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A review on adhesion behavior of chip seal pavement and aggregate

Journal of Traffic and Transportation Engineering(English Edition) 2024年第3期11卷 441-466页

作者： Yuming Zhou Zhuyi Peng Jinyu Wang jianguo Wei Hao Liu Di Wang Jinming Li Key Laboratory of Road Structure and Material of Ministry of Transport(Changsha) Changsha University of Science and TechnologyChangsha 410114China School of Traffic and Transportation Engineering Changsha University of Science and TechnologyChangsha 410114China Wuhan Huike Testing Co. Ltd.Wuhan 430000China Department of Civil Engineering University of OttawaON KIN 6N5Canada CCCC Infrastructure Maintenance Group Co. Ltd.Beijing 100102China

Chip seal is widely used for preventive maintenance to mitigate pavement deterioration,but it is prone to aggregate loss during pavement *** further promote the development and application of chip seals in road engineering in China,the research progress of the adhesion behavior of aggregate and binder in chip seals was reviewed in this paper,focusing on the adhesion mechanism of emulsified asphalt and alkaline *** Influencing factors and evaluation methodology of chip seals'aggregate adhesion behavior were also *** results demonstrate that the adhesion process between emulsified asphalt and alkaline aggregate is divided into three processes including infiltration,demulsification,and cluster,which is more complicated when compared to hot *** designing a chip seal,not only the characteristics of single material should be paid attention to,but also the combination of binder and aggregate matters a *** form good adhesion between aggregate and asphalt binder,various influencing factors such as material selection,design method,and construction technical index should be considered comprehensively in the whole design,construction,and operation *** methods for evaluating adhesion behavior are summarized,including macroscopic adhesion performance tests,image analysis technology,and model *** is not objective to evaluate the aggregate adhesion behavior of chip seal only by a single evaluation method.A comprehensive evaluation based on the micro-macro multi-scale method should be considered in the future.

关键词： Chip seal Adhesion behavior Asphalt binder Aggregate

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In-situ imaging electrocatalysis in a solid-state Li-O_(2) battery with CuSe nanosheets as air cathode

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Chinese Chemical Letters 2024年第5期35卷 466-470页

作者： Peng Jia Yunna Guo Dongliang Chen Xuedong Zhang Jingming Yao jianguo Lu Liqiang Zhang hebei Key Laboratory of Applied Chemistry College of Environmental and Chemical EngineeringYanshan UniversityQinhuangdao 066004China Clean Nano Energy Center State Key Laboratory of Metastable Materials Science and TechnologyYanshan UniversityQinhuangdao 066004China State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and EngineeringZhejiang UniversityHangzhou 310058China Key Laboratory of Low Dimensional Materials and Application Technology of Ministry of Education School of Materials Science and EngineeringXiangtan UniversityXiangtan 411105China

The development of highly efficient catalysts in the cathodes of rechargeable Li-O_(2) batteries is a considerable *** enhance the electrochemical performance of the Li-O_(2) battery,it is essential to choose a suitable catalyst *** selenide(CuSe)is considered as a more promising cathode catalyst material for Li-O_(2) battery due to its better conductivity and rich electrochemical active ***,its electrochemical reaction and fundamental catalytic mechanism remain unclear till ***,in-situ environmental transmission electron microscopy technique was used to study the catalysis mechanism of the CuSe nanosheets in Li-O_(2) batteries during discharge and charge *** is found that Li_(2)O was formed and decomposed around the ultrafine-grained Cu during the discharge and charge processes,respectively,demonstrating excellent *** indicate that the freshly formed ultrafine-grained Cu in the conversion reaction catalyzed the latter four-electron-transfer oxygen reduction reaction,leading to the formation of Li_(2)*** study provides important understanding of the electrochemistry of the LiO_(2) nanobatteries,which will aid the development of high-performance Li-O_(2) batteries for energy storage applications.

关键词： In-situ environmental transmission electron microscopy Lithium oxygen batteries CuSe nanosheets Oxygen reduction reaction Oxygen evolution reaction

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Combination of Nitrogen-Rich Skeleton and Coordination Group:Synthesis of a High-Energy Primary Explosive Based on 1H-Tetrazole-5-Carbohydrazide

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Defence Technology（防务技术） 2024年第1期31卷 271-277页

作者： Tingwei Wang Zujia Lu Shu Bu Baolong Kuang Lu Zhang Zhenxin Yi Kun Wang Shunguan Zhu jianguo Zhang State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing 100081China School of Chemical Engineering Nanjing University of Science and Technology200 Xiaolingwei StreetXuanwuNanjing 210094China Department of Chemistry Laboratory of Structure and Functional Regulation of Hybrid MaterialsAnhui UniversityMinistry of EducationHefei 230601China

The high energy coordination compounds Cu(TZCA)_(2)(ClO_(4))_(2)(ECCs-1) was prepared by 1H-tetrazole-5-carbohydrazide(TZCA) with a high energy skeleton and a strong coordination ability *** the same time,the reaction activity of the ligand was explored,and the single crystal structure of it and intermediate were *** structures of all substances were characterized by IR and *** the structure and composition of ECCs-1 are confirmed by ESP,AC,SEM and *** and chemical properties tests show that ECCs-1 has an acceptable thermal stability(T_(d)=177℃) and extremely sensitive mechanical stimulation(IS=1 J,FS=5 N).The comprehensive performance test results show that ECCs-1 has excellent initiation *** addition,the decomposition mechanism of ECCs-1 is explored from two aspects of experiment and theoretical calculation.

关键词： 1H-tetrazole-5-carbohydrazide Primary explosive Decomposition mechanism Coordination polymers Laser

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重力热管供热对葡萄越冬根区的增温效应

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农业工程学报 2023年第7期39卷 205-210页

作者：邓改革何建国李建设康宁波宁夏大学土木与水利工程学院银川750021

葡萄是宁夏特色优势产业,越冬冻害是制约贺兰山东麓葡萄产业可持续发展的关键问题之一。为解决葡萄越冬根部冻害问题,该研究设计了利用浅层地下水地热能进行葡萄根区土壤增温的重力热管系统;通过数值模拟解析不同间距条件下重力热管温... 详细信息

葡萄是宁夏特色优势产业,越冬冻害是制约贺兰山东麓葡萄产业可持续发展的关键问题之一。为解决葡萄越冬根部冻害问题,该研究设计了利用浅层地下水地热能进行葡萄根区土壤增温的重力热管系统;通过数值模拟解析不同间距条件下重力热管温度场影响范围及分布规律,通过现场试验研究重力热管的工作特性及对土壤的增温特性。结果表明:土壤温度场以重力热管为中心向四周扩散,热管中温影响区水平方向直径为30.8cm,竖直方向直径为32.8 cm;在埋深10 cm,相邻热管间距15 cm条件下热管周围温度场部分区域重合,温度场分布均匀;试验期间试验组土壤温度较对照组平均升高7.0℃,增温效果明显;重力热管正常运行期间蒸发段凝结段之间最大温差为3.7℃,蒸发段内最大温差为1.0℃,绝热段内最大温差为0.2℃,表现出了良好的等温性;热管平均启动温差为5.4℃,平均运行温差为2.9℃;研究结果将为解决葡萄根区冻害问题以及探索浅层地热能利用新途径提供理论依据和技术支撑。

关键词：温度土壤传热重力热管土壤增温数值模拟

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Hybrid structure of iron single atoms and metallic titanium for photothermal ethanol steam reforming

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Science China Chemistry 2024年第3期67卷 848-854页

作者： Dachao Yuan Guanda Han Zhixuan Wang jianguo Zhao Kailuan Li Pengfei Wang Jianjun Hao Yaguang Li Jinhua Ye College of Mechanical and Electrical Engineering Technology Innovation Center of Intelligent Agricultural EquipmentHebei Agricultural UniversityBaoding 071001China Research Center for Solar Driven Carbon Neutrality The College of Physics Science and TechnologyInstitute of Life Science and Green DevelopmentHebei UniversityBaoding 071002China International Center for Materials Nanoarchitectonics(WPI-MANA) National Institute for Materials Science(NIMS)1-1 NamikiTsukubaIbaraki 305-0044Japan Graduate School of Chemical Science and Engineering Hokkaido UniversitySapporo 060-0814Japan

Photothermal ethanol steam reforming(ESR) is currently limited by low intrinsic activity and strong solar energy ***,we synthesized Fe single atoms supported on CeO_(2)(SA Fe-CeO_(2)) to exhibit excellent low-temperature ESR activity with a hydrogen production rate of 512 mmol g^(-1)h^(-1) at 350℃,becuase of the high oxidation state of Fe single atoms to weaken the reaction barrier of ethanol ***,a heterostructure of SA Fe-CeO_(2) and Ti foil could eliminate 66% of infrared radiation via the size effect,thus achieving a 3.5 sun-driven temperature of 347℃.Consequently,the heterostructure of SA Fe-CeO_(2) and Ti foil shows a hydrogen generation rate of 984 mmol g^(-1)h^(-1) of ESR and 11.31% of solar-to-hydrogen energy conversion efficiency,which outperforms other photothermal ethanol-hydrogen production *** study provides a new path for designing active catalytic sites and trapping light energy of photothermal catalysts.

关键词： photothermal catalysis single atoms heterostructure ethanol steam reforming iron

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In situ observation of the electrochemical behavior of Li–CO_(2)/O_(2)batteries in an environmental transmission electron microscope

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Carbon Energy 2024年第4期6卷 244-255页

作者： Peng Jia Yunna Guo Dongliang Chen Jingming Yao Xuedong Zhang jianguo Lu Yuqing Qiao Liqiang Zhang hebei Key Laboratory of Applied Chemistry College of Environmental and Chemical EngineeringYanshan UniversityQinhuangdaoChina State Key Laboratory of Metastable Materials Science and Technology Clean Nano Energy CenterYanshan UniversityQinhuangdaoChina State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and EngineeringZhejiang UniversityHangzhouChina Key Laboratory of Low Dimensional Materials and Application Technology of Ministry of Education School of Materials Science and EngineeringXiangtan UniversityXiangtanChina

Li–CO_(2)/O_(2)batteries,a promising energy storage technology,not only provide ultrahigh discharge capacity but also capture CO_(2)and turn it into renewable *** electrochemical reaction pathways'ambiguity,however,creates a hurdle for their practical *** study used copper selenide(CuSe)nanosheets as the air cathode medium in an environmental transmission electron microscope to in situ study Li–CO_(2)/O_(2)(mix CO_(2)as well as O_(2)at a volume ratio of 1:1)and Li–O_(2)batteries as well as Li–CO_(2)*** discharge reactions take place successively in the Li–CO_(2)/O_(2)–CuSe nanobattery:(I)4Li^(+)+O_(2)+4e^(−)→2Li_(2)O;(II)Li_(2)O+CO_(2)→Li_(2)CO_(3).The charge reaction proceeded via(III)2Li_(2)CO_(3)→4Li^(+)+2CO_(2)+O_(2)+4e^(−).However,Li–O_(2)and Li–CO_(2)nanobatteries showed poor cycling stability,suggesting the difficulty in the direct decomposition of the discharge *** fluctuations of the Li–CO_(2)/O_(2)battery's electrochemistry were also shown to depend heavily on O_(2).The CuSe‐based Li–CO_(2)/O_(2)battery showed exceptional electrochemical *** Li^–CO_(2)/O_(2)battery offered a discharge capacity apex of 15,492 mAh g^(−1) and stable cycling 60 times at 100 mA g^(−1).Our research offers crucial insight into the electrochemical behavior of Li–CO_(2)/O_(2),Li–O_(2),and Li–CO_(2)nanobatteries,which may help the creation of high‐performance Li–CO_(2)/O_(2)batteries for energy storage applications.

关键词： CuSe nanosheets electrochemical reaction in situ environmental transmission electron microscopy Li-CO_(2)battery Li-CO_(2)/O_(2)battery Li-O_(2)battery

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Better engineering layered vanadium oxides for aqueous zinc‐ion batteries: Going beyond widening the interlayer spacing

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SmartMat 2024年第1期5卷 83-109页

作者： Yue Guo Hanmei Jiang Binbin Liu Xingyang Wang Yifu Zhang jianguo Sun John Wang Department of Materials Science and Engineering National University of SingaporeSingaporeSingapore State Key Laboratory of Fine Chemicals School of Chemical EngineeringDalian University of TechnologyDalianChina Institute of Materials Research and Engineering(IMRE) Agency for ScienceTechnology and Research(A*STAR)SingaporeSingapore

Aqueous zinc‐ion batteries(ZIBs)are regarded as among the most promising candidates for large‐scale grid energy storage,owing to their high safety,low costs,and environmental *** the past decade,vanadium oxides,which are exemplified by V2O5,have been widely developed as a class of cathode materials for ZIBs,where the relatively high theoretical capacity and structural stability are among the main ***,there are considerable challenges in the construction of vanadium‐based ZIBs with high capacity,long lifespan,and excellent rate *** widenings of the interlayer spacing in the layered vanadium oxides by pre‐intercalations appear to have reached their limitations in improving the energy density and other key performance parameters of ZIBs,although various metal ions(Na+,Ca2+,and Al3+)and even organic cations/groups have been ***,we discuss the advances made more recently,and also the challenges faced by the high‐performance vanadium oxides(V2O5‐based)cathodes,where there are several strategies to improve their electrochemical performance ranging from the new structural designs down to sub‐nano‐scopic/molecular/atomic levels,including cation pre‐intercalation,structural water optimization,and defect engineering,to macroscopic structural *** key principles for an optimal structural design of the V2O5‐based cathode materials for high energy density and fast‐charging aqueous ZIBs are examined,aiming at paving the way for developing energy storage designed for those large scales,high safety,and low‐cost systems.

关键词： aqueous zinc‐ion batteries cations pre‐intercalation defect engineering structural water vanadium oxides

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预冷方式对长枣保鲜效果的影响

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食品科学 2022年第23期43卷 261-268页

作者：李燕刘贵珊何建国李月陈亚鹏宁夏大学食品与葡萄酒学院宁夏银川750021

为了探究不同预冷方式对长枣保鲜效果的影响,本实验采用真空、压差和冷库预冷处理长枣,分析(1±1)℃贮藏期间长枣品质及抗氧化酶活力的变化。结果表明,与未预冷相比,3种预冷处理均抑制了长枣的质量损失和软化,维持了可溶性固形物含量、... 详细信息

为了探究不同预冷方式对长枣保鲜效果的影响,本实验采用真空、压差和冷库预冷处理长枣,分析(1±1)℃贮藏期间长枣品质及抗氧化酶活力的变化。结果表明,与未预冷相比,3种预冷处理均抑制了长枣的质量损失和软化,维持了可溶性固形物含量、可滴定酸质量分数及抗坏血酸含量,延缓了丙二醛积累和细胞膜透性增加。同时,预冷处理通过提高抗坏血酸过氧化物酶、超氧化物歧化酶和过氧化氢酶活力增强了细胞抗氧化能力,延缓了果实的氧化褐变和衰老。其中,压差预冷与其他处理组相比,能更显著抑制丙二醛积累和细胞膜透性增加,抑制细胞膜脂质过氧化保护细胞结构,同时维持较高的抗氧化酶活力,抵御氧化胁迫,抑制褐变,从而维持较高的贮藏品质,保鲜效果更佳。主成分分析结果进一步证明,压差预冷处理长枣贮藏稳定性更高,保鲜效果优于真空预冷和冷库预冷。综上所述,压差预冷能够有效维持长枣贮藏品质,延缓成熟和衰老进程。

关键词：长枣预冷品质保鲜

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Threshold friction velocity influenced by soil particle size within the Columbia Plateau, northwestern United States

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Journal of Arid Land 2024年第8期16卷 1147-1162页

作者： MENG Ruibing MENG Zhongju Brenton SHARRATT ZHANG jianguo CAI Jiale CheN Xiaoyan College of Desert Control Science and Engineering Inner Mongolia Agricultural UniversityHohhot 010018China Key Laboratory of Aeolian Physics and Desertification Control Engineering from Inner Mongolia Autonomous Region Inner Mongolia Agricultural UniversityHohhot 010018China Key Laboratory of Desert Ecosystem Conservation and Restoration State Forestry and Grassland Administration of ChinaInner Mongolia Agricultural UniversityHohhot 010018China USDA-Agricultural Research Service Washington State UniversityWashington 99164USA College of Resources and Environment Northwest A&F UniversityYangling 712100China Inner Mongolia Autonomous Region Academy of Social Sciences Hohhot 010010China

Wind erosion is a geomorphic process in arid and semi-arid areas and has substantial implications for regional climate and *** the Columbia Plateau of northwestern United States,the emissions from fine particles of loessial soils often contribute to the exceedance of inhalable particulate matter(PM)with an aerodynamic diameter of 10μm or less(PM10)according to the air quality ***,little is known about the threshold friction velocity(TFV)for particles of different sizes that comprise these *** this study,soil samples of two representative soil types(Warden sandy loam and Ritzville silt loam)collected from the Columbia Plateau were sieved to seven particle size fractions,and an experiment was then conducted to determine the relationship between TFV and particle size *** results revealed that soil particle size significantly affected the initiation of soil movement and TFV;TFV ranged 0.304-0.844 and 0.249-0.739 m/s for different particle size fractions of Ritzville silt loam and Warden sandy loam,***10 and total suspended particulates(TSP)emissions from a bed of 63-90μm soil particles were markedly higher for Warden sandy loam than for Ritzville silt *** with the lower TFV of Warden sandy loam,dust emissions from fine particles(he region's atmosphere,since the PM10 emissions from the soil erosion surfaces and its ensuing suspension within the atmosphere constitute an essential process of soil erosion in the Columbia *** and implementing strategic land management practices on sandy loam soils is therefore necessary to control dust emissions in the Columbia Plateau.

关键词： particle size threshold friction velocity inhalable particulate matter total suspended particles Warden sandy loam Ritzville silt loam Columbia Plateau

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Pilot Test of Preparing 2-Alkylanthraquinone Using Alkylation-Oxidation Technology

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China Petroleum Processing & Petrochemical Technology 2024年第1期26卷 88-97页

作者： Zheng Bo Qian jianguo Shi Peng Pan Zhiyong Qie Siyuan Zhang Yueqin Fei Jianqi Qiao Liang Zong Baoning SINOPEC Research Institute of Petroleum Processing Co. LtdBeijing 100083 Shijiazhuang United Petrochemical Co. LtdShijiazhuang 050011

To expedite the development of industrial technology for producing 2-alkylanthraquinone,a novel pilot test of alkylation-oxidation technology was *** process mainly included anthracene alkylation,separation of anthracene and 2-alkylanthracene,oxidation of 2-alkylanthracene,and product *** alkylation conditions yielded a 91.1%conversion of anthracene and a 71.73%selectivity for *** address the separation problem of anthracene and 2-alkylanthracene,solvent-assisted distillation technology was developed,resulting in a 98.9%purity of 2-alkylanthracene and a 91.82%separation *** the molar ratio of H2O_(2) to 2-alkylanthracene was 7:1,a 98.96%conversion of 2-alkylanthracene and a 99.94%selectivity for 2-alkylanthraquinone were achieved.A novel composition of 2-alkylanthraquinone,including 2-tert-butylanthraquinone,2-tert-amylanthraquinone,and 2-hexylanthraquinone,was *** composition could be effectively separated and purified through a combination of crystallization and washing *** elemental composition of the product met the existing standards,and its hydrogenation performance closely matched that of commercially available 2-tert-amylanthraquinone products.

关键词： anthracene 2-alkylanthracene 2-alkylanthraquinone alkylation oxidation hydrogen peroxide

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