检索结果-南通市图书馆

International Journal of Minerals,Metallurgy and Materials 2024年第4期31卷 803-811页

作者： Xiaoyan Wang Safeer jan Zhiyong Wang Xianbo Jin College of Chemistry and Molecular Sciences Hubei Key Laboratory of Electrochemical Power SourcesWuhan UniversityWuhan 430072China Engineering Research Center of organosilicon Compounds&Materials Ministry of EducationWuhan 430072China

Co_(2) electrochemical reduction(Co_(2)ER)is an important research area for carbon ***,available catalysts for Co_(2) reduction are still characterized by limited stability and ***,metallic bismuth(Bi)has emerged as a promising catalyst for Co_(2) ***,we report the solid cathode electroreduction of commercial micronized Bi2o3as a straightforward approach for the preparation of nanostructured ***-1.1 V versus reversible hydrogen electrode in a KHCo3aqueous electrolyte,the resulting nanostructure Bi delivers a formate current density of~40 mA·cm^(-2) with a current efficiency of~86%,and the formate selectivity reaches97.6% at-0.78 *** nanosized Bi2o3as the precursor can further reduce the primary particle sizes of the resulting Bi,leading to a significantly increased formate selectivity at relatively low *** high catalytic activity of nanostructured Bi is attributable to the ultrafine and interconnected Bi nanoparticles in the nanoporous structure,which exposes abundant active sites for Co_(2) electrocatalytic reduction.

关键词： bismuth carbon dioxide electrocatalysis formate solid electroreduction

Geochronology and Petrogenesis of Late Carboniferous to Early Permian Basalts in the Central Lhasa Subterrane, Southern Tibet: Implications for the Evolution of the Sumdo Paleo-Tethys ocean

在线全文

学校读者我要写书评

暂无评论

Acta Geologica Sinica(English Edition) 2024年第4期98卷 955-968页

作者： MA Wang LIU Yingchao YANG Zhusen jan-Marten HUIZENGA LI Zhenqing YUE Longlong ZHAo Sibo School of Earth Sciences and Resources China University of GeosciencesBeijing 100083China Institute of Geology Sinoprobe LaboratoryChinese Academy of Geological SciencesBeijing 100037China MLR Key Laboratory of Metallogeny and Mineral Assessment Institute of Mineral ResourcesChinese Academy of Geological SciencesBeijing 100037China Faculty of Environmental Sciences and Natural Resource Management Norwegian University of Life SciencesNO-1432ÅsNorway Economic Geology Research Centre(EGRU) College of Science and EngineeringJames Cook UniversityTownsvilleQueensland 4811Australia Department of Geology University of JohannesburgAuckland Park 2006South Africa

Basalts from the Late Carboniferous to Early Permian are extensively developed in the central Lhasa subterrane, southern Tibet. Studying the petrogenesis of these rocks may have implications for the late Paleozoic arc magmatism along the central Lhasa subterrane uncovering more of the evolution of the Sumdo Paleo-Tethys ocean and its dynamic mechanism. Basalt samples from the Luobadui Formation in the Leqingla area, NW of Linzhou City in the central Lhasa subterrane, southern Tibet exhibit arc-like geochemical signatures in a subduction-zone tectonic setting characterized by high Al_(2)o_(3) and low Tio_(2) contents, fractionated REE patterns with low Nb/La ratios and high LREE concentrations, and negative HFSE anomalies. Based on their higher Th/Ce, Nb/Zr, and lower Ba/Th, Pb/Nd ratios, slightly negative to positive ε_(Nd)(t) values, and the relatively high Sr-Pb isotopic compositions, these samples were probably derived from partial melting of a depleted mantle source of garnet + spinel lherzolite, metasomatized by subducted sediments around 297 Ma. Modeling of the trace elements indicates that these basalts experienced fractional crystallization of olivine, clinopyroxene and minor plagioclase during magma ascent and eruption. It is proposed that these Late Carboniferous–Early Permian basalts are associated with the northward subduction of the Sumdo Paleo-Tethys ocean seafloor along the southern margin of the central Lhasa subterrane.

关键词： geochemistry northward subduction Sumdo Paleo-Tethys ocean Lhasa terrane Tibet

Electronic and thermoelectric properties of YbMg_(2)X_(2)(X=P,As,Sb,Bi)zintl compounds by first-principles method

在线全文

学校读者我要写书评

暂无评论

Journal of Rare Earths 2024年第1期42卷 147-154,I0006页

作者： Sajid Khan Dil Faraz Khan R.Neffati Tariq Usman Muhammad Waqar Ahsraf Shamim Khan Saeed Ullah jan G.Murtaza Department of Physics University of Science&Technology BannuBannu28100Pakistan Department of Physics Faculty of ScienceKing Khalid UniversityP.O.Box 9004AbhaSaudi Arabia Laboratoire de Physique de La Matiere Condensee Departement de PhysiqueFaculte des Sciences de TunisUniversite Tunis El ManarCampus Universitaire1060TunisTunisia Department of Physics Shaoxing UniversityShaoxing312000China Department of Mathematics&Natural Sciences Prince Mohammad Bin Fahd UniversityAlkhobar31952Saudi Arabia Materials Modeling Lab Department of PhysicsIslamia College Peshawar25120KhyberPakhtunkhwaPakistan

In this work the structural,electronic and thermoelectric properties of YbMg_(2)X_(2)(X=P,As,Sb,Bi)zintl compounds were investigated comprehensively using first principles *** electronic properties were studied using PBE GGA,TB-mBJ and hybrid(YS-PBE0)*** the structural parameters of optimized structures are in harmonious agreement to the available *** band structure study illustrates that the titled materials manifest metallic and semi metallic nature using PBE and TB-mBJ potentials while they show wide band gap semiconducting behavior by following hybrid(YS-PBE0)*** density of states(TDoS)and partial density of states(PDoS)were also calculated to glimpse the contribution of orbitals of atoms in the formation of *** properties were studied by using BoltzTraP2 code employed to *** get enormous values of Seebeck coefficient(S),power factor(PF)and thermoelectric figure of merit(ZT)for all the samples YbMg_(2)X_(2)(X=P,As,Sb,Bi),Moreover,the overwhelming transport properties for the titled compounds indicate the optimum level of carriers’concentration which pinpoints these materials to be better thermoelectrics in the 1-2-2 zintl family.

关键词： Zintl compounds Hybrid functional Band structure Thermoelectrics Rare earths

在线全文

学校读者我要写书评

暂无评论

腹部钝器伤的检查

英国医学杂志中文版 2008年第4期11卷 222-226页

作者： jan o jansen Steven R Yule Malcolm A Loudon 陈继业(刘毅) 董家鸿(校) Department of Surgery Aberdeen Royal Infirmary Aberdeen AB25 2ZN Department of Radiology Aberdeen Royal Infirmary 不详

隐匿性出血是腹部创伤后死亡的第二大常见原因。同时，对于那些创伤后早期存活的患者，如果腹部损伤未得到及时发现常常会导致后期病情恶化甚至死亡。因而，选择合适的检查方法可帮助外科医师制定合适的治疗方案，并且可以减少创伤后各... 详细信息

隐匿性出血是腹部创伤后死亡的第二大常见原因。同时，对于那些创伤后早期存活的患者，如果腹部损伤未得到及时发现常常会导致后期病情恶化甚至死亡。因而，选择合适的检查方法可帮助外科医师制定合适的治疗方案，并且可以减少创伤后各种并发症的发生。因此，采取合适并且快捷的检查方式是非常重要的。

关键词：腹部损伤检查方式钝器伤创伤后早期存活病情恶化治疗方案隐匿性

Dielectric and physico-chemical behavior of single thermally thick wood blocks under microwave assisted pyrolysis

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Particuology 2024年第3期86卷 291-303页

作者： Nicole Vorhauer-Huget Jakob Seidenbecher Supriya Bhaskaran Francesca Schenkel Lucas Briest Suresh Gopalkrishna jan Barowski Andrea Dernbecher Liane Hilfert Ilona Rolfes Alba Dieguez-Alonso otto von Guericke University Magdeburg Universitatsplatz 239106MagdeburgGermany Ruhr University Bochum Institute of Microwave SystemsUniversitatsstraβe 15044801BochumGermany

Pyrolysis of thermally thick beech wood blocks with a size of around 2.5×8×6 cm^(3)(width×length×height)was carried out in a lab scale microwave reactor with a frequency of 2.45 GHz,operated,both,at 300 W and 600 W under inert conditions,using N_(2) at around 400 mbar absolute *** microwave cavity had a size of 20×20×20 cm^(3).The specific energy supply referred to the untreated wood block was 4-8 W/g,with slight variations depending on the initial water *** mass loss and the reflected microwave power were in-situ monitored during the *** sample surface and chamber temperatures were measured with a pyrometer and a thermocouple,***-chemical and dielectric properties of the produced solids were investigated and compared to those of chars produced under conventional pyrolysis using the same raw *** is shown that the complex dielectric permittivity of the solid products changed drastically during the pyrolysis process,with increasing heating properties as the conversion process *** was easily achieved using 60o W without ***,300 W was not enough to achieve a high conversion degree,independently of the irradiation ***,together with the physico-chemical analyses of the solids,hinted to the importance of the transport kinetics in thermally thick materials,although further investigationis still required.

关键词： Microwave assistedpyrolysis Conventional pyrolysis Dielectric measurements Penetration depth Elemental analysis

40-meter-long REBCo tapes with critical current over 4,000 A/12 mm at 4.2 K and 13 T by advanced MoCVD

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Superconductivity 2024年第1期9卷 29-34页

作者： Mahesh Paidpilli Chirag Goel Bhabesh Sarangi Siwei Chen Eduard Galstyan jan Jaroszynski Griffin Bradford Dmytro Abraimov Venkat Selvamanickam Department of Mechanical Engineering Advanced Manufacturing InstituteTexas Center for SuperconductivityUniversity of HoustonHoustonTexasUSA AMPeers LLC HoustonTexasUSA National High Magnetic Field Laboratory TallahasseeFloridaUSA

REBa_(2)Cu_(3)o_(7−δ)(REBCo,RE=rare earth)tapes doped with 5%and 15%Zr have been scaled up to lengths more than 40 m in a pilot‐scale advanced metal organic chemical vapor deposition(A‐MoCVD)*** precursor compositions used for the long tapes were guided by a study of the influence of(Ba+dopant)/Cu content on the critical current density(Jc)of 5 and 15 mol.%Hf‐and Zr‐added tapes at 4.2 K and 13 *** 40‐mlong tapes exhibited a critical current(Ic)over 4,000 A/12 mm at 4.2 K and 13 T as well as over 1,400 A/12 mm at 20 K and 20 *** critical current densities of a 40‐m‐long tape doped with 5%Zr at 4.2 K measured at the National High Magnetic Field Laboratory(NHMFL)were>10 MAcm^(−2)and>5 MAcm^(−2)at 14 T and 30 T,respectively,which are over three times those of commercial REBCo *** infield Jc of 5%Zradded 40‐m‐long tapes was similar to those of previously‐reported high‐performance short samples made with 15%Zr or *** results demonstrate the excellent potential of A‐MoCVD for manufacturing high Ic REBCo tapes for use in ultrahigh‐field magnet applications.

关键词： High‐temperature superconductors MoCVD REBCo Critical current

Planetary Homeostasis of Reactive Nitrogen Through Anaerobic Ammonium oxidation

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Engineering 2024年第7期38卷 175-183页

作者： Guibing Zhu Bangrui Lan Shuci Liu Cameron M.Callbeck Shanyun Wang Liping Jiang Asheesh Kumar Yadav jan Vymazal Mike S.M.Jetten Ganlin Zhang Yongguan Zhu Research Center for Eco-Environmental Sciences Chinese Academy of SciencesBeijing 100085China Department of Environment and Science Queensland GovernmentBrisbaneQLD 4102Australia Department of Environmental Sciences University of BaselBasel 4056Switzerland CSIR-Institute of Minerals and Materials Technology Bhubaneswar 751013India Faculty of Environmental Sciences Czech University of Life Sciences PraguePraha 16521Czech Republic Department of Microbiology Radboud UniversityNijmegen 6525 XZThe Netherlands Key Laboratory of Watershed Geographic Sciences Nanjing Institute of Geography and LimnologyChinese Academy of SciencesNanjing 210008China State Key Laboratory of Soil and Sustainable Agriculture Institute of Soil ScienceChinese Academy of SciencesNanjing 210008China University of Chinese Academy of Sciences Beijing 100049China

The availability of nitrogen(N)is crucial for both the productivity of terrestrial and aquatic ecosystems ***,the overuse of artificial fertilizers and the energy required to fix nitrogen have pushed the global nitrogen cycle(N-cycle)past its safe operating limits,leading to severe nitrogen pollution and the production of significant amounts of greenhouse gas nitrous oxide(N2o).The anaerobic ammonium oxidation(anammox)mechanism can counteract the release of ammonium and N2o in many oxygenlimited situations,assisting in the restoration of the homeostasis of the Earth’s N *** this work,we looked into the characteristics of the anammox hotspots’distribution across various types of ecosystems *** hotspots are present at diverse oxic-anoxic interfaces in terrestrial systems,and they are most prevalent at the oxic-anoxic transition zone in aquatic *** on the discovery of an anammox hotspot capable of oxidizing ammonium anoxically into N2 without N2o by-product,we then designed an innovative concept and technical routes of nature-based anammox hotspot geoengineering for climate change,biodiversity loss,and efficient utilization of water *** 15 years of actual use,anammox hotspot geoengineering has proven to be effective in ensuring clean drinking water,regulating the climate,fostering plant and animal diversity,and enhancing longterm environmental *** sustainable biogeoengineering of anammox could be a workable natural remedy to resolve the conflicts between environmental pollution and food security connected to N management.

关键词： Biogeochemical N-cycle oxic-anoxic interface Nature-based solution Biogeoengineering Nitrogen sustainable development

Dynamics of lattice disorder in perovskite materials, polarization nanoclusters and ferroelectric domain wall structures

在线全文

学校读者我要写书评

暂无评论

npj Computational Materials 2023年第1期9卷 1137-1149页

作者： jan očenášek Ján Minár Jorge Alcalá New Technologies Research Centre University of West Bohemia in Pilsen30614 PlzeňCzech Republic Department of Materials Science and Metallurgical Engineering InSupETSEIBUniversitat Politècnica de Catalunya08028 BarcelonaSpain

The nexus between classic ferroelectricity and the structure of perovskite materials hinges on the concept of lattice *** the ordered perovskites display short-range displacements of the central cations around their equilibrium points,the lattice disorder dynamically unfolds to generate a myriad of distorted rhombohedral lattices characterized by the hopping of the central cations across*** is discovered that the lattice disorder correlates with the emergence of minimum configuration energypathways for the central cations,resulting in spatially modulated ultrafast polarization nanocluster arrangements that are stabilized by the electric charge defects in the *** high-resolution phonon dispersion analyses encompassing molecular dynamics(MD)and density functional theory(DFT)simulations,we provide unequivocal evidence linking the hopping of central cations to the development of diffuse soft phonon modes observed throughout the phase transitions of the *** massive MD simulations,we unveil the impact of lattice disorder on the structures of domain walls at finite-temperature vis-à-vis collective activation and deactivation of***,our simulations demonstrate the development of hierarchical morphotropic phase boundary(MPB)nanostructures under the combined influence of externally applied pressure and stress relaxation,characterized by sudden emergence of zig-zagged monoclinic arrangements that involve dualshifts of the central *** findings have implications for tailoring MPBs in thin-film structures and for the light-induced mobilization of *** are finally uncovered to the exploration of lattice disorder through gradual shear strain application.

关键词： perovskite lattice ferroelectric

西秦岭商丹缝合带寒武纪斜长花岗岩的成因机制——对原特提斯洋俯冲起始的启示

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

岩石矿物学杂志 2024年第2期43卷 304-329页

作者：郭祺张建新毛小红武亚威中国地质科学院地质研究所北京100037 北京大学地球与空间科学学院北京100871

大洋斜长花岗岩是指分布在蛇绿岩或现今洋壳中的少量长英质侵入体,可形成在洋中脊及俯冲带等多种构造环境,虽然其在洋壳和蛇绿岩中所在体积很小,但对探究大洋岩石圈演化、俯冲起始及洋-陆转化机制具有重要意义。本文对北秦岭造山带西段... 详细信息

大洋斜长花岗岩是指分布在蛇绿岩或现今洋壳中的少量长英质侵入体,可形成在洋中脊及俯冲带等多种构造环境,虽然其在洋壳和蛇绿岩中所在体积很小,但对探究大洋岩石圈演化、俯冲起始及洋-陆转化机制具有重要意义。本文对北秦岭造山带西段商丹缝合带内新识别出的斜长花岗岩开展了岩石学、地球化学和锆石U-Pb年代学的综合研究。全岩地球化学结果指示花岗闪长岩具有高的Sio2、Al2o3含量以及较低的K2o、Tio2含量,属于低钾亚碱性、准铝质到弱过铝质的岩石。微量元素相对富Sr、贫Nb、Ta和Ti,具有平坦的稀土元素配分模式,是弧前环境中由俯冲板片在浅部层次部分熔融成因的大洋斜长花岗岩。3个斜长花岗岩样品分别记录了526±4 Ma、515±4 Ma和517±6 Ma的锆石U-Pb年龄,结合前人同时代的玻安岩、高镁安山岩的报道,西秦岭商丹缝合带保留有与伊豆-小笠原-马里亚纳(IBM)俯冲带相似的弧前岩石组合,这些弧前的玻安岩、高镁安山岩和斜长花岗岩表明商丹洋在早寒武世发生了洋壳的初始俯冲。结合区域地质资料,认为中央造山带可能在寒武纪发生了与IBM俯冲带规模相当的俯冲起始。

关键词：西秦岭商丹缝合带斜长花岗岩部分熔融俯冲起始

Water yield and biomass production for on a eucalypt-dominated Mediterranean catchment under different climate scenarios

在线全文

学校读者我要写书评

暂无评论

林业研究:英文版 2023年第5期34卷 1263-1278页

作者： Joao Rocha Ana Quintela Dalila Serpa jan Jacob Keizer Sérgio Fabres RAIZ-Forest and Paper Research Institute Quinta de S.FranciscoRua JoséEstevao(EN 230-1)3800–783 EixoAveiroPortugal Department of Environment and Planning Centre of Environmental and Marine Studies(CESAM)University of AveiroCampus Universitário de Santiago3810–193 AveiroPortugal

Worldwide,forests are vital in the regulation of the water cycle regulation and in water balance *** of ecohydrological responses of production forests is essential to support management strategies,especially where water is already *** climatological patterns are expected to impact thermopluviometric regimes,water cycle components,hydrological responses,and plant physiology,evapotranspiration rates,crop productivity and land management *** work(1)assessed the impacts of different predicted climate conditions on water yield;(2)inferred the impacts of climate change on biomass production on eucalypt-to-eucalypt succes *** this end,the widely accepted Soil and Water Assessment Tool(SWAT)was run with the RCA,HIRHAM5 and RACMo climate models for two emission scenarios(RCP 4.5 and8.5).Three 12-year periods were considered to simulate tree growth under coppice *** results revealed an overall reduction in streamflow and water yield in the catchment in line with the projected reduction in total annual ***,HIRHAM5 and RACMo models forecast a slight shift in seasonal streamflow of up to 2 months(for2024-2048)in line with the projected increase in precipitation from May to *** biomass production,the extreme climate model(RCA)and severe emis sion scenario(RCP 8.5)predicted a decrease up to 46%.However,in the less extreme and more-correlated(with actual catchment climate conditions)climate models(RACMo and HIRHAM5)and in the less extreme emission scenario(RCP 4.5),biomass production increased(up to 20%),and the growth cycle was slightly *** was proven to be a valuable tool to assess climate change impacts on a eucalypt-dominated catchment and is a suitable decision-support tool for forest managers.

关键词： Climate scenarios Forested catchments Forest ecohydrological modelling Eucalypt biomass production SWAT model