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Diffusion-Free All-Solid-State Batteries Enabled by an Ionic/Electronic Dual-Conductive Anode

Renewables 2024年第3期2卷 194-203页

作者： Yue Ji Zaifa Wang Changtai Zhao Zhiqiang Fang Yue Gong Qihang Jing Yu Xia Tengjiao Luan Yingying Jiang Jianwen Liang Xiaona Li Mengdi Zhao Ximin Zhai Xiaofei Bie Tao Jiang dongsheng geng Xueliang Sun School of Materials Science and Engineering University of Science and Technology BeijingBeijing 100083 Solid State Batteries Research Center GRINM(Guangdong)Institute for Advanced Materials and TechnologyFoshan 528051 China Automotive Battery Research Institute Co.Ltd. Beijing 100088 China FAW Corporation Limited Changchun 130013 Key Laboratory of Automobile Materials of Ministry of Education&School of Materials Science and Engineering Jilin UniversityChangchun 130025 Eastern Institute for Advanced Study Eastern Institute of TechnologyNingbo 315200 School of Chemistry and Materials Science Nanjing University of Information Science&TechnologyNanjing 210044

Silicon(Si)is one of the most promising anodes for enabling all-solid-state batteries(ASSBs)with high energy density and ***,the tremendous volume change and sluggish kinetics result in poor electrochemical ***,we proposed an ionic/electronic dual-conductive material of Li_(x)Si as a diffusion-rapid and all-active anode for *** with pure Si anode,the as-fabricated Li_(x)Si showed dramatic promotions of 35 times electronic and 400 times ionic *** three-dimensional(3D)ionic-electronic transport system of Li_(x)Si enabled rapid kinetics and uniform volume change of electrode materials in the whole electrode,corresponding to a lower volumechange *** a result,the ASSBs with LiCoO_(2)cathode exhibited a reversible discharge capacity of 154.4 mAh g−1,corresponding to an initial Coulombic efficiency of 97.3%.Besides,the batteries delivered a high rate capacity of 99.3 mAh g^(−1)at 2 C and long-term cycle stability of 94.0%after 800 cycles at 1 C,which was much better than the pure Si *** study sheds light on a new understanding of the importance of ionic conductivity for Si-based anode and might help inspire the design of advanced anode materials for ASSBs.

关键词： all-solid-state batteries lithium silicon anodes interface stability ionic-electronic conductors long-term cycling performance

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Atomic-scale tuned interface of nickel-rich cathode for enhanced electrochemical performance in lithium-ion batteries

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Journal of Materials Science & Technology 2020年第19期54卷 77-86页

作者： Yongqiang Liu Xin Wang Jiyu Cai Xiaoxiao Han dongsheng geng Jianlin Li Xiangbo Meng Beijing Advanced Innovation Center for Materials Genome Engineering Beijing Key Laboratory for Magneto-Photoelectrical Composite and Interface ScienceSchool of Mathematics and PhysicsSchool of Materials Science and EngineeringUniversity of Science and Technology BeijingBeijing100083China Department of Mechanical Engineering University of ArkansasFayettevilleAR72701United States Energy and Transportation Science Division Oak Ridge National LaboratoryOak RidgeTN37831United States

The Ni-rich layered LiNi_(0.6)Mn_(0.2)Co_(0.2)O_(2)(NMC622)is one promising cathode for lithium-ion batteries(LIBs),but suffers from poor cycling stability under high cutoff *** performance degradation was reflected as capacity fading and voltage drop,having their roots in instable interface of *** at improving interfacial stability,in this study,we deposited nanoscale ZrO_(2) coatings conformally over NMC622 cathodes using atomic layer deposition(ALD).We found that,under a high cutoff voltage(4.5 V),the ALD ZrO_(2) coatings evidently improved the performance of NMC622 cathode,showing better cyclability and higher sustainable *** addition,the ALD coatings dramatically boosted the rate capability of *** these compelling performance results are ascribed to the atomic-scale tunable ZrO_(2) coatings via ALD,which create stable interface and thereby inhibit unfavorable *** the study,we utilize a suite of characterization tools and various analyses to clarify the effects of ALD ZrO_(2) *** study will be helpful for improving the performance of nickel-rich cathodes via interfacial engineering using ALD.

关键词： Atomic layer deposition Lithium ion battery Surface coating

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Synergetic enhancement of selectivity for electroreduction of CO_(2)to C_(2)H_(4)by crystal facet engineering and tandem catalysis over silver-incorporated-cuprous oxides

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Materials Reports(Energy) 2023年第2期3卷 164-172,I0004页

作者： Gang Dong Chuang Xue Meng Li Tiantian Zhang dongsheng geng Li-Min Liu Beijing Advanced Innovation Center for Materials Genome Engineering Beijing Key Laboratory for Magneto-Photoelectrical Composite and Interface ScienceSchool of Materials Science and EngineeringUniversity of Science and Technology BeijingBeijing100083PR China School of Physics Beihang UniversityBeijing100083PR China

Electrochemical CO_(2)reduction to C_(2)H_(4)can provide a sustainable route to reduce globally accelerating CO_(2)emissions and produce energy-rich chemical ***,the poor selectivity in C_(2)H_(4)electrosynthesis limits its implementation in industrially interesting ***,we report a composite structured catalyst composed of Ag and Cu_(2)O with different crystal faces to achieve highly efficient reduction of CO_(2)to C_(2)H_(4).The catalyst composed of Ag and octahedral Cu_(2)O enclosed with(111)facet exhibits the best CO_(2)electroreduction performance,with the Faradaic efficiency(FE)and partial current density reaching 66.8%and 17.8 mA cm2 for C_(2)H_(4)product at-1.2 VRHE in 0.5 M KHCO_(3),*** characterization and electrochemical test analysis indicate that the high selectivity for C_(2)H_(4)product stems from the synergistic effect of crystal faces control engineering and tandem ***,Ag can provide optimal availability of CO intermediate by suppressing hydrogen evolution;subsequently,C-C coupling is promoted on the intimate surface of Cu_(2)O with facetdependent *** insights gained from this work may be beneficial for designing efficient multicomponent catalysts for improving the selectivity of electrochemical CO_(2)reduction reaction to generate C2þproducts.

关键词： Cu_(2)O/Ag tandem catalysts Facet-dependent selectivity CO_(2)reduction reaction C_(2)H_(4) Electrocatalysis Synergistic effect

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A novel deep learning framework with variational auto-encoder for indoor air quality prediction

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Frontiers of Environmental Science & Engineering 2024年第1期18卷 97-109页

作者： Qiyue Wu Yun geng Xinyuan Wang dongsheng Wang ChangKyoo Yoo Hongbin Liu Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources Nanjing Forestry UniversityNanjing 210037China College of Automation&College of Artificial Intelligence Nanjing University of Posts and TelecommunicationsNanjing 210023China Guangxi Key Laboratory of Clean Pulp&Papermaking and Pollution Control College of Light Industry and Food EngineeringGuangxi UniversityNanning 530004China Laboratory for Comprehensive Utilization of Paper Waste of Shandong Province Shandong Huatai Paper Co.Ltd.Dongying 257335China Department of Environmental Science and Engineering College of EngineeringKyung Hee UniversityYongin 446701Republic of Korea

Exposure to poor indoor air conditions poses significant risks to human health, increasing morbidity and mortality rates. Soft measurement modeling is suitable for stable and accurate monitoring of air pollutants and improving air quality. Based on partial least squares (PLS), we propose an indoor air quality prediction model that utilizes variational auto-encoder regression (VAER) algorithm. To reduce the negative effects of noise, latent variables in the original data are extracted by PLS in the first step. Then, the extracted variables are used as inputs to VAER, which improve the accuracy and robustness of the model. Through comparative analysis with traditional methods, we demonstrate the superior performance of our PLS-VAER model, which exhibits improved prediction performance and stability. The root mean square error (RMSE) of PLS-VAER is reduced by 14.71%, 26.47%, and 12.50% compared to single VAER, PLS-SVR, and PLS-ANN, respectively. Additionally, the coefficient of determination (R2) of PLS-VAER improves by 13.70%, 30.09%, and 11.25% compared to single VAER, PLS-SVR, and PLS-ANN, respectively. This research offers an innovative and environmentally-friendly approach to monitor and improve indoor air quality.

关键词： Indoor air quality PM_(2.5)concentration Variational auto-encoder Latent variable Soft measurement modeling

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Formation Mechanism of Curved Martensite Structures in Cu-based Shape Memory Alloys

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Journal of Materials Science & Technology 2000年第1期16卷 79-81页

作者： Yujun BAI, Qiquan SHI,Guili geng, dongsheng SUN and Xiufang BIAN (Institute of Materials Engineering, Shandong University of Technology, Jinan 250061, China) Institute of Materials Engineering Shandong University of Technology Jinan 250061 China

The curved martensite structures have been observed in CuZnAI-based shape memory alloys by both transmission electron microscope and optical microscope. It was found that the curved martensite structures observed in as-solution treated, as-aged and as-trained alloys usually occurred around dislocation tangles or precipitate, at the plate boundary or grain boundary, and when the growing plates collided with each other or alternate mutually.

关键词： Formation Mechanism of Curved Martensite Structures in Cu-based Shape Memory Alloys Cu

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Electrical Characteristics and Desorption Kinetics of Soil Boron

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Pedosphere 2000年第1期10卷 61-68页

作者： ZHUDUANWEI CHENXIUHONG 等 DepartmentofResources EnvironmentandAgrochemistryHuazhongAgriculturalUniversityWuhan430070China DepartmentofResources EnvironmentandAgrochemistryHuazhongAgriculturalUniversityWuhan

The status and activities of boron in soils were studied by the approach of electro-ultrafiltration (EUF). The samples of soils, including brown-red soil and calcareous alluvial soil, were collected from Hubei Province of China. The soil samples were incubated in saturated water and then their nutrients were ultrafiltrated with EUF equipment. Filtration and extraction were conducted in accordance with routine process, but fractions in anode and cathode were all collected. Analyses of B, K+, Mg2+, Ca2+, Cl- and pH in fractions supposed that boron existed not only in a simple form of borate but also in ion-pair with canons partly in acidic soil, and borate was the primary form existing in the calcareous soil. In studying desorption kinetics with EUF, the boron content of Fractions 2-6 was accumulated, and the accumulative quantities were fit to time factors in three kinetic equations: the zero-order, first-order, and parabolic diffusion equations. Fit degree of the parabolic diffusion equation was the best, followed by the zero-order equation, and the first-order equation was the worst.

关键词： boron desorption kinetics electro-ultrafiltration soil

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Mixed Dead-time Effect Suppression Strategy for Modular Multilevel Converters

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CSEE Journal of Power and Energy Systems 2024年第3期10卷 1075-1084页

作者： Zhi geng Minxiao Han School of Electrical and Electronic Engineering North China Electric Power UniversityBeijing 102206China IEEE

Dead time is necessary for the coupled power switches to prevent shoot-through,especially in the modular multilevel converters(MMCs)with a large number of power *** paper proposes a dead-time effect suppression strategy for MMCs with nearest level *** operational principles of MMCs are first *** to the operational features of MMCs,the method that removes a switching signal from the coupled switches and the reduced switching frequency voltage balancing algorithms(RSFVBAs)are mixed in the proposed *** the intervals that are furthest away from the zerocrossing points(ZCP)of arm currents,the single switching signal method can completely eliminate the dead-time effect(DTE).Alternatively,the DTE is suppressed by the RSFVBA in intervals that are close to the *** the combination of the two methods,the dependence of the DTE suppression method on currents is reduced and the influences of ZCP are also released without degrading the normal operation performance of ***,the output performance of MMCs is improved and the voltage stress on the arm inductor dramatically ***,the validation of the method is verified by the simulation results with the professional tool Matlab/Simulink.

关键词： Dead-time effect modular multilevel converters switching frequency voltage balancing algorithm

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Investigation and measurement of old building response to the overlapped shield tunnel of multiple schemes in the sandy cobble stratum

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Underground Space 2024年第2期15卷 260-274页

作者： Xue Li Aopeng geng School of Geoscience and Technology Southwest Petroleum UniversityChengduSichuan 610500China China Railway Construction Bridge Engineering Bureau Group Co. Ltd.Tianjin 300300China

Ground movements due to tunneling are becoming increasingly critical as buildings are located around construction *** study proposes a new combined reinforcement method using a foundation grouting oblique pipe *** former improves the bearing capacity of the subsoil,and the latter blocks the transmission of soil deformation,which weakens the influence of construction during overlapped tunnel *** on this new method,a case study of the shield tunneling response to an old building in Line 6 of China’s Chengdu Metro is ***,three-dimensional numerical models without reinforcement,traditional foundation grouting reinforcement,and the new combined reinforcement schemes were *** numerical simulation performance was verified using a set of field instrumentation data,which demonstrated that the old building response to the overlapped tunnels was under control,and the maximum deformation,angular distortion,and principal tensile strain of the building were 5.25 mm,5.1010–6 rad/m,and 0.0081%,*** with the traditional reinforcement scheme,the deformation,angular distortion,and principal tensile strain in the combined reinforcement scheme were reduced by 54.78%,71.02%,and 70.22%,*** results have important implications for the design and construction of shield tunnels and their response to old buildings.

关键词： Overlapped tunnels Reinforcement schemes Under-crossing Old building Numerical simulation

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Boosting electrocatalytic nitrate reduction to ammonia via Cu_(2)O/Cu(OH)_(2)heterostructures promoting electron transfer

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Nano Research 2024年第6期17卷 4898-4907页

作者： Jing geng Sihan Ji Anhui Province International Research Center on Advanced Building Materials School of Materials Science and Chemical EngineeringAnhui Jianzhu UniversityHefei 230601China Anhui Province Key Laboratory of Advanced Building Materials Anhui Jianzhu UniversityHefei 230601China School of Energy Materials and Chemical Engineering Hefei UniversityHefei 230601China

Electrocatalytic nitrate(NO_(3)^(−))reduction to ammonia(NH_(3))offers a viable approach for sustainable NH_(3)production and environmental ***(Cu)possesses a distinctive electronic structure,which can augment the reaction kinetics of NO_(3)^(−)and impede hydrogen evolution reaction(HER),rendering it a promising contender for the electrosynthesis of NH_(3)from NO_(3)^(−).Nevertheless,the role of Cu_(2)O in copper-based catalysts still requires further investigation for a more comprehensive ***,the Cu_(2)O/Cu(OH)_(2)heterostructures are successfully fabricated through liquid laser irradiation using CuO nanoparticles as a *** and theoretical researches reveal that Cu_(2)O/Cu(OH)_(2)heterostructure exhibits enhanced electrocatalytic performance for NO_(3)^(−)to NH_(3)because Cu(OH)_(2)promotes electron transfer and reduces the valence state of Cu active site in Cu_(2)***−0.6 V(*** hydrogen electrode(RHE)),the NH_(3)yield reaches its maximum at 1630.66±29.72μg·h^(−1)·mgcat^(−1),while the maximum of Faraday efficiency(FE)is 76.95%±5.51%.This study expands the technical scope of copper-based catalyst preparation and enhances the understanding of the electrocatalytic mechanism of NO_(3)^(−)to NH_(3).

关键词： Cu_(2)O/Cu(OH)_(2)heterostructures electron transfer ammonia synthesis electrocatalysts nitrate

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Structural engineered living materials

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Nano Research 2024年第2期17卷 715-733页

作者： Yang geng Zian Jia Ling Li 635 Prices Fork Road Department of Mechanical EngineeringVirginia Polytechnic Institute and State UniversityBlacksburg VA24061USA

Biological structural materials not only exhibit remarkable mechanical properties but also often embody dynamic characteristics such as environmental responsiveness,autonomy,and self-healing,which are difficult to achieve in conventional engineering *** merging materials science,synthetic biology,and other disciplines,engineered living materials(ELMs)provide a promising solution to combine living organisms with abiotic components,thus facilitating the construction of functional“living”*** natural materials,ELMs possess vitality and hold immense application potential in areas such as medicine,electronics,and construction,captivating increasing research attention *** an emerging branch of ELMs,structural ELMs aim to mimic living biological structural materials by achieving desired mechanical performance while maintaining important“living”*** we summarize the recent progress and provide our perspectives for this emerging research *** first summarize the superiority of structural ELMs by reviewing biological structural materials and biomimetic material design ***,we provide a systematic discussion on the definition and classifications of structural ELMs,their mechanical performance,and physiological ***,we summarize some critical challenges faced by structural ELMs and highlight directions of future *** hope this review article can provide a timely summary of the state of the art and relevant perspectives for future development of structural ELMs.

关键词： structural materials engineered living materials(ELMs) structural ELMs composites mechanical properties

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