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Facile synthesis of Au embedded CuOx-CeO2 core/shell nanospheres as highly reactive and sinter-resistant catalysts for catalytic hydrogenation of p-nitrophenol

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Nano Research 2020年第8期13卷 2044-2055页

作者： Ke Wu Xin-Yu Wang ling-ling Guo Yue-Jiao Xu Liang Zhou Ze-Yu Lyu Kang-Yu Liu Rui Si Ya-Wen Zhang ling-dong sun Chun-Hua Yan Beijing National Laboratory for Molecular Sciences State Key Laboratory of Rare Earth Materials Chemistry and ApplicationsPKU-HKU Joint Laboratory in Rare Earth Materials and Bioinorganic Chemistryand College of Chemistry and Molecular EngineeringPeking UniversityBeijing100871China Shanghai Synchrotron Radiation Facility Shanghai Institute of Applied PhysicsChinese Academy of SciencesShanghai201204China College of Chemistry and Chemical Engineering Lanzhou UniversityLanzhou730000China

Exploring cost-effective catalysts with high catalytic performance and long-term stability has always been a general concern for environment protection and energy ***,Au nanoparticles(NPs)embedded CuOx-CeO2 core/shell nanospheres(Au@CuOx-CeO2 CSNs)have been successfully prepared through a versatile one-pot method at ambient *** spontaneous auto-redox reaction between HAuCl4 and Ce(OH)3 in aqueous solution triggered the self-assembly growth of micro-/nanostructural Au@CuOx-CeO2 ***,the CuOx clusters in Au@CuOx-CeO2 CSNs are capable of improving the anti-sintering ability of Au NPs and providing synergistic catalysis *** a result,the confined Au NPs exhibited extraordinary thermal stability even at a harsh thermal condition up to 700℃.In addition,before and after the severe calcination process,Au@CuOx-CeO2 CSNs can exhibit enhanced catalytic activity and excellent recyclability towards the hydrogenation of p-nitrophenol compared to previously reported *** synergistic catalysis path between Au/CuOx/CeO2 triphasic interfaces was revealed by density functional theory(DFT)*** CuOx clusters around the embedded Au NPs can provide moderate adsorption strength of p-nitrophenol,while the adjacent CeO2-supported Au NPs can facilitate the hydrogen dissociation to form H*species,which contributes to achieve the efficient reduction of *** study opens up new possibilities for developing high-efficient and sintering-resistant micro-/nanostructural nanocatalysts by exploiting multiphasic systems.

关键词： core/shell nanostructure sinter-resistant catalysts triphasic interfaces catalysis p-nitrophenol reduction

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An analysis on the effect of mining height and floor lithology on pressure relief of upper protective layers

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Journal of Coal Science & Engineering(China) 2013年第1期19卷 46-50页

作者： Xu-chao HUANG dong-ling sun Kang-wu FENG National Key Laboratory of Gas Disaster Detecting Preventing and Emergency Controlling Chongqing 400037 ChinaChongqing Research Institute China Coal Technology and Engineering Group Chongqing 400037 China

In order to understand the effect of mining height and floor lithology at the upper protective layer face on the pressure relief of protected coal seams, this paper uses a numerical simulation method to model the pressure changes at protected coal seam during mining upper protective layer. The results show that the taller the mining height at the upper protective layer face, the greater the protection on protected coal seam due to the higher level of pressure release; the upper protective layer face with hard rock floor impedes the pressure release at the protected coal seam, which affects the overall effect of the pressure release at protected coal seam using the protective layer mining method.

关键词： mining height floor lithology mining upper protective layer pressure relief effect

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PAA-capped GdF3 nanoplates as dual-mode MRI and CT contrast agents

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Science Bulletin 2015年第12期60卷 1092-1100,I0002页

作者： Xiao-Yu Zheng ling-dong sun Tao Zheng Hao dong Yang Li Ye-FuWang Chun-Hua Yan Beijing National Laboratory for Molecular Sciences State Key Laboratory of Rare Earth Materials Chemistry and ApplicationsPKU-HKU Joint Laboratory in Rare Earth Materials andBioinorganic Chemistry College of Chemistry and Molecular Engineering Peking University Beijing 100871 China

Aiming at improving the sensitivity and accu- racy 9f diagnosis, the combination of magnetic resonance imaging （MRI） and X-ray computed tomography （CT） in a single probe is in urgent need. Here, we report the devel- opment of polyacrylic acid （PAA）-capped GdF3 nanoplates （NPs） as novel MRI and CT dual-mode contrast agents （CAs） with high longitudinal relaxivity （rl） and large X-ray attenuation coefficient. Uniform GdF3 rhombic NPs were fabricated by controlling reaction conditions and intro- ducing dopants. The average size of GdF3 NPs is （10.6 ：k 1.1） nm in long diagonal, （7.0 -t- 0.8） nm in short diagonal, and （4.2 -4- 1.2） nm in thickness. Ligand-exchange treat- ment was performed to render the NPs water-dispersible. The rl of PAA-capped GdF3 NPs （15.8 L/（mmol s）） is four times higher than that of clinically used Gd-DTPA. We suppose that the high r~ value originates from the con- struction of two-dimensional （2D） nanostructures, which endows nanocrystals with larger surface areas and longer rotational correlation time than those of sphere nanostruc- tures with the same volume. The CT contrast enhancement ability of PAA-capped GdF3 NPs was evaluated in com- parison with clinically used Iohexol. The above results suggest that the PAA-capped GdF3 NPs could serve as CAs for MRI and CT dual-mode imaging.

关键词： Nanoplates GdF3 Contrast agent MRI CT

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Metabolic syndrome vs. its components for prediction of cardiovascular mortality： A cohort study in Chinese elderly adults

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Journal of Geriatric Cardiology 2012年第2期9卷 123-129页

作者： dong-ling sun Jian-Hua Wang Bin Jiang Liang-Shou Li Lan-sun Li Lei Wu Hai-Yun Wu Yao He Institute of Geriatrics Chinese PLA General Hospital 28 Fuxing Road Beijing 100853 China Department of Acupuncture Chinese PLA General Hospital 28 Fuxing Road Beijing 100853 China Department of Epidemiology the 4th Military Medical University No.17 Changle West Road Xi'an 710032 Shaanxi Province China Department of Cardiology the 4^th Military Medical University No.17 Changle West Road Xi'an 710032 Shaanxi Province China Institute of Geriatric Cardiology Chinese PLA General Hospital 28 Fuxing Road Beijing 100853 China

Objective The predictive value of the metabolic syndrome （MetS） for mortality from all-cause and cardiovascular disease （CVD） in the Chinese population is unclear. The aim of this present study was to compare MetS with its individual components as predictors of mortality in Chinese elderly adults. Methods A cohort of 1,535 subjects （994 men and 541 women） aged 50 years or older was selected from employees of a machinery factory in 1994 and followed until 2009. Cox models were used to estimate the hazard ratios （HRs） predicted by MetS according to the harmonized defmition and by its individual components. Results The baseline prevalence of MetS was 28.0% in men and 48.4% in women. During a median follow-up of 15 years, 414 deaths occurred, of these, 153 participants died from CVD. Adjusted for age and gender, the HRs of mortality from all-cause and CVD in participants with MetS were 1.47 （95% confidence interval （CI）： 1.20-1.80） and 1.96 （95%CI： 1.42-2.72）, respectively, compared with those without MetS. Non-significant higher risk of CVD mortality was seen in those with one or two individual components （HR = 1.22, 95%CI： 0.59-2.50; fir = 1.82, 95%CI： 0.91-3.64, respectively）, while a substantially higher risk of CVD mortality only appeared in those with 3, 4, or 5 components （H_R = 2.81-3.72）, compared with those with no components. On evaluating the MetS components individually, we found that, independent of MetS, only hypertension and impaired glucose predicted higher mortality. Conclusions The number of positive MetS components seems no more informative than classifying （dichotomous） MetS for CVD risks assessment in this Chinese cohort.

关键词： Cardiovascular disease Metabolic syndrome Cohort study Chinese adults

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稀土纳米晶的上转换发光及其调控研究进展

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中国科学：化学 2020年第11期50卷 1560-1574页

作者：董浩梅晟孙聆东严纯华北京大学化学与分子工程学院稀土材料化学及应用国家重点实验室北京大学-香港大学稀土材料与生物无机化学联合实验室北京分子科学中心北京100871 兰州大学化学化工学院兰州730000

稀土纳米晶的上转换发光具有近红外光激发、可见/紫外光或短波长近红外发射的特点,在微型激光器、超分辨光学成像、光遗传学、温度探测以及多通道成像等领域具有重要的应用.针对该类纳米晶的发光效率低、发光调控手段单一的问题,本文从... 详细信息

稀土纳米晶的上转换发光具有近红外光激发、可见/紫外光或短波长近红外发射的特点,在微型激光器、超分辨光学成像、光遗传学、温度探测以及多通道成像等领域具有重要的应用.针对该类纳米晶的发光效率低、发光调控手段单一的问题,本文从稀土纳米晶的组成、结构与上转换发光的关联出发,重点介绍了电、磁场、压力以及温度对上转换发光影响的研究进展.

关键词：稀土纳米晶上转换发光核壳结构温度高压光谱

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2D CaWO4 nanosheets derived from scheelite minerals for enhanced electrocatalysis in oxygen evolution reaction

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Science China Chemistry 2025年

作者： Qing sun Yongxiang sun Yan dong Hong Zhong Hongbo Zeng National&Local United Engineering Laboratory for New Petrochemical Materials&Fine Utilization of Resources College of Chemistry and Chemical EngineeringHunan Normal University Department of Chemical and Materials Engineering University of Alberta College of Chemistry and Materials Engineering Hunan University of Arts and Science College of Chemistry and Chemical Engineering Central South University

Scheelite （CaWO4） mineral holds promise as a cost-effective and efficient catalyst for the oxygen evolution reaction （OER）crucial in renewable energy ***,challenges such as limited active site exposure and low electrocatalytic performance need *** this work,we have fabricated two-dimensional （2D） CaWO4nanosheets from scheelite minerals via a straightforward ultrasonic exfoliation method and evaluated their efficacy as OER *** to scheelite powders,these 2D nanosheets exhibited superior crystallinity and a 1.26-fold increase in electrochemical surface area,promoting active site *** 2D CaWO4nanosheet electrode demonstrated outstanding OER catalytic performance,achieving a current density of 20 mA/cm2at an overpotential of 290 m V in alkaline conditions,which was lower than that of bulk CaWO4electrodes （～340 mV）.Density functional theory calculations attributed this enhanced catalytic performance to moderate adsorption of oxygenated intermediates （*OH,*O,and*OOH） on the W sites of 2D *** situ electrochemical atomic force microscopy tests also confirmed the catalytic enhancement by 2D CaWO4nanosheets during *** findings demonstrate the potential of affordable and abundant mineral resources in advancing electrochemical catalysts for oxygen evolution,highlighting their broader application in sustainable energy technologies.

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Single-cell omics: experimental workflow, data analyses and applications

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Science China Life Sciences 2025年第1期68卷 5-102页

作者： Fengying sun Haoyan Li dongqing sun Shaliu Fu Lei Gu Xin Shao Qinqin Wang Xin dong Bin Duan Feiyang Xing Jun Wu Minmin Xiao Fangqing Zhao Jing-dong J.Han Qi Liu Xiaohui Fan Chen Li Chenfei Wang Tieliu Shi Department of Clinical Laboratory the Affiliated Wuhu Hospital of East China Normal University (The Second People's Hospital of Wuhu City) Pharmaceutical Informatics Institute College of Pharmaceutical SciencesZhejiang University Key Laboratory of Spine and Spinal Cord Injury Repair and Regeneration (Tongji University) Ministry of EducationOrthopaedic DepartmentTongji HospitalBioinformatics DepartmentSchool of Life Sciences and TechnologyTongji University Frontier Science Center for Stem Cells School of Life Sciences and TechnologyTongji University Translational Medical Center for Stem Cell Therapy and Institute for Regenerative Medicine Shanghai East HospitalBioinformatics DepartmentSchool of Life Sciences and TechnologyTongji University Research Institute of Intelligent Computing Zhejiang Lab Shanghai Research Institute for Intelligent Autonomous Systems Center for Single-cell Omics School of Public HealthShanghai Jiao Tong University School of Medicine National Key Laboratory of Chinese Medicine Modernization Innovation Center of Yangtze River DeltaZhejiang University Center for Bioinformatics and Computational Biology Shanghai Key Laboratory of Regulatory Biologythe Institute of Biomedical Sciences and School of Life SciencesEast China Normal University Beijing Institutes of Life Science Chinese Academy of Sciences Peking-Tsinghua Center for Life Sciences Academy for Advanced Interdisciplinary StudiesCenter for Quantitative Biology (CQB)Peking University Zhejiang Key Laboratory of Precision Diagnosis and Therapy for Major Gynecological Diseases Women's HospitalZhejiang University School of Medicine Key Laboratory of Advanced Theory and Application in Statistics and Data Science-MOE School of StatisticsEast China Normal University

Cells are the fundamental units of biological systems and exhibit unique development trajectories and molecular features. Our exploration of how the genomes orchestrate the formation and maintenance of each cell, and control the cellular phenotypes of various organismsis, is both captivating and intricate. Since the inception of the first single-cell RNA technology, technologies related to single-cell sequencing have experienced rapid advancements in recent years. These technologies have expanded horizontally to include single-cell genome, epigenome,proteome, and metabolome, while vertically, they have progressed to integrate multiple omics data and incorporate additional information such as spatial sc RNA-seq and CRISPR screening. Single-cell omics represent a groundbreaking advancement in the biomedical field,offering profound insights into the understanding of complex diseases, including cancers. Here, we comprehensively summarize recent advances in single-cell omics technologies, with a specific focus on the methodology section. This overview aims to guide researchers in selecting appropriate methods for single-cell sequencing and related data analysis.

关键词： single-cell sequencing genome epigenome proteomics metabolomics multimodal spatial transcriptomics CRISPR screening

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Plasmonic tandem heterojunctions enable high-efficiency charge transfer for broad spectrum photocatalytic hydrogen production

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Journal of Energy Chemistry 2025年第1期100卷 710-720页

作者： Wenxuan Chen Xiu-Qing Qiao Guo Hui Bojing sun dongfang Hou Meidi Wang Xueqian Wu Tao Wu dong-Sheng Li College of Materials and Chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials China Three Gorges University Hubei Three Gorges Laboratory College of Chemistry and Materials Science and Guangdong Provincial Key Laboratory of Supramolecular Coordination Chemistry Jinan University

Rational engineering of semiconductor photocatalysts for efficient hydrogen production is of great significance but still challenging,primarily due to the limitations in charge transfer ***,a fascinating plasmonic tandem heterojunction with the hc-CdS/Mo2C@C heterostructure is aimfully prepared for effectively promoting the charge separation kinetics of the CdS photocatalyst via the synergistic strategy of phase junction,Schottky junction,and photothermal *** difference in atomic configuration between cubic-CdS （c-CdS） and hexagonal-CdS （h-CdS） leads to effective charge separation through a typical Ⅱ charge transfer mechanism,and plasmonic Schottky junction further extracts the electrons in the hc-CdS phase junction to realize gradient charge ***,the photothermal effect of Mo2C@C helps to expand the light absorption,accelerate charge transfer kinetics,and reduce the hydrogen evolution energy *** carbon layer provides a fast channel for charge transfer and protects the photocatalyst from *** a result,the optimized hc-CMC photocatalyst exhibits a significantly high photocatalytic H2production activity of 28.63 mmol/g/h and apparent quantum efficiency of 61.8%,surpassing most of the reported *** study provides a feasible strategy to enhance the charge transfer kinetics and photocatalytic activity of CdS by constructing plasmonic tandem heterogeneous junctions.

关键词： Cadmium sulfide

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Nanoparticles for the treatment of spinal cord injury

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Neural Regeneration Research 2025年第6期20卷 1665-1680页

作者： Qiwei Yang Di Lu Jiuping Wu Fuming Liang Huayi Wang Junjie Yang Ganggang Zhang Chen Wang Yanlian Yang ling Zhu Xinzhi sun Department of Orthopedic Surgery The First Affiliated Hospital of Zhengzhou UniversityZhengzhouHenan ProvinceChina CAS Key Laboratory of Standardization and Measurement for Nanotechnology CAS Key Laboratory for Biomedical Effects of Nanomaterials and NanosafetyCAS Center for Excellence in NanoscienceNational Center for Nanoscience and TechnologyBeijingChina University of Chinese Academy of Sciences BeijingChina Department of Neurosurgery The First Affiliated Hospital of Chongqing Medical UniversityChongqingChina

Spinal cord injuries lead to significant loss of motor, sensory, and autonomic functions, presenting major challenges in neural regeneration. Achieving effective therapeutic concentrations at injury sites has been a slow process, partly due to the difficulty of delivering drugs effectively. Nanoparticles, with their targeted delivery capabilities, biocompatibility, and enhanced bioavailability over conventional drugs, are garnering attention for spinal cord injury treatment. This review explores the current mechanisms and shortcomings of existing treatments, highlighting the benefits and progress of nanoparticle-based approaches. We detail nanoparticle delivery methods for spinal cord injury, including local and intravenous injections, oral delivery, and biomaterial-assisted implantation, alongside strategies such as drug loading and surface modification. The discussion extends to how nanoparticles aid in reducing oxidative stress, dampening inflammation, fostering neural regeneration, and promoting angiogenesis. We summarize the use of various types of nanoparticles for treating spinal cord injuries, including metallic, polymeric, protein-based, inorganic non-metallic, and lipid nanoparticles. We also discuss the challenges faced, such as biosafety, effectiveness in humans, precise dosage control, standardization of production and characterization, immune responses, and targeted delivery in vivo. Additionally, we explore future directions, such as improving biosafety, standardizing manufacturing and characterization processes, and advancing human trials. Nanoparticles have shown considerable progress in targeted delivery and enhancing treatment efficacy for spinal cord injuries, presenting significant potential for clinical use and drug development.

关键词： antioxidants axon regeneration biocompatible materials drug carriers nanoparticles nerve regeneration neuroinflammatory diseases neuroprotection spinal cord injury stem cells

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基于森林空间收获问题的模拟退火算法邻域搜索技术比较

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北京林业大学学报 2017年第8期39卷 24-32页

作者：董灵波孙云霞刘兆刚东北林业大学林学院

邻域搜索是当前提高启发式算法求解效率的核心技术之一,然而近期关于该搜索策略的性能却产生了较大争议。模拟退火算法作为一种典型的启发式算法,已广泛应用于一系列的林业规划问题。为此,本研究以模拟退火算法为例,系统评估2种不同邻... 详细信息

邻域搜索是当前提高启发式算法求解效率的核心技术之一,然而近期关于该搜索策略的性能却产生了较大争议。模拟退火算法作为一种典型的启发式算法,已广泛应用于一系列的林业规划问题。为此,本研究以模拟退火算法为例,系统评估2种不同邻域搜索技术在森林空间收获安排问题中的应用效果。规划模型以50年规划周期(10个规划分期)内的最大化木材收获为目标函数,以蓄积均衡收获、蓄积期末存量、单位限制模型和绿量限制等为主要约束条件。测试方法以模拟退火算法为原型,以每次优化过程中随机选择的小班数量为标准,共包括1-邻域和2-邻域2种不同的搜索技术。模拟规划数据由3个假设的栅格数据集组成,其共产生了3 293个(林分Ⅰ)、29 536个(林分Ⅱ)和81 625个(林分Ⅲ)0-1型决策变量。研究结果表明:模拟退火算法2-邻域搜索技术能够提高各规划问题的最大目标函数值;但当规划问题的决策变量数(或小班数量)较大时(即林分数量≥3 600),单纯增加邻域范围并不能提高规划问题的平均目标函数值。因此,鉴于模拟退火算法的优化结果对规划问题具有较高的敏感性,因此森林经营决策人员应慎重选择模拟退火算法邻域搜索作为相关规划问题的优化求解技术。

关键词：邻接约束绿量约束森林收获安排模拟退火算法邻域搜索

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