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Molecular conformation-induced interfacial stress at the origin of the instability of organic transistors

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Science China Chemistry 2021年第9期64卷 1437-1438页

作者： antonio Facchetti Department of Chemistry and Materials Research Center Northwestern University2145 Sheridan RoadEvanstonIL60208USA Flexterra Corporation 8025 Lamon AvenueSkokieIL60077USA

As one of the most important organic electronic building block,organic field-effect transistors(OFeTs)have broad application prospects in the fields of flexible displays,electronic skins,and wearable *** more than 30 years of development,the performance(e.g.,the carrier mobility)and processing technology of OFeTs have made considerable progress^([1,2]).

关键词： transistors interfacial origin

The role of systematic errors

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National Science Review 2021年第10期8卷 137-138页

作者： antonio Navarra Centro euro-Mediterraneo sui Cambiamenti Climatici and Università di Bologna

General circulation models(GCMs) have progressed enormously over the last few decades and they have allowed huge advances in forecasting at every timescale, from daily to seasonal and decadal, and in climate simulations of the earth climate system. These advances have increased the relevance of the results for decision-making and the drafting of strategies and policies with far-reaching impacts.

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A Note on the Maximum Principle for Second-Order elliptic equations in General Domains

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Acta Mathematica Sinica,english Series 2007年第11期23卷 1955-1966页

作者： antonio VITOLO Department of Mathematics and Informatics University of Salerno P.Grahamstown84084 Fisciano(Salerno)Italy

We make a further advance concerning the maximum principle for second-order elliptic operators. We investigate in particular a geometric condition, first considered by Berestycki Nirenberg Varadhan, that seems to be natural in view of the application of the boundary weak Harnack inequality, on which our argument is based. Setting it free from some technical assumptions, apparently needed in earlier papers, we significantly enlarge the class of unbounded domains where the maximum principle holds, compatibly with the first-order term.

关键词： elliptic equations ABP estimate maximum principle

The off-crust origin of granite batholiths

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Geoscience Frontiers 2014年第1期5卷 63-75页

作者： antonio Castro Unidad Asociada de Petrología experimental CSIC-Universidad de Huelva.Campus El Carmen21071 Huelva Spain

Granitod batholiths of I-type features （mostly granodiorites and tonalites）, and particularly those forming the large plutonic associations of active continental margins and intracontinental collisional belts, represent the most outstanding magmatic episodes occurred in the continental crust. The origin of magmas, however, remains controversial. The application of principles from phase equilibria is crucial to understand the problem of granitoid magma generation. An adequate comparison between rock com- positions and experimental liquids has been addressed by using a projected compositional space in the plane F（Fe ＋ Mg）-Anorthite-Orthoclase. Many calc-alkaline granitoid trends can be considered cotectic liquids. Assimilation of country rocks and other not-cotectic processes are identified in the projected diagram. The identification of cotectic patterns in batholith implies high temperatures of magma segregation and fractionation （or partial melting） from an intermediate （andesitic） source. The com- parison of batholiths with lower crust granulites, in terms of major-element geochemistry, yields that both represent liquids and solid residues respectively from a common andesitic system. This is compatible with magmas being formed by melting, and eventual reaction with the peridotite mantle, of subducted mOlanges that are finally relaminated as magmas to the lower crust. Thus, the off-crust generation of granitoids batholiths constitutes a new paradigm in which important geological implica- tions can be satisfactorily explained. Geochemical features of Cordilleran-type batholiths are totally compatible with this new conception.

关键词： Batholith Granodiorite Andesite Relamination Granulite Lower crust

Covalent and Ionic Bonding between Tannin and Collagen in Leather Making and Shrinking:A MALDI-ToF Study

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journal of Renewable Materials 2021年第8期9卷 1345-1364页

作者： antonio Pizzi LeRMAB-eNSTIB University of LorraineEpinal88000France

Collagen powder hydrolysates were reacted with a solution of commercial mimosa bark tannin *** mixture was prepared at ambient temperature and prepared at 80°C to determine what reactions,if any,did occur between the collagen protein through its amino acids and the polyphenolic condensed *** reaction products obtained were analyzed by matrix assisted laser desorption ionization time-of-flight(MALDI ToF)mass *** between the two materials did appear to occur,with the formation of a relatively small proportion of covalent and ionic linkages at ambient temperature but a considerable proportion of covalent linkages tannin-protein amino acids and the disappearance of ionic *** linkages between the two materials appeared to be by amination of the phenolic–OHs of the tannin by the amino groups of the non-skeletal side chains of arginine,and by esterification by the–COOH groups of glutamic and aspartic acid of the aliphatic alcohol-OH on the C3 site of the flavonoid units heterocycle of the *** proportion of covalent linkages increases markedly and predominate with increasing *** tightening of the tannin-protein covalent network formed may be an additional contributing factor both to leather wear resistance and performance as well to leather shrinking when this is subjected to excessive temperatures.

关键词： Leather collagen vegetal tannins tanning tannin-protein reactions covalent bonds leather cross-linking leather shrinkage MALDI

effect of rhenium on the microstructure and mechanical behavior of Fe–2.25Cr–1.6W–0.25V-0.1C bainitic steels

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journal of Materials Science & Technology 2017年第12期33卷 1487-1493页

作者： josé antonio jiménez Manuel Carsí Oscar antonio Ruano Department of Physical Metallurgy Centro Nacional de lnvestigaciones MetalurgicasC.S.I.CAvda.Gregorio del Amo 828040 MadridSpain

A new ferritic creep resistant steel has been developed by eliminating Nb and adding 1.5 mass % Re to a ferritic steel grade T/P23 with the aim of enhancing its mechanical properties at high *** ingots of both steels, new grade and ASTM T/P 23, were hot rolled at 900℃ and then submitted to a thermal treatment consisting of solubilization at 1050℃ and tempering at 700℃. Tempered bainitic microstructures obtained contain second phases reinforcing carbide particles, mainly M_6C and M_（23）C_6 at the boundaries of both, prior austenite grains and bainitic ferrite laths, as well as MC within the grains. Mechanical properties at temperatures ranging from 540 to 600℃ were studied by strain-ratechange tests in compression at strain rates between 10^（-7） and 10^（-4）s^（-1）. These tests showed high stress exponents（n ≥ 20） and activation energies（Q ≈ 400 k j/mol） for both alloys, which were associated with a dislocation movement mechanism with a strong interaction between dislocations and precipitates. On the other hand, a creep exponent of 5 was derived for the stress dependence of minimum creep rate from conventional-type creep tests at 600℃. Although this stress exponent is usually related to a dislocation climb controlled creep mechanism, remarkable microstructural degradation observed with increasing creep time makes difficult to elucidate the true deformation mechanism controlling creep.

关键词： Creep resistant steel T/P23 Thermal treatment Tempered bainite High temperature mechanical properties Creep

A Review of Soy-Tannin Gelling for Resins Applications

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journal of Renewable Materials 2023年第1期11卷 1-25页

作者： antonio Pizzi LeRMAB-eNSTIB University of Lorraine27 rue PhilippeSeguinEpinal88000France

Soy flour(SF),soy protein and soy protein isolates(SPI)have been the focus of increasing research on their application as new materials for a variety of applications,mainly for wood adhesives and other *** too have been the focus of increasing research for similar *** both materials are classed as non-toxic and have achieved interesting results the majority of the numerous and rather inventive approaches have still relied on some sort of hardeners or cross-linkers to bring either of them or even their combination to achieve acceptable *** paper after a presentation of the two materials and their characteristics concentrates on the formation of gels,gelling and even hardening in the case of soy-tannin combined *** chapter than finishes with details of the formation of resins giving suitable wood adhesive of acceptable performance by the covalent coreaction of soy protein and tannin without any other hardener,thus totally bio-sourced,non-toxic and environment friendly as a base of further advances to expect in future by these two materials combination.

关键词： Soy tannin soy-tannin coreaction gelling hardening wood

estimating Latent Linear Correlations from Fuzzy Frequency Tables

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Communications in Mathematics and Statistics 2024年第3期12卷 435-461页

作者： antonio Calcagnì DPSS University of PadovaVia Venezia 835031 PaduaItaly Member of the GNCS Research Group National Institute of Advanced Mathematics(INdAM)P.le Aldo Moro 500185 RomaItaly

This research concerns the estimation of latent linear or polychoric correlations from fuzzy frequency *** counts are of particular interest to many disciplines including social and behavioral sciences and are especially relevant when observed data are classified using fuzzy categories—as for socioeconomic studies,clinical evaluations,content analysis,inter-rater reliability analysis—orwhen imprecise observations are classified into either precise or imprecise categories—as for the analysis of ratings data or fuzzy-coded *** these cases,the space of count matrices is no longer defined over naturals and,consequently,the polychoric estimator cannot be used to accurately estimate latent linear *** aim of this contribution is ***,we illustrate a computational procedure based on generalized natural numbers for computing fuzzy ***,we reformulate the problem of estimating latent linear correlations from fuzzy counts in the context of expectation–maximization-based maximum likelihood estimation.A simulation study and two applications are used to investigate the characteristics of the proposed ***,the results show that the fuzzy eM-based polychoric estimator is more efficient to deal with imprecise count data as opposed to standard polychoric estimators that may be used in this context.

关键词： Fuzzy frequency Generalized natural numbers Polychoric correlations Fuzzy data analysis

Anisotropic gold nanoparticles: Preparation and applications in catalysis

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Chinese journal of Catalysis 2016年第10期37卷 1619-1650页

作者： Peter Priecel Hammed Adekunle Salami Romen Herrera Padilla Ziyi Zhong jose antonio lopez-Sanchez 利物浦大学化学系可再生能源斯蒂芬森研究所英国利物浦新加坡科技研究局(A*STAR) 化学与工程科学研究所新加坡裕廊岛627833

Despite the high amount of scientific work dedicated to the gold nanoparticles in catalysis, most of the research has been performed utilising supported nanoparticles obtained by traditional impreg‐nation of gold salts onto a support, co‐precipitation or deposition‐precipitation methods which do not benefit from the recent advances in nanotechnologies. Only more recently, gold catalyst scien‐tists have been exploiting the potential of preforming the metal nanoparticles in a colloidal suspen‐sion before immobilisation with great results in terms of catalytic activity and the morphology con‐trol of mono‐and bimetallic catalysts. On the other hand, the last decade has seen the emergence of more advanced control in gold metal nanoparticle synthesis, resulting in a variety of anisotropic gold nanoparticles with easily accessible new morphologies that offer control over the coordination of surface atoms and the optical properties of the nanoparticles （tunable plasmon band） with im‐mense relevance for catalysis. Such morphologies include nanorods, nanostars, nanoflowers, den‐dritic nanostructures or polyhedral nanoparticles to mention a few. In addition to highlighting newly developed methods and properties of anisotropic gold nanoparticles, in this review we ex‐amine the emerging literature that clearly indicates the often superior catalytic performance and amazing potential of these nanoparticles to transform the field of heterogeneous catalysis by gold by offering potentially higher catalytic performance, control over exposed active sites, robustness and tunability for thermal‐, electro‐and photocatalysis.

关键词： Anisotropic metal nanoparticles Gold nanoparticles Gold catalysis Photocatalysis electrocatalysis Catalytic oxidation Colloidal gold nanoparticles Gold nanorod Gold nanostars Sol immobilisation