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Chinese Chemical Letters 1999年第3期10卷 243-246页

作者： hut Min MA Zhi Hua wanG Yi ZENG hut wan han Guo Quan LIU(Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080) Chinese Acad Sci Inst Chem Beijing 100080 Peoples R China

The basal levels of magnesium and copper in rat brain and flowering plum fruit dialysates, and the background concentration of calcium in pea dialysates have been determined with sensitive spectroscopic techniques including atomic absorption spectrometry and spectrophotometry based on amino G acid chlorophosphonazo. It is found that the magnesium level in flowering plum fruit dialysates is much lower than that in rat brain dialysates, indicating a considerable composition difference present between a plant dialysate and an animal one.

关键词： microdialysis spectroscopic methods physiological element analysis calcium magnesium copper

A Novel Method for Studying the interaction of Macromolecule with Small Molecule by Means of Affinity Capillary Electrophoresis

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Chinese Chemical Letters 1999年第3期10卷 235-238页

作者： Met FANG Li SHENG hut wan han Xiao YU Rut ZHAO Guo Quan LIU(Laboratory of Analytical Chemistry in Life Science, Institute of Chemistry, Chinese Academy ofSciences，Beijing 100080) Chinese Acad Sci Inst Chem Lab Analyt Chem Life Sci Beijing 100080 Peoples R China

A novel capillary electrophoresis method coupled with on-line microdialysis using an attachable electrode has been developed to study the interaction of macromolecule with small molecule. The binding constants of bovine serum album (BSA) with D,L-tryptophan (Trp), sulfamethoxazole (SMZ) with trypsin and chymotrypsin were determined. These values are 2.3 x 10(4)L/mol for BSA-L-Trp; 1.77 x 10(3) L/mol for BSA-D-Trp in pH 7.4, 50 mmol/ L phosphate; 1.4 x 10(4) L/mol for SMZ- trypsin and 6.0 x 10(3) L/mol for SMZ-chymotrypsin in pH 6.5, 25 mmol/L Tris buffer. The proposed method has merits of speed, low sample consumption and readily available to be performed in desired physiological conditions.

关键词： interaction of macromolecule with small molecule binding constant affinity capillary electrophoresis microdialysis membrane

RFFsNet-SEI:a multidimensional balanced-RFFs deep neural network framework for specific emitter identification

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Journal of Systems Engineering and Electronics 2024年第3期35卷 558-574,F0002页

作者： FAN Rong SI Chengke han Yi wan Qun School of Information and Communication Engineering University of Electronic Science and Technology of ChinaChengdu 611731China Institute of Electronic and Electrical Engineering Civil Aviation Flight University of ChinaGuanghan 618307China

Existing specific emitter identification(SEI)methods based on hand-crafted features have drawbacks of losing feature information and involving multiple processing stages,which reduce the identification accuracy of emitters and complicate the procedures of *** this paper,we propose a deep SEI approach via multidimensional feature extraction for radio frequency fingerprints(RFFs),namely,***,we extract multidimensional physical RFFs from the received signal by virtue of variational mode decomposition(VMD)and Hilbert transform(HT).The physical RFFs and I-Q data are formed into the balanced-RFFs,which are then used to train *** introducing model-aided RFFs into neural network,the hybrid-driven scheme including physical features and I-Q data is *** improves physical interpretability of ***,since RFFsNet-SEI identifies individual of emitters from received raw data in end-to-end,it accelerates SEI implementation and simplifies procedures of ***,as the temporal features and spectral features of the received signal are both extracted by RFFsNet-SEI,identification accuracy is ***,we compare RFFsNet-SEI with the counterparts in terms of identification accuracy,computational complexity,and prediction *** results illustrate that the proposed method outperforms the counterparts on the basis of simulation dataset and real dataset collected in the anechoic chamber.

关键词： specific emitter identification(SEI) deep learning(DL) radio frequency fingerprint(RFF) multidimensional feature extraction(MFE) variational mode decomposition(VMD)

Generation and Applications of a Broad Atomic Oxygen Beam with a High Flux-Density via Collision-lnduced Dissociation of O_(2)

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Chinese Journal of Chemistry 2024年第17期42卷 2010-2016页

作者： Zhiqiang han Liying Song Po-wan Shum Woon-Ming Lau Beijing Advanced Innovation Center for Materials Genome Engineering Center for Green InnovationSchool of Mathematics and PhysicsUniversity of Science and Technology BeijingBeijing100083China Shunde Innovation School University of Science and Technology BejingFoshanGuangdong 528399China School of Chemistry and Chemical Engineering Linyi UniversityLinyiShandong 276000China The Sun Age(Guangdong)New Energy Ltd ZhuhaiGuangdong 519031China

We detail the generation of a pulsed atomic oxygen(AO)broad beam with a high flux-density via collision-induced dissociation of O_(2) to support practical industrial exploitation of AOs,particularly for facilitating 2-dimenstional oxidation/etching at a fast rate of one-monolayer per second in an area≥1000 cm².This innovation fuses the following interdisciplinary concepts:(a)a high density of O^(*) can be produced in an electron-cyclotron-resonance(ECR)O2 plasma;(b)o^(*) can be extracted and accelerated with an aperture-electrode in the plasma.

关键词： Collision Atomic oxygen Ab initio calculations lon-molecule reactions Gas-phase reactions

Effects of Hydrogen Charging Time and Pressure on the Hydrogen Embrittlement Susceptibility of X52 Pipeline Steel Material

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Acta Metallurgica Sinica(English Letters) 2024年第2期37卷 293-307页

作者： Hong-Jiang wan Xiao-Qi Wu Hong-Liang Ming Jian-Qiu wang En-Hou han School of Materials Science and Engineering University of Science and Technology of ChinaShenyang110016China CAS Key Laboratory of Nuclear Materials and Safety Assessment Institute of Metal ResearchChinese Academy of SciencesShenyang110016China School of Materials Science and Engineering Northeastern UniversityShenyang110819China Institute of Corrosion Science and Technology Guangzhou510530China

The effects of hydrogen charging time and pressure on the hydrogen embrittlement(HE)susceptibility of X52 pipeline steel material are studied by slow strain rate tensile *** fracture morphologies of the specimens are observed by scanning electron *** HE susceptibility of the X52 pipeline steel material increases with an increase in both hydrogen charging time and hydrogen *** a charging time of 96 h,the HE susceptibility index reaches 45.86%,approximately 3.6 times that at a charging time of 0 ***,a charging pressure of 4 MPa results in a HE susceptibility index of 31.61%,approximately 2.5 times higher than that at a charging pressure of 0.3 MPa.

关键词： Hydrogen embrittlement X52 pipeline steel material Tubular specimen Hydrogen charging time Hydrogen charging pressure

Recent advances in visible light-mediated chemical transformations of enaminones

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Chinese Chemical Letters 2024年第2期35卷 4-15页

作者： Yu han Liyun Zhou Chengyu wang Shangti Feng Rong Ma Jie-Ping wan College of Chemistry and Chemical Engineering Jiangxi Normal UniversityNanchang 330022China School of Chemistry and Chemical Engineering Linyi UniversityLinyi 276000China Linyi Sanfeng Chemical Co. Ltd.Linyi 276000China

Enaminones,which possesses both the nucleophilic enamine as well as electrophilic enone structures,are well known versatile building blocks in organic ***,visible light-mediated reactions have emerged as useful synthetic strategy with enhanced *** the last decade,various photochemical transformations of enaminones have been developed to construct cyclic or acyclic *** this review,we describe the recent advances in visible light-mediated chemical transformations of *** discussion on the reaction mechanism of the related reactions is given to provide guide to the ***,a summary on the existing challenges and the future outlook towards the development of practical photocatalytic reactions of enaminones is also presented.

关键词： Enaminone Visible light C-H functionalization C=C bond cleavage Cyclization Multicomponent reactions

Compositional and Hollow Engineering of Silicon Carbide/Carbon Microspheres as High-Performance Microwave Absorbing Materials with Good Environmental Tolerance

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Nano-Micro Letters 2024年第9期16卷 128-146页

作者： Lixue Gai Yahui wang Pan wan Shuping Yu Yongzheng Chen Xijiang han Ping Xu Yunchen Du MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage School of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150001People’s Republic of China Anhui Provincial Laboratory of Advanced Laser Technology College of Electronic EngineeringNational University of Defense TechnologyHefei 230037People’s Republic of China

Microwave absorbing materials(MAMs)characterized by high absorption efficiency and good environmental tolerance are highly desirable in practical *** silicon carbide and carbon are considered as stable MAMs under some rigorous conditions,while their composites still fail to produce satisfactory microwave absorption performance regardless of the improvements as compared with the ***,we have successfully implemented compositional and structural engineering to fabricate hollow Si C/C microspheres with controllable *** simultaneous modulation on dielectric properties and impedance matching can be easily achieved as the change in the composition of these *** formation of hollow structure not only favors lightweight feature,but also generates considerable contribution to microwave attenuation *** the synergistic effect of composition and structure,the optimized SiC/C composite exhibits excellent performance,whose the strongest reflection loss intensity and broadest effective absorption reach-60.8 dB and 5.1 GHz,respectively,and its microwave absorption properties are actually superior to those of most SiC/C composites in previous *** addition,the stability tests of microwave absorption capacity after exposure to harsh conditions and Radar Cross Section simulation data demonstrate that hollow SiC/C microspheres from compositional and structural optimization have a bright prospect in practical applications.

关键词： SiC/C composites Compositional engineering Hollow engineering Microwave absorption Environmental tolerance

At-rest lateral earth pressure of compacted expansive soils:Experimental investigations and prediction approach

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第4期16卷 1425-1435页

作者： Zhong han Pan Zhang Weilie Zou Kewei Fan Sai K.Vanapalli Lianglong wan School of Civil Engineering Wuhan UniversityWuhanChina Key Laboratory of Rock Mechanics in Hydraulic Structural Engineering of the Ministry of Education Wuhan UniversityWuhanChina Department of Civil Engineering University of OttawaOttawaOntarioCanada Key Laboratory of Ministry of Education for Geomechanics and Embankment Engineering Hohai UniversityNanjingChina Residence Engineering Management Station of Shenzhen Municipality ShenzhenChina

This paper presents experimental studies on a compacted expansive soil,from Nanyang,China for investigating the at-rest lateral earth pressureσL of expansive *** key studies include(i)relationships between theσL and the vertical stressσV during soaking and consolidation,(ii)the influences of initial dry densityρd0 and moisture content w 0 on the vertical and lateral swelling pressures at no swelling strain(i.e.σV0 andσL0),and(iii)evolution of theσL during five long-term wetting-drying *** results demonstrated that the post-soakingσL-σV relationships are piecewise linear and their slopes in the passive state(σL>σV)and active state(σL<σV)are similar to that of the consolidationσL-σV relationships in the normal-and over-consolidated states,*** soakingσL-σV relationships converge to the consolidationσL-σV relationships at a thresholdσV where the interparticle swelling is ***σL0 andσV0 increase monotonically withρd0;however,they show increasing-then-decreasing trends with the w *** extent of compaction-induced swelling anisotropy,which is evaluated byσL0/σV0,reduces with an increase in the compaction energy and molding water ***σL reduces over moisture cycles and the stress relaxation in theσL during soaking is *** approach was developed to predict the at-rest soakingσL-σV relationships,which requires conventional consolidation and shear strength properties and one measurement of theσL-σV relationships during *** proposed approach was validated using the results of three different expansive soils available in the literature.

关键词： Lateral earth pressure Expansive soil Soaking Vertical stress Swelling pressure

Cadaverine and putrescine exposure influence carbon and nitrogen cycling genes in water and sediment of the Yellow River

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Journal of Environmental Sciences 2024年第8期142卷 236-247页

作者： wanghong Su Qiaoling Yu Jiawei Yang Qian han Sijie wang Petr Hedenec Xiaochen wang Ruijun wan-Yan Huan Li School of Public Health Lanzhou UniversityLanzhou 730000China 2 Institute for Tropical Biodiversity and Sustainable DevelopmentUniversity Malaysia Terengganu21030Kuala NerusTerengganuMalaysia State Key Laboratory of Grassland Agro-ecosystems Center for Grassland MicrobiomeCollege of pastoral agriculture science and technology Lanzhou UniversityLanzhou 730000China

The response patterns of microbial functional genes involved in biogeochemical cycles to cadaver decay is a central topic of recent environmental ***,the response mechanisms and pathways of the functional genes associated with the carbon(C)and nitrogen(N)cycling to cadaveric substances such as cadaverine and putrescine remain *** study explored the variation of functional genes associated with C fixation,C degradation and N cycling and their influencing factors under cadaverine,putrescine and mixed *** results showed only putrescine significantly increased the alpha diversity of C fixation genes,while reducing the alpha diversity of N cycling genes in *** the C cycling,the mixed treatment significantly decreased the total abundance of reductive acetyl-CoA pathway genes(i.e.,acsB and acsE)and lig gene linked to lignin degradation in water,while only significantly increasing the hydroxypropionate-hydroxybutylate cycle(i.e.,accA)gene abundance in *** the N cycling,mixed treatment significantly decreased the abundance of the nitrification(i.e.,amoB),denitrification(i.e.,nirS3)genes in water and the assimilation pathway gene(i.e.,gdhA)in *** factors(i.e.,total carbon and total nitrogen)were all negatively associated with the genes of C and N ***,cadaverine and putrescine exposure may inhibit the pathway in C fixation and N cycling,while promoting C *** findings can offer some new insight for the management of amine pollution caused by animal cadavers.

关键词： Carbon cycling Nitrogen cycling Cadaverine Putrescine Pollution management

Liver Transplantation Reverses Hepatic Myelopathy in the Decompensated Phase of Cirrhosis:Case Report and Literature Review

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Journal of Clinical and Translational Hepatology 2024年第4期12卷 436-442页

作者： Jiajun Li Sile wan Fukai Wen Qingyu Li Yifeng Cui Zhaoyang Lu han Lin Department of Hepatic Surgery The First Affiliated Hospital of Harbin Medical UniversityHarbinHeilongjiangChina

Hepatic myelopathy(HM)is a rare neurological complication in the end stage of many liver diseases and is characterized by bilateral spastic paraparesis without sensory and sphinc-ter *** occurs owing to metabolic disorders and central nervous system dysfunction associated with *** timely and effective clinical intervention,the progno-sis of these patients is *** liver transplan-tation(LT)is an effective treatment for HM,the prognosis of these patients remains *** recognition and diagnosis of this disease are essential for improving patient ***,we report a case of hepatitis B virus-asso-ciated decompensated cirrhosis with *** patient recov-ered well after *** also summarize the clinical character-istics and post-transplant outcomes of 25 patients with HM treated by LT through 2023,including this case.

关键词： Hepatic myelopathy Hepatic encephalopathy Spastic paraparesis Portosystemic shunt Liver transplantation