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Low-temperature synthesis of apatite-type La_(9.33)Ge_6O_(26) as electrolytes with high conductivity

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Chinese Physics B 2018年第4期27卷 520-525页

作者： Guang-chao Yin Guo-Dong Zhao Hong Yin fu-chao jia Qiang Jing Sheng-Gui fu Mei-Ling Sun Wei Gao Laboratory of functional Molecular Materials School of Physics and Optoelectronic Engineering Shandong University of Technology Zibo 255000 China State Key Laboratory of Superhard Materials Jilin University Changchun 130012 China

In the present study,high-quality apatite-type La9.33Ge6O26 powders are successfully synthesized by a facile moltensalt synthesis method（MSSM） at low temperatures,using Li Cl,Li Cl/Na Cl mixture（mass ratio 1：1） as molten salt,*** results indicate that the optimal mass ratio between reactant and molten salt is 1：2,and Li Cl/Na Cl mixed molten-salt is more beneficial for forming high-quality La9.33Ge6O26 powders than Li Cl individual *** with the conventional solid-state reaction method（SSRM）,the synthesis temperature of apatitetype La9.33Ge6O26 powders using the MSSM decreases more than 350℃,which can effectively avoid Ge loss in the preparation process of precursor ***,the powders obtained by the MSSM are homogeneous,nonagglomerated and well crystallized,which are very favorable for gaining dense pellets in the premise of avoiding Ge *** the basis of high-quality precursor powders,the dense and pure ceramic pellets of La（9.33）Ge6O（26） are gained at a low temperature of 1100℃ for 2 h,which exhibit higher conductivities（σ850℃（Li Cl）= 2.3 × 10^-2 S·cm^-1,σ850 ℃（Li Cl/Na Cl） = 4.9 × 10^-2 S·cm^-1） and lower activation energies（Ea（Li Cl）= 1.02 e V,Ea（Li Cl/Na Cl）= 0.99 e V） than that synthesized by the SSRM.

关键词： solid oxide fuel cells electrolyte ionic conduction

In-situ fabrication of ZnO nanoparticles sensors based on gas-sensing electrode for ppb-level H_(2)S detection at room temperature

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Chinese Physics B 2021年第2期30卷 250-256页

作者： Jing-Yue Xuan Guo-Dong Zhao Xiao-Bo Shi Wei Geng Heng-Zheng Li Mei-Ling Sun fu-chao jia Shu-Gang Tan Guang-chao Yin Bo Liu Laboratory of functional Molecular and Materials School of Physics and Optoelectronic EngineeringShandong University of TechnologyZibo 255000China Institute of Artificial Intelligence Henan Finance UniversityZhengzhou 450046China

The zinc oxide(ZnO)nanoparticles(NPs)sensors were prepared in-situ on the gas-sensing electrodes by a one-step simple sol-gel method for the detection of hydrogen sulfide(H_(2)S)*** sphere-like ZnO NPs were characterized by scanning electron microscopy(SEM),transmission electron microscopy(TEM),x-ray diffraction(XRD),energy dispersive x-ray analysis(EDX),and their H_(2)S sensing performance were measured at room *** results indicate that the ZnO NPs exhibit excellent response to H_(2)S gas at room *** response value of the optimal sample to750 ppb H_(2)S is 73.3%,the detection limit reaches to 30 ppb,and the response value is 7.5%.furthermore,the effects of the calcining time and thickness of the film on the gas-sensing performance were *** calcining time and film thickness show a negative correlation with the H_(2)S sensing *** corresponding reaction mechanism of H_(2)S detection was also discussed.

关键词： ZnO H_(2)S gas sensor room temperature

Surfing the nano-wave:Emerging trends in cancer diagnostics and therapy

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Nano Research 2025年第1期18卷 520-544页

作者： Genping fu Yuting Weng Yunfan Li Carl Ho Yiyu fu Wenxuan Wang Songbin fu Wenjing Sun Jie Lin Xiaoyu Fan Binbin jia Mengdi Cai Linlin Li Laboratory of Medical Genetics Harbin Medical UniversityHarbin 150081China Key Laboratory of Preservation of Human Genetics Resources and Disease Control in China(Harbin Medical University) Ministry of EducationHarbin 150081China Beijing Key Laboratory for Optical Materials and Photonic Devices Department of ChemistryCapital Normal UniversityBeijing 100048China College of Materials and Chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion MaterialsChina Three Gorges UniversityYichang 443002China Washington University School of Medicine in St.Louis St.LouisMO 63110USA Ningbo Institute of Materials Technology and Engineering Chinese Academy of SciencesNingbo 315201China Aix-Marseille College Wuhan University of TechnologyWuhan 430070China

Facing the growing global challenge posed by cancer,the quest for more accurate and potent cancer diagnostic and therapeutic strategies continues to require a multidisciplinary integration *** review firstly summarizes various types of nanoparticles in cancer ***,it offers a comprehensive overview of signalenhancing techniques for visualizing in situ tumors,along with multimodal diagnostic methods for detecting *** for tumor therapy,cutting-edge drug delivery methods that can cross biological barriers and the pinpoint targeting of tumor lesions for precise medical intervention are *** the domain of therapeutic diagnostics,we elucidate the theoretical underpinnings and structural paradigms that underlie a spectrum of advanced diagnostic and therapeutic ***,we present a compendium of publications delineating the clinical applications of each nano-based theragnostic integration ***,this comprehensive review discusses the safety concerns pertaining to the clinical application of nanoparticles and proposes some strategic recommendations to enhance the precision and safety of theragnostic-guided,nanotechnology-based clinical practices.A deeper understanding of nanomaterials,together with intimate interdisciplinary collaborations,nano-wave will most probably guide human beings to win the battle against cancers.

关键词： nanoparticles drug delivery gastric cancer glioma glioblastoma

Understanding the local structure and thermophysical behavior of Mg-La liquid alloys via machine learning potential

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 439-449页

作者： jia Zhao Taixi Feng Guimin Lu National Engineering Research Center for Integrated Utilization of Salt Lake Resource East China University of Science and TechnologyShanghai 200237China Joint International Laboratory for Potassium and Lithium Strategic Resources East China University of Science and TechnologyShanghai 200237China

The local structure and thermophysical behavior of Mg-La liquid alloys were in-depth understood using deep potential molecular dynamic(DPMD) simulation driven via machine learning to promote the development of Mg-La alloys. The robustness of the trained deep potential(DP) model was thoroughly evaluated through several aspects, including root-mean-square errors(RMSEs), energy and force data, and structural information comparison results;the results indicate the carefully trained DP model is reliable. The component and temperature dependence of the local structure in the Mg-La liquid alloy was analyzed. The effect of Mg content in the system on the first coordination shell of the atomic pairs is the same as that of temperature. The pre-peak demonstrated in the structure factor indicates the presence of a medium-range ordered structure in the Mg-La liquid alloy, which is particularly pronounced in the 80at% Mg system and disappears at elevated temperatures. The density, self-diffusion coefficient, and shear viscosity for the Mg-La liquid alloy were predicted via DPMD simulation, the evolution patterns with Mg content and temperature were subsequently discussed, and a database was established accordingly. Finally, the mixing enthalpy and elemental activity of the Mg-La liquid alloy at 1200 K were reliably evaluated,which provides new guidance for related studies.

关键词： magnesium-lanthanum liquid alloys local structure macroscopic properties thermodynamic behavior deep potential mo-lecular dynamic simulation

Continuous high-temperature rapid nanomanufacturing of electrocatalysts

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Nano Research 2025年第1期18卷 225-235页

作者： Xiaoyang Wang Ziyi Luo Baihua Cui Ziqi fu Yanchang Liu Weidi Liu jia Ding jianrong Zeng Yanan ChenWenbin Hu School of Materials Science and Engineering Tianjin UniversityTianjin 300350China Australian Institute for Bioengineering and Nanotechnology The University of QueenslandSt.LuciaBrisbane 4072Australia Shanghai Synchrotron Radiation Facility Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201204China Shanghai Institute of Applied Physics Chinese Academy of SciencesShanghai 201800China

Encapsulating metal nanoparticles in carbon shells(Metal@C)to enhance catalytic activity and stability has been certified ***,most existing methods for preparing Metal@C are complex,time-consuming,and lack of *** this study,a novel method that couples the high-temperature shock(HTS)with ultrasonic spray pyrolysis is reported,which can realize facile and scalable production of various Metal@C through the pyrolysis of glucose and metal chloride *** proposed HTS ultrasonic spray pyrolysis offers several advantages,including compact size,short reaction time(~120 ms),and uniform *** the Ni@C-40 nanocomposite as an example,the ultrasmall Ni nanoparticles(~10 nm)with thin carbon protective shells(~2 nm)are uniformly dispersed in the carbon matrix and applied for oxygen evolution reaction(OER)in alkaline *** Ni@C-40 optimized by tuning the thickness of carbon shell exhibits significantly enhanced OER activity with low overpotential of 242 mV at 10 mA·cm^(-2) and stability,which is attributed to the optimized interactions between Ni nanoparticles and carbon *** method also shows promise for continuous pyrolysis synthesis of various extreme materials at ultra-high temperatures using alternative electric heating materials.

关键词： ultrasonic spray pyrolysis high-temperature shock carbon shell oxygen evolution reaction Metal@C nanocomposite

Primary parenchymal squamous cell carcinoma of the kidney:A case report

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World Journal of Clinical Cases 2025年第4期13卷 34-40页

作者： Zhi-Hui Zheng Bo Shao chao-Min Xu Ke Wang jia-Zhu Wen Li-Kang Luo jia-Cheng Guan Department of Ultrasound The Second People’s Hospital of QuzhouQuzhou 324000Zhejiang ProvinceChina Department of Radiology Shulan(Quzhou)HospitalQuzhou 324000Zhejiang ProvinceChina Department of Radiology The Second People’s Hospital of QuzhouQuzhou 324000Zhejiang ProvinceChina Department of Pathology The Second people’s Hospital of QuzhouQuzhou 324000Zhejiang ProvinceChina

BACKGROUND Primary squamous cell carcinoma(SCC)of the renal parenchyma is extremely rare,with only nine cases *** SUMMARY This study reports a 51-year-old man with primary SCC of the renal *** patient was admitted with recurrent dull pain and discomfort in the right lumbar region,which had worsened over 2 weeks,accompanied by painful gross *** antigen(SCCA)levels were elevated,and imaging revealed a renal mass with associated *** patient underwent laparoscopic unilateral nephrectomy and lymph node *** pathology confirmed highly differentiated SCC with necrosis in the right renal parenchyma,with negative renal pelvis and *** pathological stage was *** months after surgery,the tumor recurred with involvement of the liver,right psoas major muscle,and inferior vena *** patient refused chemotherapy and succumbed to the disease 6 months postoperatively due to disease *** We report a case of primary SCC of the renal parenchyma,a rare renal *** clinical symptoms,laboratory tests,and imaging findings are nonspecific,making accurate and timely diagnosis *** to the literature,for patients with renal calculi accompanied by a renal mass,elevated serum SCCA levels,and magnetic resonance imaging showing cystic or cystic-solid masses within the kidney with pseudocapsules and heterogeneous mild enhancement,the possibility of this disease should be considered.

关键词： Renal tumor Renal parenchyma Squamous cell carcinoma Renal calculi Computed tomography Case report

Metabolic pathway modulation by olanzapine:Multitarget approach for treating violent aggression in patients with schizophrenia

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World Journal of Psychiatry 2025年第1期15卷 37-53页

作者： Yan-Ning Song Shuang Xia Zhi Sun Yong-chao Chen Lu jiao Wen-Hua Wan Hong-Wei Zhang Xiao Guo Hua Guo Shou-Feng jia Xiao-Xin Li Shi-Xian Cao Li-Bin fu Meng-Meng Liu Tian Zhou Lv-Feng Zhang Qing-Quan jia Department of Pharmacy The Affiliated Encephalopathy Hospital of Zhengzhou University(Zhumadian Second People's Hospital)Zhumadian 463000Henan ProvinceChina Department of Pharmacy The First Affiliated Hospital of Zhengzhou UniversityZhengzhou 450052Henan ProvinceChina Department of Pharmacy Zhumadian First People's HospitalZhumadian 463000Henan ProvinceChina Scientific Education Section The Affiliated Encephalopathy Hospital of Zhengzhou University(Zhumadian Second People's Hospital)Zhumadian 463000Henan ProvinceChina Department of Psychiatry The Affiliated Encephalopathy Hospital of Zhengzhou University(Zhumadian Second People's Hospital)Zhumadian 463000Henan ProvinceChina Clinical Laboratory The Affiliated Encephalopathy Hospital of Zhengzhou University(Zhumadian Second People's Hospital)Zhumadian 463000Henan ProvinceChina Publicity Division The Affiliated Encephalopathy Hospital of Zhengzhou University(Zhumadian Second People's Hospital)Zhumadian 463000Henan ProvinceChina

BACKGROUND The use of network pharmacology and blood metabolomics to study the patho-genesis of violent aggression in patients with schizophrenia and the related drug mechanisms of action provides new directions for reducing the risk of violent aggression and optimizing treatment *** To explore the metabolic regulatory mechanism of olanzapine in treating patients with schizophrenia with a moderate to high risk of violent *** Metabolomic technology was used to screen differentially abundant metabolites in patients with schizophrenia with a moderate to high risk of violent aggression before and after olanzapine treatment,and the related metabolic pathways were *** pharmacology was used to establish protein-protein interaction networks of the core targets of *** Ontology functional analysis and Kyoto Encyclopedia of Genes and Genomes pathway enrichment analysis were subsequently *** Compared with the healthy group,the patients with schizophrenia group presented significant changes in the levels of 24 metabolites related to the disruption of 9 metabolic pathways,among which the key pathways were the alanine,aspartate and glutamate metabolism and arginine biosynthesis *** treatment with olanzapine,the levels of 10 differentially abundant metabolites were significantly reversed in patients with *** effectively regulated six metabolic pathways,among which the key pathways were alanine,aspartate and glutamate metabolism and arginine biosynthesis *** core targets of olanzapine were involved in several key *** The metabolic pathways of alanine,aspartate,and glutamate metabolism and arginine biosynthesis are the key pathways involved in olanzapine treatment for aggressive schizophrenia.

关键词： Schizophrenia Violent aggression Olanzapine Metabolomics Network pharmacology

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基于加权最小二乘法的RAIM算法研究

电光与控制 2017年第11期24卷 7-10页

作者：王尔申杨福霞贾超颖曲萍萍庞涛沈阳航空航天大学电子信息工程学院沈阳110136 沈阳航空航天大学辽宁省通用航空重点实验室沈阳110136

针对最小二乘法在卫星故障检测和识别中存在的问题,研究将加权最小二乘算法用于卫星故障检测和识别,该算法将测量方程的协方差矩阵对角线元素作为加权因子,进而得到基于加权最小二乘法的卫星故障检测算法。通过各颗卫星伪距残差的平方... 详细信息

针对最小二乘法在卫星故障检测和识别中存在的问题,研究将加权最小二乘算法用于卫星故障检测和识别,该算法将测量方程的协方差矩阵对角线元素作为加权因子,进而得到基于加权最小二乘法的卫星故障检测算法。通过各颗卫星伪距残差的平方和建立检验统计量,根据故障检测误警率和概率密度函数得到检测门限,将计算得到的伪距残差平方和与检测门限进行比较,进而实现故障的检测和隔离。结合实测数据,验证对比了两种算法的性能,结果表明:加权最小二乘RAIM算法在故障检测的灵敏度和故障识别性能方面优于最小二乘RAIM算法的性能。

关键词：北斗卫星导航系统 RAIM 最小二乘算法加权最小二乘算法

16.48% Efficient solution-processed CIGS solar cells with crystal growth and defects engineering enabled by Ag doping strategy

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Journal of Energy Chemistry 2025年第1期100卷 59-65页

作者： Mengyu Xu Shaocong Yan Ting Liang jia jia Shengjie Yuan Dongxing Kou Zhengji Zhou Wenhui Zhou Yafang Qi Yuena Meng Litao Han Sixin Wu Key Laboratory for Special functional Materials of MOE National & Local Joint Engineering Research Centre for High-efficiency Display and Lighting Technology School of Nanoscience and Materials Engineering Henan University

Solution-processed Cu（In,Ga）Se2（CIGS） solar cells suffer from serious carrier recombination and power conversion efficiency（PCE） loss because of the poor film properties and easy formation of ***, we propose Ag&Se co-selenization strategy to enhance the crystallization and passivate harmful defects of the CIGS films. The formation of Ag-Se phase during the selenization process enables the formation of large grains and suppresses the deep level defects. It is found that Ag doping can enlarge the depletion region width, lower the Urbach energy and prolong the carrier lifetime. As a result, a champion solution-processed CIGS solar cell presents a high efficiency of 16.48% with the highly improved opencircuit voltage（VOC） of 662 m V and fill factor（FF） of 75.8%. This work provides an efficient strategy to prepare high quality solution-processed CIGS films for high-performance CIGS solar cells.

关键词： CIGS solar cells Solution-processed method Ag doping Crystal growth Defects engineering