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An electron-transfer[Fe_(2)Co_(2)]square complex exhibiting unprecedented wide room-temperature hysteresis

Science China Chemistry 2024年第4期67卷 1198-1207页

作者： xin-hua zhao Yi-Fei Deng Jia-Tao Chen Jiong Yang Yuan-Zhu Zhang Department of Chemistry Southern University of Science and Technology(SUSTech)Shenzhen 518055China

Switchable molecules with magnetic bistability that can function at standard conditions are highly desirable from the perspective of practical *** the last decade,significant progress has been made in modulating thermally induced electrontransfer-coupled spin transition(ETCST)events between diamagnetic{Fe_(LS)^(Ⅱ)(μ-CN)Co_(LS)^(Ⅲ)}and paramagnetic{Fe_(LS)^(Ⅲ)(μ-CN)-Co_(HS)^(Ⅱ)}electron configurations(named LS and HS,respectively,for short)within the Fe/Co mixed-valence cyanometallate ***,we prepared a novel[Fe_(2)Co_(2)]square complex[(pzTp)Fe(CN)_(3)Co(bnbpen)]_(2)[NO_(3)]_(2)·4CH_(3)OH·2.5H_(2)O(1·Solv)and its desolvated phase[(pzTp)Fe(CN)_(3)Co(bnbpen)]_(2)[NO_(3)]_(2)(1),obtained via single-crystal-to-single-crystal(SCSC)*** 1·Solv remaining in the diamagnetic state below room temperature exhibits an irreversible ETCST behavior accompanied by desolvation upon ***,complex 1 displays an unprecedented rate-dependent ETCST behaviour involving with two diamagnetic LS states(a dynamically favoured LS1 state and a thermodynamically favoured LS2state),between which a net one-way transition from LS1 to LS2 is accessible likely via a structural phase transition(SPT)above255 ***,two well separated transition channels(HS?LS1 at around 255 K and HS←→LS2 in the temperature range of 317-350 K)are achieved according to either fast(>20 K/min)or slow rate(<1 K/min),*** a moderate rate of 3 K/min,complex 1 shows a wide hysteresis of 66 K centered at 328 K,the largest yet reported for discrete Fe/Co cyanometallate *** 1 represents the first ETCST example coupled with dynamic SPT,providing a new strategy for manipulating bistability within this fascinating cyanometallate family.

关键词： switchable molecules cyanometallate complexes electron transfer hysteresis structural phase transition

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Trends and hotspots in gastrointestinal neoplasms risk assessment: A bibliometric analysis from 1984 to 2022

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World Journal of Gastrointestinal Oncology 2024年第6期16卷 2842-2861页

作者： Qiang-Qiang Fu Le Ma Xiao-Min Niu hua-xin zhao Xu-hua Ge hua Jin De-hua Yu Sen Yang Department of General Practice Yangpu HospitalSchool of MedicineTongji UniversityShanghai 200090China Shanghai General Practice and Community Health Development Research Center Shanghai 200090China Department of Shanghai Lung Cancer Center Shanghai Chest HospitalShanghai Jiao Tong University School of MedicineShanghai 200030China Department of Oncology Shanghai Tenth People’s HospitalTongji University School of MedicineShanghai 200090China

BACKGROUND Gastrointestinal neoplasm(GN)significantly impact the global cancer burden and mortality,necessitating early detection and *** the evolution and current state of research in this field is *** To conducts a comprehensive bibliometric analysis of publications from 1984 to 2022 to elucidate the trends and hotspots in the GN risk assessment research,focusing on key contributors,institutions,and thematic *** This study conducted a bibliometric analysis of data from the Web of Science Core Collection database using the"bibliometrix"R package,VOSviewer,and *** analysis focused on the distribution of publications,contributions by institutions and countries,and trends in *** methods included data synthesis,network analysis,and visualization of international collaboration *** This analysis of 1371 articles on GN risk assessment revealed a notable evolution in terms of research focus and *** highlights the United States'critical role in advancing this field,with significant contributions from institutions such as Brigham and Women's Hospital and the National Cancer *** last five years,substantial advancements have been made,representing nearly 45%of the examined *** rates have dramatically increased,from 20 articles in 2002 to 112 in 2022,reflecting intensified research *** study underscores a growing trend toward interdisciplinary and international collaboration,with the Journal of Clinical Oncology standing out as a key publication *** shift toward more comprehensive and collaborative research methods marks a significant step in addressing GN *** This study underscores advancements in GN risk assessment through genetic analyses and machine learning and reveals significant geographical disparities in research *** calls for enhanced global collaboration and integration of artificial intelligence to improve cancer p

关键词： Gastrointestinal neoplasms Bibliometric analysis Risk assessment Network analysis Research trends

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Application of PCR-DGGE in Research of Bacterial Diversity in Drinking Water

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Biomedical and Environmental Sciences 2006年第5期19卷 371-374页

作者： QING WU xin-hua zhao SHENG-YUE zhao Department of Environmental Science and Engineering Tianjin University Tianjin 300072 China

Objective To analyze the structure of bacteria in drinking water by molecular biological techniques, Methods DNA of bacteria in drinking water was directly extracted without culture. 16S ribosomal DNA fragments, including V-6, -7, and -8 regions, were amplified with universal primers （EUBf933CJC and EUBr1387） and analyzed by DGGE. Results DGGE indicated that amplification products could be separated, The results showed that DGGE could be used in the separation of different microbial 16SrRNA genes extracted from drinkng water. Though there were special bacteria in different water samples, the predominant bacteria were essentially the same. Three sequences of the reclaimed specific bands were obtained, and phylogenetic tree of these bands was made. Conclusion Bacterial diversity in drinking water is identified by molecular biological techniques.

关键词： Drinking water Denaturing gradient gel electrophoresis (DGGE) 16S ribosome RNA Microbial diversity

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Integration of USEPA WASP model in a GIS platform

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2010年第12期11卷 1015-1024页

作者： Sen PENG George Yu-zhu FU xin-hua zhao School of Environmental Science and Engineering Tianjin University Tianjin 300072 China Department of Construction Management and Civil Engineering Georgia Southern University Statesboro GA 30460 USA

The integration of water quality analysis simulation program (WASP) with a geographical information system (GIS) is *** integration was undertaken to enhance the data analysis and management ability of the widely used water quality *** types of data involved in WASP modeling were converted and integrated into GIS using a database *** spatial data modeling and analysis capability of GIS were used in the operation of the *** WASP water quality model was coupled with the environmental fluid dynamics code (EFDC) hydrodynamic model.A case study of the Lower Charles River Basin (Massachusetts,USA) water quality model system was conducted to demonstrate the integration *** results showed that high efficiency of the data process and powerful function of data analysis could be achieved in the integrated model,which would significantly improve the application of WASP model in water quality management.

关键词： Water quality analysis simulation program (WASP) Geographical information system (GIS) Integration Environmental fluid dynamics code (EFDC) Water quality model

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A trinuclear {Fe_(2)^(Ⅲ)Fe^(Ⅱ)} complex involving both spin and non-spin transitions exhibits three-step and wide thermal hysteresis

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Science China Chemistry 2022年第3期65卷 532-538页

作者： xin-hua zhao Dong Shao Jia-Tao Chen De-Xuan Gan Jiong Yang Yuan-Zhu Zhang Department of Chemistry Southern University of Science and Technology(SUSTech)Shenzhen 518055China

The engineering of switchable molecules with magnetic multistability is lying on the cutting-edge research topics for integrating multi-switches and ternary memory devices. Here we presented a cyanide-bridged {Fe_(2)^(Ⅲ)Fe^(Ⅱ)} desolvated complex {[(pzTp)Fe^(Ⅲ)-(CN)3]2[Fe^(Ⅱ)(L)]} (1), obtained through single-crystal-to-single-crystal (SCSC) transformation from its solvated phase {[(pzTp)-Fe^(Ⅲ)(CN)3]2[Fe^(Ⅱ)(L)]}·2CH_(3)OH·5H_(2)O (1·sol). Remarkably, 1 exhibited unprecedented three-step transition in magnetization with wide thermal hysteresis (44, 40, and 36 K) in the temperature range of 80–320 K. The detailed studies demonstrated that the tristable character originates from both an order-disorder structural phase transition (SPT) and a strongly cooperative two-step spin crossover (SCO) process. This work thus provides a new promising strategy for realizing multiple bistablity in magnetization by introducing two different transitions.

关键词： magnetic multistability cyanide complex spin crossover phase transition magnetic switching

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Removal of cadmium using MnO_2 loaded D301 resin

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Journal of Environmental Sciences 2007年第6期19卷 652-656页

作者： ZHU Zhi-liang MA Hong-mei ZHANG Rong-hua GE Yuan-xin zhao Jian-fu Key Laboratory of Yangtze Aquatic Environment of Ministry of Education State Key Laboratory of Pollution Control and Resource Reuse Tongji University Shanghai 200092 China

MnO2 loaded weak basic anion exchange resin D301 （Anion exchange resin, macroreticular weak basic styrene） as adsorbent has been prepared and applied to the removal of cadmium. The adsorption characteristics have been investigated with respect to effect of pH, equilibrium isotherms, removal kinetic data, and interference of the coexisting ions. The results indicated that the Cd^2＋ could be efficiently removed using MnO2 loaded D301 resin in the pH range of 3-8 from aqueous solutions with the co-existence of high concentration of alkali and alkaline-earth metals ions. The saturate adsorption capacity of the Cd^2＋ was 77.88 mg/g. The adsorption process followed the pseudo first-order kinetics. The equilibrium data obtained in this study accorded excellently with the Langmuir adsorption isotherm.

关键词： cadmium kinetics adsorption loaded resin removal

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Open-circuit voltage analysis of p-i-n type amorphous silicon solar cells deposited at low temperature

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Chinese Physics B 2011年第8期20卷 403-407页

作者： Ni Jian Zhang Jian-Jun Cao Yu Wang Xian-Bao Li Chao Chen xin-Liang Geng xin-hua zhao Ying Institute of Photo-electronics Thin Film Devices and Technique of Nankai University Key Laboratory of Photo-electronics Thin Film Devices and Technique of Tianjin Key Laboratory of Photo-electronicInformation Science and Technology of Ministry of Education (Nankai University) Tianjin 300071 China

This paper identifies the contributions of p-a-SiC：H layers and i-a-Si：H layers to the open circuit voltage of p-i-n type a-Si：H solar cells deposited at a low temperature of 125℃. We find that poor quality p-a-SiC：H films under regular conditions lead to a restriction of open circuit voltage although the band gap of the i-layer varies widely. A significant improvement in open circuit voltage has been obtained by using high quality p-~SiC：H films optimized at the ＂low-power regime＂ under low silane flow rates and high hydrogen dilution conditions.

关键词： amorphous silicon solar cell low temperature open-circuit voltage

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Nucleophilic substitution of hydrogen in naphthalene by chloride(Cl^-)in ionic liquids

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Chinese Chemical Letters 2011年第2期22卷 147-150页

作者： Shen Yi Shi Ai Guo Kong xin hua zhao Han Ming Ding Fan Yang Yong Kui Shan Department of Chemistry East China Normal UniversityShanghai 200062China

Nucleophilic aromatic substitution of hydrogen in non-activated aromatic ring,a very rare phenomenon in organic chemistry,is found in ionic liquids containing Cl^- as anion under mild reaction *** reaction may be carried out by the addition of the halogen-bonding adduct（Br2Cl^-） as nucleophile to aromatic ring carbon atom,leading to the formation of the nucleophilic substitution product.

关键词： Ionic liquid Aromatic compound Naphthalene Nucleophilic reaction Halogen bonding

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Desolvation–Solvation-Induced Reversible On–Off Switching of Two Memory Channels in a Cobalt(II) Coordination Polymer: Overlay of Spin Crossover and Structural Phase Transition

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CCS Chemistry 2022年第9期4卷 3064-3075页

作者： Yi-Fei Deng Yi-Nuo Wang xin-hua zhao Yuan-Zhu Zhang Department of Chemistry Southern University of Science and Technology(SUSTech)Shenzhen 518055

The engineering of switchable materials with controllable stimuli-responsive multistability remains challenging in materials ***,we present syntheses and structural and magnetic studies of a one-dimensional cobalt(Ⅱ)coordination polymer[(enbzp)Co(bpy)](ClO_(4))_(2)·-MeOH·H2O(1;enbzp=N,N′-(ethane-1,2-diyl)bis(1-phenyl-1-(pyridin-2-yl)methanimine,bpy=4,4′-bipyridine)and its desolvated analogue[(enbzp)Co(bpy)](ClO_(4))_(2)(2),obtained by reversible single-crystal-to-single-crystal(SCSC)transformation.

关键词： single-crystal-to-single-crystal transformation spin crossover structural phase transition scan-rate selectivity switchable materials

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Nickel-catalyzed carbonylative four-component 1,4-dicarbofunctionalization of 1,3-enynes

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Science China Chemistry 2024年第6期67卷 2029-2038页

作者： Yan zhao Qi-Chao Shan Hong xin Pin Gao Xu Yang xin-hua Duan Li-Na Guo Department of Chemistry School of ChemistryXi’an Key Laboratory of Sustainable Energy Material Chemistry and Engineering Research Center of Energy StorageMaterials and DevicesMinistry of EducationXi’an Jiaotong UniversityXi’an710049China School of Electrical Engineering Xi’an Jiaotong UniversityXi’an710049China

An efficient Ni-catalyzed four-component 1,4-carbocarbonylation of 1,3-enynes with activated alkyl halides and arylboronic acids under atmospheric pressure of CO is *** tuning the electronic and steric effects of alkyl radicals,both electronrich and electron-deficient 1,3-enynes were compatible with this *** protocol features mild conditions,broad substrate scope,excellent functional group compatibility and facile gram-scale synthesis,providing a practical approach to the quaternary carbon center-containing allenyl *** study revealed that the acyl-NiIIspecies plays an important role in both the coupling and the alkyl radical generation processes.

关键词： Ni catalysis four-component 1 4-carbocarbonylation 1 3-enynes

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