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Achieving ultrahigh strength and ductility in high-entropy alloys via dual precipitation

journal of Materials Science & Technology 2023年第35期166卷 67-77页

作者： j.M.Guo B.C.Zhou S.Qiu h.j.kong M.C.Niu j.h.Luan T.L.Zhang h.Wu Z.B.jiao Department of Mechanical Engineering Research Institute for Advanced ManufacturingThe Hong Kong Polytechnic UniversityHong KongChina The hong kong Polytechnic University Shenzhen Research Institute Shenzhen 518057China Department of Materials Science and Engineering City University of Hong KongHong KongChina State Key Laboratory of Powder Metallurgy Central South UniversityChangsha 410083China

The strength-ductility trade-offhas been a longstanding dilemma in metallic *** we report an innovative approach to achieve a high strength-ductility synergy via dual precipitation of sheared and bypassed precipitates.(Ni_(2) Co_(2) FeCr)_(96-x) Al_(4) Nb_(x)(at.%)alloys strengthened by nanoscale L12 particles and Laves precipitates were selected as a model for this study,and their precipitate microstructures and mechanical properties were thoroughly *** dual-precipitation-strengthened alloys exhibit a yield strength of more than 1400 MPa,an ultimate tensile strength of over 1800 MPa,and a uniform elon-gation of 18%,thus achieving a high strength-ductility *** analysis reveals that the nanoscale L1_(2) precipitates contribute to the strength via the particle shearing mechanism,whereas the Laves phase provides the strengthening through the Orowan bypass *** study of deformation microstruc-tures shows that the L1_(2) precipitates are sheared by stacking faults,which facilitates long-range disloca-tion gliding through the *** a result,deformation induces the formation of hierarchical stacking fault networks and immobile Lomer-Cottrell locks,which effectively enhance the work hardening ca-pability and plastic stability,thereby resulting in a high ductility at high strength *** are piled-up against the interface between the Laves precipitates and matrix,which increases the work hardening capability at the early stages of plastic deformation but causes stress *** dual precipitation strategy may be useful for many other alloys for achieving superior mechanical properties for technological applications.

关键词： high-entropy alloy Dual precipitation Precipitation strengthening Deformation mechanism

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A low redox potential and long life organic anode material for sodium-ion batteries

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journal of Energy Chemistry 2025年第1期100卷 557-564页

作者： Zhi Li Yang Wei Kang Zhou Xin huang Xing Zhou jie Xu Taoyi kong junwei Lucas Bao Xiaoli Dong Yonggang Wang Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Institute of New Energy Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) Fudan University Department of Chemistry Boston College School of Materials Science and Engineering Anhui University of Technology

Sodium-ion batteries （SIBs） with organic electrodes are an emerging research direction due to the sustainability of organic materials based on elements like C,h,O,and sodium ***,organic electrode materials for SIBs are mainly used as cathodes because of their relatively high redox potentials（>1 V）.Organic electrodes with low redox potential that can be used as anode are ***,a novel organic anode material （tetrasodium 1,4,5,8-naphthalenetetracarboxylate,Na4TDC） has been developed with low redox potential （hree-sodium storage mechanism was demonstrated with various in-situ/ex-situ spectroscopy and theoretical calculations,showing a high capacity of 208 mAh/g and an average decay rate of merely 0.022%per ***,the Na4TDC-hard carbon composite can further acquire improved capacity and cycling stability for 1200 cycles even with a high mass loading of up to 20 mg *** pairing with a thick Na3V2（PO4）3cathode (20.6 mg cm-2),the as-fabricated full cell exhibited high operating voltage （2.8 V）,excellent rate performance and cycling stability with a high capacity retention of 88.7% after 200 cycles,well highlighting the Na4TDC anode material for SIBs.

关键词： Organic anode material Low redox potential Composite anode Sodium-ion batteries

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Preparation of Pure Copper Powder from Acidic Copper Chloride Waste Etchant

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journal of Materials Science & Technology 2008年第1期24卷 141-142页

作者： h.S.hong M.S.kong j.K.Ghu j.K.Lee h.G.Suk Plant Engineering Center.Institute for Advanced Engineering Yongin 449-863 Korea Dept. of Advanced Mater. Eng. Korea Polytechnic University Shihung 429-793 Korea Nano-surface Treat. Tech. Team Korea Inst. of Industrial Technology Incheon 463-130 Korea Dept. of Mater. and Met. Eng. Kangwon National University Samcheok 245-711 Korea

The method for the recycling of copper from copper chloride solution was developed. This process consists of extraction of copper, purification and particle size reduction. In the first step, reductive metal scraps were added to acidic copper chloride waste enchants produced in the PCB industry to obtain copper powder. Composition analysis showed that this powder contained impurities such as Fe, Ni, and water. So, drying and purification were carried out by using microwave and a centrifugal separator. Thereby the copper powder had a purity of higher than 99% and spherical form in morphology. The copper powder size was decreased by ball milling.

关键词： Copper chloride liquid waste Printed circuit board (PCB), Liquid waste highpurity copper powder

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Dynamics and functions of E‑cadherin complexes in epithelial cell and tissue morphogenesis

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Marine Life Science & Technology 2023年第4期5卷 585-601页

作者： Na Zhang Matthias häring Fred Wolf jörg Großhans Deqing kong Department of Biology Philipps University35043 MarburgGermany Göttingen Campus Institute for Dynamics of Biological Networks(CIDBN) Georg August University Göttingen37073 GöttingenGermany

Cell–cell adhesion is at the center of structure and dynamics of epithelial tissue.E-cadherin–catenin complexes mediate Ca^(2+)-dependent trans-homodimerization and constitute the kernel of adherens *** the basic function of cell–cell adhesion,recent progress sheds light the dynamics and interwind interactions of individual E-cadherin–catenin complex with E-cadherin superclusters,contractile actomyosin and mechanics of the cortex and *** nanoscale architecture of E-cadherin complexes together with cis-interactions and interactions with cortical actomyosin adjust to junctional tension and mechano-transduction by reinforcement or weakening of specific features of the *** post-translational modifications such as phosphorylation and glycosylation have been implicated,their role for specific aspects of in E-cadherin function has remained ***,we provide an overview of the E-cadherin complex in epithelial cell and tissue morphogenesis focusing on nanoscale architectures by super-resolution approaches and post-translational modifications from recent,in particular in vivo,***,we review the computational modelling in E-cadherin complexes and highlight how computational modelling has contributed to a deeper understanding of the E-cadherin complexes.

关键词： Nanoscale architectures Phosphorylation Glycosylation Computational modelling

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INFLUENCE OF SILICON IN STEELS ON GALVANIZED COATINGS

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Acta Metallurgica Sinica(English Letters) 2006年第2期19卷 85-90页

作者： C.S. Che j.T. Lu G. kong Q.Y. Xu j.h. Chen College of Materials Science and Engineering South China University of Technology Guangzhou 510640 China

After steel sheets （0.37wt%Si） pre-electroplated with a thin layer of pure Fe were immersed in molten zinc for various time, the change in the microstructure of the galvanized coating on the steel and the change of α-Fe/Г interface were studied. The EDS （energy dispersive sepectroscopy） resuits show that excessive silicon accumulates on the surface of the steel substrate due to the low solubility of silicon in the Г layer after the Fe layer is depleted by the increasing growth of the compound layers. With the movement of α-Fe/Г interface towards the substrate by the Fe/Zn reaction, silicon-rich α-Fe peels off from the substrate and breaks into particles. The particles, much like an inert marker in a Kirkendall effect experiment, move towards the δ layer through the Г layer because silicon-rich α-Fe can not be adsorbed in the Г layer. On reaching the 8/F interface, the particles quickly dissolve in the δ layer, and accelerate its growth, resulting in the gradual disappearance of the Г layer. At the same time, the normal coating is quickly changed into coatings typical of reactive steels as silicon dissolved in the δ layer soon diffuses toward the ζ layer. A similar process may happen in the initial stage of galvanizing reactive steels on a small scale, although it is hard to be observed.

关键词： Zn coating intermetallics steel electrodeposition

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Nanostructured steels for advanced structural applications

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Materials Futures 2022年第1期1卷 97-100页

作者： h.j.kong T Yang T L Zhang B X Cao C T Liu Department of Mechanical Engineering Department of Material Science and EngineeringHong Kong Institute for Advanced StudyCity University of Hong KongHong KongPeople’s Republic of China

This vision summarizes the recent advancement of nanostructured steels foradvanced structural applications, foresees possible challenges and pinpoints futuredirections as well as opportunities in this new era of indus... 详细信息

关键词： nanostructured steels extreme environments advanced manufacturing shape memory

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Communications in Nonlinear Science and Numerical Simulation 1999年第3期4卷 186-190页

作者： Guoqian ChEN and j. h. W. LEE(Centre for Environmental Sciences, Peking University, Beijing 100871, China) (Department of Civil Engineering, University of hong kong, hong kong, China) Centre for Environmental Sciences Peking University Beijing 100871 China Department of Civil Engineering University of Hong Kong Hong Kong China

IntroductionThethermal,abodyofbuoyalfluidinafluidwithwhichitcanmixandgivennamebygliderpilotstothosemassesofwarmairrisingfromhotgroundwarmedbysunshineinwhichtheycansoar,***],duetoi... 详细信息

IntroductionThethermal,abodyofbuoyalfluidinafluidwithwhichitcanmixandgivennamebygliderpilotstothosemassesofwarmairrisingfromhotgroundwarmedbysunshineinwhichtheycansoar,***],duetoi...

关键词： environmental fluid mechanics thermal turbulence modeling

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Turbulent Gravity Current of Lock Release Type: A Numerical Study

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Communications in Nonlinear Science and Numerical Simulation 1999年第1期4卷 20-24页

作者： G. Q. ChEN(Centre for Environment Sciences, Peking University, Beijing 100871, China) and j. h. W. LEE(Department of Civil Engineering, University of hong kong, hong kong, China) Centre for Environment Sciences Peking University Beijing 100871 China Department of Civil Engineering University of Hong Kong Hong Kong Hong Kong

The time evolution of a turbulent gravity current of lock release type, formed by a finite volume of homogenous fluid released instantaneously into another fluid of slightly lower density, is studied numerically via the renormalization group (RNG) k - model for Reynolds-stress closure to characterize the flow with transitional and highly localized turbulence. Consistent with previous experimental observations the numerical results show that the gravity current passes through two distinct phases, an initial slumping phase in which the current head advances steadily, and a second self-similar phase in which the front velocity decreases like the negative third power of the time after release. An overall entrainment ratio proportional to the distance from the release point is found and compares well with available experimental data for the slumping phase.

关键词： turbulent flow gravity current numerical simulation

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Giant Magneto-impedance Effect in Composite Wires with Different Core Layer

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Nano-Micro Letters 2013年第2期5卷 140-144页

作者： R.L.Wang X.Li X.h.kong Y.X.Guo j.Z.Ruan Z.j.Zhao Department of Physics Engineering Research Center for Nanophotonics & Advanced Instrument Ministry of Education East China Normal University Experimental Teaching Center of Physics Shanghai Ocean University

Composite structure materials were potential sensing elements for magnetic sensors due to Giant magnetoimpedance(GMI) effect. Two kinds of composite wires with different magnetic/non-magnetic structures were fabricated by using electroless deposition methods and the magnetoimpedance properties were investigated. The maximum GMI ratio of 114% was acquired at 60 Mhz in the composite wires with a ferromagnetic core, whereas, 116% of maximum GMI ratio was found in the composite wires with a conductive core at low frequency of 600 k hz. These results exhibit that the GMI ratio reaches the maximum when magnetoresistance ratio ?R/R and magnetoinductance ratio ?X/X make the comparative contributions to the total magnetoimpedance(MI). The obvious GMI effect obtained in the composite wires with conductive core frequency may provide a candidate for applications in magnetic sensors, especially at low frequencies.

关键词： Composite wires Electroless deposition Giant Magnetoimpedance effect Resistivity

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A functional tacrolimus-releasing nerve wrap for enhancing nerve regeneration following surgical nerve repair

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Neural Regeneration Research 2025年第1期20卷 291-304页

作者： Simeon C.Daeschler Katelyn j.W.So Konstantin Feinberg Marina Manoraj jenny Cheung jennifer Zhang Kaveh Mirmoeini jPaul Santerre Tessa Gordon Gregory hBorschel SickKids Research Institute Neuroscience and Mental Health ProgramTorontoONCanada Institute of Biomaterials and Biomedical Engineering University of TorontoTorontoONCanada Indiana University School of Medicine IndianapolisINUSA Division of Plastic and Reconstructive Surgery the Hospital for Sick ChildrenTorontoONCanada Translational Biology and Engineering Program Ted Rogers Centre for Heart ResearchInstitute of Biomedical EngineeringFaculty of DentistryUniversity of TorontoTorontoONCanada

Axonal regeneration following surgical nerve repair is slow and often incomplete,resulting in poor functional recovery which sometimes contributes to lifelong ***,there are no FDA-approved therapies available to promote nerve *** accelerates axonal regeneration,but systemic side effects presently outweigh its potential benefits for peripheral nerve *** authors describe herein a biodegradable polyurethane-based drug delivery system for the sustained local release of tacrolimus at the nerve repair site,with suitable properties for scalable production and clinical application,aiming to promote nerve regeneration and functional recovery with minimal systemic drug *** is encapsulated into co-axially electrospun polycarbonate-urethane nanofibers to generate an implantable nerve wrap that releases therapeutic doses of bioactive tacrolimus over 31 *** and drug loading are adjustable for applications in small and large caliber nerves,and the wrap degrades within 120 days into biocompatible *** released from the nerve wrap promotes axon elongation in vitro and accelerates nerve regeneration and functional recovery in preclinical nerve repair models while off-target systemic drug exposure is reduced by 80%compared with systemic *** its surgical suitability and preclinical efficacy and safety,this system may provide a readily translatable approach to support axonal regeneration and recovery in patients undergoing nerve surgery.

关键词： biodegradable local drug delivery nerve injury nerve regeneration nerve wrap tacrolimus

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