检索结果-南通市图书馆

Journal of Energy Chemistry 2023年第4期79卷 242-252页

作者： Qixu Hu Xiaoyu Yang Ying Qi Peng Wei jian cheng Yahong Xie State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources School of Chemical Engineering and TechnologyXinjiang UniversityUrumqi 830017XinjiangChina Department of Materials&Chemical Engineering Hanyang UniversitySeoul 04763South Korea

Optimizing the interfacial properties between perovskite and carbon electrodes has always been an important way to improve the photoelectric conversion efficiency(PCE)of carbon-based perovskite solar cells(C-PSCs)and facilitate their commercialization.In this paper,nitrogen-doped graphene quantum dots(N-GQDs)with fluorescent properties were successfully prepared using inexpensive coal as raw material by a facile and environmentally friendly chemical reagent oxidation.The results show that the electron-rich pyridinic nitrogen in N-GQDs can act as Lewis bases to form coordination bonds with uncoordinated lead ions by sharing electron pairs,thereby reducing the defect density and nonradiative recombination of photo-generated electron-hole,and extending lifetime of charge carriers.In addition,due to the passivation of N-GQDs,the hysteresis effect of the device is significantly reduced and the long-term stability is also improved.By optimizing the concentration,the PCE of C-PSCs achieved a maximum of 14.31%,which was improved by 20.25%compared with 11.90%of the pristine C-PSCs.This work provides a facile,environmentally friendly and efficient strategy for improving the overall performance of C-PSCs using inexpensive coal-based N-GQDs.

关键词： Carbon-basedPSCs Nitrogen-doped GQDs Reducing the defect density Nonradiative recombination

Hexnut[12]arene and its derivatives: Synthesis, host-guest properties, and application as nonporous adaptive crystals

在线全文

学校读者我要写书评

暂无评论

Science China Chemistry 2022年第3期65卷 539-545页

作者： jian cheng Bingbing Gao Hao Tang Zhihong Sun Linxian Xu Lingyun Wang Derong Cao State Key Laboratory of Luminescent Materials and Devices School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou 510641China

Hexnut[12]arene(HN[12])and its derivatives,a new class of sixfold macrocyclic arenes,were designed and synthesized in reasonable yield by a one-pot reaction at room temperature using dimethoxymethane as a methylene source.HN[12],which bears a large,symmetric,and rigid cavity,was easily functionalized at both the methylene bridges and the hydroquinone units.A water-soluble fluorescent HN[12]was synthesized and used as a host to encapsulate benzyl viologen dichloride in water with a high binding affinity of(3.4±0.2)×10^(6)M^(-1).The nonporous adaptive crystal(NAC)of HN[12]was found to capture not only inorganic molecules(iodine)but also trace amounts of large organic molecules(basic fuchsine)from water,which greatly expands the scope of NACs for adsorption.

关键词： hexnutarene nonporous adaptive crystals macrocycle macrocyclic arene pillararene iodine capture dye capture

Transcatheter arterial chemoembolization after percutaneous microwave ablation and portal vein embolization for advanced hepatocellular carcinoma

在线全文

学校读者我要写书评

暂无评论

Hepatobiliary & Pancreatic Diseases International 2023年第2期22卷 213-216页

作者： jian cheng De-Fei Hong cheng-Wu Zhang Xiao-Ming Fan Zu-Yan Luo Wei-Feng Yao Li-Ming Jin General Surgery Cancer CenterDepartment of Hepatobiliary&Pancreatic Surgery and Minimally Invasive SurgeryZhejiang Provincial People’s HospitalAffiliated People’s Hospital of Hangzhou Medical CollegeHangzhou 310014China Department of General Surgery Sir Run Run Shaw HospitalZhejiang University School of MedicineHangzhou 310020China

To the Editor: Associating liver partition and portal vein ligation for staged hepatectomy(ALPPS) promotes the future liver remnant(FLR) rapid proliferation in the short term, which in turn provides an opportunity for... 详细信息

关键词： hepatocellular liver microwave

Analyzing the surface passivity effect of germanium oxynitride:a comprehensive approach through first principles simulation and interface state density

在线全文

学校读者我要写书评

暂无评论

Nuclear Science and Techniques 2024年第5期35卷 74-84页

作者： Sheng-Jie Du Xiu-Xia Li Yang Tian Yuan-Yuan Liu Ke Jia Zhong-Zheng Tang jian-Ping cheng Zhi Deng Yu-Lan Li Zheng-Cao Li Sha-Sha Lv College of Nuclear Science and Technology Joint Laboratory of Jinping Ultra‑Low Radiation Background Measurement of Ministry of Ecology and Environment Key Laboratory of Beam Technology of Ministry of Education Beijing Normal UniversityBeijing Normal UniversityBeijing 100875China Joint Research Center Nuctech Company LimitedBeijing 100084China Department of Engineering Physics Key Laboratory of Particle&Radiation Imaging of Ministry of EducationTsinghua UniversityBeijing 100084China Key Laboratory of Advanced Materials(MOE) School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China

High-purity germanium(HPGe)detectors,which are used for direct dark matter detection,have the advantages of a low threshold and excellent energy resolution.The surface passivation of HPGe has become crucial for achieving an extremely low energy threshold.In this study,first-principles simulations,passivation film preparation,and metal oxide semiconductor(MOS)capacitor characterization were combined to study surface passivation.Theoretical calculations of the energy band structure of the -H,-OH,and -NH_(2) passivation groups on the surface of Ge were performed,and the interface state density and potential with five different passivation groups with N/O atomic ratios were accurately analyzed to obtain a stable surface state.Based on the theoretical calculation results,the surface passivation layers of the Ge_(2)ON_(2) film were prepared via magnetron sputtering in accordance with the optimum atomic ratio structure.The microstructure,C-V,and I-V electrical properties of the layers,and the passivation effect of the Al/Ge_(2)ON_(2)/Ge MOS were characterized to test the interface state density.The mean interface state density obtained by the Terman method was 8.4×10^(11) cm^(-2) eV^(-1).The processing of germanium oxynitrogen passivation films is expected to be used in direct dark matter detection of the HPGe detector surface passivation technology to reduce the detector leakage currents.

关键词： Surface passivation High purity germanium detector Germanium nitrogen oxide Interface state density

Theoretical Analysis and Experimental Research of Surface Texture Hydrodynamic Lubrication

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Mechanical Engineering 2022年第2期35卷 174-188页

作者： Dan Li Xuefeng Yang Yuanbo Wu jian cheng Shouren Wang Zhuang Wan Wenbo Liu Guofeng Xia College of Mechanical Engineering University of JinanJinan 250022China College of Mechanical Engineering Hubei University of TechnologyHubei 430068China University of Science and Technology of China HefeiChina

The research on surface texture is developing from single macro-texture to composite micro-nano texture.The current research on the anti-friction mechanism and theoretical models of textures is relatively weak.Studying the characteristics of different types of surface textures and determining the applicable working conditions of each texture is the focus of current research.In this paper,a mathematical model of hydrodynamic lubrication is established based on Navier-Stokes equations.The FLUENT software is used to simulate and analyze the four texture models,explore the dynamic pressure lubrication characteristics of different texture types,and provide data support for texture optimization.The key variable values required by the mathematical model are obtained through the simulation data.The friction coefficient of the texture under different working conditions was measured through friction and wear experiments,and the mathematical model was verified by the experimental results.The research results show that circular texture is suitable for low to medium speed and high load conditions,chevron texture is suitable for medium to high speed and medium to high load conditions,groove texture is suitable for high speed and low load conditions,and composite texture is suitable for high speed and medium to high load conditions.Comparing the experimental results with the results obtained by the mathematical model,it is found that the two are basically the same in the ranking of the anti-friction performance of different textures,and there is an error of 10%−40%in the friction coefficient value.In this study,a mathematical model of hydrodynamic lubrication was proposed,and the solution method of the optimal surface texture model was determined.

关键词： Hydrodynamic lubrication Tribological characteristics Surface texture

Nanomedicine integrating the lipidic derivative of 5-fluorouracil,miriplatin and PD-L1 si RNA for enhancing tumor therapy

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2024年第6期35卷 385-391页

作者： An Lu Yuhao Guo Yi Yan Lin Zhai Xiangyu Wang Weiran Cao Zijie Li Zhixia Zhao Yujie Shi Yuanjun Zhu Xiaoyan Liu Huining He Zhiyu Wang jian-cheng Wang Beijing Key Laboratory of Molecular Pharmaceutics and New Drug Delivery Systems State Key Laboratory of Natural and Biomimetic DrugsSchool of Pharmaceutical SciencesPeking UniversityBeijing 100191China Tianjin Key Laboratory on Technologies Enabling Development of Clinical Therapeutics and Diagnostics School of PharmacyTianjin Medical UniversityTianjin 300070China Department of Immuno-oncology The Fourth Hospital of Hebei Medical UniversityShijiazhuang 050011China Department of Pharmacy Clinical Trial Research CenterChina-Japan Friendship HospitalBeijing 100029China Laboratory of innovative formulations and pharmaceutical excipients Ningbo Institute of Marine MedicinePeking UniversityNingbo 315832China

Immunosuppressive microenvironments present critical problems in clinical chemotherapy.To regulate the tumor immune microenvironment for enhancing antitumor effect,a combination of immune checkpoint inhibitors(ICIs)with chemotherapeutics has been applied clinically.In this study,miriplatin(MiPt),the lipidic derivative of 5-fluorouracil(Fu-OA),as well as the programmed death ligand 1(PD-L1)target si RNA(siPD-L1)were integrated into Lip-Pt/Fu@siPD-L1 nanoparticles(NPs)for chemo-immunotherapy.In vitro results showed that Lip-Pt/Fu@siPD-L1 NPs could exhibit effective siRNA gene silencing and promote the phagocytosis of tumor cells by macrophages.Furthermore,in vivo results revealed that LipPt/Fu@siPD-L1 NPs showed significantly higher anti-tumor efficiency than that of the physical mixing of Mi Pt,5-fluorouracil,and Lip@siPD-L1 NPs(delivery of siPD-L1 by liposomes).The best anti-tumor efficiency of Lip-Pt/Fu@siPD-L1 NPs resulted from the synergistic immunotherapeutic effects of Mi Pt and siPD-L1 based on the inhibition of CD47 expression and the downregulation of PD-L1 in tumor cells,which elicited a robust anti-tumor immune response through the activation of macrophage phagocytosis and immune checkpoint inhibition.The Lip-Pt/Fu@siPD-L1 NPs provide a potential strategy for tumor chemo-immunotherapy.

关键词： Chemo-immunotherapy Immune checkpoint inhibition Gene silencing Miriplatin Macrophage phagocytosis Nanotechnology

Origin and evolution of the main starch biosynthetic enzymes

在线全文

学校读者我要写书评

暂无评论

Synthetic and Systems Biotechnology 2023年第3期8卷 462-468页

作者： Hong Chang Jie Bai Hejian Zhang Rong Huang Huanyu Chu Qian Wang Hao Liu jian cheng Huifeng jiang College of Biotechnology Tianjin University of Science and TechnologyTianjin300457China Key Laboratory of Engineering Biology for Low-carbon Manufacturing Tianjin Institute of Industrial BiotechnologyChinese Academy of SciencesTianjin300308China National Center of Technology Innovation for Synthetic Biology Tianjin300308China

Starch,a semi-crystalline energy storage form primarily found in plant plastids plays a crucial role in various food or no-food applications.Despite the starch biosynthetic pathway’s main enzymes have been characterized,their origin and evolution remained a subject of debate.In this study,we conducted the comprehensive phylogenetic and structural analysis of three types of starch biosynthetic enzymes:starch synthase(SS),starch branching enzyme(SBE)and isoamylase-type debranching enzyme(ISA)from 51,151 annotated genomes.Our findings provide valuable insights into the possible scenario for the origin and evolution of the starch biosynthetic pathway.Initially,the ancestor of SBE can be traced back to an unidentified bacterium that existed before the formation of the last eukaryotic common ancestor(LECA)via horizontal gene transfer(HGT).This transfer event likely provided the eukaryote ancestor with the ability to synthesize glycogen.Furthermore,during the emergence of Archaeplastida,one clade of SS was transferred from Deltaproteobacteria by HGT,while ISA and the other clade of SS originated from Chlamydiae through endosymbiosis gene transfer(EGT).Both these transfer events collectively contributed to the establishment of the original starch biosynthetic pathway.Subsequently,after the divergence of Viridiplantae from Rhodophyta,all three enzymes underwent multiple duplications and N-terminus extension domain modifications,resulting in the formation of functionally specialized isoforms and ultimately leading to the complete starch biosynthetic pathway.By shedding light on the evolutionary origins of key enzymes involved in the starch biosynthetic pathway,this study provides important insights into the evolutionary events of plants.

关键词： Origin Evolution Starch biosynthesis Starch synthase Starch branching enzyme Isoamylase-type debranching enzyme

Positive effects of PVP in MIC:Preparation and characterization of Al-Core heterojunction fibers

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Defence Technology（防务技术） 2023年第1期19卷 52-62页

作者： Fuwei Li Yue-ting Wang cheng-ai Wang Yun Shen Ze-hua Zhang jian cheng Shuang-zhang Wu Ying-hua Ye Rui-qi Shen School of Chemistry and Chemical Engineering Nanjing University of Science&TechnologyNanjing210094China Micro-Nano Energetic Devices Key Laboratory Ministry of Industry and Information TechnologyNanjingJiangsu210094China College of Field Engineering Army Engineering University of PLANanjing210007China

The core-shell metastable intermolecular composites(MIC)have attracted much attention in the past few years due to their unique properties.Here,the preparation of Al-Core heterojunction fibers using PVP as a template is proposed.The nano-Al was directly added to the precursor solution of cupric acetate monohydrate(CAM)/Polyvinylpyrrolidone(PVP),and the initial Al@CAM/PVP fibers were obtained via electrospinning.The core-shell MIC fibers are then obtained by calcining the initial fibers.The morphology,structure,and composition of Al-core MIC fibers were characterized,that the energetic fibers calcined at 300℃,350℃,and 400℃have a core-shell structure with shell compositions CuxO and PVP,CuxO and Cu O,respectively.The energy release characteristics of Al-core MIC were investigated,and preliminary ignition tests were performed using an ignition temperature measuring instrument and a pulsed laser.The energetic fibers calcined at 300℃exhibited unique properties.The decomposition of PVP in the shell layer promoted exotherm,and a low-temperature exothermic peak was shown at 372-458℃.Lower ignition temperatures and higher flame heights were observed in the combustion tests than calcination at 350℃and 400℃.An unexpected result was that PVP can play a positive role in Al/CuO nanothermites.Simultaneously,this preparation method provided an idea for the integrated preparation of core-shell Al-Core MIC fibers and tuning the properties of MIC.

关键词： Al-Core heterojunction structure Metastable intermolecular composites(MIC) Al/CuO nanothermites Polyvinylpyrrolidone(PVP)

A Meta-Analysis of the Prognostic and Clinicopathological Significance of circZFR in Human Gastrointestinal Cancers

在线全文

学校读者我要写书评

暂无评论

International Journal of Clinical Medicine 2024年第3期15卷 134-144页

作者： Christian Cedric Bongolo Erick Thokerunga Yu Zhang jian-cheng Tu Wuhan Life Origin Biotech Joint Stock Co Ltd. Wuhan China College of Life Sciences and Technology Huazhong Agricultural University Wuhan China Department & Program of Clinical Laboratory Medicine and Center for Gene Diagnosis Zhongnan Hospital of Wuhan University Wuhan China

Background: Studies of gastrointestinal (GIT) cancers have shown that circZFR could be involved in the development and progression of various GIT cancers. However, small sample sizes limit the clinical significance of these studies. Here, a meta-analysis was conducted to ascertain the actual involvement of circZFR in the development and prognosis of GIT cancers. Methods: PubMed, Embase, Web of Science, and the Cochrane Library were searched up to December 31, 2023. Hazard ratios (HRs) or odds ratios (ORs) with 95% confidence intervals (CIs) were pooled to evaluate the association between circZFR expression and overall survival (OS). Publication bias was measured using the funnel plot and Egger’s test. Results: 10 studies having 659 participants were enrolled for meta-analysis. High circZFR expression was associated with poor OS (HR = 1.4, 95% CI: 1.20, 1.70). High circZFR expression also predicted larger tumor size (OR = 4.38, 95% CI 2.65, 7.25), advanced clinical stage (OR = 5.33, 95% CI 3.10, 9.16), and tendency for distant metastasis (OR = 2.89, 95% CI: 1.62, 5.11), but was not related to age, gender, and histological grade. Conclusions: In summary, high circZFR expression was associated with poor OS, larger tumor size, advanced stage cancer and tendency for distant metastasis. These findings suggested that circZFR could be a prognostic marker for GIT cancers.

关键词： CircZFR Gastrointestinal Prognostic Significance Meta-Analysis

Searching for the Highest Energy of Pulsation and Critical Luminosity of Swift J0243.6+6124 Observed by Insight-HXMT

维普期刊数据库博看期刊评论

在线全文

学校读者我要写书评

暂无评论

Research in Astronomy and Astrophysics 2024年第5期24卷 61-69页

作者： Qing-Xia Zhao Xian Hou Ming-Yu Ge Shuang-Nan Zhang Yun-Xiang Xiao You-Li Tuo Zi-Xu Yang Ling-Da Kong Jin-Lu Qu Shu Zhang jian-cheng Wang Yunnan Observatories Chinese Academy of SciencesKunming 650216China Key Laboratory of Particle Astrophysics Institute of High Energy PhysicsChinese Academy of SciencesBeijing 100049China University of Chinese Academy of Sciences ChineseAcademy of SciencesBeijing 100049China Key Laboratory for the Structure and Evolution of Celestial Objects Chinese Academy of SciencesKunming 650216China Institut fur Astronomic und Astrophysik Sand 1D-72076 TabingenGemany School of Physics and Optoelectronic Engineering Shandong University of TechnologyZibo 255000China

Owing to the broad energy coverage of Insight-HXMT in the hard X-ray band,we detected the highest energy of pulsation exceeding 200 keV around the 2017–2018 outburst peak of the first Galactic pulsating ultraluminous X-ray source (PULX) Swift J0243.6+6124,which is the highest energy detected from PULXs to date.We also obtained the highest energy of pulsation of every exposure during the outburst in 2017–2018,and found the highest energy is roughly positively correlated with luminosity.Using our newly developed method,we identified the critical luminosity being 4×10~(38)erg s~(-1) when the main peaks of the low and high energy pulse profiles became aligned,which separates the fan-beam dominated and pencil-beam dominated accretion regimes.Above the critical luminosity,the phase of the main peak shifted gradually from 0.5 to 0.8 until the outburst peak in al energy bands is reached,which is in agreement with the phase shift found previously at low energies.Our result is consistent with what is derived from spectral analysis.

关键词： (stars:)pulsars-individual(Swift J0243.6+6124)-X-rays binaries–stars neutron