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Reversed charge transfer induced by nickel in Fe-Ni/Mo_(2)C@nitrogen-doped carbon nanobox for promoted reversible oxygen electrocatalysis

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Journal of Energy Chemistry 2024年第1期88卷 202-212,I0005页

作者： Zhicheng Nie Lei Zhang Qiliang zhu Zhifan Ke Yingtang Zhou Thomas Wågberg Guangzhi hu School of Materials Science and Engineering Anhui University of Science and TechnologyHuainan 232001AnhuiChina Institute for Ecological Research and Pollution Control of Plateau Lakes School of Ecology and Environmental ScienceYunnan UniversityKunming 650504YunnanChina National Engineering Research Center for Marine Aquaculture Marine Science and Technology CollegeZhejiang Ocean UniversityZhoushan 316004ZhejiangChina Department of Physics UmeåUniversityUmeåS-90187Sweden

The interaction between metal and support is critical in oxygen catalysis as it governs the charge transfer between these two entities,influences the electronic structures of the supported metal,affects the adsorption energies of reaction intermediates,and ultimately impacts the catalytic *** this study,we discovered a unique charge transfer reversal phenomenon in a metal/carbon nanohybrid ***,electrons were transferred from the metal-based species to N-doped carbon,while the carbon support reciprocally donated electrons to the metal domain upon the introduction of *** led to the exceptional electrocatalytic performances of the resulting Ni-Fe/Mo_(2)C@nitrogen-doped carbon catalyst,with a half-wave potential of 0.91 V towards oxygen reduction reaction(ORR)and a low overpotential of 290 m V at 10 mA cm^(-2)towards oxygen evolution reaction(OER)under alkaline ***,the Fe-Ni/Mo_(2)C@carbon heterojunction catalyst demonstrated high specific capacity(794 mA h g_(Zn)~(-1))and excellent cycling stability(200 h)in a Zn-air *** calculations revealed that Mo_(2)C effectively inhibited charge transfer from Fe to the support,while secondary doping of Ni induced a charge transfer reversal,resulting in electron accumulation in the Fe-Ni alloy *** local electronic structure modulation significantly reduced energy barriers in the oxygen catalysis process,enhancing the catalytic efficiency of both ORR and ***,our findings underscore the potential of manipulating charge transfer reversal between the metal and support as a promising strategy for developing highly-active and durable bi-functional oxygen electrodes.

关键词： Metal-support interaction Charge transfer reversal Oxygen reduction reaction Oxygen evolution reaction Zinc-air battery

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Dynamic coupling of ferrihydrite transformation and associated arsenic desorption/redistribution mediated by sulfate-reducing bacteria

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Journal of Environmental Sciences 2024年第1期135卷 39-50页

作者： Wenjing Zhou huiyan zhu Shiwen hu Bowei Zhang Kun Gao Zhi Dang Chongxuan Liu State Environmental Protection Key Laboratory of Integrated Surface Water-Groundwater Pollution Control School of Environmental Science and EngineeringSouthern University of Science and TechnologyShenzhen 518055China The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters Ministry of EducationSouth China University of TechnologyGuangzhou 510006China

Sulfate-reducing bacteria play an important role in the geochemistry of iron(oxyhydr)oxide and arsenic(As)in natural environments;however,the associated reaction processes are yet to be fully *** this study,batch experiments coupled with geochemical,spectroscopic,microscopic,and thermodynamic analyses were conducted to investigate the dynamic coupling of ferrihydrite transformation and the associated As desorption/redistribution mediated by Desulfovibrio vulgaris(***).The results indicated that *** could induce ferrihydrite transformation via S^(2-)-driven and direct reduction *** the absence of SO_(4)^(2-),*** directly reduced ferrihydrite,and As desorption and re-sorption occurred simultaneously during the partial transformation of ferrihydrite to *** increase in SO_(4)^(2-)loading promoted the S^(2-)-driven reduction of ferrihydrite and accelerated the subsequent mineralogical *** the low and medium SO_(4)^(2-)treatments,ferrihydrite was completely transformed to a mixture of magnetite and mackinawite,which increased the fraction of As in the residual phase and stabilized *** the high SO_(4)^(2-)treatment,although the replacement of ferrihydrite by only mackinawite also increased the fraction of As in the residual phase,22.1%of the total As was released into the solution due to the poor adsorption affinity of As to mackinawite and the conversion of As^(5+)to As^(3+).The mechanisms of ferrihydrite reduction,mineralogy transformation,and As mobilization and redistribution mediated by sulfate-reducing bacteria are closely related to the surrounding SO_(4)^(2-)*** results advance our understanding of the biogeochemical behavior of Fe,S,and As,and are helpful for the risk assessment and remediation of As contamination.

关键词： Sulfate-reducing bacteria Arsenic Ferrihydrite Transformation Redistribution

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Mechanistic investigation on the Hg^(0)elimination ability of MnO_(x)-CeO_(x)nanorod adsorbents:effects of Mn/Ce molar ratio

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Waste Disposal and Sustainable Energy 2024年第2期6卷 185-196页

作者： Shujie Gao Xiaoxiang Wang Yaolin Wang Kai zhu Changxing hu Dong Ye College of Quality and Safety Engineering China Jiliang UniversityHangzhou 310018China Key Laboratory of Biomass Chemical Engineering of Ministry of Education Institute of Industrial Ecology and EnvironmentCollege of Chemical and Biological EngineeringZhejiang UniversityHangzhou 310027China Department of Electrical Engineering and Electronics University of LiverpoolLiverpool L693GJUK Ningbo Tech University No.1 Qianhu South RoadNingbo 315100China

Mercury pollution is created by coal combustion processes in multi-component *** injection was identified as a potential strategy for capturing Hg^(0)from waste gases,with adsorbents serving as the primary *** hydro-thermal approach was used to synthesize a series of MnO_(x)-CeO_(x)nanorod adsorbents with varying Mn/Ce molar ratios to maximize the Hg^(0)capture *** CeO,had weak Hg elimination activity;<8%Hg^(0)removal efficiency was obtained from 150℃to 250℃.With the addition of MnOr,the amount of surface acid sites and the relative concentration of Mn4+*** ensured the sufficient adsorption and oxidation of Hg while overcoming the limitations of restricted adsorbate-adsorbent interactions caused by the lower surface area,endowing MnO_(x)-CeO_(x)with increased Hg^(0)removal *** the molar ratio of Mn/Ce reached 6/4,the adsorbent's Hg^(0)removal efficiency remained over 92%at 150℃and 200℃.As the molar ratio of Mn/Ce grew,the adsorbent's Hg^(0)elimination capacity declined due to decreased surface area,weakened acidity,and decreased activity of Mn^(4+);<75%Hg^(0)removal efficiency was reached between 150℃and 250℃for virgin *** the overall Hg'elimination reactions,Mn4+and *** in charge of oxidizing Hg^(0)to Hg^(0),with Ce^(4+)acting as a promoter to aid in the regeneration of Mn^(4+),Because of its limited adaptability to flue gas components,further optimization of the MnO_(x)-CeO_(x)nanorod adsorbent is required.

关键词： Hg^(0)capture MnO_(x)-CeO_(x)nanorods Mn/Ce molar ratio Acid properties Redox behaviors

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Electrocatalytic stability of two-dimensional materials

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Journal of Energy Chemistry 2024年第10期97卷 302-320页

作者： huijie zhu Youchao Liu Yongsen Wu Yushan He Yang Cao Sheng hu State Key Laboratory of Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) College of Chemistry and Chemical Engineering Xiamen University Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM)

In electrocatalysis,two-dimensional(2D) materials have attracted extensive interests due to their unique electronic structure and physical *** recent years,many efforts have been devoted to improving the catalytic activity of 2D ***,the stability of 2D materials under catalytic conditions,as a critical issue,requires better understanding for any practical *** review summarizes recent progress in electrocatalytic stability of 2D materials,including four intrinsic factors that affect the stability of 2D materials:*** interactions between 2D catalyst and substrate;2,delamination of 2D catalyst layers;*** phase of 2D materials;*** and environmental instability of 2D ***,some corresponding solutions are summarized for each *** addition,this review proposes potential routes for developing 2D catalytic materials with both high activity and stability.

关键词： 2D materials Electrocatalyst Stability

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Defocus spot detection of astronomical optical system

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Research in Astronomy and Astrophysics 2020年第3期20卷 162-169页

作者： Tian-zhu hu Yong Zhang Xiang-Qun Cui Ye-Ping Li hua Bai Xiu-Shan Pan National Astronomical Observatories/Nanjing Institute of Astronomical Optics&Tech no logy.Chinese Academy of Science Nanjing 210042China Key Laboratory of Astronomical Optics&Technology Nanjing Institute of Astronomical Optics&TechnologyChinese Academy of SciencesNanjing 210042China University of the Chinese Academy of Sciences Beijing 100049China

Defocusing spot size detection is especially essential for aberration analysis and correction of optical systems. In the case of far defocusing, the celestial forms a pupil image on the detector, and the size of the image is linearly changed with the defocusing distance, and can be used to correct the optical system and analyze the image quality. Based on the focal plane attitude detection of Large Sky Area MultiObject Fiber Spectroscopy Telescope(LAMOST), this paper uses a variety of methods to detect the size of the defocusing spot of LAMOST telescope. For the particularity of the spot, the average value spacing algorithm, the peak value spacing algorithm, the ellipse fitting algorithm, and the multi-peak Gaussian fitting algorithm are used to detect the spot size. This paper will introduce these four methods, in which the average value spacing algorithm is proposed by the author of this paper. The advantages and disadvantages of the four methods are compared. The experimental results show that the average value spacing algorithm can achieve better accuracy of spot size detection in the four algorithms.

关键词： methods data analysis-techniques image processing-telescopes

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Research on Restoration of Murals Based on Diffusion Model and Transformer

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CMC-COMPUTERS MATERIALS & CONTINUA 2024年第3期80卷 4433-4449页

作者： Wang, Yaoyao Xiao, Mansheng hu, Yuqing Yan, Jin zhu, Zeyu hunan Univ Technol Sch Comp Zhuzhou 412000 Peoples R China hunan Software Vocat & Tech Univ Sch Comp Xiangtan 411100 Peoples R China

Due to the limitations of a priori knowledge and convolution operation, the existing image restoration techniques cannot be directly applied to the cultural relics mural restoration, in order to more accurately restore the original appearance of the cultural relics mural images, an image restoration based on the denoising diffusion probability model (Denoising Diffusion Probability Model (DDPM)) and the Transformer method. The process involves two steps: in the first step, the damaged mural image is firstly utilized as the condition to generate the noise image, using the time, condition and noise image patch as the inputs to the noise prediction network, capturing the global dependencies in the input sequence through the multi-attention mechanism of the input sequence and feedforward neural network processing, and designing a long skip connection between the shallow and deep layers in the Transformer blocks between the shallow and deep layers using long skip connections to fuse the feature information of global and local outputs to maintain the overall consistency of the restoration results; In the second step, taking the noisy image as a condition to direct the diffusion model to back sample to generate the restored image. Experiment results show that the PSNR and SSIM of the proposed method are improved by 2% to 9% and 1% to 3.3%, respectively, which are compared to the comparison methods. This study proposed synthesizes the advantages of the diffusion model and deep learning model to make the mural restoration results more accurate.

关键词： Transformer deep learning noise estimation network diffusion model mural restoration

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Conjugate Vectors Method Applied to Asymmetrical Fault Analysis of Power Electronized Power Systems

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CSEE Journal of Power and Energy Systems 2024年第4期10卷 1536-1549页

作者： Yingbiao Li Xing Liu Jiabing hu Jianhang zhu Jianbo Guo State Key Laboratory of Advanced Electromagnetic Technology(huazhong University of Science and Technology) Wuhan 430074China China Electric Power Research Institute Beijing 100192China

With the wide application of power electronized resources(PERs),the amplitude and frequency of voltages show significant time-varying characteristics under asymmetrical *** a result,the traditional phasor model,impedance model,and symmetrical components method based on the constant amplitude and frequency of voltages are facing great ***,a novel asymmetrical fault analysis method based on conjugate vectors is proposed in this paper which can meet the modeling and analysis requirements of the network excited by voltages with time-varying amplitude/***,asymmetrical fault characteristics are *** an application,a faulted phase identification(FPI)strategy is proposed based on the fault *** correctness and superiority of the asymmetrical fault analysis method and FPI strategy are verified in time-domain simulations and a real-time digital simulator.

关键词： Asymmetrical fault characteristics conjugate vectors method dynamic asymmetrical fault analysis time-varying amplitude/frequency

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Synthesis of 2, 6-(substituded)pyridine Derivatives Using Amide and Imine Groups

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Chinese Chemical Letters 2003年第6期14卷 572-574页

作者： Mei Ying LI, Pei Zhi hu*, Wan Ren zhu, Kuo Xi XU College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072 Coll. of Chem. and Molecular Science Wuhan University Wuhan 430072 China

A new wo-armed?acyclic diamide Ia 2, 6-bis(1-ethanecarbozamido-2-amino)pyridine, and a new series of aromatic aldehyde schiff bases containing pyridine ring and amide bridge, IIa-f, were prepared. The compounds were characterized by elemental analysis, IR, 1HNMR and MS. The bioactivity half inhibitory concentration C1/2 is given.

关键词： Aromatic aldehyde Schiff bases pyridine amide bridge.

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PHOTOLUMINESCENCE OF GaP(N, Te, Zn) UNDER HYDROSTATIC PRESSURE

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Chinese Physics Letters 1984年第1期1卷 15-18页

作者： ZHAO Xue-shu LI Guo-hua HAN He-xiang WANG Zhao-ping TANG Ru-ming hu Jing-zhu Institute of Semiconductors Academia Sinica Institute of Physics Academia.Sinica

Photoluminescence spectrum of Gap ( N, Te , Zn ) under hydrostatic pressure was measured at 77K. Pressure coefficients for Te donor level as well as energy levels of excitons bound to N, NN1, NN3, and neutral donor Te were obtained. The pressure shifts of these levels were discussed. The zero phonon line of free exciton in Gap was observed for the first time.

关键词： donor neutral hydrostatic

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Comparison of toxicity between lanthanum oxide nanoparticles and lanthanum chloride

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Journal of Rare Earths 2024年第2期42卷 424-430,I0007页

作者： Kun huang Songchang Lai Miao Guo Xingwu zhu Jiashuangwei Yuan Zhehao Liu Gonghua hu Yanfang Gao School of Public Health and Health Management Gannan Medical UniversityGanzhou341000China

Due to the wide application of rare earth elements,lanthanum(La) is gradually accumulated in our living *** can enter the body through a variety of routes,which has a series of effects on various *** a consequence,the safety of lanthanum deserves our *** study aims to compare the toxicity of lanthanum oxide nanoparticles(La_(2)O_(3) NPs) and lanthanum chloride(LaCl_(3)) and enrich the toxicity evaluation of ***,a 30 d intragastal experiment was conducted.C57BL/6j mice were given by La_(2)O_(3) NPs solution and LaCl_(3) solution respectively at doses of 0,30,60 and120 mg/kg BW(lanthanum content).The results show that,compared with the control group,both La_(2)O_(3)NPs and LaCl_(3) can reduce the body weight of female mice in the high-dose group,but for male mice,the high-dose La_(2)O_(3) NPs solution can increase the body weight,while LaCl_(3) has the opposite *** coefficients of liver,kidney,heart,lung,uterine and ovaries increase first and then decrease with the exposure dose,but testes and epididymides coefficient keep increasing with the exposure of LaCl_(3) and La_(2)O_(3) ***_(2)O_(3) NPs and LaCl_(3) can reduce the concentration of triglycerides(TG) and increase the level of low density lipoprotein(LDL),but the effect of La_(2)O_(3) NPs is more ***_(2)O_(3) NPs and LaCl_(3) can reduce the concentration of malondialdehyde(MDA),increase the total antioxidant capacity(T-AOC)and enhance the activity of catalase(CAT),but LaCl_(3) has more obvious protective effects on oxidative ***_(2)O_(3) NPs and LaCl_(3) have potential risks to liver,and the toxicity of La_(2)O_(3) NPs might be higher than that of LaCl_(3).

关键词： Rare earth elements Lanthanum oxide nanoparticles Lanthanum chloride Lipid metabolism Oxidative stress

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