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Physical Properties of Liquid Terbium Measured by Levitation Techniques

Journal of Rare Earths 2007年第6期25卷 665-669页

作者： Paul-francois Paradis Takehiko Ishikawa Noriyuki Koike Yuki Watanabe Japan Aerospace Exploration Agency Institute of Space and Astronautical Science ISS Science Project Office 2-1-1 Sengen Tsukuba Ibaraki 305-8505 Japan Chiba Institute of Technology Tsudanuma Narashino Chiba Japan Advanced Engineering Service Co. Ltd. Tsukuba Ibaraki 305-0032 Japan

To understand the nature and behavior of rare earth metals in their liquid phases, accurate values of their physical properties are essential. However, to measure their physical properties, the samples should be maintained in liquid phases for prolonged time, and this raises a formidable challenge. This is mainly explained by their high melting temperatures （e.g., 1629 K for Tb）, high vapor pressure, and the risk of melt contamination with a crucible or support. An electrostatic levitation furnace alleviated these difficulties and allowed the determination of density, surface tension, and viscosity of several metals above their melting temperature. Here, first, the levitation furnace facility and the noncontact diagnostic procedures were briefly discussed, followed by the explanation of their thermophysical property measurements over wide temperature ranges. The density was obtained using an ultraviolet-based imaging technique that allowed excellent illumination, even at elevated temperatures. Over the 1615 to 1880 K temperature span, the density measurements could be expressed as p（T） =7.84 × 10^3 -0.47 （T - Tm）（kg · m^-3） with Tm = 1629 K, yielding a volume expansion coefficient a（T） = 6.0 × 10^-5 （K^-1）. In addition, the surface tension and the viscosity could be determined by inducing a drop oscillation to a molten sample. Using this technique, the surface tension data could be expressed as σ（T） = 8.93 × 10^2 - 0.10 （T - Tm）（mN· m^-1） and those for viscosity as η（T） =0.583 exp [4.1 × 10^4/（RT）] （MPa·s） over the 1690 to 1980 K temperature range

关键词： levitation liquid noncontact terbium rare earths

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X-ray microscopic investigation of molecular orientation in a hole carrier thin film for organic solar cells

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Nano Research 2018年第5期11卷 2771-2782页

作者： Quentin Arnoux Benjamin Watts Sufal Swaraj francois Rochet Ludovic Tortech Laboratoire de Chimie Physique Matiere et Rayonnement (LCPMR) UMR 7614 Sorbonne Universites UPMC Univ Paris 06 Paris F-75005 France Institut Parisien de Chimie Moleculaire (IPCM) UMR 8232 Sorbonne Universites UPMC Univ Paris 06 Paris F-75005 France Laboratoire d'Innovation en Chimie des Surfaces et Nanosciences (LICSEN) NIMBE UMR 3685 CEA Saday Gif-sur-Yvette F-91191 France Paul Scherrer Institute Villigen Psi 5232 Switzerland Synchrotron SOLEIL L'Orme des Merisiers Saint-Aubin BP 48 Gif-sur-Yvette F-91192 France

As dipyranylidenes are excellent hole carriers, applications in organic solar cells or organic light emitting diode are envisaged. In the present study, we investigate the morphology of 2,2＇,6,6＇-tetraphenyl-4,4＇-dipyranylidene （DIPO-Ph4） deposited under vacuum on a silicon nitride （Si3N4） substrate, a paradigmatic system for the study of molecular crystal/inorganic substrate interfaces. Samples with various coating ratios and different thermal treatments were prepared. The films were characterized by atomic force microscopy and scanning transmission X-ray microscopy to gain insight into material growth. The results show a change in orientation at a molecular level depending upon the evaporation conditions. We are now able to tailor an organic layer with a specific molecular orientation and a specific electronic behavior.

关键词： organic solar cells scanning transmission X-ray microscopy molecular orientation inorganic/organic interface

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Timescales of interface-coupled dissolution-precipitation reactions oncarbonates

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Geoscience Frontiers 2019年第1期10卷 17-27页

作者： francois Renard Anja Royne Christine V.Putnis The Njord Centre Physics of Geological Processes Departments of Geoscience and Physics University of Oslo Univ. Grenoble Alpes Univ. Savoie Mont Blanc CNRS Institut für Mineralogie University of Münster The Institute for Geoscience Research (TIGeR) Department of Chemistry Curtin University

In the Earth's upper crust, where aqueous fluids can circulate freely, most mineral transformations are controlled by the coupling between the dissolution of a mineral that releases chemical species into the fluid and precipitation of new minerals that contain some of the released species in their crystal structure, the coupled process being driven by a reduction of the total free-energy of the system. Such coupled dissolution-precipitation processes occur at the fluid-mineral interface where the chemical gradients are highest and heterogeneous nucleation can be promoted, therefore controlling the growth kinetics of the new minerals. Time-lapse nanoscale imaging using Atomic Force Microscopy(AFM) can monitor the whole coupled process under in situ conditions and allow identifying the time scales involved and the controlling parameters. We have performed a series of experiments on carbonate minerals(calcite, siderite, dolomite and magnesite) where dissolution of the carbonate and precipitation of a new mineral was imaged and followed through time. In the presence of various species in the reacting fluid(e. g. antimony, selenium, arsenic, phosphate), the calcium released during calcite dissolution binds with these species to form new minerals that sequester these hazardous species in the form of a stable solid phase. For siderite, the coupling involves the release of Fe^(2+) ions that subsequently become oxidized and then precipitate in the form of FeIIIoxyhydroxides. For dolomite and magnesite,dissolution in the presence of pure water(undersaturated with any possible phase) results in the immediate precipitation of hydrated Mg-carbonate phases. In all these systems, dissolution and precipitation are coupled and occur directly in a boundary layer at the carbonate surface. Scaling arguments demonstrate that the thickness of this boundary layer is controlled by the rate of carbonate dissolution,the equilibrium concentration of the precipitates and the kinetics of diffus

关键词： Carbonates Atomic force microscopy Dissolution Precipitation Boundary layer Replacement

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The potential value of intravascular ultrasound imaging in diagnosis of aortic intramural hematoma

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Journal of Geriatric Cardiology 2011年第4期8卷 224-229页

作者： Wei Hu francois Schiele Nicolas Meneveau Marie-France Seronde Pierre Legalery Jean-francois Bonneville Sidney Chocron Jean-Pierre Bassand Department of Cardiology Min Hang District Central HospitalShanghai 201100China Department of Cardiology University Hospital Jean MinjozBesançon 25000France Department of Radiology University Hospital Jean MinjozBesançon 25000France Department of Cardiac Surgery University Hospital Jean MinjozBesançon 25000France

Objective To evaluate the potential value of intravascular ultrasound(IVUS)imaging in the diagnosis of aortic intramural hematoma(AIH).Methods From September 2002 to May 2005,a consecutive series of 15 patients with suspected aortic dissection(AD)underwent both IVUS imaging and spiral computed tomography(CT).Six patients diagnosed as acute type B AIH by CT or IVUS composed the present study *** The study group consisted of five males and one female with mean age of 66 years *** of them had chest or back *** one patient,CT omitted a localized AIH and an associated penetrating atherosclerotic ulcer(PAU),which were detected by *** another patient,CT mistaken a partly thrombosed false lumen as an AIH,whereas IVUS detected a subtle intimal tear and slow moving blood in the false *** the four rest patients,both CT and IVUS made the diagnosis of AIH,however,IVUS detected three PAUs in three of them,only one of them was also detected by CT,and two of them escaped initial CT and were confirmed by follow up CT or magnetic resonance *** IVUS imaging is a safe examination and has high accuracy in the diagnosis of AIH,particularly for diagnosing localized AIH,distinguishing AIH with thrombosed classic AD and detecting accompanied small PAUs.

关键词： intravascular ultrasound diagnosis aortic intramural hematom

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Is it possible to save the environment and satisify consumers with artificial meat?

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Journal of Integrative Agriculture 2015年第2期14卷 206-207页

作者： Jean-francois Hocquette Herbivore Research Unit Member of JIA Editorial BoardNational Institute for Agricultural Research (INRA) Theix 63122 Saint-Genes Champanelle France

Our modern society is facing major challenges such as reducing world hunger by increasing protein resources despite an increase in protein demands due to the presence of more and more human beings on the earth. Other challenges include reducing potential environmental degradation due to human activities and also due to livestock. In addition to that, some people are concerned by reducing potential discomfort of animals on modern farms or maybe avoiding killing animals to eat them.

关键词： livestock concerned challenges avoiding maybe despite pleased acceptance discomfort technological

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Dedicated population genomics for the silent world： the specific questions of marine population genetics

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Current Zoology 2016年第6期62卷 545-550页

作者： Nicolas BIERNE francois BONHOMME Sophie ARNAUD-HAOND Universite de Montpellier Montpellier France UMR 5554 UM - CNRS - IRD - EPHE Station Marine OREME Sete France CNRS - Institut des Sciences de I'Evolution Montpellier UMR 5554 UM - CNRS - IRD - EPHE Station Marine OREME Sete France Ifremer - MARine Biodiversity Exploitation and Conservation UMR 9190 IRD - IFREMER - UM - CNRS Sete France

Introduction The life cycle of most marine species is characterized by high fecundity, dispersal during a planktonic larval phase and a sessile or sedentary adult phase with large census population size （Figure 1 ）.... 详细信息

关键词：种群遗传学基因组学海洋人群世界

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Inverse Design of Strained Graphene Surfaces for Electron Control

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Communications in Computational Physics 2023年第6期33卷 235-260页

作者： francois Fillion-Gourdeau Emmanuel Lorin Steve Maclean Institute for Quantum Computing University of WaterlooWaterlooOntarioCanadaN2L 3G1 School of Mathematics and Statistics Carleton UniversityOttawaCanadaK1S 5B6 Centre de Recherches Mathematiques Universite de MontrealMontrealCanadaH3T 1J4

This paper is devoted to the inverse design of strained graphene surfaces for the control of electrons in the semi-classical optical-like *** that charge carriers are described by the Dirac equation in curved-space and exploiting the fact that wave propagation can be described by ray-optics in this regime,a general computational strategy is proposed in order to find strain fields associated with a desired effective refractive index *** latter is first determined by solving semi-classical trajectories and by optimizing a chosen objective functional using a genetic ***,the graded refractive index corresponding to the strain field is obtained by using its connection to the metric component in isothermal *** coordinates are evaluated via numerical quasiconformal transformations by solving the Beltrami equation with a finite volume *** graphene surface deformation is finally optimized,also using a genetic algorithm,to reproduce the desired index of *** analytical results and numerical experiments are performed to illustrate the methodology.

关键词： Graphene isothermal coordinates Beltrami equation gravitational lens waveguide finite volume method genetic algorithm Dirac equation

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Code interoperability extends the scope of quantum simulations

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npj Computational Materials 2021年第1期7卷 302-311页

作者： Marco Govoni Jonathan Whitmer Juan de Pablo francois Gygi Giulia Galli Materials Science Division and Center for Molecular Engineering Argonne National LaboratoryLemontIL 60439USA Department of Chemical and Biomolecular Engineering University of Notre DameNotre DameIN 46556USA Pritzker School of Molecular Engineering University of ChicagoChicagoIL 60637USA Department of Computer Science University of CaliforniaDavisCA 95616USA Department of Chemistry University of ChicagoChicagoIL 60637USA

The functionality of many materials is critically dependent on the integration of dissimilar components and on the interfaces that arise between *** description of such heterogeneous components requires the development and deployment of first principles methods,coupled to appropriate dynamical descriptions of matter and advanced sampling techniques,in order to capture all the relevant length and time scales of importance to the materials’*** is thus essential to build simple,streamlined computational schemes for the prediction and design of multiple properties of broad classes of materials,by developing interoperable codes which can be efficiently coupled to each other to perform complex *** discuss the use of interoperable codes to simulate the structural and spectroscopic characterization of materials,including chemical reactions for catalysis,the description of defects for quantum information science,and heat and charge transport.

关键词： quantum catalysis spectroscopic

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A comparison of the water management systems in France and China

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Frontiers of Environmental Science & Engineering 2013年第5期7卷 721-734页

作者： Xiaoliu YANG Jian XU Jean-francois DONZIER Coralie NOEL College of Urban and Environmental Sciences Peking University Beijing 100871 China Asia-Pacific Centre for Water Security of Tsinghua University Beijing 100084 China International Office for Water and Permanent Technical Secretary of the International Network of Basin Organizations Paris 75008 France

This paper compares legal systems for water management in France and China, with a focus on integrated water resources management and regarding in particular the formulation of policies and their implemen- tation. The research shows that China has committed itself to the efficient management of water resources through the development of various policy tools during the current period. This commitment, however, has often been interrupted and distorted by politics, resulting in the neglect of socioeconomic and environmental priorities. France has developed a legislative framework and practical instruments to apply integrated water resources manage- ment at the river basin level since the 1960s. This experience and the current implementation of the European Water Framework Directive brings elements that can contribute to Chinese society meeting its water challenges.

关键词： legislation regulation water policy integrated river basin management protection of water quality,water permitting

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思想之路:从间距到前所未闻

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国际社会科学杂志（中文版） 2024年第2期41卷 15-45,5,9页

作者：弗朗索瓦·朱利安赵婉雪(译) 北京大学法语系

本文回顾了弗朗索瓦·朱利安教授由西方哲学转向中国语言思想的探索之路。经由中国,发问困境中解放出来,并发展出一系列具有内在连贯性及持续性的概念,重新审视了策略、伦理道德以及美学等领域。思想上的背井离乡开拓了诸多未思之地。

关键词：对话形式朱利安弗朗索瓦研究线索楷体字研究脉络宋体字提问

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