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Copper-based oxygen carriers supported with alumina/lime for the chemical looping conversion of gaseous fuels

Journal of Energy Chemistry 2017年第5期26卷 891-901页

作者： Syed K Haider María Erans felix donat Lunbo Duan Stuart A Scott Vasilije Manovic Edward J Anthony Combustion and CCS Centre Cranfield UniversityBedfordshire MK43 0ALUK Key Laboratory of Energy Thermal Conversion and Control Ministry of EducationSchool of Energy and EnvironmentSoutheast UniversityNanjing 210096JiangsuChina Department of Engineering University of CambridgeTrumpington StreetCambridgeUK

Copper（Ⅱ） oxide in varying ratios was combined with either an alumina-based cement（Al300）, or CaO derived from limestone as support material in a mechanical pelletiser. This production method was used to investigate its influence on possible mechanical and chemical improvements for oxygen carriers in chemical looping processes. These materials were tested in a lab-scale fluidised bed with CO or CH;as a reducing gas at 950 °C. As expected, the oxygen carriers containing a greater ratio of support material exhibited an enhanced crushing strength. Oxygen carriers comprised of a 1:3 ratio of support material to active CuO exhibited increased crushing strength by a minimum of 280% compared to pure CuO *** oxygen carriers exhibited a high CO conversion yield and were fully reducible from CuO to Cu. For the initial redox cycle, Al300-supported oxygen carriers showed the highest fuel and oxygen carrier conversion. The general trend observed was a decline in conversion with an increasing number of redox *** the case of CaO-supported oxygen carriers, all but one of the oxygen carriers suffered *** agglomeration was more severe in carriers with higher ratios of CuO. Oxygen carrier Cu25Al75（75 wt% aluminate cement and 25 wt% CuO）, which did not suffer from agglomeration, showed the highest attrition with a loss of approximately 8% of its initial mass over 25 redox cycles. The reducibility of the oxygen carriers was limited with CH;in comparison to CO. CH;conversion were 15%-25% and 50% for Cu25Ca75（25 wt% CuO and 75 wt% CaO） and Cu25Al75, respectively. Cu25Ca75 demonstrated improved conversion, whereas Cu25Al75 exhibited a trending decrease in conversion with increasing redox cycles.

关键词： Chemical-looping Oxygen carrier Copper Carbon capture

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Neuronal trafficking as a key to functional recovery in immune-mediated neuropathies

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Neural Regeneration Research 2024年第11期19卷 2331-2332页

作者： felix Kohle Michael Schroeter Department of Neurology University of Cologne and University Hospital CologneCologneGermany

Immune-mediated neuropathies are rare diseases of the peripheral nervous system(PNS),substantially affecting patients’functionality and quality of *** are amenable to immunomodulatory treatments,which in many cases stabilize disease progression,but long-term deficits persist in many *** long-term deficits are particularly observed in monophasic autoimmune neuropathies like Guillain-Barrésyndrome and also in chronic variants,e.g.,chronic inflammatory demyelinating neuropathy(Fadia et al.,2019).

关键词： diseases autoimmune

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The semiotics of humor in cultural trauma:a pilot study on digital methodology concerning the evolution and overcoming of trauma through humor on the example of Rick and Morty

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Language and Semiotic Studies 2024年第2期10卷 203-221页

作者： felix Poschinger Christopher Shannon University of Hamburg Hamburg20148Germany Independent TokyoJapan

This pilot study on humor in cultural trauma uses innovative digital methodologies in speech recognition and social media analysis via Postman and Python in the Twitter API v2 to propose different forms to gather and analyze empirical data on semiotics and humor to be used in a broader *** given example of humorous instances on the cultural trauma of 9/11 in the fictional sitcom Rick and Morty is limited but corroborated by a second example that is structurally different from the first:humor about 9/11 in stand-up comedy by Louis *** on the data,humor in trauma seems to undergo a 5-phase-typology related to the Kübler-Ross model of grief,which is mended by the(digital)participation of ***,we argue,both shapes the discourse on humor in trauma and overcomes the traumatic effects through humorous discourse.

关键词： cultural trauma humor theory Kübler-Ross model collective memory

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Cognitive dissonance and mindset perturbations during crisis:“ecosocio-psycho-somatic”perspectives

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World Journal of Psychiatry 2024年第2期14卷 215-224页

作者： felix Tretter Henriette Löffler-Stastka Department of Systems Medicine and Healthcare Systems Bertalanffy Center for the Study of Systems ScienceVienna 1040Austria Department of Psychoanalysis and Psychotherapy Medical University ViennaVienna 1090Austria

Mandatory and restrictive health regulations during the corona pandemic caused psychic disorders in many people,which even led to clinically relevant mental *** the same time,there was gradually a polarization of opinions among the *** order to improve future pandemic management,an integrative understanding of these psychosocial processes therefore seems *** we start theoretically with the mental effects of inconsistencies of the information environment by referring to concepts such as the theory of cognitive *** a next step,we use the psychodynamic theory to understand the affective-motivational defense mechanisms underlying these cognitive states and ***,a broader theoretical framework of psychoanalysis seems to make sense,because self-referential processing also influences the style of *** this reason,we use a more comprehensive psychological systems theoretical framework model to integrate these different *** integrative view refers in part to basic knowledge of health psychology regarding the resistance of unhealthy ways of thinking and behaviors and the possibilities for interventions for *** then extend this model to a broader picture that also covers the relationship between men and their *** results in the perspective of a multidimensional socioecological theoretical framework,which as a heuristic reference model and related to other ecological approaches could also be helpful for various theoretical questions for public health,and could provide a better public understanding of health *** line with this perspective,we hypothesize that with regard to the coronavirus disease 2019 pandemic,the acceptance of public health narratives could be increased if a more consistent picture of the scientific descriptions and explanations of the pandemic-similar to the model proposed-could be provided,which would enable the understanding of the origin,course and countermeasur

关键词： Infodemic Affective-cognitive dissonance Systems model of the mind Socioecological model

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Exploring the size of Andean condor foraging groups along an altitudinal and latitudinal gradient in the Tropical Andes: Ecological and conservation implications

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Current Zoology 2024年第2期70卷 225-232页

作者： Diego Mendez felix Hernan Vargas JoséHernan Sarasola Pedro P.Oleaa Departamento de Ecologia Universidad Autonoma de MadridCalle Darwin 228049MadridSpain Museo Nacional de Historia Natural Calle 26 s/nCota CotaLa PazBolivia The Peregrine Fund 5668 West Flying Hawk LaneBoiseID 83709USA Centro para el Estudio y Conservacion de Aves Rapaces en Argentina(CECARA) Universidad Nacional de La PampaAvda Uruguay 1516300 Santa RosaLa PampaArgentina Instituto de las Ciencias Ambientales y de la Tierra de La Pampa(INCITAP-CONICET) Avda.Uruguay 1516300 Santa RosaLa PampaArgentina Centro de Investigacion en Biodiversidad y Cambio Global(CIBC-UAM) Universidad Autonoma de MadridMadridCalle Darwin 228049Madrid Snain

Patterns of variation in the size of vulture foraging groups,and their ecological causes and consequences,remain litle explored despite strong links with the carrion recycling service that this key functional group *** documented the group size-frequency pattern of Andean con-dors Vultur gryphus gathered to feed on 42 equine carcasses experimentally placed in Bolivia,between 2012 and 2019,along an elevation range of 1,300-4,500 m *** on the location(altitude and latitude)of the foraging groups,we examined the relationship between their size and species'population parameters(size and trend),habitat conditions,and livestock carcass availability and *** utilized a high frequency(93%)of carcasses forming groups that ranged from 1 to 80 individuals(mean=25,median=18)and shaped a"lazy-J curve"typical pattern of size-frequency distribution whereby few groups(5,12%)were large(>55 individuals)and most(21,50%)were relatively small(<19 individuals).Group size related to altitude in that most larger groups formed at lower sites(below c.3,000 m asl),likely following an altitudinal gradient whereby larger groups are more likely to form around larger carcasses(i.e.,cattle),which are more likely to occur at lower *** of population size,group size could be an adaptive response of condors via local enhancement for improving individual scavenging *** information gaps on this topic still exist,thus we provide a set of questions to address them,especially amidst the unrestricted impacts of human activities that condition vulture survival globally.

关键词： condor andino fusion-fission dynamics group size scavenger social foraging vultures.

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A CFD Model to Evaluate Near-Surface Oil Spill from a Broken Loading Pipe in Shallow Coastal Waters

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Fluid Dynamics & Materials Processing 2024年第1期20卷 59-77页

作者： Portia felix Lee Leon Derek Gay Stefano Salon Hazi Azamathulla Department of Civil and Environmental Engineering The University of the West IndiesSt.AugustineTrinidad and Tobago National Institute of Oceanography and Experimental Geophysics-OGS TriesteItaly

Oil spills continue to generate various issues and concerns regarding their effect and behavior in the marine environment,owing to the related potential for detrimental environmental,economic and social *** is essential to have a solid understanding of the ways in which oil interacts with the water and the coastal ecosystems that are located *** study proposes a simplified model for predicting the plume-like transport behavior of heavy Bunker C fuel oil discharging downward from an acutely-angled broken pipeline located on the water *** results show that the spill overall profile is articulated in three major flow *** first,is the source field,i.e.,a region near the origin of the initial jet,followed by the intermediate or transport field,namely,the region where the jet oil flow transitions into an underwater oil plume flow and starts to move horizontally,and finally,the far-field,where the oil re-surface and spreads onto the shore at a significant distance from the spill *** behavior of the oil in the intermediate field is investigated using a simplified injection-type oil spill model capable of mimicking the undersea trapping and lateral migration of an oil plume originating from a negatively buoyant jet spill.A rectangular domain with proper boundary conditions is used to implement the *** Projection approach is used to discretize a modified version of the Navier-Stokes equations in two dimensions.A benchmark fluid flow issue is used to verify the model and the results indicate a reasonable relationship between specific gravity and depth as well as agreement with the aerial data and a vertical temperature profile plot.

关键词： CFD model Navier-Stokes equations projection method water surface oil spill shallow coastal waters

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Seasonal influence of freshwater discharge on spatio-temporal variations in primary productivity, sea surface temperature, and euphotic zone depth in the northern Bay of Bengal

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Acta Oceanologica Sinica 2024年第6期43卷 1-14页

作者： Hafez Ahmad felix Jose Md.Simul Bhuyan Md.Nazrul Islam Padmanava Dash Geosystems Research Institute/Department of Geosciences Mississippi State UniversityStarkville 39759USA Department of Oceanography University of ChittagongChittagong 4331Bangladesh Department of Marine&Earth Sciences Florida Gulf Coast UniversityFort Myers 33965USA Bangladesh Oceanographic Research Institute Cox’s Bazar 4730Bangladesh Faculty of Marine Sciences&Fisheries Institute of Marine SciencesUniversity of ChittagongChittagong 4331Bangladesh Department of Geography and Environment Jahangirnagar UniversityDhaka 1342Bangladesh Department of Geosciences Mississippi State UniversityStarkville 39759USA

Ocean productivity is the foundation of marine food web,which continuously removes atmospheric carbon dioxide and supports life at sea and on ***-temporal variability of net primary productivity(NPP),sea surface temperature(SST),sea surface salinity(SSS),mixed layer depth(MLD),and euphotic zone depth(EZD) in the northern B ay of Bengal(BoB) during three monsoon seasons were examined in this study based on remote sensing data for the period 2005 to *** compare the NPP distribution between the coastal zones and open BoB,the study area was divided into five zones(Z1-Z5).Results suggest that most productive zones Z2 and Zl are located at the head bay area and are directly influenced by freshwater discharge together with riverine sediment and nutrient *** Z1-Z5,the NPP ranges from 5 315.38 mg/(m~2·d) to 346.7 mg/(m~2·d)(carbon,since then the same).The highest monthly average NPP of 5 315.38 mg/(m~2·d) in February and 5 039.36 mg/(m~2·d) in June were observed from Z2,while the lowest monthly average of 346.72 mg/(m~2·d) was observed in March from Z4,which is an oceanic *** values vary from 6-154 m for the study area,and it has an inverse correlation with NPP *** is deeper during the summer season and shallower during the wintertime,with a corresponding increase in *** the year,monthly SST shows slight fluctuation for the entire study area,and statistical analysis shows a significant correlation among NPP,and EZD,overall positive between NPP and MLD,whereas no significant correlation among SSS,and SST for the northern ***-term trends in SST and productivity were significantly po sitive in head bay zones but negatively productive in the open *** findings in this study on the distribution of NPP,SST,SSS,MLD,and EZD and their seasonal variability in five different zones of BoB can be used to further improve the management of marine resources and overall environmental condition in response to climate change

关键词： chlorophyll a sea surface temperature euphotic zone depth primary productivity Ganges-Brahmaputra ocean color Bay of Bengal monsoon

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Amyloid-β-induced disruption of axon-initial-segment mitochondria localization:consequences for TAU missorting in Alzheimer's disease pathology

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Neural Regeneration Research 2025年第5期20卷 1407-1408页

作者： Daniel Adam felix Langerscheidt Hans Zempel Institute of Human Genetics University Hospital CologneCologneGermany Center for Molecular Medicine Cologne(CMMC) University of CologneCologneGermany

TAU is a neuronal microtubule-associated protein preferentially located in *** a battery of neurodegenerative diseases termed"tauopathies,"including Alzheimer's disease (AD),TAU is missorted and abnormally phosphorylated,leading to filamentous accumulations of hyperphosphorylated TAU,a pathological hallmark and potential disease driver of AD and related tauopathies (Zempel,2024).

关键词： Alzheimer tau diseases

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Starch Orodispersible Film Loaded with Melatonin for Human Supplementation

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Journal of Renewable Materials 2024年第7期12卷 1343-1354页

作者： Fabio Tamanini Tatiane Zucchini de Souza Creusa Sayuri Tahara Amaral Antônio Joséfelix Carvalho Eliane Trovatti Department of Health and Biological Sciences University of Araraquara(UNIARA)São Paulo14801-340Brazil Department of Materials Engineering São Carlos School of EngineeringUniversity of São PauloSão Paulo13563-120Brazil

An innovative pharmaceutical form for administering melatonin,based on starch orodispersibleﬁlm(ODF),was designed and *** composition of the ODF included starch as the polymer matrix,the active drug melatonin,and a ***,a natural hormone produced by the pineal gland in the brain,can be absorbed by passive diffusion across the mucous membrane,resulting in improved bioavailability when compared to conventional oral *** study shows a simple and efﬁcient method for preparing melatonin-loaded orodispersibleﬁlms with a physically stable and commercially viable matrix,suitable for use in the pharmaceutical ***ﬁlms were prepared by treating the starch with microwave irradiation,followed by plasticization with glycerol,melatonin loading and drying by solvent *** tests showed theﬁlms’robustness,with a modulus of approximately 97 MPa,indicating good handling *** uptake analysis showed fast water absorption,reaching about 150%within 2 min,indicating its fast oral disintegration *** tests in artiﬁcial saliva and dissolution studies indicated the release of the drug in min-utes,indicating the potential properties of theﬁlm for oral drug *** the best of our knowledge,there is no melatonin ODF based on starch described in the literature.

关键词： Starch orodispersibleﬁlm melatonin drug delivery

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Prediction of Porous Media Fluid Flow with Spatial Heterogeneity Using Criss-Cross Physics-Informed Convolutional Neural Networks

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Computer Modeling in Engineering & Sciences 2024年第2期138卷 1323-1340页

作者： Jiangxia Han Liang Xue Ying Jia Mpoki Sam Mwasamwasa felix Nanguka Charles Sangweni Hailong Liu Qian Li State Key Laboratory of Petroleum Resources and Prospecting China University of PetroleumBeijing102249China Department of Oil-Gas Field Development Engineering College of Petroleum EngineeringChina University of PetroleumBeijing102249China Exploration Production Research Institute SinopecBeijing102249China Ministry of Energy Tanzania Petroleum Development CorporationTowerDar es Salaam2774Tanzania Ministry of Energy Building Petroleum Upstream Regulatory Authority in Tanzania(PURA)Dar es Salaam11439Tanzania

Recent advances in deep neural networks have shed new light on physics,engineering,and scientific *** the data-centered viewpoint with physical simulation is one of the research *** physicsinformedneural network(PINN)is currently the most general framework,which is more popular due to theconvenience of constructing NNs and excellent generalization *** automatic differentiation(AD)-basedPINN model is suitable for the homogeneous scientific problem;however,it is unclear how AD can enforce fluxcontinuity across boundaries between cells of different properties where spatial heterogeneity is represented bygrid cells with different physical *** this work,we propose a criss-cross physics-informed convolutionalneural network(CC-PINN)learning architecture,aiming to learn the solution of parametric PDEs with spatialheterogeneity of physical *** achieve the seamless enforcement of flux continuity and integration ofphysicalmeaning into CNN,a predefined 2D convolutional layer is proposed to accurately express transmissibilitybetween adjacent *** efficacy of the proposedmethodwas evaluated through predictions of several petroleumreservoir problems with spatial heterogeneity and compared against state-of-the-art(PINN)through numericalanalysis as a benchmark,which demonstrated the superiority of the proposed method over the PINN.

关键词： Physical-informed neural networks(PINN) flow in porous media convolutional neural networks spatial heterogeneity machine learning

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