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FLOW OF OLDROYD-B FLUID IN ROTATING CURVED SQUARE DUCTS

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Journal of Hydrodynamics 2007年第1期19卷 36-41页

作者： ZHANG Ming-kan SHEN Xin-rong MA jian-feng ZHANG Ben-zhao Institute of Fluid Engineering Zhejiang University Hangzhou 310027 China

The fully developed Oldroyd-B fluid flow through rotating square ducts was numerically studied. The effects of the rotation on secondary flow, axial velocity, and axial normal stress were examined in detail. The results indicated that all of the secondary flow, the axial flow, and the axial normal stress were evidently affected by the rotation. The Taylor-Proudman phenomenon could be observed in the flow. For the secondary flow, the four vortices structure and the six vortices structure were described. Recent studies also showed the effects of rotation on the axial normal stress.

关键词： curved ducts Oldroyd-B fluid rotating axialnormal stress

Glucose,cellobiose,lactose and raffinose used as chiral stationary phases in HPLC

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Chinese Chemical Letters 2008年第10期19卷 1248-1251页

作者： jian Yu Wang feng zhao Mei Zhang Ya Peng Li Ming Yuan Department of Chemistry Yunnan Normal University Kunming 650092 China

This paper presents the enantioseparation using glucose, cellobiose, lactose and raffinose as chiral selector bonded to silica gel via an arm in HPLC. Surprisingly, they also possess high enantioseparation selectivity, may be used in normal-phase and reversed- phase mode, and there is a big chiral discriminating complementary. This work indicates that oligosaccharides could soon become very attractive as a new class of chiral stationary phase for HPLC.

关键词： Oligosaccharides Chiral stationary phase HPLC

Purification and Characterization of a New Heme-Binding （HBP59） from the Mutant Strain DJ35 of Azotobacter vinelandii

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Journal of Integrative Plant Biology 2007年第3期49卷 336-342页

作者： Shao-Min Bian Huang-Ping Wang Hui-Na Zhou Ying zhao jian-feng zhao Ju-Fu Huang Key Laboratory of Photosynthesis and Environmental Molecular Physiology Institute of Botany the Chinese Academy of Sciences Beijing 100093 China Bioengineering College Fujian Normal University Fuzhou 350007 China Graduate School the Chinese Academy of Sciences Beijing 100039 China

A new protein, an approximately 59-kDa monomer containing iron atoms, was first isolated from the mutant strain DJ35 of Azotobacter vinelandii Llpmann. After analysis by matrix-assisted laser desorptlon ionization time-of-flight mass spectrometry, the protein was Identified as the product of a predicted gene. Thus, the protein was tentatively called HBP59. Its absorption spectra （ABS） In the reduced state exhibited three peaks at 421,517, and 556 nm and the maximal peak was shifted from 421 to 413 nm after exposure of HBP59 to air. The Soret circular dichrolsm （CD） spectrum of HBP59 In the reduced state displayed four positive peaks at 364, 382, 406, and 418 nm and two negative peaks at 398 and 433 nm; the △ε （CD extinction coefficient） values of these peaks were found to be 0.92, 0.58, 0.87, 0.72, -0.65 and -1.12 L/mol per cm, respectively. Titration with heme showed that the protein has 0.1 heme molecules/protein molecule. After HBP59 had fully Interacted with heme, Its maximal ABS value and Soret CD Intensity were increased by approximately 10-fold compared with values before Interaction. Therefore, It seems that one molecule of HBP59 can be interacted with only one heme. These results indicate that HBP59 contains heme with low spin and may be Involved In heme utilization or adhesion.

关键词： absorption spectra Azotobacter vinelandii characterization by matrix-assisted laser desorption ionization time-of-flight (MALDI-TOF) circular dichroism spectra and titration heme-binding protein (HBP59) mutant strain DJ35 purification

Identification of Contaminations Hiding Beneath the α- and β-Subunits of Partially Purified Nitrogenase MoFe Protein on the Sodium Dodecyl Sulfate Gel

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Journal of Integrative Plant Biology 2005年第11期47卷 1364-1371页

作者： Hui-Na ZHOU Ying zhao Shao-Min BIAN jian-feng zhao Fei REN Huang-Ping WANG Ju-Fu HUANG Key Laboratory of Photosynthesis and Environmental Molecular Physiology Institute of Botany the Chinese Academy of Sciences Beijing 100093 China Graduate School of the Chinese Academy of Sciences Beijing 100039 China China Agricultural University Beijing 100094 China Fujian Normal University Fuzhou 350007 China

To identify the unknown proteins that would contaminate the α- and β-subunits of nitrogenase MoFe protein on sodium dodecyl sulfate-polyacrylamide gel electrophoresis （SDS-PAGE）, the partially purified MoFe protein （Avl） preparation was obtained from Azotobacter vinelandii Lipmann OP by chroma- tography on DEAE-cellulose （DE52） and Sephacryl S-200 columns and analyzed by PAGE and matrix- assisted laser desorption/ionization time-of-flight （MALDI-TOF） mass spectrometry. The Av 1 preparation was shown to have two main bands at the position of the α- and β-subunits of crystalline Avl on the SDS gel. However, on the anoxic native PAGE, in addition to the Avl band, the preparation was shown to have three other main bands that migrated slower than Av 1. Of these three main bands, the protein with the fastest migration was identified as bacterioferritin elsewhere. The proteins on the other two bands, termed Upper and Middle, were suggested to be two different homopolymers with the same apparent subunit electrophoretic mobilities as the α- and β-subunits of Avl, respectively. By analysis of MALDI-TOF mass spectrometry, the Upper was identified as GroEL, which belongs to the heat shock protein 60 family, and the Middle was identified as glucose-6-phosphate isomerase （PGI）. In our preparation, anoxic native electrophoresis indicated that GroEL was composed of 14 identical subunits and that PGI was composed of 10 identical subunits. This is the first report of PGI, with so many subunits. The contaminating proteins in the Av 1 preparation, mainly GroEL and PGI, could be totally or partially removed from Av 1 if the shoulders and center of the elution peak were collected separately from the Sephacryl S-200 column and the center fraction was purified further by Q-Sepharose developed with an NaC1 concentration gradient. Thus, Avl with more than 90% purity was obtained. Obviously, this modified method is useful for the purification of mutant MoFe proteins with a high purity.

关键词： Azotobacter vinelandii chaperonin GroEL glucose-6-phosphate isomerase nitrogenase Av 1.

Thermal Behavior,Nonisothermal Decomposition Reaction Kinetics of Mixed Ester Double-base Gun Propellants

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Chemical Research in Chinese Universities 2008年第5期24卷 608-614页

作者： YI jian-hua zhao feng-qi XU Si-yu GAO Hong-xu HU Rong-zu Xi＇an Modern Chemistry Research Institute Xi＇an 710065 P. R. China

The thermal decomposition behavior and nonisothermal reaction kinetics of the double-base gun propellants containing the mixed ester of triethyleneglycol dinitrate（TEGDN） and nitroglycerin（NG） were investigated by thermogravimetry（TG） and differential thermogravimetry（DTG）, and differential scanning calorimetry（DSC） under the high-pressure dynamic ambience. The results show that the thermal decomposition processes of the mixed nitric ester gun propellants have two mass-loss stages. Nitric ester evaporates and decomposes in the first stage, and nitrocellulose and centralite II（C2） decompose in the second stage. The mass loss, the DTG peak points, and the terminated temperatures of the two stages are changeable with the difference of the mass ratio of TEGDN to NG. There is only one obvious exothermic peak in the DSC curves under the different pressures. With the increase in the furnace pressure, the peak temperature decreases, and the decomposition heat increases. With the increase in the content of TEGDN, the decomposition heat decreases at 0.1 MPa and rises at high pressure. The variety of mass ratio of TEGDN to NG makes few effect on the exothermic peak temperatures in the DSC curves at different pressures. The kinetic equation of the main exothermal decomposition reaction of the gun propellant TG0601 was determined as： dα/dt=1021.59（1-α）3e-2.60×104/T. The reaction mechanism of the process can be classified as chemical reaction. The critical temperatures of the thermal explosion（Tbe and Tbp） obtained from the onset temperature（Te） and the peak temperature（Tp） are 456.46 and 473.40 K, respectively. ΔS≠, ΔH≠, and ΔG≠ of the decomposition reaction are 163.57 J·mol^-1·K^-1, 209.54 kJ·mol^-1, and 133.55 kJ·mol^-1, respectively.

关键词： Mixed nitric ester gun propellant Triethyleneglycol dinitrate Thermal behaviors Nonisothermal decomposition reaction kinetics

Suppression of low-frequency ultrasound broadband vibration using star-shaped single-phase metamaterials

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Defence Technology（防务技术） 2024年第4期34卷 217-224页

作者： Rui zhao jian Zheng Jin Guo Yunbo Shi Hengzhen feng Jun Tang Jun Liu Science and Technology on Electronic Test&Measurement Laboratory North University of ChinaTaiyuan 030051ShanxiChina School of Mechatronical Engineering Beijing Institute of TechnologyBeijing 100081China

In order to suppress the low-frequency ultrasound vibration in the broadband range of 20 k Hz—100 k Hz,this paper proposes and discusses an acoustic metamaterial with low-frequency ultrasound vibration attenuation properties,which is configured by hybrid arc and sharp-angle convergent star-shaped *** effect of the dispersion relation and the bandgap characteristic for the scatterers in star-shaped are simulated and *** target bandgap width is extended by optimizing the geometry parameters of arc and sharp-angle convergent *** proposed metamaterial configured by optimized hybrid lattices exhibits remarkable broad bandgap characteristics by bandgap complementarity,and the simulation results verify a 99%vibration attenuation amplitude can be obtained in the frequency of20 k Hz—100 k *** the fabrication of the proposed hybrid configurational star-shaped metamaterial by 3D printing technique,the transmission loss experiments are performed,and the experimental results indicate that the fabricated metamaterial has the characteristics of broadband vibration attenuation and an amplitude greater than 85%attenuation for the target *** results demonstrate that the hybrid configurational star-shaped metamaterials can effectively widen the bandgap and realize high efficiency attenuation,which has capability for the vibration attenuation in the application of highprecise equipment.

关键词： Star-shaped metamaterials Broadband Vibration attenuation Low-frequency ultrasound vibration Transmission loss

H-and J-aggregation of conjugated small molecules in organic solar cells

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Journal of Energy Chemistry 2024年第6期93卷 174-192,I0005页

作者： Qiaoqiao zhao feng He State Key Laboratory of Biobased Material and Green Papermaking Qilu University of TechnologyShandong Academy of SciencesJinan 250353ShangdongChina Shenzhen Grubbs Institute and Department of Chemistry Southern University of Science and TechnologyShenzhen 518055GuangdongChina Guangdong Provincial Key Laboratory of Catalysis Southern University of Science and TechnologyShenzhen 518055GuangdongChina

As H-and J-aggregation receive more and more attention in the research of organic solar cells(OSCs),especially in small molecular systems,deep understanding of aggregation behavior is needed to guide the design of conjugated small molecular structure and the fabrication process of OSC *** this end,this review is ***,the review firstly introduced the basic information about H-and J-aggregation of conjugated small molecules in ***,the characteristics of H-and J-aggregation and the methods to identify them were ***,it reviewed the research progress of H-and J-aggregation of conjugated small molecules in OSCs,including the factors influencing H-and J-aggregation in thin film and the effects of H-and J-aggregation on OPV performance.

关键词： H-aggregation J-aggregation Organic solar cells Small molecules Efficiency Stability

后现代地理语境下同性恋社会空间与社交网络——以北京为例

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地理学报 2016年第10期71卷 1815-1832页

作者：冯健赵楠北京大学城市与环境学院北京100871

采用参与式观察、问卷调查和访谈相结合的方法,以北京作为实证研究地区,探讨后现代地理语境下同性恋社会空间与社交网络的发展特点。北京同性恋场所呈现出多元化的发展趋势,场所影响参与者的行为和心理,而人也对场所产生反作用,群体活... 详细信息

采用参与式观察、问卷调查和访谈相结合的方法,以北京作为实证研究地区,探讨后现代地理语境下同性恋社会空间与社交网络的发展特点。北京同性恋场所呈现出多元化的发展趋势,场所影响参与者的行为和心理,而人也对场所产生反作用,群体活动使物理空间具备性别特征,并转变为充满主观感觉的"地方"。同性恋社交网络表现出对互联网的依赖性和不稳定性特点,并与同性恋者的"日常生活"空间相脱离。社交空间的破碎化、参与者的不稳定性和政府管制的影响都促成了同性恋社交网络的不稳定性。后现代地理中打破语言中心主义、提倡多元化和权力关系反转等原理可用来诠释同性恋的社交空间,另外,同性恋空间的研究从亚文化或少数群体文化的层面诠释了社会—空间辩证法。本文还对西方文献中"同性恋聚居区"和"同性恋的城市本质"论断进行了中国的回应。

关键词：同性恋社会空间社交网络 “社会—空间”辩证法北京

Large deflection deformation behavior of a Zr-based bulk metallic glass for compliant spinal fixation application

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Journal of Materials Science & Technology 2024年第6期173卷 86-99页

作者： Diao-feng Li Chun-Guang Bai Zhi-Qiang Zhang Hui-Bo Zhang Nan Li jian zhao Shi-Changxu Innovation Center for Advanced Materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China

A novel compliant spinal fixation designed based on the concept of compliant mechanisms can reduce the stress-shielding effect and adjacent segment degeneration(ASD)effectively,but propose higher requirements for the properties of the used *** metallic glasses(BMGs),as a kind of young biomaterials,exhibiting excellent comprehensive properties,which are attractive for compliant spinal ***,according to the practical service condition of the basic elements in compliant spinal fixation,large deflection deformation behaviors of Zr_(61)Ti_(2)Cu_(25)Al_(12)(at.%,ZT1)BMG beam,including elastic,yielding and plastic were investigated *** was shown that the theoretical nonlinear analytical solution curve as the benchmark not only with the capacity to predict the nonlinear load-deflection relation within the elastic deformation regime,but also assists to capture the yielding event roughly,which can be used as a powerful design tool for *** capture the beginning of the yielding event exactly,bending proof strength(σ_(p),0.05%)accompanied with tiny permanent strain of 0.05% was proposed and determined for BMGs in biomedical implant applications,which is of significance for setting the allowable operating limits of the basic flexible *** approach of interrupted loading-unloading cycles,plastic deformation driven by the bending moment can be classified into two typical stages:the initial stage which mainly characterized by the nucleation and intense interaction of abundant shear bands when the plastic strain below the critical value,and the second stage which dominated by the progressive propagation of shear bands and coupled with the emergence of shear offsets on tensile *** plasticity of BMG beam structures depends on the BMG's inherent plastic zone size(rp).When the half beam thickness less than that of the rp,the plastic deformation of BMGs will behave in a stable manner,which can be acted as the margin of safety effectiv

关键词： Metallic glasses Biomaterials Compliant spinal fixation Large deflection deformation Plastic deformation