Glucose,cellobiose,lactose and raffinose used as chiral stationary phases in HPLC
Glucose,cellobiose,lactose and raffinose used as chiral stationary phases in HPLC作者机构:Department of Chemistry Yunnan Normal University Kunming 650092 China
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:2008年第19卷第10期
页 面:1248-1251页
核心收录:
学科分类:0710[理学-生物学] 071010[理学-生物化学与分子生物学] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术]
主 题:Oligosaccharides Chiral stationary phase HPLC
摘 要:This paper presents the enantioseparation using glucose, cellobiose, lactose and raffinose as chiral selector bonded to silica gel via an arm in HPLC. Surprisingly, they also possess high enantioseparation selectivity, may be used in normal-phase and reversed- phase mode, and there is a big chiral discriminating complementary. This work indicates that oligosaccharides could soon become very attractive as a new class of chiral stationary phase for HPLC.