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Chinese Chemical Letters 2014年第1期25卷 183-186页

作者： Ramin Rezaei fatemeh Moezzi Mohammad Mahdi Doroodmand Department of Chemistry Firoozabad BranchIslamic Azad University Department of Chemistry College of Sciences& Nanotechnology Research CenterShiraz University

A simple, efficient, and ecofriendly procedure has been developed using propane-l,2,3-triyl tris（hydrogen sulfate） as a catalyst for the synthesis of biscoumarin derivatives in water and solvent-free conditions. The significant features of the present protocol are simplicity, environmentally benign, high yields, no chromatographic separation, and recyclability of the catalyst.

关键词： Biscoumarin Aldehyde4-Hydroxycoumarin Propane-1 2 3-triyl tris(hydrogen sulfate)Homogeneous catalyst

Dynamics of host immune responses to SARS-CoV-2

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World Journal of Clinical Cases 2021年第18期9卷 4480-4490页

作者： Reza Taherkhani Sakineh Taherkhani fatemeh Farshadpour Department of Virology Bushehr University of Medical SciencesBushehr ***Iran Persian Gulf Tropical Medicine Research Center Bushehr University of Medical SciencesBushehr ***Iran School of Medicine Arak University of Medical SciencesArak ***Iran

Severe acute respiratory syndrome coronavirus 2(SARS-CoV-2),the most recent global health threat,is spreading throughout the world with worrisome speed,and the current wave of coronavirus disease 2019(COVID-19)seems to have no *** this mysterious virus challenges our ability to control viral infections,our opportunities to control the COVID-19 pandemic are gradually ***,pandemic management relies on preventive *** prevention is a good strategy to mitigate SARS-CoV-2 transmission,it still cannot be considered an absolute solution to eliminate this ***,developing a potent immunity against this viral infection seems to be the most promising strategy to drive down this ongoing global ***,with the emergence of new challenges in the context of immune responses to COVID-19,the road to control this devastating pandemic seems bumpier;thus,it is pivotal to characterize the dynamics of host immune responses to COVID-19,in order to develop efficient prophylactic and therapeutic *** begs the question of whether the effector mechanisms of the immune system are indeed potent or a possible contributing factor to developing more severe and lethal forms of *** this review,the possible role of the immunopathologic phenomena including antibody-dependent enhancement,cytokine storm,and original antigenic sin in severity and mortality of COVID-19 will be discussed.

关键词： SARS-CoV-2 COVID-19 Immune response Antibody-dependent enhancement Cytokine storm Original antigenic sin

Folic Acid Functionalized Vertically Aligned Carbon Nanotube (FA-VACNT) Electrodes for Cancer Sensing Applications

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Journal of Materials Science & Technology 2016年第7期32卷 617-625页

作者： Somayeh Zanganeh fatemeh Khodadadei S. Rafizadeh Tafti Mohammad Abdolahad Nano Bio Electronic Devices Lab. School of Electrical and Computer Engineering. University of Tehran. RO. Box 14395/515. Tehran. Iran Nanoelectronic Center of Excellence Thin Film and Nanoelectronic Lab. School of Electrical and Computer Engineering University of Tehran RO. Box 14395/515 Tehran Iran School of Chemical Engineering College of Engineering University of Tehran P.O. Box 11155-4563 Tehran Iran

An electrical cancer biosensor was developed using amine-functionalized vertically aligned carbon nanotubes （VACNTs） conjugated to folic acid （FA） molecules. Specific binding of FA to folate receptor （FR） existing on the membrane of cancer cells assisted their entrapment on VACNTs. For the conjugation of FA to CNTs, amine （--NH2） functional groups were attached to the side walls of the nanotubes by plasma treatment. The amount and shape of entrapped cancer cells on FA-VACNTs were noticeably higher and more uniform than the cells entrapped on bare VACNTs. The comparative signal spike of the FA-VACNTs and VACNTs covered impedance sensor in interaction with the same concentration of lung cancer cells （QUDB） showed sharper response for the functionalized sensor. Moreover, electron microscopy and florescent images as well as impedance diagrams verified the spherical and non-deformed shape of the cells entrapped by FA-VACNT, This sensor would be useful in assaying the cells vitality in time evolution. This device could be applied in diagnostic and time monitoring applications in the field of cancer such as extreme drug resistance assay （EDR）.

关键词： Carbon nanotubeImpedance biosensorFolic acidCancer ceil detectionFunctionalization

Voltammetric determination of stability constants of lead complexes with diallyl disulfide, dimethyl disulfide, and diallyl sulfide

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Chinese Chemical Letters 2016年第1期27卷 71-76页

作者： Mohammad Ali Kamyabi fatemeh Soleymani-Bonoti Saeed Zakavi Department of Chemistry University of Zanjan Department of Chemistry Institute for Advanced Studies in Basic Sciences

The complexation of Pb^（2＋）by diallyl disulfide（DADS）, dimethyl disulfide（DMDS） and diallyl sulfide（DAS）has been studied by differential pulse voltammetry. Stability constants,（log b）, of the 1：1（PbL） and 1：2（PbL_2） complexes, where L = ligand, were found to be in the range of ca. 3.8-4.2 and 9.4-10.2,respectively. Complex formation is accompanied with a significant decrease in the peak current and the shift of the Pb2＋/Pb half-wave potential to a higher one upon the addition of the sulfur containing ligands（L）. The formation of 1：1 and 1：2 complexes, i.e., PbL^（2＋）and PbL_2^（2＋）was observed in the case of the three ligands. The consecutive formation constants of labile lead complexes with DADS, DMDS, and DAS were determined at 298 K by the method of De Ford and Hume. Apparently due to the large size of the lead ion,steric hindrance caused by the greater steric bulk of DADS compared to that of DMDS have little or no effects on the formation constants, so that very similar values were obtained in the case of the two ligands. Also, the possible participation of C=C double bonds in coordination with the metal center in the case of DADS appears to compensate for the steric effects caused by the larger size of this ligand. In agreement with the Jorgensen principle of symbiosis, the second formation constants were found to be approximately six orders of magnitude greater than the first ones.

关键词： Garlic oil Organic sulfur compounds Pb^(2+)-DADS,DMDS,and DAS complexes Stability constant

Landslide susceptibility mapping using Genetic Algorithm for the Rule Set Production(GARP) model

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Journal of Mountain Science 2018年第9期15卷 2013-2026页

作者： fatemeh ADINEH Baharak MOTAMEDVAZIRI Hasan AHMADI Abolfazl MOEINI Department of Forest Range and Watershed Management Science and Research Branch Islamic Azad University

Investigation on landslide phenomenon is necessary for understanding and delineating the landslide prone and safer places for different land use practices. On this basis, a new model known as genetic algorithm for the rule set production was applied in order to assess its efficacy to obtain a better result and a more precise landslide susceptibility map in Klijanerestagh area of Iran. This study considered twelve landslide conditioning factors(LCF) like altitude, slope, aspect, plan curvature, profile curvature, topographic wetness index(TWI), distance from rivers, faults, and roads, land use/cover, and lithology. For modeling purpose, the Genetic Algorithm for the Rule Set Production(GARP) algorithm was applied in order to produce the landslide susceptibility map. Finally, to evaluate the efficacy of the GARP model, receiver operating characteristics curve as well as the Kappa index were employed. Based on these indices, the GARP model predicted the probability of future landslide incidences with the area under the receiver operating characteristics curve(AUC-ROC) values of 0.932, and 0.907 for training and validating datasets, respectively. In addition, Kappa values for the training and validating datasets were computed as 0.775, and 0.716, respectively. Thus, it can be concluded that the GARP algorithm can be a new but effective method for generating landslide susceptibility maps(LSMs). Furthermore, higher contribution of the lithology, distance from roads, and distance from faults was observed, while lower contribution was attributed to soil, profile curvature, and TWI factors. The introduced methodology in this paper can be suggested for other areas with similar topographical and hydrogeological characteristics for land use planning and reducing the landslide damages.

关键词： Landslide susceptibility mapping GIS GARP model Klijanerestagh watershed Iran

Evidence-Based Immunotherapeutic Effects of Herbal Compounds on Humoral Immunity:Ancient and New Approaches

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Chinese Journal of Integrative Medicine 2021年第4期27卷 313-320页

作者： fatemeh Nejatbakhsh Mohammad Ali Zareian Mahdi Yaseliani Hassan Abolhassani Department of Iranian Traditional Medicine School of Traditional MedicineTehran University of Medical SciencesTehran(14166)Iran Research Center for Immunodeficiencies Pediatrics Center of ExcellenceChildren's Medical CenterTehran University of Medical SciencesTehran(14194)Iran Division of Clinical Immunology Department of Laboratory MedicineKarolinska InstituteKarolinska University Hospital HuddingeStockholm(SE-14186)Sweden

The human immune system represents a dynamic multiscale system with high complexity in *** immunity,as the main branch of adaptive immunity,is characterized by differentiated stages of the Blymphocytes,producing the final product of antibodies that has a diversity of the tuning mechanisms within genetic and epigenetic levels in confrontation with environmental *** because of disturbed humoral immunity are linked with dysregulation of feedback-regulated signaling and the dynamic of immune components that determine the overall *** products,mainly herbal components have a significant role in tailoring the immune system micro-ecosystem which can diversify the adaptive nature of humoral ***,we review the current evidence-based approaches for the impact of medicinal herbs on humoral immunity signaling and antibody production with a focus on immunotherapeutic applications.

关键词： Bcells adaptive immunity antibody immunotherapy medicinal herb

Kinetic studies on extra heavy crude oil upgrading using nanocatalysts by applying CFD techniques

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Chinese Journal of Chemical Engineering 2018年第2期26卷 343-355页

作者： Javad Aminian Dehkordi Arezou Jafari Seyyed Amir Sabet fatemeh Karami Faculty of Chemical Engineering Tarbiat Modares UniversityTehranIran Islamic Azad University ShahroodIran

Regarding the growth of global energy consumption and the paucity of light crude oil, extracting and using heavy and extra heavy crude oil has received much more attention, but the application of this kind of oil is complicated due to its very high molecular weight. High viscosity and low flowability complicate the transportation of heavy and extra heavy crude oil. Accordingly, it is essential to reduce the viscosity of heavy and extra heavy crude oil through in-situ operations or immediate actions after extraction to reduce costs. Numerical simulations are influential methods, because they reduce calculation time and costs. In this study, the cracking of extra heavy crude oil using computational fluid dynamics is simulated, and a unique kinetic model is proposed based on experimental procedures to predict the behavior of extra heavy crude oil cracking reaction. Moreover, the hydrodynamics and heat transfer of the system and influence of nanocatalysts and temperature on the upgrading of crude oil are studied. The geometry of a reactor is produced using commercial software, and some experiments are performed to examine the validity and accuracy of the numerical results. The findings reveal that there is a good agreement between the numerical and experimental results. Furthermore, to investigate the main factors affecting the process, sensitivity analysis is adopted. Results show that type of catalyst and concentration of catalyst are the parameters that influence the viscosity reduction of extra heavy crude oil the most. The findings further revealed that when using a 25 nm SiO_2 nanocatalyst, a maximum viscosity reduction of 98.67% is observed at 623 K. Also, a catalyst concentration of 2.28 wt% is best for upgrading extra heavy crude oil. The results obtained through sensitivity analysis, simulation model, and experiments represent effectual information for the design and development of high performance upgrading processes for energy applications.

关键词： Upgrading Extra heavy oil Simulation Nanocatalyst

Petrogenesis of Middle-Eocene granitoids and their Mafic microgranular enclaves in central Urmia-Dokhtar Magmatic Arc(Iran): Evidence for interaction between felsic and mafic magmas

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Geoscience Frontiers 2019年第2期10卷 705-723页

作者： Kazem Kazemi Ali Kananian Yilin Xiao fatemeh Sarjoughian School of Geology College of ScienceUniversity of Tehran Department of Geochemistry and Environmental Science School of Earth and Space SciencesUniversity of Science and Technology of China Department of Earth Sciences Faculty of SciencesUniversity of Kurdistan

Whole rock major and trace element geochemistry together with zircon U-Pb ages and Sr-Nd isotope compositions for the Middle Eocene intrusive rocks in the Haji Abad region are presented. The granitoid hosts, including granodiorite and diorite, yielded zircon U-Pb ages with a weighted mean value of 40.0 ± 0.7 Ma for the granodiorite phase. Mafic microgranular enclaves(MMEs) are common in these plutons, and have relatively low SiO_2 contents(53.04-57.08 wt.%) and high Mg#(42.6-60.1), probably reflecting a mantle-derived origin. The host rocks are metaluminous(A/CNK = 0.69-1.03), arc-related calc-alkaline, and I-type in composition, possessing higher SiO_2 contents(59.7-66.77 wt.%) and lower Mg#(38.6-52.2); they are considered a product of partial melting of the mafic lower crust. Chondritenormalized REE patterns of the MMEs and granitoid hosts are characterized by LREE enrichment and show slight negative Eu anomalies(Eu/Eu* = 0.60-0.93). The host granodiorite samples yield(^(87)Sr/^(86)Sr);ratios ranging from 0.70498 to 0.70591,positive eNd(t) values varying from +0.21 to +2.3, and TDM2 ranging from 760 to 909 Ma, which is consistent with that of associated mafic microgranular enclaves(^(87)Sr/^(86)Sr)i = 0.705111-0.705113, ε_(Nd)(t)= +2.14 to +2.16, T_(DM2) = 697-785 Ma). Petrographic and geochemical characterization together with bulk rock Nd-Sr isotopic data suggest that host rocks and associated enclaves originated by interaction between basaltic lower crust-derived felsic and mantlederived mafic magmas in an active continental margin arc environment.

关键词： Geochemistry U-Pb geochronology Granitoid Haji Abad Low angle subduction Urumieh-Dokhtar Magmatic Arc

Covalent immobilization and characterization of Rhizopus oryzae lipase on core-shell cobalt ferrite nanoparticles for biodiesel production

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Chinese Journal of Chemical Engineering 2021年第9期34卷 128-136页

作者： Saboura Ashkevarian Jalil Badraghi fatemeh Mamashli Behdad Delavari Ali Akbar Saboury Research Institute of Applied Sciences ACECRShahid Beheshti UniversityTehranIran Institute of Biochemistry and Biophysics University of TehranTehranIran Center of Excellence in Biothermodynamics University of TehranTehranIran

Rhizopus oryzae lipase(ROL)was immobilized on the surface of silica coated amino modified CoFe_(2)O_4 nanoparticles and applied for biodiesel *** results indicated more affinity of the ROL toward its substrate upon immobilization,as revealed by a lower Km value for the immobilized ROL compared to its free *** fluorescence spectroscopy indicated a lower intensity for ROL immobilized on CoFe_(2)O_4 ***,immobilized ROL steady state anisotropy measurements presented lower values,which implied assembly of ROL molecules on magnetic nanoparticles upon immobilization as well as their restricted rotation upon covalent *** stability analysis revealed improved activity at higher temperatures for the immobilized enzyme compared to its free ***,Pace analysis to determine protein thermal stability revealed preservation of the protein conformation in the presence of increasing temperatures upon immobilization on ***,ROL immobilized on CoFe_(2)O_(4)nanoparticles exhibited improved efficiency of biodiesel production in agreement with thermal activity ***,the authors suggest application of the lipase molecules immobilized on CoFe_(2)O_(4)nanoparticles for more efficient biodiesel production.

关键词： Lipase immobilization CoFe_(2)O_(4)magnetic nanoparticles Steady state anisotropy Biodiesel Biocatalysis Protein stability

Synthesis and characterization of niobium-promoted cobalt/iron catalysts supported on carbon nanotubes for the hydrogenation of carbon monoxide

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燃料化学学报 2016年第7期44卷 815-821页

作者： Zahra Gholami Noor Asmawati Mohd Zabidi fatemeh Gholami Mohammadtaghi Vakili Centralized Analytical Laboratory Universiti Teknologi PETRONAS Department of Fundamental and Applied Sciences Universiti Teknologi PETRONAS Department of Mechanical Engineering Faculty of EngineeringUniversity of Malaya School of Industrial Technology Universiti Sains Malaysia

Bimetallic Co /Fe catalysts supported on carbon nanotubes( CNTs) were prepared,and niobium( Nb) was added as promoter to the 70 Co ∶30Fe /CNT catalyst. The physicochemical properties of the catalysts were characterized,and the catalytic performances were analyzed at the same operation conditions( H_2 ∶CO( volume ratio) = 2 ∶1,p = 1 MPa,and t = 260 ℃) in a tubular fixed-bed microreactor system. The addition of Nb to the bimetallic catalyst decreases the average size of the oxide nanoparticles and improves the reducibility of the bimetallic catalyst. Evaluation of the catalyst performance in a Fischer-Tropsch reaction shows that the catalyst results in high selectivity to methane,and the selectivity to C_(5+) increased slightly in the bimetallic catalyst unlike that in the monometallic catalysts. The addition of 1% Nb to the bimetallic catalyst increases CO conversion and selectivity to C_(5+). Meanwhile,a decrease in methane selectivity is observed.

关键词： Fischer-Tropsch synthesis bimetallic catalyst niobium promoter carbon nanotubes