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Chemical Research in Chinese Universities 2024年第3期40卷 475-483页

作者： WANG Huan GONG Guannan SUN guohua QI Jian YU Ranbo WANG Dan Hebei Key Laboratory of Flexible Functionals Materials School of Materials Science and EngineeringHebei University of Science and TechnologyShijiazhuang 050000P.R.China Department of Physical Chemistry School of Metallurgical and Ecological EngineeringUniversity of Science&Technology BejingBeijing 100083P.R.China State Key Laboratory of Biochemical Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190P.R.China

CeO_(2) with excellent oxygen storage-exchange capacity and NiO with excellent surface activity were used to construct a heterogeneous NiO-CeO_(2)−δhollow multi-shelled structure(HoMS)by spray *** turned out that as the proportion of CeO_(2) increases,the overpotential and Tafel slope of NiO-CeO_(2)−δHoMSs first decreased and then *** is mainly because the construction of the NiO-CeO_(2)−δHoMSs not only increases the specific surface area,but also introduces oxygen vacancy defects,thus improving the interface charge transfer capability of the materials and further improving the oxygen evolution reaction(OER)***,the increase of the calcination temperature will induce the decay of the OER performance of NiO-CeO_(2)−δHoMSs,which is mainly due to the decrease of the specific surface area,the reduction of oxygen vacancy defects,and the weakening of interface charge transfer ***,a series of heterogeneous composite HoMSs,such as Ni/Co,Mo/Ni,Al/Ni and Fe/Ni oxides was successfully constructed by spray drying,which enriched the diversity of HoMSs.

关键词： Heterogeneous composite structure Hollow multishelled structure Oxygen vacancy defect Oxygen evolution reaction

Optical edge-to-screw singularity state conversions

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Photonics Research 2024年第8期12卷 1689-1695页

作者： HAOLIN LIN JUNHUI JIA guohua LIU YANWEN HU ZHEN LI ZHENQIANG CHEN SHENHE FU Department of Optoelectronic Engineering Jinan UniversityGuangzhou 510632China Guangdong Provincial Key Laboratory of Optical Fiber Sensing and Communications Guangzhou 510632China Guangdong Provincial Engineering Research Center of Crystal and Laser Technology Guangzhou 510632China

Optical singularity states,which significantly affect propagation properties of light in free space or optical medium,can be geometrically classified into screw and edge *** different types of singularity states do not exhibit direct connection,being decoupled from each other in the absence of external *** we demonstrate a novel optical process in which a higher-order edge singularity state initially nested in the propagating Gaussian light field gradually involves into a screw singularity with a new-born topological charge determined by order of the edge *** considered edge state comprises an equal superposition of oppositely charged vortex and antivortex *** theoretically and experimentally realize this edge-to-screw conversion process by introducing intrinsic vortex–antivortex *** also present a geometrical representation for mapping this dynamical process,based on the higher-order orbital Poincaré*** this framework,the edge-to-screw conversion is explained by a mapping of state evolution from the equator to the north or south pole of the Poincaré*** demonstration provides a novel approach for manipulating singularity state by the intrinsic vortex–antivortex *** presented phenomenon can be also generalized to other wave systems such as matter wave,water wave,and acoustic wave.

关键词： interaction Poincaré wave

3-D Tunnel Seismic Advance Prediction Method with Wide Illumination and High-Precision

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Journal of Earth Science 2024年第3期35卷 970-979页

作者： Peng Guan Cuifa Shao Yuyong Jiao guohua Zhang Junpeng Zou Fei Tan Faculty of Engineering China University of GeosciencesWuhan 430074China

Tunnel seismic advance prediction can effectively reduce the construction risk during tunnel *** with the 2-D method,the 3-D method is more conducive to describing the spatial characteristics of the geological body by adding the seismic data in the vertical ***,some drawbacks still need improvement in the current 3-D tunnel seismic prediction method.(1)The geometry is complex,which is destructiveness,high cost,and time-consuming,and will delay the tunnel construction schedule.(2)Illumination of the anomalous body is insufficient,and the precision of migration imaging is low.(3)Shot points are far away from the tunnel face,the energy loss at the shot points is more serious.(4)The received signals at the tunnel wall have the surface wave with strong energy when the shot points are placed on the tunnel wall.(5)The geometry is not linear,so the directional filtering method cannot be used to extract the reflection *** overcome the drawbacks of the current prediction method,a new 3-D symmetrical tunnel seismic prediction method is *** geophones are installed on the tunnel wall,two on the left side,two on the right side,and two on the top ***-four shot points are placed on the tunnel face and near both sides of the tunnel wall,twelve shot points on the left side and twelve shot points on the right *** shot points will move along with the forward excavation of the *** wavefield analysis,illumination statistics,and 3-D reverse time migration imaging are used to evaluate the proposed *** result of modeled data indicates that the proposed 3-D geometry has some advantages:(1)the geometry is simple and the geophone installation time is short;(2)it has high illumination energy,wide illumination range,and can improve the prediction distance and imaging accuracy;(3)the proposed 3-D method can better estimate the velocity of surrounding rock and is more conducive to extracting the reflection wave with high resolut

关键词： tunnels excavation geophone shot points migration imaging method engineering ge-ology.

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磁铰链约束下的微纳聚合体卫星柔顺变构控制

哈尔滨工业大学学报 2020年第12期52卷 66-73页

作者：康国华刘奇弦吴佳奇王强南京航空航天大学航天学院南京210016

为使磁铰链约束下的微纳聚合体卫星克服磁铰链阻力矩的阻碍作用成功实现变构,并防止变构过程中磁铰链的脱附,减小模块再拼接时的碰撞冲击,设计了一种用于微纳聚合体卫星的柔顺变构控制方法.首先利用第2类拉格朗日方程建立了磁铰链约束... 详细信息

为使磁铰链约束下的微纳聚合体卫星克服磁铰链阻力矩的阻碍作用成功实现变构,并防止变构过程中磁铰链的脱附,减小模块再拼接时的碰撞冲击,设计了一种用于微纳聚合体卫星的柔顺变构控制方法.首先利用第2类拉格朗日方程建立了磁铰链约束下的多刚体系统的动力学模型,设计了微纳聚合体卫星变构的模糊控制律;然后根据柔顺控制的要求设计了一种量化因子K e与K c的模糊调节器,引入到原模糊控制器中以改进控制方法.此控制方法具有不依赖系统动力学模型、仅需对参与变构的模块施加控制的优点.为量化评估变构过程的柔顺程度,设计了两个柔顺程度评估参数;最后通过仿真与气浮台物理试验对控制方法进行了验证,对比了固定量化因子与量化因子在线调节两种控制方法下变构过程的柔顺程度.数学仿真与气浮台的物理试验结果表明,改进后的模糊控制相比于固定量化因子的模糊控制,可使变构过程中模块相对运动角速度变化更加平缓,模块再拼接时相对角速度更小,达到了柔顺变构的目标.

关键词：磁铰链微纳聚合体卫星构型重构柔顺控制模糊控制

Twisted Integration of Complex Oxide Magnetoelectric Heterostructures via Water‑Etching and Transfer Process

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Nano-Micro Letters 2024年第1期16卷 360-369页

作者： Guannan Yang guohua Dong Butong Zhang Xu Xu Yanan Zhao Zhongqiang Hu Ming Liu State Key Laboratory for Manufacturing Systems Engineering Electronic Materials Research LaboratoryKey Laboratory of the Ministry of EducationEngineering Research Center of Spin Quantum Sensor ChipsUniversities of Shaanxi ProvinceSchool of Electronic Science and EngineeringXi’an Jiaotong UniversityXi’an 710049People’s Republic of China

Manipulating strain mode and degree that can be applied to epitaxial complex oxide thin films have been a cornerstone of strain *** recent years,lift-off and transfer technology of the epitaxial oxide thin films have been developed that enabled the integration of heterostructures without the limitation of material types and crystal ***,twisted integration would provide a more interesting strategy in artificial magnetoelectric heterostructures.A specific twist angle between the ferroelectric and ferromagnetic oxide layers corresponds to the distinct strain regulation modes in the magnetoelectric coupling process,which could provide some insight in to the physical *** this work,the La_(0.67)Sr_(0.33)MnO_(3)(001)/0.7Pb(Mg_(1/3)Nb_(2/3))O_(3)-0.3PbTiO_(3)(011)(LSMO/PMN-PT)heterostructures with *** *** angles were assembled via water-etching and transfer *** transferred LSMO films exhibit a fourfold magnetic anisotropy with easy axis along LSMO.A coexistence of uniaxial and fourfold magnetic anisotropy with LSMO[110]easy axis is observed for the 45°Sample by applying a 7.2 kV cm^(−1)electrical field,significantly different from a uniaxial anisotropy with LSMO[100]easy axis for the 0°*** fitting of the ferromagnetic resonance field reveals that the strain coupling generated by the 45°twist angle causes different lattice distortion of LSMO,thereby enhancing both the fourfold and uniaxial *** work confirms the twisting degrees of freedom for magnetoelectric coupling and opens opportunities for fabricating artificial magnetoelectric heterostructures.

关键词： Magnetoelectric heterostructures Twist angle Epitaxial lift-off Magnetic anisotropy Ferromagnetic resonance

Delayed Fluorescence and Amplified Chirality via Modified Substitution Position for Deep-red Circularly Polarized Organic Light Emitting-diodes

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Chemical Research in Chinese Universities 2024年第4期40卷 657-663页

作者： ZHU Lixun LIU Dan WU Kaiwen XIE guohua ZHAO Zheng TANG Ben Zhong School of Science and Engineering Shenzhen Institute of Aggregate Science and TechnologyThe Chinese University of Hong KongShenzhen(CUHK-Shenzhen)Shenzhen518172P.R.China Department of Chemistry Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and ReconstructionThe Hong Kong University of Science and TechnologyHongkong999077P.R.China The Institute of Flexible Electronics(Future Technologies) Xiamen UniversityXiamen361005P.R.China

Developing easily accessible deep-red/near-infrared circularly polarized emitters for practical organic light-emitting diodes remains a significant ***,a practical strategy has been proposed for developing deep-red circularly polarized delayed fluorescent emitters based on a novel chiral acceptor *** changing triphenylamine(TPA)substitution position from para to meta,R/S-M-TBBTCN demonstrated thermally activated delayed fluorescence(TADF)properties with a delayed lifetime of 6.6µs that R/S-P-TBBTCN doesn’t ***,R/S-M-TBBTCN showed a 65 nm red-shift in emission and a 10-fold enhancement in asymmetry factor(glum),compared with R/*** solution-processed nondoped circularly polarized organic light-emitting diodes(CP-OLEDs)based on R-M-TBBTCN display deep-red emission and 2.2%external quantum efficiency.

关键词： Amplified chirality Deep-red circularly polarized organic light emitting-diode Binaphthol based chiral acceptor

Hierarchical Disturbance Propagation Mechanism and Improved Contract Net Protocol for Satellite TT&C Resource Dynamic Scheduling

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Complex System Modeling and Simulation 2024年第2期4卷 166-183页

作者： Zhiqing Xiang Yi Gu Xinwei Wang guohua Wu the School of Traffic and Transportation Engineering Central South UniversityChangsha 410075China the School of Engineering and Materials Science Queen Mary University of LondonLondonE14NSUK the School of Automation Central South UniversityChangsha 410083China

The practical engineering of satellite tracking telemetry and command(TT&C)is often disturbed by unpredictable external factors,including the temporary rise in a significant quantity of satellite TT&C tasks,temporary failures and failures of some TT&C resources,and so *** improve the adaptability and robustness of satellite TT&C systems when faced with uncertain dynamic disturbances,a hierarchical disturbance propagation mechanism and an improved contract network dynamic scheduling method for satellite TT&C resources were designed to address the dynamic scheduling problem of satellite TT&C ***,the characteristics of the dynamic scheduling problem of satellite TT&C resources are analyzed,and a mathematical model is established with the weighted optimization objectives of maximizing the revenue from task completion and minimizing the degree of plan ***,a bottom-up distributed dynamic collaborative scheduling framework for satellite TT&C resources is proposed,which includes a task layer,a resource layer,a central internal collaboration layer,and a central external collaboration *** disturbances are propagated layer by layer from the task layer to the central external collaboration layer in a bottom-up manner,using efficient heuristic strategies in the task layer and the resource layer,*** use improved contract network algorithms in the center internal collaboration layer and the center external collaboration layer,the original scheduling plan is quickly adjusted to minimize the impact of disturbances while effectively completing dynamic task ***,a large number of simulation experiments were carried out and compared with various comparative *** results show that the proposed algorithm can effectively improve the solution effect of satellite TT&C resource dynamic scheduling problems,and has good application prospects.

关键词： satellite tracking telemetry and command(TT&C) dynamic resource scheduling bottom-up mechanism heuristic strategy contract net protocol algorithm

基于Gauss-Newton和UKF结合的微小卫星姿态确定算法

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中国空间科学技术 2018年第2期38卷 16-23页

作者：康国华范凯周琼峰梁尔涛南京航空航天大学微小卫星研究中心南京210016 上海卫星工程研究所上海201109

为提高微型低成本姿态敏感器的姿态确定精度,文章基于磁强计/太阳敏感器/陀螺的姿态敏感器配置,设计了高斯牛顿(Gauss-Newton,GN)迭代算法和无迹卡尔曼滤波(Unscented Kalman Filter,UKF)有机结合的微小卫星姿态确定算法,先用Gauss-New... 详细信息

为提高微型低成本姿态敏感器的姿态确定精度,文章基于磁强计/太阳敏感器/陀螺的姿态敏感器配置,设计了高斯牛顿(Gauss-Newton,GN)迭代算法和无迹卡尔曼滤波(Unscented Kalman Filter,UKF)有机结合的微小卫星姿态确定算法,先用Gauss-Newton算法融合磁强计和太阳敏感器的数据,迭代计算最优四元数,然后以最优四元数联合陀螺数据作为观测量,以姿态四元数和惯性系下的角速度为状态量进行UKF,降低观测维数,并将观测方程转化为线性方程,显著减小计算量,同时克服了测量误差对姿态确定精度的影响。

关键词：微小卫星姿态确定高斯牛顿迭代算法无迹卡尔曼滤波

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MEMS陀螺旋转导航误差的分析与仿真

中国空间科学技术 2016年第4期36卷 74-80页

作者：周琼峰康国华陈雪芬南京航空航天大学航天学院南京210016 南京航空航天大学自动化学院南京210016

目前基于高精度陀螺导航的旋转调制技术研究及应用已相当成熟,为实现低成本、低精度微机电系统(Microelectromechanical Systems,MEMS)陀螺的高精度应用,文章引入旋转调制技术。对旋转调制前后导航误差进行了理论分析和仿真,对比了相同... 详细信息

目前基于高精度陀螺导航的旋转调制技术研究及应用已相当成熟,为实现低成本、低精度微机电系统(Microelectromechanical Systems,MEMS)陀螺的高精度应用,文章引入旋转调制技术。对旋转调制前后导航误差进行了理论分析和仿真,对比了相同条件下对不同精度陀螺的调制效果,分析了影响陀螺误差调制的因素。仿真结果表明,相同条件下低精度MEMS陀螺的旋转调制效果比高精度陀螺更加明显,在100s内导航误差降低了30%以上。另外,对旋转导航误差的分析表明,研制高精度旋转调制转台是提高MEMS陀螺旋转调制精度的关键技术。

关键词：旋转调制 MEMS陀螺调制转台导航误差调制速率误差

Investigating the Impact of Ocean Acidification on Anti-Stress Mechanisms in Sepia esculenta Larvae Based on Transcriptome Profiling

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Journal of Ocean University of China 2024年第4期23卷 1054-1066页

作者： WANG Yongjie LIU Xiumei LV Tingjin WANG Weijun SUN guohua YANG Jianmin LI Zan School of Agriculture Ludong UniversityYantai 264025China College of Life Sciences Yantai UniversityYantai 264005China Yantai Institute of Marine Economy Yantai 264003China

With the rapid development of oil,energy,power and other industries,CO_(2) emissions rise sharply,which will cause a large amount of CO_(2) in the air be absorbed by the ocean and lead to ocean *** growth and development of organisms can be seriously affected by acidified *** esculenta is a mollusk with high nutritional and economic value and is widely cultured in offshore waters of *** are the early life forms of the organism and are more vulnerable to changes in the external *** low pH will lead to some adverse reactions in larvae,which will affect metabolism,immune response and other life *** this study,we sequenced the transcriptome of *** subjected to acidified seawater stress and identified 1072differentially expressed genes(DEGs).The detected atypical expression of DEGs substantiates cellular malformation and translocation in *** under low pH ***,this also substantiates the notable impact of ocean acidification on *** DEGs were used for functional enrichment analysis of GO and KEGG,and the top twenty items of the biological process classification in GO terms and 11 KEGG signaling pathways were significantly ***,the constructed proteinprotein interaction network(PPI)was used to analyze protein-protein interactions,and 12 key DEGs and 3 hub genes were *** reliability of 12 genes was verified by quantitative RT-PCR.A comprehensive analysis of the KEGG signaling pathway and PPI revealed that ocean acidification leads to abnormalities in lipid metabolism in *** larvae,which can lead to cancer development and metastasis,accompanied by some degree of *** results of the study will help to further investigate the physiological processes of *** when stimulated by ocean acidification,and provide a reference to cope with the captive breeding of *** affected by acidification.

关键词： Sepia esculenta ocean acidification protein-protein interaction network transcriptome immunity