Nucleophilic substitution of hydrogen in naphthalene by chloride(Cl^-)in ionic liquids

作     者：Shen Yi Shi Ai Guo Kong Xin Hua Zhao Han Ming Ding Fan Yang Yong Kui Shan 

作者机构：Department of ChemistryEast China Normal UniversityShanghai 200062China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2011年第22卷第2期

页      面：147-150页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：the key project of Shanghai Science and Technology Committee(Nos.05JC14070 06DZ05025  08JC1408600) for financial supports 

主　　题：Ionic liquid Aromatic compound Naphthalene Nucleophilic reaction Halogen bonding 

摘      要：Nucleophilic aromatic substitution of hydrogen in non-activated aromatic ring,a very rare phenomenon in organic chemistry,is found in ionic liquids containing Cl^- as anion under mild reaction *** reaction may be carried out by the addition of the halogen-bonding adduct（Br2Cl^-） as nucleophile to aromatic ring carbon atom,leading to the formation of the nucleophilic substitution product.