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Effects of Magnetic Fields on Morphology and Nanostructure Evolution of Incipient Soot Particles from n-heptane/2,5-dimethylfuran Inverse Diffusion Flames

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Journal of Thermal Science 2020年第3期29卷 820-839页

作者： jiang bo WANG Pengfei LIU Dong MIIT Key Laboratory of Thermal Control of Electronic Equipment School of Energy and Power EngineeringNanjing University of Science and TechnologyNanjing 210094China Advanced Combustion Laboratory School of Energy and Power EngineeringNanjing University of Science and TechnologyNanjing 210094China jiangsu Province Key Laboratory of Aerospace Power System Nanjing 210016China

Differences of the morphology and nanostructure evolution of incipient soot particles generated in n-heptane/2,5-dimethylfuran(DMF)inverse diffusion flames(IDFs)with/without magnetic fields were *** a high resolution transmission electron spectroscopy,the morphology and nanostructures of soot sampled from spatial locations at different heights in IDFs were *** graphitization and the oxidation reactivity of soot were tested by an X-ray diffraction and a thermogravimetric analyzer,*** demonstrated that the magnetic force on paramagnetic species,such as oxygen molecules,can modify the soot formation and *** incipient soot particles with larger diameters appeared in chains or branches or tufted forms on the flame wing region and the higher position than that on the flame centerline region and the lower *** magnetic fields,greater amounts of clustered soot particles displayed more crowded distribution and larger *** particles with typical structures of the core-shell were promoted to own more orderly bordered lamellae with longer fringe length and smaller fringe tortuosity by the magnetic force acting on oxygen at the same sample *** modifications resulted in relatively larger diffraction angle of the peak,higher graphitization degree and slightly lower oxidation reactivity of soot.

关键词： magnetic fields incipient soot particle n-heptane/DMF morphology nanostructure evolution

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Magnesium hydroxide whisker modified via in situ copolymerization of n-butyl acrylate and maleic anhydride

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Rare Metals 2017年第12期36卷 997-1002页

作者： Yu-Zhi jiang Yu-Lian Wang chun-Yan Wang Li-Mei Bai Xin Li Yan-bo Li Collogy of Materials Science and Engineering Shenyang Ligong University Shenyang 110159 China Kailong Lanfeng New Material Technology Co. LtdZhenjiang 212132 China College of Mining Engineering Hebei United UniversityTangshan 063009 China School of Materials Science and Engineering Central South University Changsha 410083 China

Magnesium hydroxide(MH) whiskers were modified via in situ polymerization of n-butyl acrylate and maleic anhydride. Sodium dodecyl sulfonate was used as emulsifier. The modifying effect was evaluated by using contact angle and activation index. The thermal stability,functional groups, structure, morphology, phase composition and surface element valence of MH whiskers were characterized by thermogravimetry-differential scanning calorimetry(TG-DSC), Fourier transform infrared spectroscopy(FTIR), X-ray diffraction(XRD), scanning electron microscopy(SEM) and X-ray photoelectron spectroscopy(XPS). Results reveal that the contact angle and activation index of modified MH whiskers are 105°and 76.5%, the thermal stability shows little change, and the decomposition temperature ranges between 38 and419 ℃. The copolymer of n-butyl acrylate and maleic anhydride absorbed on the surface of MH whiskers leads to the increased diameter and makes the surface of whiskers be rougher. Furthermore, the absorption of element C on the surface of MH whiskers increases, and the diffraction intensity of C 1 s spectra increases; thus, the compatibility of whiskers in the organic phase can be improved significantly. Lastly, the surface molecular model of MH whiskers modified via in situ copolymerization of n-butyl acrylate and maleic anhydride is established.

关键词： Magnesium hydroxide whiskers n-Butyl acrylate Maleic anhydride In situ copolymerization Surface molecular model

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Ultra-thin Glass Film Coated with Graphene: A New Material for Spontaneous Emission Enhancement of Quantum Emitter

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Nano-Micro Letters 2015年第3期7卷 261-267页

作者： Lu Sun chun jiang State Key Laboratory of Advanced Optical Communication System and Networks Shanghai Jiao Tong University

We propose an ultra-thin glass film coated with graphene as a new kind of surrounding material which can greatly enhance spontaneous emission rate(SER) of dipole emitter embedded in it. With properly designed parameters,numerical results show that SER-enhanced factors as high as 1.286 9 106 can be achieved. The influences of glass film thickness and chemical potential/doping level of graphene on spontaneous emission enhancement are also studied in this paper. A comparison is made between graphene and other coating materials such as gold and silver to see their performances in SER enhancement.

关键词： Graphene surface plasmons Graphene plasmonics Quantum electrodynamics Superradiance Subwavelength structures

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Preoperative inflammation-based markers predict early and late recurrence of hepatocellular carcinoma after curative hepatectomy

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Hepatobiliary & Pancreatic Diseases International 2016年第3期15卷 266-274页

作者： Yue Liu Zhong-Xia Wang Yin Cao Guang Zhang Wei-bo Chen chun-Ping jiang Department of Hepatobiliary Surgery the Affiliated Drum Tower Hospital of Nanjing University Medical School

BACKGROUND： Recurrence of hepatocellular carcinoma （HCC） after curative resection remains a major cause of treatment failure and tumor-related death. Patterns of HCC recur- rence can be categorized into early recurrence and late recurrence which have different underlying mechanisms. In this study, we investigated if simple inflammation-based clinical markers can distinguish patterns of recurrence after curative resection of HCC.

关键词： hepatocellular carcinoma inflammation prognosis recurrence hepatectomy

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Thermal decomposition characteristics and kinetics of methyl linoleate under nitrogen and oxygen atmospheres

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Petroleum Science 2015年第3期12卷 518-524页

作者： Xue-chun Wang Jian-Hua Fang bo-Shui Chen Jiu Wang jiang Wu Di Xia Department of Military Oil Application & Administration Engineering Logistical Engineering University

The thermal decomposition characteristics of methyl linoleate （ML） under nitrogen and oxygen atmo- spheres were investigated, using a thermogravimetric analyzer at a heating rate of 10 ~C/min from room tem- perature to 600℃. Furthermore, the pyrolytic and kinetic characteristics of ML at different heating rates were stud- ied. The results showed that the thermal decomposition characteristics of ML under nitrogen and oxygen atmo- spheres were macroscopically similar, although ML exhibited relatively lower thermal stability under an oxy- gen atmosphere than under a nitrogen atmosphere. The initial decomposition temperature, the maximum weight loss temperature, the peak decomposition temperature, and the rate of maximum weight loss of ML under an oxygen atmosphere were much lower than those under a nitrogen atmosphere and increased with increasing heating rates under either oxygen or nitrogen atmosphere. In addition, the kinetic characteristics of thermal decomposition of ML were elucidated based on the experimental results and by the multiple linear regression method. The activation energy, pre-exponential factor, reaction order, and the kinetic equation for thermal decomposition of ML were obtained. The comparison of experimental and calculated data and the analysis of statistical errors of pyrolysis ratios demonstrated that the kinetic model was reliable for pyrolysis of ML with relative errors of about 1%. Finally, the kinetic compensation effect between the pre-exponential factors and the activation energy in the pyrolysis of ML was also confirmed.

关键词： Methyl linoleate Pyrolysis characteristics Kinetics Thermogravimetric analysis Biodiesel

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Synergistic Catalysis with Azomethine Ylides

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Chinese Journal of Chemistry 2021年第1期39卷 15-24页

作者： Liang Wei chun-jiang Wang Engineering Research Center of Organosilicon Compounds&Materials Ministry of EducationCollege of Chemistry ond Molecular SciencesWuhan UniversityWuhanHubei 430072China State Key Laboratory of Elemento organic Chemistry Nankoi UniversityTionjin 300071China

Azomethine ylides are useful intermediates for the rapid construction of chiral N-containing ***,its synthetic potential has not been fully developed due to the limited reaction *** combination with synergistic catalysis and azomethine ylide chemistry,we have developed several types of novel catalytic system including Cu/Pd,Cu/Ir and PTC/Ir catalysis;which can convert readily-available azomethine ylides to various high-valued molecules such as unnatural a-amino acids,homoallylic amines and *** with the traditional mono-catalysis,the synergistic catalyst system exhibits enhanced catalytic efficiency and chiral induction ability in many *** addition,we have demonstrated that these strategies could be applied in the construction of bioactive compounds and natural products.

关键词： Azomethine ylides Synergistic catalysis Asymmetric synthesis N-Heterocycles α-Amino acids

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Aerobic glycolysis and high level of lactate in cancer metabolism and microenvironment

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Genes & Diseases 2017年第1期4卷 25-27页

作者： bo jiang Department of Oncology Avis General HospitalBeijingChina

Metabolic abnormalities is a hallmark of *** 100 years ago,Nobel laureate Otto Heinrich Warburg first described high rate of glycolysis in cancer *** more and more novel opinions about cancer metabolism supplement to this hypothesis,consist of glucose uptake,lactic acid generation and secretion,acidification of the microenvironment and cancer immune *** we briefly review metabolic pathways generating lactate,and discuss the function of higher lactic acid in cancer microenvironments.

关键词： Aerobic glycolysis Cancer metabolism Glucose metabolism Immune escape Lactate

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Personal Review:Progress and prospect in electro-Fenton process for wastewater treatment

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2007年第7期8卷 1118-1125页

作者： jiang Cheng-chun ZHANG Jia-fa School of Civil and Environmental Engineering Shenzhen Polytechnic Shenzhen 518055 China College of Civil Engineering Huaqiao University Quanzhou 362021 China

As a novel advanced oxidation process (AOP), electro-Fenton process is powerful for degrading most organic compounds including toxic and non-biodegradable ones, and so has attracted great attention. This paper reviews this process in detail including the mechanism, electrolytic bath, electrode materials, aerations and operation parameters. The application of electro-Fenton method in wastewater treatment is evaluated and summarized. Future work in this field is suggested, and three main directions of new electrode exploitation, development of assisted technologies and mechanistic study should be strengthened.

关键词： Electro-Fenton Hydroxyl radicals Advanced oxidation process (AOP) Refractory wastewater

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ATTRACTORS FOR DISCRETIZATION OF GINZBURG-LANDAU-BBM EQUATIONS

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Journal of Computational Mathematics 2001年第2期19卷 195-204页

作者： Mu-rong jiang bo-ling Guo Department of Mathematics Yunnan UniversityKunming 650091China R&D Center for Parallel Software Institute of SoftwareChinese Academy of SciencesBeijing 100080China Institute of Applied Physics and Computational Mathematics Beijing 100088China

Focuses on a study which discreted Ginzburg-Landau-BBM equations with periodic initial boundary value conditions by the finite difference method in spatial direction. Background on the discretization of the equations and the priori estimates; Existence of the attractors for the discrete system; Estimates of the upper bounds of Hausdorff and fractal dimensions for the attractors.

关键词： attractor spatially discreted Ginzburg-Landau-BBM equations Hausdorff and fractal dimensions

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The quantized chemical reaction resonantly driven by multiple MIR-photons:From nature to the artificial

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Nano Research 2021年第12期14卷 4367-4369页

作者： Feng Zhang bo Song Lei jiang Shanghai Key Lab of Modern Optical System School of Optical-Electrical Computer EngineeringUniversity of Shanghai for Science and TechnologyShanghai200093China Key Laboratory of Bio-inspired Materials and Interfacial Science Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing100190China School of Future Technology University of Chinese Academy of SciencesBeijing100049China

Biochemical reactions in vivo occur at the temperature usually lower than that in vitro,however the underlying mechanism still remains a *** by our recent studies of adenosine triphosphate(ATP)releasing photons to resonantly drive DNA replication in a quantum way,we propose a quantized chemical reaction driven by multiple mid-infrared(MIR)*** space confinement effect of enzymes on a reactant molecule increases the lifetime of excitation state of its bond vibration,providing a chance for the bond to resonantly absorb multiple *** the energy of each MIR photon is significantly lower than that of chemical bond,the resonant absorption of multiple photons can break the appointed bond of confined *** from the traditional thermochemistry and photochemistry,the quantized chemical reactions could have a high energy efficiency and ultrahigh *** addition,we also suggest a quantum driving source for our quantum-confined superfluid reactions proposed *** quantized chemical reaction resonantly driven by multiple MIR photons holds great promise to develop novel approaches for the chemical engineering in future.

关键词： quantized chemical reaction quantized bio-synthesis quantized chemical engineering multiple mid-infrared(MIR)/far-infrared(FIR)-photon driving high efficiency and ultrahigh selectivity

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