A low redox potential and long life organic anode material for sodium-ion batteries
作者机构：Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Institute of New Energy Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) Fudan University Department of Chemistry Boston College School of Materials Science and Engineering Anhui University of Technology
出 版 物：《Journal of Energy Chemistry》 (能源化学(英文版))
年 卷 期：2025年第100卷第1期
页 面：557-564页
核心收录：
学科分类：0808[工学-电气工程] 08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学]
基 金：financially supported by the National Key Research and Development Program of China (2022YFB2402200) the National Natural Science Foundation of China (22225201,22379028) the Fundamental Research Funds for the Central Universities (20720220010) the Shanghai Pilot Program for Basic Research–Fudan University 21TQ1400100 (21TQ009) the Key Basic Research Program of Science and Technology Commission of Shanghai Municipality (23520750400)
主 题：Organic anode material Low redox potential Composite anode Sodium-ion batteries
摘 要：Sodium-ion batteries （SIBs） with organic electrodes are an emerging research direction due to the sustainability of organic materials based on elements like C,H,O,and sodium ***,organic electrode materials for SIBs are mainly used as cathodes because of their relatively high redox potentials（1 V）.Organic electrodes with low redox potential that can be used as anode are ***,a novel organic anode material （tetrasodium 1,4,5,8-naphthalenetetracarboxylate,Na4TDC） has been developed with low redox potential （0.7 V） and excellent cyclic *** three-sodium storage mechanism was demonstrated with various in-situ/ex-situ spectroscopy and theoretical calculations,showing a high capacity of 208 mAh/g and an average decay rate of merely 0.022%per ***,the Na4TDC-hard carbon composite can further acquire improved capacity and cycling stability for 1200 cycles even with a high mass loading of up to 20 mg *** pairing with a thick Na3V2（PO4）3cathode (20.6 mg cm-2),the as-fabricated full cell exhibited high operating voltage （2.8 V）,excellent rate performance and cycling stability with a high capacity retention of 88.7% after 200 cycles,well highlighting the Na4TDC anode material for SIBs.
同方期刊数据库