay between the pulses and their chirp *** analytical model reveals that the splitting of vortex spirals is caused by the sign changing of the chirp-induced frequency-dependent time *** showed that to obtain the counterpart of the PMD under a pair of counter-rotating circularly polarized chirped pulses,both chirp parameters and ordering of pulses need to be reversed.

关键词： photoionization ultrafast processes ultrafast dynamics electron vortex

Soil type and wetting intensity control the enhancement extent of N_(2)O efflux in soil with drought and rewetting cycles

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International Soil and Water Conservation Research 2024年第1期12卷 137-144页

作者： Panpan jiao Lei Yang Zhongwu Li Peng Zheng Xiaodong Nie School of Geographical Sciences Hunan Normal UniversityChangsha 410081China State Key Laboratory of Soil Erosion and Dryland Farming on the Loess Plateau The Research Center of Soil and Water Conservation and Ecological EnvironmentChinese Academy of Sciences and Ministry of EducationYangling 712100China Institute of Soil and Water Conservation Chinese Academy of Sciences and Ministry of Water ResourcesYangling 712100China University of Chinese Academy of Sciences Beijing 100049China Key Laboratory of Soil Environment and Pollution Remediation Institute of Soil ScienceChinese Academy of SciencesNanjing 210008China

Climate change alters the intensity and frequency of drought and rewetting(D/W)events;however,the influence patterns of D/W on soil N_(2)O efflux in the water-limited area were not fully ***,the impacts of D/W cycles varying in different extent of rewetting and frequency to N_(2)O efflux in two kinds of soil on the Loess Plateau were *** incubation conditions consisted of 1)D/W treatments with four 7-day cycles from 10%water holding capacity(WHC)to 60%WHC or 90%WHC,2)constant moisture of 60%WHC and 90%*** pulse of N_(2)O efflux rate under 10-60%WHC treatment was higher than that under 10-90%WHC treatment in calcic cambisols,while opposite trend was observed in earth-cumuli-orthic ***,the pulse of N_(2)O efflux rate decreased as cycle number increased for different wetting intensities and soil *** direct N_(2)O efflux under 10-60%WHC and 10-90%WHC treatments were 5.49 and 1.89μg N_(2)O-N g^(-1)soil in calcic cambisols,with those being 1.92 and 10.85μg N_(2)O-N g^(-1)soil in earth-cumuli-orthic anthrosols,*** N loss in earth-cumuli-orthic anthrosols was approximately 5.74 times greater than that in calcic cambisols under 10-90%WHC treatment,whereas the N loss under 10-60%WHC treatment was about 2.86 times greater in calcic cambisols than that in earth-cumuli-orthic *** study suggested that extreme rainfall events can enhance the N_(2)O efflux and N loss in agricultural soils on the Loess Plateau in terms of soil type and wetting intensity,which should not be ignored in the N fertilizer management.

关键词： Drought/rewetting cycles N_(2)O efflux Wetting intensity Microbial biomass N Dissolved organic N Loess plateau

Synergistic enhancement of Ce-ZnO/g-C_(3)N_(4)photocatalytic performance using N,O-bis-vacancy induction and S-scheme heterojunctions

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Journal of Rare Earths 2024年第5期42卷 817-826,I0001页

作者： Guyu Zhang Yuan Zhang Xinlei Zhao Yujiang jiao Yumin Yan Jianhui Jiang Engineering Laboratory of Chemical Resources Utilization in South Xinjiang of Xinjiang Production and Construction Corps College of Chemistry a Chemical EngineeringTarimUniversityAlar843300China

The photocatalytic decontamination of organic pollutants is an environmentally friendly and efficient water treatment *** introduction of vacancies,heterojunctions,and doping can enhance the performance of photocatalysts for such *** this study,N,O double-vacancy Ce-ZnO/g-C_(3)N_(4)S-scheme heterojunction photocatalysts were prepared,It is found that the electron separation and transfer efficiencies are considerably improved by the presence of nitrogen vacancies in graphitic ca rbon nitride(g-C_(3)N_(4))and oxygen vacancies in ZnO,in addition to the S-scheme heterojunction created between the two *** the degradation of methylene blue and ciprofloxacin,the degradation rates exhibited by Ce-ZnO/g-C_(3)N_(4)are significantly higher than those of the g=C_(3)N_(4)/ZnO *** remarkable photocatalytic performance of Ce-ZnO/g-C_(3)N_(4)may result from three key factors;(ⅰ)Ce doping,which produces impurity energy levels;(ⅱ)the generation of electron capture centres by the N and O vacancies;and(ⅲ)the synergistic effect of the S-type heterojunction formed at the interface between the two materials,This study therefore provides new approaches for the use of doping,vacancies,and heterojunctions to induce the efficient degradation of organic pollutants.

关键词： Photocatalysis Vacancy S-scheme Ce-ZnO/g-C_(3)N_(4) Degradation Rare earths

Hydrochemical Characteristics and Evolution of Underground Brine in Lop Nur,Northwestern China

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Acta Geologica Sinica(English Edition) 2024年第3期98卷 786-800页

作者： BO Ying LIU Chenglin jiao Pengcheng LU Fenglin ZHANG Hua MNR Key Laboratory of Metallogeny and Mineral Assessment Institute of Mineral ResourcesChinese Academy of Geological SciencesBeijing 100037China

Lop Nur is located at the eastmost end of the Tarim Basin in Xinjiang,Northwestern *** study reviews the hydrochemical characteristics and evolution of underground brine in Lop Nur,based on analytical data from 429 water samples(mainly brine).It is found that in the NE-SW direction,from the periphery to the Luobei sub-depression,while the hydrochemical type varies from the sodium sulfate subtype(S)to the magnesium sulfate subtype(M),the corresponding brine in the phase diagram transfers from the thenardite phase(Then)area,through the bloedite phase(Blo),epsomite phase(Eps),picromerite phase(Picro),finally reaching the sylvite phase(Syl)*** for the degree of evolution,the sequence is the periphery

关键词： brine evolution isotope enrichment potassium Lop Nur