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Multiblock poly(ether-b-amide)copolymers comprised of PA1212 and PPO-PEO-PPO with specific moisture-responsive and antistatic properties

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Chinese Journal of Chemical Engineering 2023年第1期53卷 421-430页

作者： Jie jiang Wei Cheng Qiuyu Tang Xun Pan Jinjin li ling Zhao Zhenhao xi Weikang Yuan State Key Laboratory of Chemical Engineering School of Chemical EngineeringEast ChinaUniversity of Science and TechnologyShanghai 200237China Shanghai Key Laboratory of Multiphase Materials Chemical Engineering East China University of Science and TechnologyShanghai 200237China Flinders Institute for Nanoscale Science and Technology Flinders UniversitySA 5042Australia College of Chemistry and Chemical Engineering Xinjiang UniversityUrumqi 830046China

Functional multiblock poly(ether-b-amide)(PEBA)copolymers,comprised of PA1212(polyamide 1212)as hard segments and Jeffamine ED-2003 as soft segments,were successfully prepared via two-step melt polycondensation without any amidation ***,using diamino-terminated poly(propylene oxide)-poly(ethylene oxide)-poly(propylene oxide)(PPO-PEO-PPO),Jeffamine ED-2003,enhances the compatibility between polyamide oligomer and polyether,which is better than the traditional route using hydroxyl-terminated *** chemical structure of multiblock PEBAs,as well as the microphase separated structure with crystalline phase of polyamide and polyether,were confirmed by heteronuclear multiple-bond correlation spectrum,heteronuclear multiple quantum correlation spectrum,Fourier transform infrared spectroscopy(FT-IR),differential scanning calorimetry and dynamic mechanical *** hydrophilic PEBA copolymers showed water adsorption ranging from 87.3%to 17.1%depending on the polyether content,and specially showed moisture responsive behavior within seconds when exposed to *** corresponding mechanism was studied using time-resolved attenuated total reflectance FT-IR spectroscopy in the molecular level and the water diffusion coefficient was estimated to be 1.07×10^(–8)cm^(2)∙s^(-1).Two-dimensional correlation FT-IR spectra analysis was performed to confirm that the interaction between water and polyether phase was in preference to that between water and polyamide matrix,and water molecule only forms hydrogen bond with the polyether *** to the incorporation of PEO segments,the PEBAs have the surface resistivity varying from 5.6×10^(9)to 6.5×10^(10)Ω,which makes PEBA potential candidate as permanent antistatic agent.

关键词： Poly(ether-b-amide)s Moisture-responsive Antistatic In situ FT-IR 2D FT-IR analysis

Effective-Field Theory on High Spin Systems with Biaxial Crystal Field

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Communications in Theoretical Physics 2006年第6X期46卷 1105-1108页

作者： jiang Wei GUO An-Bang li xin WANG xi-Kun BAI Bao-Dong College of Sciences Shenyang University of Technology Shenyang 110023 China School of Electrical Engineering Shenyang University of Technology Shenyang 110023 China

Based on the effective-field theory with self-spin correlations and the differential operator technique, physical properties of the spin-2 system with biaxial crystal field on the .simple cubic, body-centered cubic, as well as faced-centered lattice have been studied. The influences of the external longitudinal magnetic field on the magnetization, internal energy, specific heat, and susceptibility have been discussed in detail The phenomenon that the magnetization in the ground state shows quantum effects produced by the biaxial transverse crystal field has been found.

关键词： effective-field theory magnetic properties biaxial crystal field quantum effects

Influence of electroacupuncture on ghrelin and the phosphoinositide 3-kinase/protein kinase B/endothelial nitric oxide synthase signaling pathway in spontaneously hypertensive rats

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Journal of Integrative Medicine 2022年第5期20卷 432-441页

作者： Yue Zhang Dong-ling Zhong Ya-ling Zheng Yu-xi li Yi-jie Huang Yi-jing jiang Rong-jiang Jin Juan li School of Health Preservation and Rehabilitation Chengdu University of Traditional Chinese MedicineChengdu 610075Sichuan ProvinceChina Department of Rehabilitation Medicine The Second People’s Hospital of ChengduChengdu 610017Sichuan ProvinceChina Department of Rehabilitation Medicine The Seventh Affiliated Hospital of Sun Yat-Sen UniversityShenzhen 518107Guangdong ProvinceChina Department of Rehabilitation Medicine Rehabilitation Hospital Affiliated to Fujian University of Traditional Chinese MedicineFuzhou 350003Fujian ProvinceChina

Objective To investigate the influence of electroacupuncture(EA)on ghrelin and the phosphoinositide 3-kinase/protein kinase B/endothelial nitric oxide synthase(PI3K/Akt/eNOS)signaling pathway in spontaneously hypertensive rats(SHRs).Methods Eight Wistar-Kyoto rats were used as the healthy blood pressure(BP)control(normal group),and 32 SHRs were randomized into model group,EA group,EA plus ghrelin group(EA+G group),and EA plus PF04628935 group(a potent ghrelin receptor blocker;EA+P group)using a random number *** in the normal group and model group did not receive treatment,but were immobilized for 20 min per day,5 times a week,for 4 continuous *** in the EA group,EA+G group and EA+P group were immobilized and given EA treatment in 20 min sessions,5 times per week,for 4 ***,1 h before EA,SHRs in the EA+G group and EA+P group were intraperitoneally injected with ghrelin or PF04628935,respectively,for 4 *** tail-cuff method was used to measure *** the 4-week intervention,the rats were sacrificed by cervical dislocation,and pathological morphology of the abdominal aorta was observed using hematoxylin-eosin(HE)***-linked immunosorbent assay(EliSA)was used to detect the levels of ghrelin,nitric oxide(NO),endothelin-1(ET-1)and thromboxane A2(TXA2)in the *** thoracic aortic ring experiment was performed to evaluate *** blot was used to measure the expression of PI3K,Akt,phosphorylated Akt(p-Akt)and eNOS proteins in the abdominal ***,quantitative real-time polymerase chain reaction(qRT-PCR)was conducted to measure the relative levels of mRNA expression for PI3K,Akt and eNOS in the abdominal *** EA significantly reduced the systolic BP(SBP)and diastolic BP(DBP)(Plium to some *** of EliSA indicated that higher concentrations of ghrelin and NO,and lower concentrations of ET-1 and TXA2 we

关键词： Electroacupuncture Hypertension Vascular endothelial dysfunction Ghrelin PI3K/Akt/eNOS signaling pathway

Influence of channel length on discharge performance of anode layer Hall thruster studied by particle-in-cell simulation

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Chinese Physics B 2018年第8期27卷 368-373页

作者： xi-Feng Cao Hui liu Wen-Jia jiang Zhong-xi Ning Run li Da-Ren Yu Laboratory of Plasma Propulsion Harbin Institute of Technology（HIT）Harbin 150001China

Hall thruster has the advantages of simple structure, high specific impulse, high efficiency, and long service life, and so on. It is suitable for spacecraft attitude control, North and South position keeping, and other track tasks. The anode layer Hall thruster is a kind of Hall thruster. The thruster has a longer anode area and a relatively short discharge channel. In this paper, the effect of the channel length on the performance of the anode layer Hall thruster is simulated by the PIC simulation method. The simulation results show that the change of the channel length has significant effect on the plasma parameters, such as potential and plasma density and so on. The ionization region mainly concentrates at the hollow anode outlet position, and can gradually move toward the channel outlet as the channel length decreases. The collision between the ions and the wall increases with the channel length increasing. So the proper shortening of the channel length can increase the life of the thruster. Besides, the results show that there is a best choice of the channel length for obtaining the best performance. In this paper, thruster has the best performance under a channel length of 5 mm.

关键词： anode layer Hall thruster channel length potential

Arabidopsis thaliana NOP10 is required for gametophyte formation

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Journal of Integrative Plant Biology 2018年第8期60卷 723-736页

作者： lin-xiao li Hong-Ze liao li-xi jiang Qing Tan De Ye Xue-Qin Zhang State Key Laboratory of Plant Physiology and Biochemistry College of Biological Sciences China Agricultural University State Key Laboratory of Non-Food Biomass Energy and Enzyme Technology National Engineering Research Center for Non-Food Biorefinery and Guangxi Key Laboratory of Biorefinery Guangxi Academy of Sciences College of Agriculture & Biotechnology Zhejiang University

The female gametophyte is crucial for sexual reproduction of higher plants, yet little is known about the molecular mechanisms underlying its development. Here, we report that Arabidopsis thaliana NOP10 （AtNOP10） is required for female gametophyte formation. AtNOP10 was expressed predominantly in the seedling and reproductive tissues, including anthers, pollen grains, and ovules. Mutations in AtNOP10 interrupted mitosis of the functional megaspore during early development and prevented polar nuclear fusion in the embryo sacs. AtNOP10 shares a high level of amino acid sequence similarity with Saccharornycescerevisiae （yeast） NOPIo （ScNOP1o）, an important compo- nent of the H/ACA small nucleolar ribonucleoprotein particles （H/ACA snoRNPs） implicated in 18S rRNA synthe- sis and rRNA pseudouridylation. Heterologous expression of ScNOP10 complemented the mutant phenotype of Atnop10. Thus, AtNOPIo influences functional megaspore mitosis and polar nuclear fusion during gametophyte formation in Arabidopsis.

关键词： Figure Arabidopsis thaliana NOP10 is required for gametophyte formation

Nucleation kinetics of paramagnetic and diamagnetic metal melts under a high magnetic field

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Journal of Materials Science & Technology 2021年第14期73卷 165-170页

作者： Zhipeng Long Qiuyue jiang Jiantao Wang Long Hou xing Yu Yves Fautrelle Zhongming Ren xi li State Key Laboratory of Advanced Special Steels Shanghai UniversityShanghai200072China SIMAP-EPM-Madylam/G-INP/CNRS PHELMABP 75.38402St Martin d'Heres Cedex.France

The influence of a high magnetic field(HMF)on the nucleation kinetics of paramagnetic aluminum and diamagnetic zinc melts has been investigated by differential thermal analysis(DTA).It is found that the application of an HMF increases the undercooling of pure aluminum and pure zinc at the same heatingcooling ***,the quantitative analysis of activation energy calculated from the DTA results using the Kissinger method manifests that the HMF reduces the activation energy of pure aluminum and pure *** of magnetism,the nucleation frequency under an HMF is higher than that without an ***,the increase in undercooling under the HMF is mainly attributed to the increase of the contact angle,calculated by the functional relationship between the cooling rate and *** result is consistent with the increase of the calculated nucleation work for pure aluminum and pure ***,the increase in undercooling caused by the HMF is partly ascribed to the magnetic field-induced suppression of thermal convection in the undercooled melt.

关键词： Undercooling Activation energy Nucleation work High magnetic field

Three-dimensional ATUM-SEM reconstruction and analysis of hepatic endoplasmic reticulum-organelle interactions

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Journal of Molecular Cell Biology 2021年第9期13卷 636-645页

作者： Yi jiang linlin li xi Chen Jiazheng liu Jingbin Yuan Qiwei xie Hua Han National Laboratory of Pattern Recognition Institute of AutomationChinese Academy of SciencesBeijing 100190China School of Artificial Intelligence University of Chinese Academy of SciencesBeijing 101408China School of Future Technology University of Chinese Academy of SciencesBeijing 101408China Data Mining Lab Beijing University of TechnologyBeijing 100124China CAS Center for Excellence in Brain Science and Intelligence Technology Shanghai 200031China

The endoplasmic reticulum(ER)is a contiguous and complicated membrane network in eukaryotic cells,and membrane contact sites(MCSs)between the ER and other organelles perform vital cellular functions,including lipid homeostasis,metabolite exchange,calcium level regulation,and organelle ***,we establish a whole pipeline to reconstruct all ER,mitochondria,lipid droplets,lysosomes,peroxisomes,and nuclei by automated tape-collecting ultramicrotome scanning electron microscopy and deep learning techniques,which generates an unprecedented 3D model for mapping liver ***,the morphology of various organelles and the MCSs between the ER and other organelles are systematically *** found that the ER presents with predominantly flat cisternae and is knitted tightly all throughout the intracellular space and around other *** addition,the ER has a smaller volume-to-membrane surface area ratio than other organelles,which suggests that the ER could be more suited for functions that require a large membrane surface *** data also indicate that ER-mitochondria contacts are particularly abundant,especially for branched *** study provides 3D reconstructions of various organelles in liver samples together with important fundamental information for biochemical and functional studies in the liver.

关键词： 3D reconstruction ATUM-SEM deep learning liver ER MCSs

Isomaltooligosaccharide and Bacillus regulate the duration of farrowing and weaning-estrous interval in sows during the perinatal period by changing the gut microbiota of sows

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Animal Nutrition 2021年第1期7卷 72-83页

作者： Xueling Gu jiang Chen Hao li Zehe Song ling Chang xi He Zhiyong Fan Engineering Research Center for Feed Safety and Efﬁcient Utilization of Ministry of Education Institute of Animal NutritionHunan Agricultural UniversityHunan410128China Hunan Co-Innovation Center of Animal Production Safety Hunan Agricultural UniversityHunan410128China

This study investigated the effects of isomaltooligosaccharide(IMO)and Bacillus in perinatal diets on the duration of farrowing and post-weaning estrus,serum reproductive hormone concentrations,and gut microbiota and its metabolites of *** sows(n=130)were fed diets without IMO(control,CON group),or diets containing only IMO(IMO group),IMO and Bacillus subtilis(IMOS group),IMO and Bacillus licheniformis(IMOL group),and IMO and *** and ***(IMOSL group),*** results indicate that the duration of farrowing and post-weaning estrus was shorter in sows in the IMOS,IMOL,and IMOSL groups,and the weaning-estrous interval was lower in sows in the IMOL *** addition,the lowest fecal score was observed in the IMOL group during d 106 to 112 of *** in most of the treatment groups had a higher concentration of serum prolactin and prostaglandin at farrowing,but a lower serum concentration of estradiol,oxytocin,and progesterone on d 18 of lactation than sows in the CON *** treatment groups had a higher abundance of Candidatus Methanoplasma and Bacillus and a lower abundance of Escherichia-Shigella in their feces at ***,the treatment groups had higher concentrations of total short-chain fatty acids(SCFA)in feces at farrowing and a higher concentration of branched fatty acids in feces on d 18 of ***,the abun-dance of Bacillus in feces was positively correlated with serum prostaglandin concentrations and fecal total SCFA of sows at farrowing,but was negatively correlated with the duration of ***,dietary IMO and Bacillus supplementation affected the concentration of serum reproductive hormones and the duration of farrowing and post-weaning estrus,and the gut microbiota is a key factor.

关键词： Sow Isomaltooligosaccharide Bacillus Perinatal period Duration of farrowing Gut microbiota

X射线透视引导下不同方式建立兔椎间盘退变模型的结果对比

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中国组织工程研究 2025年第5期29卷 995-1002页

作者：丁至立黄杰蒋强李土胜刘江丁宇安徽医科大学海军临床学院北京市100048 安徽医科大学第五临床医学院安徽省合肥市230032 解放军总医院第六医学中心中医医学部骨伤科北京市100048

背景:国内外学者认为新西兰大白兔腰椎解剖形态与人类腰椎更为相似,是理想的模型动物。在X射线引导下采用不同方式建立兔椎间盘退变模型目前尚缺乏系统性比较。目的:基于X射线引导采用针刺法、终板注射法以及改良终板注射法建立兔腰椎... 详细信息

背景:国内外学者认为新西兰大白兔腰椎解剖形态与人类腰椎更为相似,是理想的模型动物。在X射线引导下采用不同方式建立兔椎间盘退变模型目前尚缺乏系统性比较。目的:基于X射线引导采用针刺法、终板注射法以及改良终板注射法建立兔腰椎间盘退变模型,比较3种方法造模的效果。方法:6月龄新西兰大白兔16只随机分为4组,分别为针刺组、终板注射组、改良终板注射组及空白对照组,针刺组对3个连续节段(L2/3、L3/4、L4/5)椎间盘进行针刺造模,终板注射组在3个连续节段终板单点注射50μL无水乙醇,改良终板注射组对3个连续节段椎间盘进行针刺并在相应节段终板4个方位点注射50μL无水乙醇,空白对照组不进行干预。术后2,4,8周进行X射线检查,测量椎间隙高度指数,然后取椎间盘组织进行解剖学观察、病理学检查。结果与结论:①解剖学观察显示,针刺组以纤维环破溃为主要表现,终板注射组主要以髓核退变为主要表现,改良终板注射组以全椎间盘结构紊乱为主要表现;②与空白对照组相比,针刺组术后2周椎间隙高度指数降低最明显,终板注射组术后2,4周椎间隙高度指数降低明显,改良终板注射组术后2,4,8周椎间隙高度指数均显著降低;③病理学检查显示,针刺组纤维环结构出现破损,内层纤维环向内凸入,终板注射组表现为终板裂隙、排列混乱及细胞核丢失,改良终板注射组表现为整体椎间盘结构紊乱,髓核失水皱缩,与破损的纤维环无明显边界。结果表明,针刺法、终板注射法及改良终板注射法均能建立兔椎间盘退变模型,改良终板注射法较单一方法可大幅加快并加重椎间盘退变,可有效缩短实验周期。

关键词：组织工程椎间盘退变纤维环穿刺法终板注射法 X射线新西兰大白兔