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Journal of Thermal Science 2024年第2期33卷 591-601页

作者： WANG Zhaowen ZHOU hao LUO Jiawei LI Yawei fang hao LIU Tianxiao State Key Laboratory of Clean Energy Utilization Institute for Thermal Power EngineeringZhejiang UniversityHangzhou310027China

This paper studied the thermal physical properties of foundation materials in the molten salt tank of thermal energy storage system after molten salt leakage by Transient plane source experiment and X-ray computed microtomography simulation *** microstructure,thermal properties and pressure resistance with different particle diameters were *** measured heat conductivities from Transient plane source experiment for three cases are 0.49 W/(m·K),0.48 W/(m·K),and 0.51 W/(m·K),and the porosity is 30.1%,30.7%,and 31.2% *** heat conductivity simulating results of three cases are 0.471 W/(m·K),0.482W/(m·K),and 0.513 W/(m·K).The ratio of difference between the results of simulation and Transient plane source measurement is as low as 1.2%,verifying the reliability of experimental and simulation results to a certain *** with the heat conductivity of 0.097-0.129 W/(m·K) and porosity of 71.6%-78.9% without leaking salt,the porosity is reduced by more than 50% while the heat conductivity increased by 4 to 5 times after molten salt *** significant increase in heat conductivity has a great impact on security operation,structure design,and modeling of the tank foundation for solar power plants.

关键词： heat conductivity X-ray computed microtomography foundation materials three-phase threshold algorithm molten salt leakage

Cobalt-nitrogen co-doped porous carbon sphere as highly efficient catalyst for liquid-phase cyclohexane oxidation with molecular oxygen and the active sites investigation

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Frontiers of Chemical Science and Engineering 2024年第3期18卷 101-112页

作者： Lei Chen Yuan Sun Jinshan Chi Wei Xiong Pingle Liu fang hao College of Chemical Engineering National&Local United Engineering Research Centre for Chemical Process Simulation and IntensificationXiangtan UniversityXiangtan411105China

The selective oxidation of cyclohexane to cyclohexanone and cyclohexanol(KA oil)is a challenging issue in the chemical *** present the industrial conversion of cyclohexane to cyclohexanone and cyclohexanol is normally controlled at less than 5%***,the development of highly active and stable catalysts for the aerobic oxidation of cyclohexane is necessary to overcome this low-efficiency ***,we have developed a cobalt-nitrogen co-doped porous sphere catalyst,Co-NC-x(x is the Zn/Co molar ratio,where x=0,0.5,1,2,and 4)by pyrolyzing resorcinol-formaldehyde resin *** achieved 88.28%cyclohexanone and cyclohexanol selectivity and a cyclohexane conversion of 8.88%under *** results showed that the introduction of zinc effectively alleviated the aggregation of Co nanoparticles and optimized the structural properties of the *** addition,Co0 and pyridinic-N are proposed to be the possible active species,and their proportion efficiently increased in the presence of Zn^(2+)*** this study,we developed a novel strategy to design highly active catalysts for cyclohexane oxidation.

关键词： KA oil production cyclohexane selective oxidation cobalt-nitrogen co-doped porous carbon spheres metal-organic framework

Characteristics,origins,and significance of pyrites in deep-water shales

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Science China Earth Sciences 2024年第2期67卷 313-342页

作者： Chao LIANG Shichao JI Yingchang CAO Keyu LIU Jing WU fang hao National Key Laboratory of Deep Oil and Gas China University of Petroleum(East China)Qingdao266580China School of Geosciences China University of PetroleumQingdao266000China Laboratory for Marine Mineral Resource Qingdao National Laboratory for Marine Science and TechnologyQingdao266071China College of Earth Science and Engineering Shandong University of Science and TechnologyQingdao266590China

As important metal sulfides in the geochemical cycle of sulfur,the characteristics and formation processes of pyrites can provide useful clues regarding their *** on previous findings,shale pyrites were divided into three major classes(euhedral pyrites,framboidal pyrites(framboids)and metasomatic pyrites)and six sub-classes in this *** the microscopic scale,each type of pyrite is associated with a different formation *** are formed by burst nucleation in environments with a homogeneous distribution of nutrients while euhedral pyrites are usually formed on pre-existing sites(such as=FeS on the minerals surface)in the heterogeneous *** pyrites formed by the replacement of other ions in accountable material by iron ions and hydrogen sulfide ions in hydrothermal *** morphology and isotope value of pyrite provide information to track the origins of their nutrient and characteristics of sulfur and iron *** addition,the trace element content of pyrite can serve as a proxy for paleo-ocean trace element abundance,indicating changes in atmospheric oxygen ***,pyrite can also serves as an indicator of shale gas reservoirs.

关键词： Shale Pyrite Sulfate reduction reaction Isotope fractionation Pyrite element

Hydrocarbon Charging and Accumulation Process of the Large Bozhong19-6 Condensate Gas Reservoirs in the Southwestern Bozhong Sub-Basin,Bohai Bay Basin,China

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Journal of Earth Science 2024年第2期35卷 613-630页

作者： Quanyun Miao Changgui Xu fang hao Minjunshi Xie Qi Wang Jie Yin Huayao Zou General Prospecting Institute of China National Administration of Coal Geology Beijing100039China State Key Laboratory of Petroleum Resource and Prospecting China University of PetroleumBeijing102249China Tianjin Branch of China National Offshore Oil Company Ltd. Tianjin300452China School of Geosciences China University of PetroleumQingdao266580China School of Geosciences Yangtze UniversityWuhan430100China

The Bozhong19-6(BZ19-6)condensate gas reservoirs,located in the southwestern Bozhong sub-basin,Bohai Bay Basin,China,were paleo-oil reservoirs in the geological past and have undergone at least three successive hydrocarbon charging *** hydrocarbon migration and accumulation process of“early oil and late gas”has occurred in the current *** the end of the sedimentation of the Guantao Formation(N_(1)g,∼12 Ma),the reservoirs began to fill with first stage low-moderate mature crude *** the late stage of the Lower Minghuazhen Formation(N_(1)ml)(∼6.7 Ma),the reservoirs were largely charged with second stage high mature crude *** the deposition of the upper Minghuazhen Formation(N_(2)m^(u),∼5.1 Ma),the paleo-oil reservoirs were transformed into shallow Neogene reservoirs due to the reactivation of basement *** the late stage of the N_(2)m^(u)to the present day(∼2.8–0 Ma),the reservoirs were rapidly filled by natural gas within a short *** addition,analysis of the formation of the reservoir bitumen and the conspicuous loss of the lower molecular weight n-alkanes in the crude oil reveal that the injection of a large amount of gas in the late stage caused gas flushing of the early charged oil.

关键词： Bohai Bay Basin BZ19-6 condensate gas reservoirs fluid inclusions hydrocarbon charging and accumulation petroleum geology

Genetic source,migration and accumulation of helium under deep thermal fluid activities:A case study of Ledong diapir area in Yinggehai Basin,South China Sea

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Petroleum Exploration and Development 2024年第3期51卷 753-766页

作者： FENG Ziqi hao fang HU Lin HU Gaowei ZHANG Yazhen LI Yangming WANG Wei LI hao XIAO Junjie TIAN Jinqiang State Key Laboratory of Deep Oil and Gas China University of Petroleum(East China)Qingdao 266580China School of Geosciences China University of Petroleum(East China)Qingdao 266580China Laboratory for Marine Mineral Resources Qingdao Marine Science and Technology CenterQingdao 266237China Hainan Branch of CNOOC(China)Co. Ltd.Haikou 570312China

Based on the geochemical parameters and analytical data,the heat conservation equation,mass balance law,Rayleigh fractionation model and other methods were used to quantify the in-situ yield and external flux of crust-derived helium,and the initial He concentration and thermal driving mechanism of mantle-derived helium,in the Ledong Diapir area,the Yinggehai Basin,in order to understand the genetic source,migration and accumulation mechanisms of helium under deep thermal fluid *** average content of mantle-derived He is only 0.0014%,the 3 He/4 He value is(0.002–2.190)×10^(−6),and the R/Ra value ranges from 0.01 to 1.52,indicating the contribution of mantle-derived He is 0.09%–19.84%,while the proportion of crust-derived helium can reach over 80%.Quantitative analysis indicates that the crust-derived helium is dominated by external input,followed by in-situ production,in the Ledong diapir *** crust-derived helium exhibits an in-situ 4 He yield rate of(7.66–7.95)×10^(−13)cm^(3)/(a·g),an in-situ 4 He yield of(4.10–4.25)×10^(−4)cm^(3)/g,and an external 4 He influx of(5.84–9.06)×10^(−2)cm^(3)/*** results may be related to atmospheric recharge into formation fluid and deep rock-water *** ratio of initial mole volume of 3 He to enthalpy(W)is(0.004–0.018)×10−11 cm^(3)/J,and the heat contribution from the deep mantle(XM)accounts for 7.63%–36.18%,indicating that deep hot fluid activities drive the migration of mantle-derived 3 *** primary helium migration depends on advection,while the secondary migration is controlled by hydrothermal degassing and gas-liquid *** deep to shallow layers,the CO_(2)/3 He value rises from 1.34×10^(9)to 486×10^(9),indicating large amount of CO_(2)has *** the influence of deep thermal fluid,helium migration and accumulation mechanisms include:deep heat driven diffusion,advection release,vertical hydrothermal degassing,shallow lateral migration,accumulation in traps far from faults,partial pr

关键词： deep thermal fluid helium genetic source migration and accumulation mechanism Yinggehai Basin

Surface growth approach for bulk reconstruction in the AdS/BCFT correspondence

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Chinese Physics C 2024年第6期48卷 222-231页

作者：方西浩陈方中孙佳睿 School of Physics and Astronomy Sun Yat-Sen UniversityGuangzhou 510275China

In this study,we extend the surface growth approach for bulk reconstruction into the Ad S spacetime with a boundary in the Ad S/BCFT *** show that the geometry in the entanglement wedge with a boundary can be constructed from the direct growth of bulk extremal surfaces layer by ***,we observe that the surface growth configuration in BCFT can be connected with the defect multi scale entanglement renormalization ansatz(MERA)tensor ***,we investigate the entanglement of purification within the surface growth process,which not only reveals more refined structure of entanglement entropy in the entanglement wedge but also suggests a selection rule for surface growth in the bulk reconstruction.

关键词： AdS/CFT correspondence gauge/gravity duality models of quantum gravity

Multi-spherical interactions and mechanisms of hydrocarbon enrichment in the Southeast Asian archipelagic tectonic system

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Science China Earth Sciences 2024年第2期67卷 566-583页

作者： Rixiang ZHU Hongjun WANG Huajian WANG Xiaomei WANG Bo WAN Wang ZHANG Houqin ZHU Yuke LIU Junlai LIU Qingren MENG fang hao Zhijun JIN State Key Laboratory of Lithospheric Evolution Institute of Geology and GeophysicsChinese Academy of SciencesBeijing100029China State Key Laboratory of Enhanced Oil and Gas Recovery PetroChina Research Institute of Petroleum Exploration and DevelopmentBeijing100083China School of Earth Sciences and Resources China University of GeosciencesBeijing100083China State Key Laboratory of Deep Oil and Gas China University of Petroleum(East China)Qingdao266580China Institute of Energy Peking UniversityBeijing100871China

Global cooling began since 50 Ma,but a warm climate was maintained in the archipelagic tectonic system in Southeast Asia where a wealth of Cenozoic oil and gas resources was formed and *** the perspective of Earth system,this study analyzes Cenozoic tectonic activities,climatic and environmental evolution,and petroleum enrichment in Southeast Asia,and provides the following insights:(1)Subduction of oceanic plates and the extension of overlying continental lithosphere resulted in widespread volcanic eruptions as well as the formation of rift basins and shallow marine shelves,leading to complex interactions between deep tectonic processes and Earth’s surface including mountains,basins,and seas.(2)Microcontinental accretion and prolonged stay in equatorial low-latitude regions have changed trade winds into monsoons,altered ocean current pathways and flow rates,and profoundly affected rainfall and climate.(3)The archipelagic tectonic system,coupled with a hot and rainy climate,fostered tropical rainforests,mangroves,and phytoplankton,providing abundant organic matter and promoting the development of petroleum resources.(4)Combinations of rift basin development and marine transgression and regression led to an effective superposition of source-reservoir-seal combinations from multiplepetroleum *** deep burial of organic matter and high geothermal gradients facilitated the generation and large-scale accumulation of oil and gas.(5)Multi-spherical(such as atmosphere,biosphere,hydrosphere and lithosphere)interactions on the Earth,which resulted from the convergence of multiple tectonic plates,are believed as the primary driver for exceptional enrichments of Cenozoic oil and gas resources in Southeast *** understandings are significant for developing theories of oil and gas enrichment under the guidance of Earth System *** order to continue making significant oil and gas exploration discoveries in the deep-layers,deep-waters,and unconventio

关键词： Southeast Asia Archipelagic tectonic system Interactions of Earth’s spheres Oil and gas resources Cenozoic

点云数据直线检测及其在人工林树木计数中的应用

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武汉大学学报（信息科学版） 2024年第2期49卷 208-215页

作者：方浩李红军北京林业大学理学院北京100083

基于激光点云数据进行人工林调查时,由于激光扫描时树木的遮挡与自遮挡、树木被砍伐等原因造成扫描的点云数据有缺失,遗漏树木的位置判断不准确,森林调查结果误差大,解决这一问题的关键是实现缺失树木的填补。定义了离散点集共线度的概... 详细信息

基于激光点云数据进行人工林调查时,由于激光扫描时树木的遮挡与自遮挡、树木被砍伐等原因造成扫描的点云数据有缺失,遗漏树木的位置判断不准确,森林调查结果误差大,解决这一问题的关键是实现缺失树木的填补。定义了离散点集共线度的概念,构建了一个基于点集共线度最大化模型并结合直线检测进行缺失数据填补的方法。模拟数据实验结果:该方法的平均准确率为97.28%;人工林数据实验结果:该方法检测到9棵缺失树的位置,共线度由0.2193增大为0.2705。实验结果表明,该方法不仅可以实现缺失位置的最优推断,加强填补后数据的共线关系,也可应用于人工林的缺失树木计数。

关键词：离散点集直线检测缺失数据填补树木计数共线度

“文学阅读与创意表达”学习任务群下的单篇教学

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教学与管理 2024年第5期 50-54页

作者：费浩芳於丹浙江省海宁市南苑小学

《义务教育语文课程标准(2022年版)》倡导以学习任务群展开课程内容的组织。立足文学阅读与创意表达学习任务群,以六年级上册第七单元《京剧趣谈》单篇课文教学为例,通过梳理单元要素逻辑线、编织单篇学习实践网、创设任务驱动支架轴等... 详细信息

《义务教育语文课程标准(2022年版)》倡导以学习任务群展开课程内容的组织。立足文学阅读与创意表达学习任务群,以六年级上册第七单元《京剧趣谈》单篇课文教学为例,通过梳理单元要素逻辑线、编织单篇学习实践网、创设任务驱动支架轴等策略,提升学生语文学科核心素养。

关键词：学习任务群文学阅读与创意表达单元统整单篇教学

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诉源治理机制研究

西部学刊 2024年第2期 96-99,112页

作者：方皓中共池州市委党校(池州行政学院) 池州247000

以矛盾纠纷前端预防化解、综合治理为特点的诉源治理,是国家治理现代化的重要内容,也是防止我国成为“诉讼大国”的有效路径。现阶段实务界和理论界对于“诉源治理”及其机制建设研究所呈现出的概念扩大化、主体模糊化、流程碎片化等问... 详细信息

以矛盾纠纷前端预防化解、综合治理为特点的诉源治理,是国家治理现代化的重要内容,也是防止我国成为“诉讼大国”的有效路径。现阶段实务界和理论界对于“诉源治理”及其机制建设研究所呈现出的概念扩大化、主体模糊化、流程碎片化等问题已成为推进诉源治理机制建设的重要障碍。强调矛盾纠纷“源头预防、前端化解、关口把控”的治理理念在实践中的理解偏差所引致的追求“治理全面开花”“矛盾法院主导”“民声有求必解”,使得诉源治理必须充分考虑治理主体、治理内容及治理手段的涵盖范围与应用形式,以契合当下治理诉求与治理理念的脱节、治理主体与治理手段单一的不适症。

关键词：诉源治理诉源治理机制合作治理分层化解