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Conductive polypyrrole incorporated nanocellulose/MoS_(2)film for preparing flexible supercapacitor electrodes

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Frontiers of Materials Science 2021年第2期15卷 227-240页

作者： qi yuan Ming-Cuo MA Research Center of Biomass Clean Utilization Beijing Key Laboratory of Lignocellulosic ChemistryCollege of Materials Science and TechnologyBeijing Forestry UniversityBeijing 100083China

Conductive films have emerged as appealing electrode materials in flexible supercapacitors owing to their conductivity and mechanical ***,the unsatisfactory electrode structure induced poor output performance and undesirable cycling stability limited their ***,a well-designed film was manufactured by the vacuum filtration and in-situ polymerization method from cellulose nanofibrils(CNFs),molybdenum disulfide(MoS_(2)),and *** electrode presented an outstanding mechanical strength(21.3 MPa)and electrical conductivity(9.70 S cm^(-1)).Meanwhile,the introduce of hydrophilic CNFs induced a desirable increase in diffusion path of electrons and ions,along with the synergistic effect among the three components,further endowed the electrode with excellent specific capacitance(0.734 F·cm^(-2))and good cycling stability(84.50%after 2000 charge/discharge cycles).More importantly,the flexible all-solid-state symmetric supercapacitor delivered a high specific capacitance(1.39 F·cm^(-2)at 1 mA·cm^(-2))and a volumetric energy density(6.36 mW·h·cm^(-3)at the power density of 16.35 mW cm^(-3)).This work provided a method for preparing composite films with desired mechanical and electrochemical performance,which can broaden the high-value applications of nanocellulose.

关键词： cellulose nanofibril molybdenum disulfide polypyrrole flexible supercapacitor

Heat Capacity and Enthalpy of Fusion of Crystalline Pyrimethanil Decylate(C_(22)H_(33)N_3O_2)

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Chemical Research in Chinese Universities 2005年第6期21卷 697-701页

作者： SUN Xiao-hong LIU yuan-fa TAN Zhi-cheng WANG Mei-han JIA Ying-qi College of Chemical Engineering Chemical Research Institute Northwest University Xi＇an 710069 P. R. China Department of Chemistry Northwest University Xi＇an 710069 P. R. China Thermochemistry Laboratory Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian 116023 P. R. China

Low-temperature heat capacities of pyrimethanil decylate （ C22 H33 N3 O2 ） were precisely measured with an automated adiabatic calorimeter over the temperature range from 78 to 373 K. The sample was observed to melt at （311.04 ± 0.06） K. The molar enthalpy and entropy of fusion as well as the chemical purity of the compound were determined to be（45876± 12） J/mol, （147. 50 ±0. 05） J. mol^-1 · K^-1 and （99. 21 ±0. 03）% （mass fraction）, respectively. The extrapolated melting temperature for the absolutely pure compound obtained from fractional melting experiments is （311. 204±0. 035 ） K.

关键词： Pyrimethanil decylate Heat capacity Adiabatic calorimetry DSC

Strength Activity Index of Air Quenched Basic Oxygen Furnace Steel Slag

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Journal of Iron and Steel Research International 2015年第3期22卷 219-225页

作者： Lei GAN Hai-feng WANG Xiu-ping LI yuan-hong qi Chun-xia ZHANG School of Metallurgical and Chemical Engineering Jiangxi University of Science and Technology State Key Laboratory of Advanced Steel Processes and Products Central Iron and Steel Research Institute

Air quenched basic oxygen furnace steel slag （BOF-SS） is processed at very high cooling rate, which is expected to have different cementitious properties from conventional slowly cooled BOF-SS. For this purpose, the strength activity indexes of air quenched and slowly cooled BOF-SS are investigated. The results reveal that, under the specific surface area （S） of 490 m^2/kg, the compressive strength activity index reaches 1.24 after 28 days with replacement of 15% air quenched BOF-SS and reaches 1.05 after 28 days with replacement of 20% air quenched BOF-SS and 30%granulated blast furnace slag （GBFS）. The cementitious activity of air quenched BOF-SS is obviously higher than that of slowly cooled BOF-SS, mainly because it contains more C3 S and glassy phases.

关键词： basic oxygen furnace steel slag strength activity index mineral characteristics cementitious property tricalcium silicate (C3 S)

Mechanistic insight into lysyl oxidase in vascular remodeling and angiogenesis

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Genes & Diseases 2023年第3期10卷 771-785页

作者： Zhao-Jun Wang qi-Wen Guan hong-Hao Zhou Xiao-yuan Mao Fang-Hui Chen Department of Clinical Pharmacology Xiangya HospitalCentral South UniversityChangshaHunan 410008China Institute of Clinical Pharmacology Central South UniversityHunan Key Laboratory of PharmacogeneticsChangshaHunan 410078China Engineering Research Center of Applied Technology of Pharmacogenomics Ministry of EducationChangshaHunan 410078China National Clinical Research Center for Geriatric Disorders ChangshaHunan 410008China Department of Pharmacy The First Affliated Hospital of Gannan Medical UniversityGanzhouJiangxi 341000China

Vascular remodeling and angiogenesis are two key processes in the maintenance of vascular homeostasis and involved in a wide array of vascular pathologies. Following these processes, extracellular matrix (ECM) provides the mechanical foundation for vascular walls. Lysyl oxidase (LOX), the key matrix-modifying enzyme, has been demonstrated to significantly affect structural abnormality and dysfunction in the blood vessels. The role of LOX in vascular remodeling and angiogenesis has always been the subject in the current medical research. Therefore, we presently make a summarization of the biosynthesis of LOX and the mechanisms involved in vascular remodeling and angiogenesis, as well as the role of LOX in diseases associated with vascular abnormalities and the therapeutic potential via targeting LOX. In particular, we give a proposal that LOX likely reshapes matrisome-associated genes expressions in the regulation of vascular remodeling and angiogenesis, which serves as a mechanistic insight into the critical role of LOX in these two aspects. Additionally, LOX has also dual effects on the vascular dysfunction, namely, inhibition of LOX for improving hypertension, restenosis and malignant tumor while activation of LOX for curing arterial aneurysm and dissection. LOX-targeted therapy may provide a promising therapeutic strategy for the treatment of various vascular pathologies associated with vascular remodeling and angiogenesis.

关键词： Angiogenesis Disease pathology Lysyl oxidase Therapeutic target Vascular homeostasis Vascular remodeling

Direct Reduction Experiment on Iron-Bearing Waste Slag

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Journal of Iron and Steel Research International 2013年第3期20卷 24-29,35页

作者： CHENG Xiang-li ZHAO Kai qi yuan-hong SHI Xue-feng ZHEN Chang-liang State Key Laboratory of Advanced Steel Process and Products Central Iron and Steel Research Institute

A lot of iron-bearing slags were produced,and whose grade is much more than that of industrial iron ore *** analysis and phase identification shows that the iron-bearing slag is amorphous,has fayalite main phase,iron grade is 36.10%,and is difficult to recover iron from the *** calculation indicates that CO cannot reduce fayalite at high temperature and carbon direct reduction can be ***,the reaction begins at 770 ℃ and the temperature can be reduced down to 500℃ when CaO is *** this basis,a method is put forward to making direct enrichment of iron by taking carbon contained pellets to realize the rapid reduction of fayalite,and the direct reduction process were studied in this *** show that xC/xO should be less than 1.5 for the need of reduction and carburization,and CaO and Al2O3 can spur the reduction of *** conditions that xC/xO is 1.2,metallization rate can be 77% when temperature is 1 250 ℃ and only carbon is added,and metallization rate can be 74% when temperature is 1 200 ℃ and only CaO is *** the addition of Al2O3 can get a higher metallization rate（10% or so） than usual as R is between 0.4 and *** the optimized condition of R equals to 0.6,temperature of 1 250 ℃,slag melting point of 1 320 ℃,and time of 30 min,the metallization rate can reach 88.43%.

关键词： iron-bearing slag fayalite metallization rate basicity

Radiological environmental impact analysis of a 2-MW thorium molten salt reactor during an accident

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Nuclear Science and Techniques 2019年第5期30卷 70-81页

作者： Chang-qi Chen Xiao-Bin Xia Zhi-hong Zhang Jun Cai Chang-yuan Li Shanghai Institute of Applied Physics Chinese Academy of Sciences University of Chinese Academy of Sciences

The thorium molten salt reactor–liquid fuel(TMSR-LF1) has inherent safety features. The accident occurrence possibility and their consequences are much lower for the TMSR-LF1 than that of traditional *** on accident analysis, the maximum credible accident and the radioactive source terms of the TMSR-LF1 were first estimated. Then, the total effective dose of the maximum credible accident was calculated. Based on calculations, the cover gas flow rate can significantly affect the radiation consequences of the maximum credible accident when it changes from 0 to 10 L/min. If no cover gas is flowing, a site-area emergency would be required within the range of 50–73 m from the reactor. In the case of cover gas flow, only an abnormal notification and an alert two emergency class would be required within the range of 50 m.

关键词： TMSR-LF1 Accident classification and description Maximum credible accident Emergency class

Challenges and perspectives of combustion chemistry research

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Science China Chemistry 2017年第11期60卷 1391-1401页

作者： Wenhao yuan Yuyang Li Fei qi Key Laboratory for Power Machinery and Engineering of Ministry of Education Shanghai Jiao Tong UniversityShanghai 200240China

In the past decades, combustion chemistry research grew rapidly due to the development of combustion diagnostic methods,quantum chemistry methods, kinetic theory, and computational techniques. A lot of kinetic models have been developed for fuels from hydrogen to transportation fuel surrogates. Besides, multi-scale research method has been widely adopted to develop comprehensive models, which are expected to cover combustion conditions in real combustion devices. However, critical gaps still remain between the laboratory research and real engine application due to the insufficient research work on high pressure and low temperature combustion chemistry. Besides, there is also a great need of predictive pollutant formation model. Further development of combustion chemistry research depends on a closer interaction of combustion diagnostics, theoretical calculation and kinetic model development. This paper summarizes the recent progress in combustion chemistry research briefly and outlines the challenges and perspectives.

关键词： combustion chemistry combustion diagnostics validation experiments quantum chemistry calculation rate constant calculation kinetic model

About 300 days Optical Quasi-periodic Oscillations in the Long-term Light Curves of the Blazar PKS 2155-304

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Research in Astronomy and Astrophysics 2022年第8期22卷 284-293页

作者： qi Zheng Xue-Guang Zhang qi-Rong yuan School of Physics and Technology Nanjing Normal UniversityNanjing 210023China

Based on the long-term light curves collected from the Catalina Sky Survey(CSS)(from 2005 to 2013)and the All-Sky Automated Survey for Supernovae(ASAS-SN)(from 2014 to 2018),optical quasi-periodic oscillations(QPOs)about 300 days can be well determined in the well-known blazar PKS 2155-304 through four different methods:the generalized Lomb-Scargle periodogram(GLSP)method,the weighted wavelet Z-transform technique,the epoch-folded method and the redfit *** GLSP determined significance level for the periodicity is higher than 99.9999%based on a false alarm *** redfit provided confidence level for the periodicity is higher than 99%in the ASAS-SN light curve,after considering the effects of red *** on continuous autoregressive process created artificial light curves,the probability of detecting fake QPOs is lower than 0.8%.The determined optical periodicity of 300 days from the CSS and ASAS-SN light curves is well consistent with the reported optical periodicity in the ***,three possible models are discussed to explain the optical QPOs in PKS 2155-304:the relativistic frame-dragging effect,the binary black hole model and the jet precession model.

关键词： (galaxies:)BL Lacertae objects:individual(PKS 2155-304) galaxies:active (galaxies:)quasars:supermassive black holes

A carbon-carbon hydrolase from human gut probiotics Flavonifractor plautii catalyzes phloretin conversion

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Food Bioscience 2022年第6期50卷 2000-2008页

作者： Ting yuan qiu Tian Gong Shuai Zhang qi Hang Chen Ching yuan Hu Yong hong Meng The Engineering Research Center for High-Valued Utilization of Fruit Resources in Western China Ministry of EducationNational Research&Development Center of Apple Processing TechnologyCollege of Food Engineering and Nutritional ScienceShaanxi Normal University620 West Changan AvenueXianShaanxi710119PR China Department of Human Nutrition Food and Animal SciencesCollege of Tropical Agriculture and Human ResourcesUniversity of Hawaii at Manoa1955 East-West RoadAgSci.415J HonoluluHI96822USA

Although the catabolic pathway of some flavonoids in the human colon has been elucidated,knowledge of related gut microbes and responsible enzymes is still *** this study,a phloretin hydrolase gene(phy)from Flavonifractor plautii(***)was synthesized and heterologously expressed in Escherichia coli BL21(*** BL 21).Phloretin hydrolase(PHY)was purified from cell extracts of recombinant *** BL21,and PHY's molecular weight was about 32 *** purified PHY effectively cleaved phloretin into 3-(4-hydroxyphenyl)propionic acid(HPPA)and phloroglucinol(PG).PHY's kinetic parameters were determined:Km was 2.8×10−3±0.4 mM and Vmax was 411.2±7.1 U/***,PHY's optimal temperature and pH were 50°C and 7.5,respectively,and PHY exhibited 75%activity after 5 h at 50°***,PHY's activity was inhibited in the presence of Ba2+,Cu2+,and Fe2+,while Mg2+slightly elevated PHY's ***,the catalytic model between phloretin and PHY was built using molecular docking,and PHY's conformational changes were further demonstrated through the multispectral *** study is conducive to understanding phloretin metabolism in the colon and adding a valuable source of PHY for food industry application.

关键词： Phloretin hydrolase Flavonifractor plautii Gut microbe