检索结果-南通市图书馆

Novel ternary metals-based telluride electrocatalyst with synergistic effects of high valence non-3d metal and oxophilic Te for pH-universal hydrogen evolution reaction

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2023年第5期80卷 736-743,I0015页

作者： Seunghwan Jo Wenxiang Liu Yanan Yue Ki hoon Shin Keon Beom Lee Hyeonggeun choi Bo Hou Jung Inn Sohn Division of Physics and Semiconductor Science Dongguk UniversitySeoul 04620Republic of Korea School of Power and Mechanical Engineering Wuhan UniversityWuhan 430072HubeiChina School of Physics and Astronomy Cardiff UniversityCardiff CF243AAWalesUK

Electrocatalyst designs based on oxophilic foreign atoms are considered a promising approach for developing efficient pH-universal hydrogen evolution reaction(HER)electrocatalysts by overcoming the sluggish alkaline HER ***,we design ternary transition metals-based nickel telluride(Mo WNi Te)catalysts consisting of high valence non-3d Mo and W metals and oxophilic Te as a first demonstration of non-precious heterogeneous electrocatalysts following the bifunctional *** Mo WNi Te showed excellent HER catalytic performance with overpotentials of 72,125,and 182 mV to reach the current densities of 10,100,and 1000 mA cm^(-2),respectively,and the corresponding Tafel slope of 47,52,and 58 mV dec-1in alkaline media,which is much superior to commercial Pt/***,the HER performance of Mo WNi Te is well maintained up to 3000 h at the current density of 100 mA cm^(-2).It is further demonstrated that the Mo WNi Te exhibits remarkable HER activities with an overpotential of 45 mV(31 mV)and Tafel slope of 60 mV dec-1(34 mV dec-1)at 10 mA cm^(-2)in neutral(acid)*** superior HER performance of Mo WNi Te is attributed to the electronic structure modulation,inducing highly active low valence states by the incorporation of high valence non-3d transition *** is also attributed to the oxophilic effect of Te,accelerating water dissociation kinetics through a bifunctional catalytic mechanism in alkaline *** functional theory calculations further reveal that such synergistic effects lead to reduced free energy for an efficient water dissociation process,resulting in remarkable HER catalytic performances within universal pH environments.

关键词： Telluride catalyst Oxophilic effect High valence non-3d metal Bifunctional mechanism pH-universal hydrogen evolution reaction

Comparison of the meibomian gland dysfunction in patients with chronic ocular graft-versus-host disease and Sjogren's syndrome

在线全文

学校读者我要写书评

暂无评论

International Journal of Ophthalmology(English edition) 2019年第3期12卷 393-400页

作者： Won choi Jun Young Ha Ying Li Jung Han choi Yong Sok ji Kyung Chul Yoon Department of Ophthalmology and Research Institute of Medical Sciences Chonnam National University Medical School and Hospital

AIM: To investigate the abnormalities in the meibomian gland in patients with dry eye disease(DED) associated with chronic ocular graft-versus-host disease(coGVHD) in comparison with Sj?gren's syndrome(SS), a major form of aqueous deficient DED and meibomian gland dysfunction(MGD), a common cause of evaporative ***: A total 135 eyes of 135 subjects included in this study: patients with DED associated with coGVHD(n=30), patients with SS(n=35), patients with MGD(n=35), and normal controls(n=35). All participants completed the Ocular Surface Disease Index(OSDI) questionnaire, ocular surface examination [Schirmer test, tear film breakup time(TFBUT), and ocular surface staining], and meibomian gland assessment [meiboscore(gland dropout detected on meibography using infrared camera of the Keratograph 5 M), meibum expressibility score(MES), meibum quality score(MQS), lid margin abnormality]. In addition, correlations of meibomian gland characteristics with ocular surface parameters as well as disease severity score were investigated in coGVHD ***: The coGVHD group showed significantly higher meiboscore, MES, and MQS than the other 3 groups(all P<0.05). In the coGVHD group, parameters of meibomian gland showed a significant correlation each other and those of ocular surface. The correlation between meibomian gland parameters and severity score of co GVHD was also established(meiboscore, r=0.62; MES, r=0.47; MQS, r=0.47; lid margin abnormality score, r=0.55; all P<0.05).CONCLUSION: Patients with DED associated with co GVHD show poorer gland morphology and worse glandfunction than other types of DED. In addition, meibomian gland damage is not only associated with ocular surface damage but also disease severity of coGVHD.

关键词： chronic ocular graft-versus-host disease Sjogren's syndrome dry eye disease meibomian gland dysfunction meibography

Deep learning for development of organic optoelectronic devices:efficient prescreening of hosts and emitters in deep-blue fluorescent OLEDs

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

npj Computational Materials 2022年第1期8卷 1406-1416页

作者： Minseok Jeong Joonyoung F.Joung jinhyo Hwang Minhi Han Chang Woo Koh Dong hoon choi Sungnam Park Department of Chemistry and Research Institute for Natural Science Korea UniversitySeoul02841Korea

The highest occupied molecular orbital(HOMO)and lowest unoccupied molecular orbital(LUMO)energies,which are key factors in optoelectronic devices,must be accurately estimated for newly designed ***,we developed a deep learning(DL)model that was trained with an experimental database containing the HOMO and LUMO energies of 3026 organic molecules in solvents or solids and was capable of predicting the HOMO and LUMO energies of molecules with the mean absolute errors of 0.058 ***,we demonstrated that our DL model was efficiently used to virtually screen optimal host and emitter molecules for organic light-emitting diodes(OLEDs).Deep-blue fluorescent OLEDs,which were fabricated with emitter and host molecules selected via DL prediction,exhibited narrow emission(bandwidth=36 nm)at 412 nm and an external quantum efficiency of 6.58%.Our DL-assisted virtual screening method can be further applied to the development of component materials in optoelectronics.

关键词： emitter optoelectronic OLEDs

Calcium channel blocker monotherapy versus combination with reninangiotensin system inhibitors on the development of new-onset diabetes mellitus in hypertensive Korean patients

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Geriatric Cardiology 2019年第6期16卷 439-447页

作者： Yong hoon Kim Ae-Young Her Seung-Woon Rha Byoung Geol choi Se Yeon choi Jae Kyeong Byun Yoonjee Park Dong Oh Kang Won Young Jang Woohyeun Kim Woong Gil choi Tae Soo Kang jihun Ahn Sang-Ho Park ji Young Park Min-Ho Lee Cheol Ung choi Chang Gyu Park Hong Seog Seo Division of Cardiology Department of Internal Medicine Kangwon National University School of Medicine Chuncheon South Korea Cardiovascular Center Korea University Guro Hospital Seoul South Korea Department of Medicine Korea University Graduate School Seoul South Korea Cardiology Department Konkuk University Chungju Hospital Chungju South Korea Department of Internal Medicine Cardiovascular Division Dankook University Hospital Cheonan South Korea Department of Cardiology Soonchunhyang University Gumi Hospital Gumi South Korea Cardiology Department Soonchunhyang University Cheonan Hospital Cheonan South Korea Division of Cardiology Department of Internal Medicine Cardiovascular Center Nowon Eulji Medical Center Eulji University Seoul South Korea Department of Cardiology Soonchunhyang University College of Medicine Seoul South Korea

Background In real practice, two or more antihypertensive drugs are needed to achieve target blood pressure. We investigated the comparative beneficial actions of combination therapy of renin-angiotensin system inhibitors (RASI), with calcium channel blockers (CCB) over CCB monotherapy on the development of new-onset diabetes mellitus (NODM) in Korean patients during four-year follow-up periods. Methods A total of 3208 consecutive hypertensive patients without a history of diabetes mellitus who had been prescribed CCB were retrospectively enrolled from January 2004 to December 2012. These patients were divided into the two groups according to the additional use of RASI (the RASI group, n = 1221 and the no RASI group, n = 1987). Primary endpoint was NODM, defined as a fasting blood glucose ≥ 126 mg/dL or hemoglobin A1c ≥ 6.5%. Secondary endpoint was major adverse cardiac events (MACE) defined as total death, myocardial infarction (MI) and percutaneous coronary intervention (PCI). Results After propensity score-matched (PSM) analysis, two propensity- matched groups (939 pairs, n = 1878, C-statistic = 0.743) were generated. The incidences of NODM (HR = 1.009, 95% CI: 0.700–1.452, P = 0.962), MACE (HR = 0.877, 95% CI: 0.544–1.413, P = 0.589), total death, MI, PCI were similar between the two groups after PSM during four years. Conclusions The use of RASI in addition to CCB showed comparable incidences of NODM and MACE compared to CCB monotherapy in non-diabetic hypertensive Korean patients during four-year follow-up period. However, large-scaled randomized controlled clinical trials will be required for a more definitive conclusion.

关键词： Calcium channel blocker Diabetes mellitus Renin-angiotensin system inhibitors

A flexible electromagnetic interference shielding film coated with a hybrid solder-magnetic powder mixture on a PET substrate

在线全文

学校读者我要写书评

暂无评论

Journal of Materiomics 2018年第4期4卷 390-401页

作者： Jae Hyang Lee Dong Seok Kang Sang hoon Kim Min-Jung Son Jae Won choi Dae Keun choi Joon-Phil choi Clodualdo Aranas Jr Metal 3D Printing Convergence Research Team Korea Institute of Machinery and Materials156 Gajeongbuk-roYuseong-guDaejeon34103Republic of Korea Metal Powder Department Korea Institute of Materials Science797 Changwon-daeroSeongsan-guChangwon-siGyeongsangnam-do51508Republic of Korea Digital Manufacturing Process Group Korea Institute of Industrial Technology113e58 Seohaean-roSiheung-siGyeonggi-do15014Republic of Korea Department of Printed Electronics Korea Institute of Machinery and Materials156 Gajeongbuk-roYuseong-guDaejeon34103Republic of Korea Department of Mining and Materials Engineering McGill University3610 University StreetMontrealQuebecH3A 0C5Canada Mechanical Engineering University of New Brunswick15 Dineen DriveFrederictonNew BrunswickE3B 5A3Canada

A flexible electromagnetic interference(EMI)shielding film was innovatively fabricated using both low melting temperature solder arrays and amorphous soft magnet particulates consolidated on a polyethylene terephthalate(PET)***,the IneSneBi solder arrays presented a low melting point of 99.4C,which enabled attachment to the heat-sensitive plastic substrate without any thermal damage,and a low electrical resistivity of 14.1 mU cm,making them very effective at interrupting EM ***,the solder arrays with a high thermal conductivity of 61.2 W/(m$K)at 298.15 K were also useful as a thermal conductor for a heat ***,the solder arrays provide efficient electrical and thermal channels for electron transport induced by abruptly or consistently created EM waves due to suddenly turning on and the long term operation of electronics,***,the Fe-based magnetic particulates were added and resulted in effective saturation magnetization of 161.1 emu/g,remanence of 2.9 emu/g,and coercivity of 12.5 G,thus were able to disturb the EM pathway because of their soft magnetic ***,the hybrid EMI shielding film with exceptionally high electrical and thermal conductivity and superior soft magnetic properties provided remarkable shielding effectiveness of 102.5 dB at 10.2 GHz.

关键词： Flexible EMI shielding film PET substrate Solder arrays Magnetic particulates

Simple keratectomy and corneal tattooing for limbal dermoids:results of a 3-year study

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

International Journal of Ophthalmology(English edition) 2013年第4期6卷 463-466页

作者： Dong Min Cha Kyung-hoon Shin Keun Ho Kim ji-Won Kwon Department of Ophthalmology Jeju National University College of Medicine Jeju National University Hospital Department of Ophthalmology Myongji HospitalKwandong University College of Medicine

AIM:To evaluate and report the efficacy of combined surgical excision and corneal tattooing in patients with limbal dermoids.·METHODS:In a retrospective interventional case series,9 eyes of 8 patients were treated with combined surgery of simple keratectomy and corneal tattooing for limbal *** records,including best-corrected visual acuity,anterior segment photography,demographic,clinical data,and follow-up information were reviewed.·RESULTS:The mean follow up period in this study was 50±15(range 36-77) *** was no evidence of infection or recurrent limbal dermoids in any of the eyes during the follow-up *** patients achieved good cosmetic outcomes with no complications.·CONCLUSION:Simple keratectomy and corneal tattooing of limbal dermoids could be an alternative option for surgery,especially when a donor cornea is not available.

关键词： corneal tattooing limbal dermoid simple keratectomy

Variations in microstructure and bending formability of extruded Mg–Al–Zn–Ca–Y–MM alloy with precompression and subsequent annealing treatment conditions

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Magnesium and Alloys 2022年第9期10卷 2475-2490页

作者： Jong Un Lee Sang-hoon Kim Dong Hee Lee Hyun ji Kim Young Min Kim Sung Hyuk Park School of Materials Science and Engineering Kyungpook National UniversityDaegu 41566Republic of Korea Agency for Defense Development Daejeon 34186Republic of Korea Implementation Research Division Korea Institute of Materials ScienceChangwon 51508Republic of Korea

In this study, the bending formability of an extruded Mg–9Al–1Zn–0.3Mn–0.9Ca–0.6Y–0.5 MM(AZXWMM91100, wt%) alloy at room temperature is significantly improved through application of a combined precompression and subsequent annealing(PCA) treatment. As the amount of precompression applied along the extrusion direction(ED)(i.e., the total strain) increases from 4% to 6%, the area fraction of ED-oriented grains of the PCA-treated alloy increases, which consequently causes an improvement in its bending formability because these grains accommodate larger tensile strain along the ED during bending. As the temperature of the subsequent annealing treatment increases from 350 ℃ to 450 ℃, both the area fraction of the ED-oriented grains and the average grain size increase, and the residual dislocation density decreases owing to the promotion of boundary migration and occurrence of the recovery process at higher ***, the bending formability of both the 4%-precompressed and the 6%-precompressed samples increases with an increase in the annealing temperature. However, when the precompressed samples are annealed at 300 ℃, their bending formability is lower than that of the extruded alloy because the dislocations formed by precompression remain even after the subsequent annealing at this temperature.

关键词： Magnesium Extrusion Bending Formability Texture

Synthesis and electrocatalytic applications of flower-like motifs and associated composites of nitrogen-enriched tungsten nitride(W2N3)

在线全文

学校读者我要写书评

暂无评论

Nano Research 2020年第5期13卷 1434-1443页

作者： Sha Tan Brian M.Tackett Qun He ji hoon Lee jingguang G.Chen Stanislaus S.Wong Department of Chemistry State University of New York at Stony BrookStony BrookNY 11794-3400USA Department of Chemical Engineering Columbia UniversityNew YorkNY 10027USA Chemistry Department Building 555Brookhaven National LaboratoryUptonNY 11973USA

We have sought to improve the electrocatalytic performance of tungsten nitride through synthetic control over chemical composition and *** particular,we have generated a thermodynamically unstable but catalytically promising nitrogen-rich phase of tungsten via a hydrothermal generation of a tungsten oxide intermediate and subsequent annealing in *** net product consisted of three-dimensional(3D)micron-scale flower-like motifs of W2N3;this architecture not only evinced high structural stability but also incorporated the favorable properties of constituent two-dimensional *** a performance perspective,as-prepared 3D W2N3 demonstrated promising hydrogen evolution reaction(HER)activities,especially in an acidic environment with a measured overpotential value of−101 mV at a current density of 10 mA/cm^*** further enhance the electrocatalytic activity,small amounts of precious metal nanoparticles(such as Pt and Au),consisting of variable sizes,were uniformly deposited onto the underlying 3D W2N3 motifs using a facile direct deposition method;these composites were applied towards the CO2 reduction reaction(CO2RR).A highlight of this series of experiments was that Au/W2N3 composites were found to be a much more active HER(as opposed to either a CO2RR or a methanol oxidation reaction(MOR))catalyst.

关键词： tungsten nitride synthesis composite morphology control electrocatalysis

Practical operating flexibility of a bifunctional freestanding membrane for efficient anion exchange membrane water electrolysis across all current ranges

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Carbon Energy 2024年第9期6卷 306-324页

作者： Hong-jin Son Jeemin Hwang Min Young choi Seung Hee Park Jae Hyuk Jang Byungchan Han Sung hoon Ahn Department of Bio-Chemical Engineering Chosun UniversityGwangjuRepublic of Korea Fuel Cell Research and Demonstration Center Hydrogen Energy Research DivisionKorea Institute of Energy Research(KIER)Buan-gunJeollabuk-doRepublic of Korea Department of Chemical and Biomolecular Engineering Yonsei UniversitySeoulRepublic of Korea Center for Research Equipment Korea Basic Science InstituteDaejeonRepublic of Korea

This study explores a symmetric configuration approach in anion exchange membrane(AEM)water electrolysis,focusing on overcoming adaptability challenges in dynamic ***,a rapid and mild synthesis technique for fabricating fibrous membrane-type catalyst electrodes is *** method leverages the contrasting oxidation states between the sulfur-doped NiFe(OH)_(2) shell and the metallic Ni core,as revealed by electron energy loss *** evaluations confirm that the S–NiFe(OH)_(2) active sites optimize free energy for alkaline water electrolysis *** technique bypasses traditional energy-intensive processes,achieving superior bifunctional activity beyond current *** symmetric AEM water electrolyzer demonstrates a current density of 2 A cm^(-2) at 1.78 V at 60℃ in 1 M KOH electrolyte and also sustains ampere-scale water electrolysis below 2.0 V for 140 h even in ambient *** results highlight the system's operational flexibility and structural stability,marking a significant advance-ment in AEM water electrolysis technology.

关键词： AEM water electrolysis fibrous membrane iR correction free operational stability symmetric configuration