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Preferential Formation of Ethylene via Electrocatalytic CO_(2) Reduction on Mesoporous Cu_(2)O Nanoparticles:Synergistic Effects of Pore Structure Confinement and Surface Amine

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Chinese Journal of Chemistry 2024年第16期42卷 1846-1852页

作者： Haifeng Zhang Dun Li Zhifang chen Yingying Wang Haoyu Sun feng Liu Maochang Liu Yiqun Zheng Hongwen Huang school of Chemistry Chemical Engineering and MaterialsJining UniversityQufuShandong 273155China College of Materials Science and engineering Hunan UniversityChangshaHunan 410082China Health Management Department Shandong Vocational College of Light IndustryZiboShandong 255300China International Research Center for Renewable Energy National Key Laboratory of Multiphase Flow in Power engineering Xi'an Jiotong UniversityXi'anShaanxi 710049China

We present a facile synthetic strategy to create mesoporous Cu_(2)O nanocrystals with tunable pore structures and surface functional groups of amine derivatives for efficient and preferable electrochemical conversion of CO_(2) into *** structural characteristics of theseCu_(2)O nanocrystals can be manipulated using a set of amine derivatives,such as pyridine,4,4'-bipyridine,and hexamethylenetetramine,during the oxidative etching process of Cu nanocrystals by bubbling gaseous oxygen in N,N-dimethylformamide *** amine derivatives not only serve as surface functional groups but also significantly affect the resulting pore *** synergistic effect of pore structure confinement and surface amine functionalization leads to the superb Faradaic efficiency(FE)of 51.9% for C_(2)H_(4),respectively,together with the C_(2)H_(4) partial current density of -209.4 mA·cm^(-2) at -0.8 V *** hydrogen electrode(RHE).The relatively high selectivity towards C_(2)H_(4) was investigated using DFT simulations,where 4,4'-bipyridine functionalized Cu_(2)O seemed to favor the C_(2)H_(4) formation with the low free energy of the *** study provides a feasible strategy to manipulate the pore structure and surface functionalization of mesoporous Cu_(2)O nanocrystals by regulating the oxidative etching process,which sheds light on the rational preparation of high-performance CO_(2)RR electrocatalysts.

关键词： Amines Ethylene Cuprous oxide CO_(2)reduction Mesoporous materials

Surface-phonon-polariton-enhanced photoinduced dipole force for nanoscale infrared imaging

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National Science Review 2024年第5期11卷 227-235页

作者： jian Li Junghoon Jahng Xuezhi Ma Jing Liang Xue Zhang Qianhao Min Xiao-Liang Wang Shuangjun chen Eun Seong Lee Xing-Hua Xia State Key Lab of Analytical Chemistry for Life Science School of Chemistry and Chemical Engineering Nanjing University Hyperspectral Nano-Imaging Team Korea Research Institute of Standards and Science Institute of Materials Research and engineering Agency for ScienceTechnology and Research College of Materials Science and engineering Nanjing Tech University

The photoinduced dipole force(Pi DF) is an attractive force arising from the Coulombic interaction between the light-induced dipoles on the illuminated tip and the sample. It shows extreme sample-tip distance and refractive index dependence, which is promising for nanoscale infrared(IR) imaging of ultrathin samples. However, the existence of Pi DF in the mid-IR region has not been experimentally demonstrated due to the coexistence of photoinduced thermal force(Pi TF), typically one to two orders of magnitude higher than Pi DF. In this study, we demonstrate that, with the assistance of surface phonon polaritons, the Pi DF of c-quartz can be enhanced to surpass its Pi TF, enabling a clear observation of Pi DF spectra reflecting the properties of the real part of permittivity. Leveraging the detection of the Pi DF of phonon polaritonic substrate, we propose a strategy to enhance the sensitivity and contrast of photoinduced force responses in transmission images, facilitating the precise differentiation of the heterogeneous distribution of ultrathin samples.

关键词： surface phonon polariton photoinduced dipole force nanoscale infrared imaging ultrathin sample

A Comprehensive Study of the Association between LEPR Gene rs1137101 Variant and Risk of Digestive System Cancers

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Biomedical and Environmental Sciences 2024年第5期37卷 445-456页

作者： HU Wei Qiong ZHOU Wei Guang ZHOU Guang Wei LIAO Jia Xi SHI Jia Xing XIE fengYang LI Shou Heng WANG Yong feng Xian Hong GU Xiu Li chen Bi feng Department of Biological Science and Technology School of ChemistryChemical Engineering and Life SciencesWuhan University of TechnologyWuhan 430070HubeiChina Institute of WUT-AMU Wuhan University of TechnologyWuhan 430070HubeiChina Department of Clinical Laboratory Wuhan Xinzhou District People’s HospitalWuhan 430499HubeiChina Department of Reproductive Genetics Wuhan Huake Reproductive HospitalWuhan 430013HubeiChina

Objective The leptin receptor,encoded by the LEPR gene,is involved in tumorigenesis.A potential functional variant of LEPR,rs1137101(Gln223Arg),has been extensively investigated for its contribution to the risk of digestive system(DS)cancers,but results remain conflicting rather than ***,we performed a case–control study and subsequent meta-analysis to examine the association between rs1137101 and DS cancer *** A total of 1,727 patients with cancer(gastric/liver/colorectal:460/480/787)and 800 healthy controls were *** of rs1137101 was conducted using a polymerase chain reactionrestriction fragment length polymorphism(PCR-RFLP)assay and confirmed using Sanger ***-four eligible studies were included in the *** After Bonferroni correction,the case–control study revealed that rs1137101 was significantly associated with the risk of liver cancer in the Hubei Chinese *** meta-analysis suggested that rs1137101 is significantly associated with the risk of overall DS,gastric,and liver cancer in the Chinese *** The LEPR rs1137101 variant may be a genetic biomarker for susceptibility to DS cancers(especially liver and gastric cancer)in the Chinese population.

关键词： LEPR gene rs1137101 Digestive system cancers Genetic susceptibility Meta-analysis

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Recent advances in structural modification on graphitic carbon nitride(g-C_(3)N_(4))-based photocatalysts for high-efficiency photocatalytic H_(2)O_(2)production

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Nano Research Energy 2024年第1期3卷 101-151页

作者： feng Ming Yap Grayson Zhi Sheng Ling Brenden Jing Su jian Yiing Loh Wee-Jun Ong school of Energy and chemical engineering Xiamen University MalaysiaSelangor Darul Ehsan 43900Malaysia Center of Excellence for NaNo Energy&Catalysis Technology(CONNECT) Xiamen University MalaysiaSelangor Darul Ehsan 43900Malaysia State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China Gulei Innovation Institute Xiamen UniversityZhangzhou 363200China Shenzhen Research Institute of Xiamen University Shenzhen 518057China

To date,extensively high demand for hydrogen peroxide(H_(2)O_(2))has been predominantly supplied by the anthraquinone process for several worldwide applications,encompassing wastewater treatment,environmental remediation,and chemical ***,the compacted manufacturing,massive energy input and the release of tremendous wastes have restricted commercialization *** to mitigate such issues,the photocatalytic H_(2)O_(2)production by utilizing g-C_(3)N_(4)catalysts has endowed a greener,sustainable and promising alternative,considering that it involves water and oxygen as reactants in the present of sunlight as energy ***,we have manifested a comprehensive overview of the research progress for g-C_(3)N_(4)-based semiconductors for photocatalytic H_(2)O_(2)*** review has systematically elucidated state-of-the-art development of different modifications on g-C_(3)N_(4)to unravel the fundamental mechanism of H_(2)O_(2)evolution via oxygen reduction reaction(ORR)and water oxidation reaction(WOR).In addition,the contribution made by vacancy introduction,doping,heterogenization,and co-catalyst passivation with respect to photoefficiency enhancement have been ***,the current challenges and perspective of future development directions on photocatalytic H_(2)O_(2)production have also been *** such,g-C_(3)N_(4)stands as the next step toward advancement in the configuration and modulation of high-efficiency photocatalysts.

关键词： photocatalysis g-C_(3)N_(4) H_(2)O_(2)production structural modification

Effect of Free Radicals on Irradiation Chemistry of a Double-Coordination Organotin(Sn_(4))Photoresist by Adjusting Alkyl Ligands

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CCS Chemistry 2024年第8期6卷 2044-2053页

作者： Hao chen Yifeng Peng Haichao Fu Fuping Han Guangyue Shi feng Luo Jun Zhao Danhong Zhou Pengzhong chen Xiaojun Peng State Key Laboratory of Fine chemicals Frontiers Science Center for Smart MaterialsSchool of Chemical EngineeringDalian University of TechnologyDalian 116024 Research and Development Center of Valiant Co. Ltd.YEDAYantai 264006 school of Materials Science and engineering Nankai UniversityTianjin 300350 Shanghai Advanced Research Institute Chinese Academy of SciencesShanghai 201203 State Key Laboratory of Fine chemicals College of Materials Science and EngineeringShenzhen UniversityShenzhen 518060

Metal oxide cluster(MOC)photoresists are highly promising materials for the next generation of extreme ultraviolet lithography(EUVL).The consecutive exploration of novel MOC materials and their structural irradiation chemistry are the major concerns associated with ***,we report two bicoordinated tin-oxo clusters(TOCs),the organic ligands of which contain both adamantane carboxylic acids and alkyl groups(methyl:Sn_(4)–Me–C10;butyl:Sn_(4)–Bu–C10).We explore the correlation between the structures of the TOCs and their patterning properties by adjusting the alkyl groups coordinated to the Sn *** structural variation causes different irradiation chemistry,with Sn_(4)–Me–C10 exhibiting improved resolution and Sn_(4)–Bu–C10 demonstrating higher *** differences are attributed to the bonding energies of the Sn-methyl and Sn-butyl groups,the size of the resulting alkyl radicals,and their reaction *** clusters occur in the reactions of Sn–C bond cleavage and the decarboxylation of adamantane carboxylic acids upon ***,the entire process exhibits distinct *** on the electron-beam lithography and other experiments,we proposed irradiationinduced reaction mechanisms for both *** Sn_(4)–Bu–C10 cluster predominantly undergoes alkane chain linkage,whereas the Sn_(4)–Me–C10 cluster mainly follows the adamantanes linkage pathway.

关键词： extreme ultraviolet photoresist tin-oxo clusters free radical alkyl ligand lithographic process semiconductor manufacturing

Design of highly active and durable oxygen evolution catalyst with intrinsic chlorine inhibition property for seawater electrolysis

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Nano Materials Science 2024年第4期6卷 413-418页

作者： Jieli chen Xiaodong Shi Suyang feng Jing Li Xiaohong Gao Xiao Wu Ke Li Anyuan Qi chenghang You Xinlong Tian school of Marine Science and engineering School of Chemical Engineering and Technology Hainan University National Energy Group Ledong Power Generation Co. Ltd

High-efficiency seawater electrolysis is impeded by the low activity and low durability of oxygen evolution catalysts due to the complex composition and competitive side reactions in ***,a heterogeneousstructured catalyst is constructed by depositing NiFe-layered double hydroxides （NiFe-LDH） on the substrate of MXene （V2CTx） modified Ni foam （NF）,and abbreviated as NiFe-LDH/V2CTx/*** demonstrated,owing to the intrinsic negative charge characteristic of V2CTx,chlorine ions are denied entry to the interface between NiFeLDH and V2CTx/NF substrate,thus endowing NiFe-LDH/V2CTx/NF catalyst with high corrosion resistance and durable stability for 110 h at 500 mA ***,the two-dimensional structure and high electrical conductivity of V2CTxcan respectively enlarge the electrochemical active surface area and guarantee fast charge transfer,thereby synergistically promoting the catalytic performance of NiFe-LDH/V2CTx/NF in both deionized water electrolyte (261 m V at 100 m A cm-2) and simulated seawater electrolyte (241 mV at 100 mA cm-2).This work can guide the preparation of oxygen evolution catalysts and accelerate the industrialization of seawater electrolysis.

关键词： NiFe-LDH/V 2 CT x /NF catalyst Oxygen evolution reaction Seawater electrolysis Chlorine inhibition

In-situ physical/chemical cross-linked hydrogel electrolyte achieving ultra-stable zinc anode-electrolyte interface towards dendrite-free zinc ion battery

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Journal of Energy Chemistry 2024年第10期97卷 342-351,I0007页

作者： chen-Yang Li jiang-Lin Wang Dong-Ting Zhang Min-Peng Li Hao chen Wei-Hai Yi Xin-Ying Ren Bao Liu Xue-feng Lu Mao-cheng Liu State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals Lanzhou University of TechnologyLanzhou 730050GansuChina school of Materials Science and engineering Lanzhou University of TechnologyLanzhou 730050GansuChina Chaowei Power Group Co. LTDChangxing 313100ZhejiangChina school of Vehicle engineering Jiangsu UniversityNanjing 210031jiangsuChina

Hydrogen evolution reaction(HER),zinc corrosion,and dendrites growth on zinc metal anode are the major issues limiting the practical applications of zinc-ion ***,an in-situ physical/chemical cross-linked hydrogel electrolyte(carrageenan/polyacrylamide/ZnSO_(4),denoted as CPZ)has been developed to stabilize the zinc anode-electrolyte interface,which can eliminate side reactions and prevent dendrites *** in-situ CPZ hydrogel electrolyte improves the reversibility of zinc anode due to eliminating side reactions caused by active water ***,the electrostatic interaction between the SO_(4)^(-)groups in CPZ and Zn^(2+)can encourage the preferential deposition of zinc atoms on(002)crystal plane,which achieve dendrite-free and homogeneous zinc *** in-situ hydrogel electrolyte offers a streamlined approach to battery manufacturing by allowing for direct integration into the ***,the Zn//Zn half battery with CPZ hydrogel electrolyte can enable an ultra-long cycle over 5500 h at a current density of 0.5 mA cm^(-2),and the Zn//Cu half battery reach an average coulombic efficiency of 99.37%.The Zn//V_(2)O_5-GO full battery with CPZ hydrogel electrolyte demonstrates94.5%of capacity retention after 2100 *** study is expected to open new thought for the development of commercial hydrogel electrolytes for low-cost and long-life zinc-ion batteries.

关键词： In-suit CPZ hydrogel electrolyte Hydrogen evolution reaction and zinc corrosion Dendrites growth Zinc anode-electrolyte interface Zn ion batteries

维普期刊数据库

Pt single atoms coupled with Ru nanoclusters enable robust hydrogen oxidation for high-performance anion exchange membrane fuel cells

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Nano Research 2024年第7期17卷 6147-6156页

作者： jianmei Wang Bingxing Zhang Xiaozhong Zheng Xuerui Liu Wei Guo Zhouxin Luo Yongfeng Liu Mingxia Gao jian chen Zhongbin Zhuang Hongge Pan Wenping Sun school of Materials Science and engineering Zhejiang UniversityHangzhou 310058China Beijing Advanced Innovation Center for Soft Matter Science and engineering Beijing University of Chemical TechnologyBeijing 100029China State Key Lab of Organic–Inorganic Composites Beijing University of Chemical TechnologyBeijing 100029China Institute of Science and Technology for New Energy Xi’an Technological UniversityXi’an 710021China State Key Laboratory of Clean Energy Utilization Zhejiang UniversityHangzhou 310027China

The sluggish reaction kinetics of alkaline hydrogen oxidation reaction(HOR)is one of the key challenges for anion exchange membrane fuel cells(AEMFCs).To achieve robust alkaline HOR with minimized cost,we developed a single atom-cluster multiscale structure with isolated Pt single atoms anchored on Ru nanoclusters supported on nitrogen-doped carbon nanosheets(Pt1-Ru/NC).The well-defined structure not only provides multiple sites with varied affinity with the intermediates but also enables simultaneous modulation of different sites via interfacial *** addition to weakening Ru–H bond strength,the isolated Pt sites are heavily involved in hydrogen adsorption and synergistically accelerate the Volmer step with the help of Ru ***,this catalyst configuration inhibits the excessive occupancy of oxygen-containing species on Ru sites and facilitates the HOR at elevated *** Pt1-Ru/NC catalyst exhibits superior alkaline HOR performance with extremely high activity and excellent *** AEMFC with a 0.1 mg·cmPGM^(−2)loading of Pt1-Ru/NC anode catalyst achieves a peak powder density of 1172 mW·cm^(−2),which is 2.17 and 1.55 times higher than that of Pt/C and PtRu/C,*** work provides a new catalyst concept to address the sluggish kinetics of electrocatalytic reactions containing multiple intermediates and elemental steps.

关键词： nanoclusters multiscale structure hydrogen oxidation reaction electrocatalysis anion exchange membrane fuel cells

Reply to Comment on“chemical vapor deposition synthesis and Raman scattering investigation of quasi-one-dimensional ZrS_(3) nanoflakes”

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Nano Research 2024年第9期17卷 8649-8650页

作者： Yang chen Yuanyuan Jin Junqiang Yang Yizhang Ren Zhuojun Duan Xiao Liu jian Sun Song Liu Xukun Zhu Xidong Duan Institute of chemical Biology and Nanomedicine(ICBN) College of Chemistry and Chemical EngineeringHunan UniversityChangsha 410082China Hunan Key Laboratory of Two-Dimensional Materials and State Key Laboratory for Chemo/Biosensing and Chemometrics College of Chemistry and Chemical EngineeringHunan UniversityChangsha 410082China Department of Chemistry Southern University of Science and TechnologyShenzhen 518055China school of Physics and Electronics Central South UniversityChangsha 410083China

1 Introduction Thanks very much for *** taking time to comment on our recent paper regarding“chemical vapor deposition synthesis and Raman scattering investigation of quasi-one-dimensional ZrS_(3) nanoflakes”.We summarize the suggestions of *** as made in the comment[1].First,*** suggested that there are just three peaks of two S 2p doublets in Fig.2(b)in the original paper[1],which is inconsistent to the four peaks of previous reports[2-4].Second,*** mentioned that the ratio of two S 2p doublets is helpful to identify the sulfur vacancies,which have a great impact on the n-type semiconducting nature of ZrS_(3).Third,*** mentioned that Zr 3d peak appearing at 184.7 eV is wider than previous reports[2,4],which may be accounted by the appearance of ZrS_(2)O,and Zr remains in the tetravalent state.

关键词： state. synthesis quasi