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Journal of Environmental Sciences 2004年第3期16卷 513-519页

作者： JIANGXia jinxiang-can YANChang-zhou AyferYediler OUZi-qing AntoniusKettrup ChineseResearchAcademyofEnvironmentalScienceBeijing100012 China GSF-NationalResearchCenterforEnvironmentandHealth InstituteofEcologicalChemistry.lngolstaedterLandstraβe185764NeuherbergGermany InstituteofAppliedEeology ChineseAcademyofSciencesShenyang110015China

Advanced closed chamber system was used to study the fate of phenanthrene (3 rings PAHs) in the presence of linear alkylbenzene sulphonates(LAS). The results showed mineralization and metabolism of phenanthrene are fast in the “culture solution lava plant air' model ecological system. The distribution proportions of applied 14 C activity in this simulative ecological system were 41%—45%, 14% to 10% and 1% in plant, lava and culture solution respectively, and 18% to 29%, 11% to 8% recovered in the forms of VOCs and CO 2. Main parts of the applied 14 C activity exist in two forms, one is polar metabolites(25%) which mainly distribute in the root(23%), the other is unextractable part(23%) which have been constructed into plant root(8 98%), shoot(0 53%) or bonded to lava(13 2%). The main metabolites of phenanthrene were polar compounds(25% of applied 14 C activity), and small portion of 14 C activity was identified as non polar metabolites(6% of applied 14 C activity) and apparent phenanthrene(1 91% of applied 14 C activity). Phenanthrene and its metabolites can be taken up through plant roots and translocated to plant shoots. The presence of LAS significantly increased the the concentration of 14 C activity in the plant and production of VOCs, at the same time it decreased the phenanthrene level in the plant and the production of CO 2 at the concentration of 200 mg/L.

关键词： phenanthrene LAS plant closed chamber systems

Environmental Soil Phosphorus Testing and Phosphorus Release in Taihu Lake,China

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Pedosphere 2004年第4期14卷 461-466页

作者： HUANGQing-Hui WANGZi-Jian WANGDong-Hong： MAMei jinxiang-can GraduateSchooloftheChineseAcademyofSciences Beijing（China）

A microtiter plate assay (MPA) for soluble reactive phosphorus (SRP) was applied to samples in overlying water and pore water as well as in three forms of environmental soil test phosphorus (P) types: water soluble phosphorus (WSP),diluted calcium chloride extractable phosphorus (PCaCl2), and Olsen-P in the sediments of Taihu Lake, China, where potential P release in response to pH was analyzed. MPA for rapid P analysis was shown to be promising when applied on samples of natural water and sediment extracts. Concentrations of WSP and PCaCl2 in the sediments were much lower than those of Olsen-P. Olsen-P levels in the littoral sediments along the north coast of Meiliang Bay in Taihu Lake (80to 140 mg kg-1) were much higher than those in the mouth of the bay (less than 50 mg kg-1). The risk of P release in the mouth area of Meiliang Bay was lower than that in the north littoral zone with a risk of sediment P release induced by pH increases.

关键词： bioavailability microplate phosphorus release risk

Production of linear alkylbenzene over Ce containing Beta zeolites

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Chinese Journal of Chemical Engineering 2024年第3期67卷 220-227页

作者： Shiqi Zhang Shengzhi Gan Baoyu Liu jinxiang Dong School of Chemical Engineering and Light Industry Guangdong Provincial Key Laboratory of Plant Resources BiorefineryGuangzhou Key Laboratory of Clean Transportation Energy ChemistryGuangdong University of TechnologyGuangzhou 510006China Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory(Rongjiang Laboratory) Jieyang 515200China

Ce-encapsulated Beta zeolite was synthesized by a one-pot hydrothermal method with citric acid complexing Ce in the absence of Na *** citric acid can effectively prevent the deposition of Ce species during the hydrothermal synthesis of zeolites,leading to uniform distribution of Ce cluster in the framework of Beta ***,the sodium-free synthesis system resulted that the Brønsted acid sites were mainly located on the straight channels and external surface of Beta zeolites,improving the utilization of Brønsted acid *** addition,Ce encapsulated Beta zeolites showed enhanced activity and robust stability in the alkylation of benzene with 1-dodecene based on the synergistic effect between Ce species and Brønsted acid sites,which pave the way for its practical application in the production of alkylbenzene.

关键词： Beta zeolites Catalysis Alkylation Long-chain olefins

Highly Improved Creep Resistance in Polypropylene Through Thermally Reduced Graphene Oxide and Its Creep Lifetime Prediction

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Chinese Journal of Polymer Science 2024年第2期42卷 256-266,I0010页

作者： can-can Zhang Jun-Long Yang Ya-Jiang Huang Guang-Xian Li College of Polymer Science and Engineering State Key Laboratory of Polymer Materials Engineering of ChinaSichuan UniversityChengdu610065China

Polypropylene(PP) exhibits suboptimal creep resistance due to the presence of methyl groups on its main chain, leading to irregular chain segment distribution, diminished inter-chain interaction, and crystallinity. This structural feature causes chain slippage in PP under stress,significantly constraining its service lifetime. In this study, thermally reduced graphene oxide(TrGO) nanosheets were incorporated into the PP matrix, yielding a nanocomposite with exceptional creep resistance performance. Results demonstrated that at a stress of 25 MPa, a 2.0 wt% TrGO content could enhance the creep failure lifetime of PP by 21.5 times compared to neat PP. Rheology, transmission electron microscopy(TEM),and scanning electron microscopy(SEM) characterization techniques were employed to analyze the mechanism of TrGO's influence on PP's creep behavior. It was observed that when TrGO content exceeded 1.0 wt%, an effective particle network structure formed within the PP matrix. This homogeneously dispersed TrGO-formed particle network structure restricted the migration and rearrangement of PP molecular chains, enabling prolonged stress resistance without structural failure. By combining the time-strain superposition method with the critical failure strain as a criterion, generalized creep compliance curves for PP and its composites were established, facilitating the prediction of material creep failure lifetimes, with a strong agreement between experimental and predicted lifetime values. This research proposes a novel strategy aimed at developing polypropylene materials and products with enhanced long-term stability and durability, thus extending service life, reducing failure risk, and broadening their potential across various application domains.

关键词： Thermally reduced graphene oxide Polypropylene Creep failure and lifetime prediction

Partial aging can counter-intuitively couple with sulfidation to improve the reactive durability of zerovalent iron

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Frontiers of Environmental Science & Engineering 2024年第2期18卷 1-11页

作者： Yiwei Liu Kaili Gu Jinhua Zhang jinxiang Li Jieshu Qian Jinyou Shen Xiaohong Guan Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse School of Environmental and Biological EngineeringNanjing University of Science and TechnologyNanjing 210094China School of Ecological and Environmental Sciences East China Normal UniversityShanghai 200241China

Sulfated zero-valent iron(SZVI)has shown promising applications in wastewater ***,the rapid decline in the reactivity of SZVI with time limits its real *** mediate this problem,partial aging was proposed to improve the reactive durability of *** Cr(VI)as the target contaminant,we found that the aged ZVI(AZVI)gradually lost reactivity as aging time increased from 0.5 to 2 ***-intuitively,the partially aged SZVI(ASZVI)showed greater reactivity than SZVI when exposed to oxygenated water for a period ranging from 0.5 to 14 *** addition,the ASZVI with 0.5 d of aging time(ASZVI-0.5)not only maintained reactivity in successive runs but also increased the Cr(VI)removal capacity from 9.1 mg/g by SZVI to 19.1 mg/g by *** analysis further revealed that the electron transfer from the Fe0 core to the shell was mediated by the conductive FeS and FeS2 in the subshell of ***,the lepidocrocite and magnetite on the surface of ASZVI facilitated Cr(VI)adsorption and subsequent electron transfer for Cr(VI)***,the iron(hydr)oxide shell could retain the conductive FeS and FeS2 in the subshell,allowing ASZVI to reduce Cr(VI)efficiently and *** general,partial aging can enhance the reactive durability of ZVI when coupled with sulfidation and this synergistic effect will be beneficial to the application of SZVI-based technology for wastewater treatment.

关键词： Zerovalent iron Sulfidation Partial aging Interface reconstruction Electron transfer

Effect of sodium starch octenyl succinate-based Pickering emulsion on the physicochemical properties of hairtail myofibrillar protein gel subjected to multiple freeze-thaw cycles

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Food Science and Human Wellness 2024年第2期13卷 1018-1028页

作者： Huinan Wang Jiaxin Zhang Xinran Liu jinxiang Wang Xuepeng Li Jianrong Li Key Laboratory of Food Nutrition and Safety Ministry of EducationCollege of Food Science and EngineeringTianjin University of Science and TechnologyTianjin 300457China College of Food Science and Technology Bohai UniversityNational R&D Branch Center of Surimi and Surimi Products ProcessingJinzhou 121013China

A Pickering emulsion based on sodium starch octenyl succinate(SSOS)was prepared and its effects on the physicochemical properties of hairtail myofibrillar protein gels(MPGs)subjected to multiple freeze-thaw(F-T)cycles were *** whiteness,water-holding capacity,storage modulus(G')and texture properties of the MPGs were significantly improved by adding 1%-2%Pickering emulsion(Pcan enhance the gel properties and the F-T stability of MPGs.

关键词： Pickering emulsion Myofibrillar protein Gel properties Freeze-thaw stability Intermolecular interactions

Sirt5 desuccinylates Cdc42 to mediate osteoclastogenesis and bone remodeling in mice

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Genes & Diseases 2024年第3期11卷 75-78页

作者： Yuang Zhanngg Jing Wang Jing Luan Chuanju Liu Yazhou Cui jinxiang Han Department of Orthopedics The First Affiliated Hospital of Shandong First Medical University&Shandong Provincial Qianfoshan HospitalJi'nanShandong 250014China Biomedical Sciences College&Shandong Medicinal Biotechnology Centre Shandong First Medical University&Shandong Academy of Medical SciencesJi'nanShandong 250117China NHC Key Laboratory of Biotechnology Drugs(Shandong Academy of Medical Sciences) Ji'nanShandong 250117China Key Lab for Rare&Uncommon Diseases of Shandong Province Ji'nanShandong250117China Department of Orthopaedic Surgery New York University Grossman School of MedicineNew YorkNY 10003USA Department of Cell Biology New York University Grossman School of MedicineNewYorkNY10016USA

Post-translational modifications(PTMs)play a critical role in bone remodeling,with phosphorylation and acetylation being particularly well ***,succinylation,a relatively uncommon PTM on lysine,has received considerable research attention for its influence on several physiological and pathological processes and conditions.1 Several substrates involved in mitochondrial pathways have been validated as substrates for the desuccinylase sirtuin 5(Sirt5),a key regulator of succinylation.2 Bone is one of the most metabolically active organs,but the role of succinylation during bone remodeling is not well characterized.

关键词： remodeling organs media

Stereochemical editing:Catalytic racemization of secondary alcohols and amines

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Chinese Chemical Letters 2024年第5期35卷 17-31页

作者： Jun Zhang Zhiyao Zheng can Zhu Department of Chemistry Fudan UniversityShanghai 200438China Department of Organic Chemistry Arrhenius LaboratoryStockholm UniversityStockholm 10691Sweden

Chiral alcohols and amines are important structural units widely existing in pharmaceuticals,agrochemicals,and food *** kinetic resolution(DKR)is an efficient strategy to deliver optically active alcohols and amines from their *** the development of DKR method,racemization catalyst plays as a crucial element with the requirement of compatibility with the kinetic resolution(KR)*** this paper,recent advance in the catalytic racemization of secondary alcohols and amines is summarized based on different types of racemizing intermediates,which are redox racemization via ketone/imine intermediates,racemization via radical intermediates,and racemization via carbocation *** racemization of secondary alcohols and amines is also enclosed.

关键词： Racemization Secondary alcohols Amines Kinetic resolution Dynamic kinetic resolution

Effectively improving the extreme-pressure capacity of a class of intercalated zirconium phosphate materials

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Science China(Technological Sciences) 2024年第3期67卷 753-764页

作者： NIU WenXing ZHAO XinRui YUAN Min HOU ZhiGuo LIU Lei XU Hong DONG jinxiang Shanxi Key Laboratory of Chemical Product Engineering Cllege of Chemical Engineering and TechnologyTaiyuan University of TechnologyTaiyuan 030024China School of Chemical and Environmental Engineering Pingdingshan UniversityPingdingshan 467000China

We studied different long-chain ammonium ions intercalated zirconium phosphate α-ZrP, methylamine intercalated ZrP(MAZrP), tetramethylammonium hydroxide intercalated ZrP(TMAH-ZrP), dodecyltrimethylammonium bromide intercalated ZrP(DTAB-ZrP), and stearyl trimethyl ammonium bromide intercalated ZrP(STAB-ZrP) as grease co-additives in combination with isobutylene sulfide(SIB). The grease with co-additives displayed excellent extreme-pressure and anti-wear ***, the combination of the longest chain ammonium ion intercalated zirconium phosphate, STAB-ZrP/SIB, had the best tribological properties. In comparison to α-ZrP, the advantage of STAB-ZrP was that it did not form a large area of the dense physical film like α-ZrP on the worn surface, but rather gave the SIB a chance to contact with the fresh metal surface to generate a chemical film. Therefore, the sub-micron physical film and nanoscale chemical film always exist side by side on the contact surface during the friction process. This intercalated α-ZrP/SIB additive has great potential for use in harsh operating conditions.

关键词： intercalatedα-ZrP/SIB physical film chemical film tribological properties

Ytterbium modified birnessite MnO_(2) for improving deep oxidation of toluene

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Journal of Rare Earths 2024年第4期42卷 668-675页

作者： Linjiang Sun Yan Cheng Yujie Liu can Yi Faculty of Geosciences and Environmental Engineering Southwest Jiaotong UniversityChengdu611756China

A series of rare earth metals modified birnessite manganese dioxides(RE-Mn)was synthesized by hydrothermal method and their catalytic degradation of toluene was ***-Mn shows the best toluene oxidation activity with the conversion of T50%and T99%at 196 and 226℃,*** physiochemical characterizations identified that the high catalytic performance and excellent stability of Yb-Mn are mainly associated with its higher molar ratios of Mn^(4+)/Mn^(3+),more lattice oxygen(Olatt),and better mobility of surface adsorbed oxygen(O_(ads)).Moreover,it is confirmed that introduction of Yb into birnessite MnO_(2) facilitates the production of acetic acid at lower *** results can aid the design of high-efficiency manganese oxide catalysts for the catalytic combustion of VOCs.

关键词： Manganese oxide Rare earth metal doping Toluene Catalytic combustion