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Artificial oxygen carriers,from nanometer-to micrometer-sized particles,made of hemoglobin composites substituting for red blood cells

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Particuology 2022年第5期20卷 43-55页

作者： takashi Matsuhira Hiromi Sakai Department of Chemistry Nara Medical University840 Shijo-choKashihara 634-8521Japan

Blood transfusions are regarded as the most well-known and frequently performed cell *** current transfusion systems are sophisticated,they cannot be freed from the inherent difficulties that include infection,short shelf life,and blood type *** oxygen carriers produced using hemoglobin(Hb)are designated as Hb-based oxygen carriers(HBOCs),which are anticipated for use as biomaterials that have potential to resolve issues of transfusion by a radical paradigm *** HBOCs,nanometer-sized to micrometer-sized bioparticles having an oxygen-carrying function,are developed for use as substitutes for red blood cells(RBCs).This paper presents an overview of the classification of HBOCs with reference to their histories,preparations,structures,functions,and in vitro and in vivo ***,we give a more detailed introduction of our academic studies of liposome encapsulated Hb,designated as Hb-vesicles(HbV),which mimic the physiologically important corpuscular structure of *** review outlines perennial efforts and approaches to mimic RBC functions through chemical,genetic,and encapsulation *** will provide important insights into the eventual realization of an alternative for RBC transfusion.

关键词： Blood substitutes Cross-linking Hemoglobin(Hb)-based oxygen carriers(HBOCs) Liposome Supramolecular assembly Transfusion alternatives

Unsteady separation of jet branch by cutout of rotating Pelton bucket

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Science China(Technological Sciences) 2011年第2期54卷 302-310页

作者： KUBOTA takashi College of Electric Power South China University of Technology

As a part of boundaries for a free curved surface of a Pelton bucket,the cutout is indispensable to secure the smooth entrance of the unsteady inflow of water jet into the rotating *** cutout of the rotating bucket unsteadily separates a free jet into two branches in both space and time:the impinging branch landing on the relevant bucket surface,and the flow-off branch separated by the cutout toward the preceding *** order to investigate the unsteady jet separation by the cutout three-dimensionally,a semicircular free jet was discretized into 641 nodes of boundary-fitted *** position P of impinging jet branch landing on the bucket surface was acquired with the relative velocity W and the water depth D at each *** trailing edge surface of the flow-off jet branch was simultaneously computed *** complicate unsteady interaction of the bucket cutout with the branched free jets was clarified visually with the 3D view of illustrations in order to research the unsteady hydraulic performance of Pelton turbines in space and time.

关键词： cutout rotating bucket jet branch trailing edge surface of jet unsteady in space and time

NON-UNIQUENESS OF THE RECONSTRUCTION FOR CONNECTED AND SIMPLY CONNECTED SETS IN THE PLANE BY THEIR FIXED FINITE PROJECTIONS

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Acta Mathematica Scientia 2012年第4期32卷 1637-1646页

作者： takashi Takiguchi Department of Mathematics National Defense Academy of JapanYokosuka Kanagawa 239-8686 Japan

We discuss a problem to reconstruct the measurable sets in the plane from their fixed finite projections. In the main theorem, we construct an example of connected and simply connected polygons which are not uniquely reconstructed by their fixed finite projections. We also make a comparison between our main theorem and the known results on this problem.

关键词： Radon transform inverse problem

On the Numerical Modeling of the Deep Mantle Water Cycle in Global-Scale Mantle Dynamics:The Effects of the Water Solubility Limit of Lower Mantle Minerals

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Journal of Earth Science 2017年第4期28卷 563-577页

作者： takashi Nakagawa Department of Mathematical Science and Advanced Technology Japan Agency for Marine-Earth Science and TechnologyYokohama 236-0001Japan

Water is the most important component in Earth system evolution. Here, I review the current understanding of the fate of water in the mantle dynamics system based on high-pressure and temperature experiments, geochemical analyses, seismological and geomagnetic observations, and nu- merical modeling of both regional- and giobal-scale mantle dynamics. In addition, as a numerical ex- ample, I show that the water solubility of the deep mantle is strongly sensitive to global-scale water cir- culation in the mantle. In a numerical example shown here, water solubility maps as functions of tem- perature and pressure are extremely important for revealing the hydrous structures in both the mantle transition zone and the deep mantle. Particularly, the water solubility limit of lower mantle minerals should be not so large as ~100 ppm for the mantle transition zone to get the largest hydrous reservoir in the giobal-scale mantle dynamics system. This result is consistent with the current view of mantle water circulation provided by mineral physics, which is also found as a hydrous basaltic crust in the deep mantle and the water enhancement of the mantle transition zone simultaneously. In this paper, I also discuss some unresolved issues associated with mantle water circulation, its influence on the onset and stability of plate motion, and the requirements for developing Earth system evolution in mantle dy- namics simulations.

关键词： numerical modeling mantle convection water cycle water solubility limit.

Experiment study on RC frame retrofitted by the external structure

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Earthquake Engineering and Engineering Vibration 2016年第3期15卷 563-574页

作者： Liu Chunyang Shi Junji Hiroshi Kuramoto Taguchi takashi Kamiya takashi College of Civil Engineering Shandong Jianzhu University Division of Global Architecture Graduate School of Engineering Osaka University Earthquake Engineering Technology Institute Yahagi Construction Co. Ltd

A new retrofitting method is proposed herein for reinforced concrete （RC） structures through attachment of an external structure. The external structure consists of a fiber concrete encased steel frame, connection slab and transverse beams. The external structure is connected to the existing structure through a connection slab and transverse beams. Pseudo- static experiments were carried out on one unretrofitted specimen and three retrofitted frame specimens. The characteristics, including failure mode, crack pattern, hysteresis loops behavior, relationship of strain and displacement of the concrete slab, are demonstrated. The results show that the load carrying capacity is obviously increased, and the extension length of the slab and the number of columns within the external frame are important influence factors on the working performance of the existing structure. In addition, the displacement difference between the existing structure and the outer structure was caused mainly by three factors： shear deformation of the slab, extraction of transverse beams, and drift of the conjunction part between the slab and the existing frame. Furthermore, the total deformation determined by the first two factors accounted for approximately 80% of the damage, therefore these factors should be carefully considered in engineering practice to enhance the effects of this new retrofitting method.

关键词： extemal structure seismic retrofitted pseudo-static experiment seismic performance deformation analysis

Large Deformation Analysis and Synthesis of Elastic Closed-loop Mechanism Made of a Certain Spring Wire Described by Free Curves

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Chinese Journal of Mechanical Engineering 2015年第4期28卷 756-762页

作者： IWATSUKI Nobuyuki KOSAKI takashi Department of Mechanical Sciences and Engineering Graduate School of Science and EngineeringTokyo Institute of Technology

Recently novel mechanisms with compact size and without many mechanical elements such as bearing are strongly required for medical devices such as surgical operation devices. This paper describes analysis and synthesis of elastic link mechanisms of a single spring beam which can be manufactured by NC coiling machines. These mechanisms are expected as disposable micro forceps. Smooth Curvature Model（SCM） with 3rd order Legendre polynomial curvature functions is applied to calculate large deformation of a curved cantilever beam by taking account of the balance between external and internal elastic forces and moments. SCM is then extended to analyze large deformation of a closed-loop curved elastic beam which is composed of multiple free curved beams. A closed-loop elastic link is divided into two free curved cantilever beams each of which is assumed as serially connected free curved cantilever beams described with SCM. The sets of coefficients of Legendre polynomials of SCM in all free curved cantilever beams are determined by taking account of the force and moment balance at connecting point where external input force is applied. The sets of coefficients of Legendre polynomials of a nonleaded closed-loop elastic link are optimized to design a link mechanism which can generate specified output motion due to input force applied at the assumed dividing point. For example, two planar micro grippers with a single pulling input force are analyzed and designed. The elastic deformation analyzed with proposed method agrees very well with that calculated with FEM. The designed micro gripper can generate the desired pinching motion. The proposed method can contribute to design compact and simple elastic mechanisms without high calculation costs.

关键词： elastic link mechanism closed-loop spring beam large deformation analysis smooth curvature model force balance equation synthesi

Effect of annealing temperature on multiferroic properties of Bi_(0.85)Nd_(0.15)FeO_3 thin films prepared by sol-gel method

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Science China(Technological Sciences) 2010年第6期53卷 1572-1575页

作者： GOTO takashi Institute for Materials Research Tohoku UniversitySendai 980-8577Japan

Bi0.85Nd0.15FeO3 films were prepared on Pt/Ti/SiO2/Si substrate by a sol-gel method,and annealed at different *** effect of annealing temperature on the crystal structure,dielectric,ferroelectric,and ferromagnetic properties was *** the Bi0.85Nd0.15FeO3 films were annealed at 490-600°C,the single phase was ***0.85Nd0.15FeO3 film annealed at 600°C showed good multiferroic properties with εr of 145 (at 1 MHz),Ms of 44.8 emu/cm3,and 2Pr of 16.6 μC/cm2.

关键词： Bi0.85Nd0.15FeO3 thin films sol-gel method annealing temperature ferroelectric properties ferromagnetic properties

A Review:Structural Oxide Coatings by Laser Chemical Vapor Deposition

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Journal of Wuhan University of Technology(Materials Science) 2016年第1期31卷 1-5页

作者： takashi GOTO Institute for Materials Research Tohoku University

Yttria-stabilized zirconia and-alumina films were prepared by laser chemical vapor deposition at deposition rates of several hundred micrometers per ***,the structural oxide coatings by laser chemical vapor deposition are *** laser can significantly accelerate the chemical reaction and grain growth in CVD,yielding high deposition *** films contain large amounts of nanopores that act as thermal insulation and are thus promising as coating materials for gas turbine blades of Ni-based superalloys and WC-Co cutting tools.

关键词： laser CVD yttria-stabilized zirconia alumina plasma nano-pores

SYNTHESIS AND OPTICAL PROPERTIES OF POLY (THIENYLACETYLENES)

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Chinese Journal of Polymer Science 1999年第1期17卷 81-86页

作者：唐本忠 takashi Monde Department of Chemistry Hong Kong University of Science & Technology Clear Water Bay Kowloon Hong Kong China Central Research Laboratory Neos Co. Ltd Kosei-Cho Koga-Gun Shiga Japan

3-Ethynyl-4-(trimethylsilyl)thiophene (1a) and 3-ethynyl-4-bromothiophene (1b) selectively undergo acetylene polymerizations in the presence of the MoCl5- and WCl6-Ph3SiH catalysts to give soluble, high-molecular-weight poly(thienylacetylenes) (2) (M-w up to 602000) in high yields (up to 100%). Light transmission spectra of THF solutions of 2 continuously red-shift with increasing concentration. The concentratochromism shows a logarithmic concentration dependence; that is, the optical transitions of 2 are predictably tunable by simply changing their concentrations.

关键词： polyacetylenes poly(thienylacetylenes) conjugated polymers optical materials pi-pi interaction light transmission chromic effects