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Friction 2021年第6期9卷 1390-1405页

作者： kang LIU jia-jie kang Guang-an ZHANG Zhi-bin LU Wen YUE School of Engineering and Technology China University of Geosciences(Beijing)Beijing 100083China Key Laboratory of Deep GeoDrilling Technology of Ministry of Natural Resources Beijing 100083China Zhengzhou Institute China University of Geosciences(Beijing)Zhengzhou 451283China State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000China

Diamond-like carbon(DLC)and graphite-like carbon(GLC)coatings have good prospects for improving the surface properties of engine ***,further understanding is needed on the effect of working conditions on tribological *** this study,GLC and two types of DLC coatings were deposited on GCr15 substrate for *** friction and wear properties of self-mated and steel-mated pairs were *** temperatures(25 and 90℃),three lubrication conditions(base oil,molybdenum dithiocarbamate(MoDTC)-containing oil,MoDTC+zinc dialkyldithiophosphate(ZDDP)-containing oil),and high Hertz contact stress(2.41 GPa)were applied in the *** results showed that high temperature promoted the effect of ZDDP on steel-mated pairs,but increased wear under base oil *** increased wear for steel-mated pairs lubricated by MoDTC-containing oil was due to abrasive wear probably caused by MoO_(3) andβ-FeMoO_(4).It was also found that in most cases,the tribological properties of self-mated pairs were better than those of steel-mated pairs.

关键词： diamond-like carbon(DLC) graphite-like carbon(GLC) mating pair temperature oil additives

Effect of vacuum heat treatment on microstructure and corrosion behavior of HVOF sprayed AICoCrFeNiCu high entropy alloy

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Journal of Iron and Steel Research International 2023年第8期30卷 1550-1561页

作者： Yong-kuan Zhou l jia-jie kang Guo Jin Xiu-fang Cui jie Zhang Guo-zheng Ma Zhi-qiang Fu Li-na Zhu Ding-shun She Yu-yun Yang School of Engineering and Technology China University of Geosciences(Beijing)Beijing 100083China School of Materials Science and Engineering Jiangsu University of Science and TechnologyZhenjiang 212100JiangsuChina Zhengzhou Institute China University of Geosciences(Beijing)Zhengzhou 451283HenanChina College of Material Science and Chemical Engineering Harbin Engineering UniversityHarbin 150001HeilongjiangChina Department of Mechanical Engineering Imperial College LondonLondon SW72AZUK National Key Lab for Remanufacturing Academy of Armored Forces EngineeringBeijing 100072China

To improve the corrosion resistance of coalbed methane drilling equipment,an AICoCrFeNiCu high entropy alloy coating was prepared on the AISI 4135(35CrMo)steel substrate by high velocity oxygen fuel(HVOF)technology,and the coating was subjected to vacuum heat treatment(VHT)at different temperatures(500,700,900 and 1100℃).The corrosion test of the substrate and the coatings after VHT in coalbed methane drilling fluid was carried *** results show that the HVOF sprayed AICoCrFeNiCu high entropy alloy(HEA)coating has a good bonding with the substrate,and the porosity of the coating is about 2.4%.There is partial segregation in the coating,and the coating mainly consists of body-centered cubic *** coating has good thermal stability,and the phase structure and microstructure of the coatings have changed after VHT at different *** with the substrate,the as-sprayed coating has better uniform corrosion resistance,and the corrosion resistance of the coating after VHT is further *** VHT at 500℃,the HVOF-sprayed AICoCrFeNiCu HEA coating has the best corrosion resistance.

关键词： High velocity oxygen fuel AICoCrFeNiCu high entropy alloy coating Vacuum heat treatment Microstructure Corrosion

Synthesis and application of green solvent dispersed organic semiconducting nanoparticles

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Nano Research 2023年第12期16卷 13419-13433页

作者： Siwen Zhang Hong Zhang Shuo Yang Xin Zhang Shilin Li Liqing Huang Ya-nan Jing Linge Xiao Yuan Zhang Bing Han jia-jie kang Huiqiong Zhou China School of Engineering and Technology China University of Geosciences(Beijing)Beijing 100083China CAS Key Laboratory of Nanosystem and Hierarchical Fabrication National Center for Nanoscience and TechnologyBeijing 100190China Beijing Tingrun Membrane Technology Development Co. Ltd.Beijing 101102China School of Chemistry Beihang UniversityBeijing 100191China The Department of thoraciccardio surgery PLA Rocket Force Characteristic Medical CenterBeijing 100088China

Organic photovoltaic semiconductors have made significant progress and have promising application prospects after decades of *** compared with traditional semiconductors,the solution method for preparing photovoltaic semiconductors shows the advantages of low cost and convenient ***,because of the extremely poor solubility of the polymers used to prepare semiconductors,toxic solvents must be used when using the solution method,which has significant negative effects on the environment and operators and severely limits its development *** nanoparticles(NPs),on the other hand,can avoid these *** NPs are typically water or alcohol-based,no toxic solvents are ***,NPs have been used in organic solar cells,hydrogen catalysis,organic light-emitting diodes,and other fields after nearly two decades of development,and their preparation methods have been *** describe the preparation,optimization,and application of NPs in photovoltaic semiconductors in this review.

关键词： nanoparticle organic semiconductor miniemulsion method nanoprecipitation method surfactant

Solution-processed Molybdenum Oxide Hole Transport Layer Stabilizes Organic Solar Cells

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Chinese Journal of Polymer Science 2023年第2期41卷 202-211页

作者： Yan-Fu Liu Si-Wen Zhang Yan-Xun Li Shi-Lin Li Li-Qing Huang Ya-Nan Jing Qian Cheng Lin-Ge Xiao Bo-Xin Wang Bing Han jia-jie kang Yuan Zhang Hong Zhang Hui-Qiong Zhou CAS Key Laboratory of Nanosystem and Hierarchical Fabrication National Center for Nanoscience and TechnologyBeijing100190China College of Chemistry Zhengzhou UniversityZhengzhou450001China School of Chemistry Beihang UniversityBeijing100191China School of Engineering and Technology China University of Geosciences(Beijing)Beijing100083China The Department of thoraciccardio surgery PLA Rocket Force Characteristic Medical CenterBeijing100088China

The hole transport layer(HTL)affects the device performance and stability of organic solar *** this work,a stable molybdenum oxide(MoO_(x))hole transport layer with low cost was prepared by adjusting the state of the precursor solution with an alcoholic solution of molybdenum acetylacetonate through an *** MoO_(x) transport layer has good transmittance with a work function of 5.07 eV and higher surface *** PM6:Y6 devices using MoO_(x) HTL achieve a high efficiency of 16.8%.MoO_(x) HTL exhibits good applicability with excellent performance in both ternary and all-polymer *** storage stability T80 of the all-polymer device using MoO_(x) HTL was over 600 h,much higher than 70 h of the PEDOT:PSS-based device,and its thermal stability at 85℃ and operational stability under light show better stability than that of the PEDOT:PSS hole transport *** work provides a facile and low-cost method to fabricate HTL for organic solar cells,which is beneficial to improve their efficiency and stability.

关键词： Hole transport layer Molybdenum oxide Stability

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长链非编码RNA在神经系统疾病中的作用

生命科学 2018年第2期30卷 151-156页

作者：奚佳捷康九红同济大学生命科学与技术学院上海200092

转录本长度超过200个核苷酸(nt)的非编码RNA被称为长链非编码RNA(lncRNA)。lncRNA可在转录和转录后水平调控基因的表达,并作为信号分子、蛋白质复合物支架、分子诱饵实现其生物功能;lncRNA的表达与多种疾病的发生密切相关。现将综述lnc... 详细信息

转录本长度超过200个核苷酸(nt)的非编码RNA被称为长链非编码RNA(lncRNA)。lncRNA可在转录和转录后水平调控基因的表达,并作为信号分子、蛋白质复合物支架、分子诱饵实现其生物功能;lncRNA的表达与多种疾病的发生密切相关。现将综述lncRNA的功能及其在神经系统疾病中的研究进展,以期了解这些疾病的发病机制,并为治疗提供新的思路。

关键词：长链非编码RNA 阿尔茨海默病帕金森氏症亨廷顿舞蹈症肌萎缩侧索硬化症精神分裂症

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聚苯胺-改性木质素磺酸的制备及电化学性能

电源技术 2018年第8期42卷 1204-1208页

作者：贾羽洁孙康陈超中国林业科学研究院林产化学工业研究所江苏南京210042

木质素磺酸经H2O2氧化之后,与甲醛和亚硫酸钠反应制得改性木质素磺酸(MLS),其具有较高的磺化度和较多的磺酸基团。利用苯胺单体和改性木质素磺酸通过原位聚合法制备聚苯胺-改性木质素磺酸(PAn-MLS)。通过热重(TG)分析MLS和PAn-MLS的结... 详细信息

木质素磺酸经H2O2氧化之后,与甲醛和亚硫酸钠反应制得改性木质素磺酸(MLS),其具有较高的磺化度和较多的磺酸基团。利用苯胺单体和改性木质素磺酸通过原位聚合法制备聚苯胺-改性木质素磺酸(PAn-MLS)。通过热重(TG)分析MLS和PAn-MLS的结构性质,结果表明与LS相比,MLS具有更好的热稳定性和更高的交联度,可以弱化PAn链之间的相互作用。采用红外光谱和X射线光电子光谱法(XPS)研究PAn-MLS的组成和表面性质,结果表明经过磺酸化改性可以提高LS的磺化度和PAn-MLS的磺酸根掺杂度。采用循环伏安法、恒电流循环寿命测试等电化学手段对比研究Pan、PAn-LS和PAn-MLS的电化学性能,在10~100 m V/s的扫速下,PAn-MLS的比电容比PAn和PAn-LS高出50.6%~70.2%。在充放电电流密度为0.2 A/g时,PAn-MLS的比电容为316.2 F/g(PAn、PAn-LS分别为242.0和254.6 F/g)。

关键词：聚苯胺木质素磺酸磺化改性电化学电容

Viscosity and structure relationship with equimolar substitution of CaO with MgO in the CaO–MgO–Al_(2)O_(3)–SiO_(2)slag melts

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 70-79页

作者： Yong Hou Shuo Zhang jie Dang jia Guo Hanghang Zhou Xuewei Lü College of Materials Science and Engineering Chongqing UniversityChongqing 400044China Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and New Materials Chongqing UniversityChongqing 400044China

Currently,the Al_(2)O_(3)content in the high-alumina slag systems within blast furnaces is generally limited to 16wt%–18.5wt%,making it challenging to overcome this *** most studies that concentrated on managing the MgO/Al_(2)O_(3)ratio or basicity,this paper explored the effect of equimolar substitution of MgO for CaO on the viscosity and structure of a high-alumina CaO-MgO-Al_(2)O_(3)-SiO_(2)slag system,providing theoretical guidance and data to facilitate the application of high-alumina *** results revealed that the viscosity first decreased and then increased with higher MgO substitution,reaching a minimum at 15mol%MgO *** transform infrared spectroscopy(FTIR)results found that the depths of the troughs representing[SiO_(4)]tetrahedra,[AlO_(4)]tetrahedra,and Si-O-Al bending became progressively deeper with increased MgO *** of the Raman spectra showed that the average number of bridging oxygens per Si atom and the X_(Q^(3))/X_(Q^(2))(X_(Q^(i))is the molar fraction of Q^(i) unit,and i is the number of bridging oxygens in a[SiO_(4)]tetrahedral unit)ratio increased from 2.30 and 1.02 to 2.52 and 2.14,respectively,indicating a progressive polymerization of the silicate structure.X-ray photoelectron spectroscopy(XPS)results highlighted that non-bridging oxygen content decreased from 77.97mol% to 63.41mol% with increasing MgO concentration,whereas bridging oxygen and free oxygen contents *** analysis demonstrated a gradual increase in the polymerization degree of the tetrahedral structure with the increase in MgO ***,bond strength is another important factor affecting the slag *** occurrence of a viscosity minimum can be attributed to the complex evolution of bond strengths of non-bridging oxygens generated during depolymerization of the[SiO_(4)]and[AlO_(4)]tetrahedral structures by CaO and MgO.

关键词： aluminosilicate viscosity structure spectroscopy

A low redox potential and long life organic anode material for sodium-ion batteries

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Journal of Energy Chemistry 2025年第1期100卷 557-564页

作者： Zhi Li Yang Wei kang Zhou Xin Huang Xing Zhou jie Xu Taoyi Kong Junwei Lucas Bao Xiaoli Dong Yonggang Wang Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Institute of New Energy Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) Fudan University Department of Chemistry Boston College School of Materials Science and Engineering Anhui University of Technology

Sodium-ion batteries （SIBs） with organic electrodes are an emerging research direction due to the sustainability of organic materials based on elements like C,H,O,and sodium ***,organic electrode materials for SIBs are mainly used as cathodes because of their relatively high redox potentials（>1 V）.Organic electrodes with low redox potential that can be used as anode are ***,a novel organic anode material （tetrasodium 1,4,5,8-naphthalenetetracarboxylate,Na4TDC） has been developed with low redox potential （<0.7 V） and excellent cyclic *** three-sodium storage mechanism was demonstrated with various in-situ/ex-situ spectroscopy and theoretical calculations,showing a high capacity of 208 mAh/g and an average decay rate of merely 0.022%per ***,the Na4TDC-hard carbon composite can further acquire improved capacity and cycling stability for 1200 cycles even with a high mass loading of up to 20 mg *** pairing with a thick Na3V2（PO4）3cathode (20.6 mg cm-2),the as-fabricated full cell exhibited high operating voltage （2.8 V）,excellent rate performance and cycling stability with a high capacity retention of 88.7% after 200 cycles,well highlighting the Na4TDC anode material for SIBs.

关键词： Organic anode material Low redox potential Composite anode Sodium-ion batteries

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脑卒中全周期康复的思考与策略

中国全科医学 2025年第2期28卷 129-134页

作者：贾杰复旦大学附属华山医院康复医学科上海市200040 福建医科大学附属第一医院福建省福州市350004 国家老年疾病临床医学研究中心(华山) 上海市200040 国家神经疾病医学中心上海市200040 国家区域医疗中心福建省福州市350000

脑卒中后患者常会遗留不同程度功能障碍,从医疗机构返回至社区家庭过程中,需要各级医疗机构配合互动、上下转介,形成良好的全周期康复闭环。目前,脑卒中全周期康复的落地应用正逐步推进,但仍存在一些阻力。本文以脑卒中全周期康复理念... 详细信息

脑卒中后患者常会遗留不同程度功能障碍,从医疗机构返回至社区家庭过程中,需要各级医疗机构配合互动、上下转介,形成良好的全周期康复闭环。目前,脑卒中全周期康复的落地应用正逐步推进,但仍存在一些阻力。本文以脑卒中全周期康复理念为基础,结合脑卒中社区康复发展现状,思考脑卒中全周期康复-社区康复环节的发展,强调“社区拐点康复”的重要意义以及基层社区康复标准建立的必要性,重视脑卒中患者康复的全周期阶段,探讨社区基层康复的发展策略,切实提高脑卒中患者社区及家庭生存质量。

关键词：脑卒中全周期康复社区康复康复标准

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Association of stent thrombectomy and conventional treatment with neuroprotection, complications, anxiety, and depression in acute ischemic stroke patients

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World Journal of Psychiatry 2025年第1期15卷 72-82页

作者： Kai-jie Yang jia-jian Huang Cai-Xia Xuan Department of Neurology Qinzhou Second People's HospitalQinzhou 535000Guangxi Zhuang Autonomous RegionChina

BACKGROUND Acute ischemic stroke(AIS)is an abrupt blood flow cessation to a specific brain region within a vascular zone,causing a subsequent decline in neurological *** thrombectomy is a recently established technique for treating *** provides the benefits of being a relatively simple and safe procedure,capable of partially enhancing a patient’s ***,some patients may experience endothelial damage and recurrent thrombosis,with clinical outcomes that are not always ***,the efficacy of this method remains *** To survey the association of stent thrombectomy vs standard treatment with neurological function protection,complications,and short-term prognosis in patients diagnosed with *** This study assigned 90 patients with AIS to the observation and control groups(n=45 patients)from December 2020 to December *** thrombectomy was conducted in the observation group,whereas routine treatment was provided to the control *** study assessed the therapeutic outcomes of two groups,including a comparison of their neurological function,living ability,anxiety and depression status,plaque area,serum inflammatory factors,serum Smur100βprotein,neuron-specific enolase(NSE),homocysteine(Hcy),and vascular endo-thelial ***,the incidence of complications was calculated and analyzed for each *** The total effective rate of treatment was 77.78%and 95.56%in the control and observation groups,*** 8 weeks of treatment,the scores on the National Institutes of Health Stroke Scale,Hamilton Anxiety Scale,and Hamilton Depression Scale decreased remarkably;the Barthel index increased remarkably,with better improvement effects of the scores in the observation group(P<0.05);total cholesterol,triglyceride,C-reactive protein,and plaque area lessened remarkably,with fewer patients in the observation group(P<0.05);S-100βprotein,NSE,and Hcy levels lessened remarkably,with fewer patients in

关键词： Stent thrombectomy Acute ischemic stroke Neurological function Complications Short-term prognosis