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A review of anodic catalysts and their application in(non-)Kolbe electrocatalytic decarboxylation of carboxylic acids

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Carbon Resources Conversion 2023年第4期6卷 287-297页

作者： Shichun Wang dezhang ren Yueying Du Mengjie Zhang Nahui Zhang Yaguang Sun Zhibao Huo College of Marine Ecology and Environment Shanghai Ocean University999 Huchenghuan RoadShanghai 201306China The Key Laboratory of Inorganic Molecule-Based Chemistry of Liaoning Province Shenyang University of Chemical TechnologyShenyang110142China Shanghai Engineering Research Center of River and Lake Biochain Construction and Resource Utilization Shanghai201702China

Biomass,as the exclusive and abundant organic resources,is considered to be the promising renewable *** acids are one of the many compounds that can be obtained from raw *** of carboxylic acids into fuels and chemicals via electrochemical method at mild reaction condition has been studied for many ***(non-)Kolbe reaction,one of the oldest organic electrochemical reactions,is the decarboxylation of carboxylic acids to produce alkanes,alcohols,esters,*** electrode materials influence the production of electrocatalytic decarboxylation products from carboxylic ***,this work mainly reviews the recent advances in applications of anodic materials for(non-)Kolbe electrocatalytic decarboxylation of carboxylic *** discusses the reaction mechanism of(non-)Kolbe electrolytic reaction,and the electrocatalytic oxidation of carboxylic acid using different electrodes and electrolytic systems to synthesize fuels and ***,various types of electrode catalysts,such as Pt-based catalysts,C-based catalysts,and other catalysts,are introduced in ***,the challenges and future trends of the(non-)Kolbe reaction of carboxylic acids are *** review found that platinum-based electrocatalysts proved to be the most promising catalysts at *** in recent years,a variety of synthesis methods have been developed to synthesize small size and high-performance noble metal based amorphous *** approach is to study catalysts without platinum electricity,such as Ru,Ir,Ti and carbon *** review is helpful in understanding and know the anodic materials and their application in(non-)Kolbe electrocatalytic decarboxylation of carboxylic acids for the readers.

关键词： Electrocatalytic decarboxylation Carboxylic acid (non-)Kolbe reaction Anode material Catalysis

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Carbon materials in electrocatalytic oxidation systems for the treatment of organic pollutants in wastewater:A review

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Carbon Resources Conversion 2023年第4期6卷 262-273页

作者： Xintong Duan dezhang ren Shichun Wang Mengjie Zhang Yaguang Sun Shujing Sun Zhibao Huo Nahui Zhang College of Marine Ecology and Environment Shanghai Ocean University999 Huchenghuan RoadShanghai 201306China The Key Laboratory of Inorganic Molecule-Based Chemistry of Liaoning Province Shenyang University of Chemical TechnologyShenyang 110142China Liaoning Ecological Environmental Monitoring Center Shenyang 110165China

Carbon materials are widely used as catalysts in electrocatalytic oxidative(EO)degradation of wastewater due to their large specific surface area and low *** materials can also be used as catalyst carriers for EO reactions due to their ease of functionalization with other heteroatoms and metals/metal *** improve the catalytic activity and current efficiency of carbon materials,modifying the structural and physicochemical properties of conventional carbon materials are common improvement *** review briefly outlines the recent research progress of carbon materials in EO for organic pollutants *** also discusses the modification strategies and corresponding electrocatalytic properties of various carbon materials(carbon nanomaterials and porous carbon materials),and explores the EO ***,some summaries of the remaining challenges and future developments of carbon materials in the field of electrocatalysis are given.

关键词： Carbon materials Electrocatalytic oxidation Industrial wastewater Mechanism

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Quantifying the sources of dissolved inorganic carbon within the sulfate-methane transition zone in nearshore sediments of Qi'ao Island, Pearl River Estuary, Southern China

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Science China Earth Sciences 2016年第10期59卷 1959-1970页

作者： WU ZiJun ZHOU HuaiYang ren dezhang GAO Hang LI JiangTao State Key Laboratory of Marine Geology Tongji University

The significance of the various biogeochemical pathways that drive carbon cycling and the relative fractions of dissolved inorganic carbon(DIC) produced by these reactions within the sulfate-methane transition zone(SMTZ) are still being debated. Unraveling these processes is important to our understanding of the benthic DIC sources and their contributions to the global carbon cycle. Here, we measure pore water geochemistry(chlorine, sulfate, methane, Ca^(2+), Mg^(2+), DIC and δ^(13)C-DIC) as well as solid geochemistry(sedimentary organic carbon(SOC) and δ^(13)C of SOC) in nearshore sediments from Qi'ao Island in the Pearl River Estuary of the Southern China Sea. Our analysis indicates that SOC originates from the mixing of carbon from terrestrial and marine sources, and that terrestrial materials dominate the net loss of SOC during the degradation of organic matter, especially at sites located near the river outlets. Sulfate reduction via SOC degradation is not appreciable in the upper sediment layer due to conservative mixing-dilution by freshwater. However, below this layer, the anaerobic oxidation of methane(AOM) and methanogenesis occur. Within the SMTZ, the δ^(13)C mass balance shows that the proportions of DIC derived from organoclastic SO_4^(2-) reduction(OSR) and AOM are 50.3% to 66.7% and 0.1% to 17.9%, respectively, whereas methanogenesis contributes 17.0% to 43.9%. This study reveals that the upward diffusion of DIC from ongoing methanogenesis significantly influences carbon cycling within the SMTZ in these estuarine sediments. As a result, we suggest that the plots of the ratio of change in sulfate to change in DIC in pore water should be used with caution when discriminating between sulfate reduction pathways in methane-rich sediments.

关键词：硫酸盐还原近岸沉积物溶解无机碳无机碳源淇澳岛过渡区珠江口甲烷

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Improved two-step hydrothermal process for acetic acid production from carbohydrate biomass

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Journal of Energy Chemistry 2015年第2期24卷 207-212页

作者： Zhibao Huo Yan Fang Guodong Yao Xu Zeng dezhang ren Fangming Jin School of Environmental Science and Engineering the State Key Laboratory of Metal Matrix CompositesShanghai Jiao Tong University State Key Laboratory of Pollution Control and Resources Reuse College of Environmental Science and EngineeringTongji University

An improved two-step process for converting carbohydrate biomass to acetic acid under hydrothermal conditions is proposed. The first step consists of the production of lactic acid from carbohydrate biomass, and the second step consists of conversion of the lactic acid obtained in the first step to acetic acid using CuO as an oxidant. The results indicated that CuO as an oxidant in the second step can significantly improve the production of high-purity acetic acid from lactic acid, and the maximum yield of acetic acid was 61%, with a purity of 90%. The yield of acetic acid obtained using the improved two-step hydrothermal process from carbohydrate biomass, such as glucose, cellulose and starch, was greater than that obtained using traditional two-step process with H_2O_2 or O_2. In addition, a proposed pathway for the production of acetic acid from lactic acid in the second step with CuO was also discussed. The present study provides a useful two-step process for the production of acetic acid from carbohydrate biomass.

关键词： carbohydrate biomass lactic acid CuO acetic acid hydrothermal reactions

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Catalytic transfer hydrogenation of levulinate ester intoγ-valerolactone over ternary Cu/ZnO/Al2O3 catalyst

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Journal of Energy Chemistry 2019年第5期28卷 189-197页

作者： Chuntao Zhang Zhibao Huo dezhang ren Zhiyuan Song Yunjie Liu Fangming Jin Wanning Zhou School of Environmental Science and Engineering Shanghai Jiao Tong University800 Dongchuan RoadMinhang districtShanghai 200240China College of Marine Ecology and Environment Shanghai Ocean University999 Huchenghuan RdNanhui New CityShanghai 201306China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China

An effective catalytic transfer hydrogenation (CTH) process of bio-based levulinate esters into γ-valerolactone (GVL) was explored over ternary Cu/ZnO/Al2O3 catalyst which was prepared by coprecipitation method and could be sustainably used. As a result, quantitative conversion of ethyl levulinate (EL) and 99.0% yield of GVL were obtained in the CTH process using i-PrOH as hydrogen donor. The Cu/ZnO/Al2O3 catalyst with high-surface-area could be reused at least four times without the loss of catalytic activity. Furthermore, the structure and properties of Cu/ZnO/Al2O3 catalyst was characterized through XRD, BET, SEM, TEM and H2-TPR. Also, the influence of different support oxides and calcination temperatures was investigated.

关键词： Bio-based compounds Cu/ZnO/Al2O3 Transfer hydrogenation γ-valerolactone Green process

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Heterogeneous Cu_2O-mediated ethylene glycol production from dimethyl oxalate

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Journal of Energy Chemistry 2016年第3期25卷 507-511页

作者： Lu Li dezhang ren Jun Fu Yunjie Liu Fangming Jin Zhibao Huo School of Environmental Science and Engineering the State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong University State Key Laboratory of Fine Chemicals Dalian University of Technology

An efficient process for the conversion of dimethyl oxalateinto ethylene glycol with high selectivity and high yield over CuO was investigated. In situ formed Cu as a true catalytically active species showed a good ca... 详细信息

关键词： Dimethyl oxalate Ethylene glycol Cu_2O Hydrothermal reactions Chemicals

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Catalytic conversion of ethyl lactate to 1,2-propanediol over CuO

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Chinese Journal of Chemical Engineering 2016年第1期24卷 126-131页

作者： Song Zhang Zhibao Huo dezhang ren Jiang Luo Jun Fu Lu Li Fangming Jin School of Environmental Science and Engineering The State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong University

An efficient conversion of biomass-derived ethyl lactate to 1,2-propanediol(1,2-PDO) over CuO was *** the catalysts we tested, CuO, Cu2 O and Co showed excellent catalytic activity for the conversion of ethyl lactate to 1,2-PDO in water, and CuO was more active and gave the best result. The 1,2-PDO yield of 93.6% was achieved when Zn acted as a reductant. The results indicated that in situ formed hydrogen by the oxidation of Zn in water is more effective than gaseous hydrogen, which failed to produce the 1,2-PDO from ethyl *** a practical point of view, the present method may provide a useful route for the production of 1,2-PDO from ethyl lactate.

关键词：乳酸乙酯 CuO 丙二醇催化剂转化高效转换催化活性有效路径

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左心耳增大及降主动脉左移对风湿性二尖瓣病变的诊断价值(附112例X线平片分析)

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实用放射学杂志 1993年第4期 205-208页

作者：周德章任大成四川南充地区医院

本文对112例风心和11例非风心的分析,我们认为:左心耳增大对风湿性二尖瓣病变具有特异的诊断价值;降主动脉左移对判断左心房增大是有帮助的。

关键词：左心耳降主动脉风湿性二尖瓣病变

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双菌多糖的抗肿瘤活性研究

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长春理工大学学报（自然科学版） 2008年第2期31卷 77-80页

作者：张青于航陈潇滢马德章徐任于源华长春教育学院长春130061 长春理工大学生命科学技术学院长春130022

以蒙古口蘑多糖(MOP)和紫蘑菇多糖(COP)为实验材料,分别对两种多糖和混合多糖(MCP)进行了体外和体内抗肿瘤实验,用MTT比色法测定了MOP、COP、MCP对肝癌细胞(HepG2)和人宫颈癌细胞(Hela)的抑制作用,并利用统计学方法进行分析,结果表明:... 详细信息

以蒙古口蘑多糖(MOP)和紫蘑菇多糖(COP)为实验材料,分别对两种多糖和混合多糖(MCP)进行了体外和体内抗肿瘤实验,用MTT比色法测定了MOP、COP、MCP对肝癌细胞(HepG2)和人宫颈癌细胞(Hela)的抑制作用,并利用统计学方法进行分析,结果表明:三者对HepG2和Hela两种癌细胞均有一定的抑制作用,但MCP的抑制效果最好,对HepG2抑制率为72.33%,对Hela的抑制率为80.68%。MCP对S180在KM小鼠体内的增殖有明显的抑制效果,最大抑制率达到58.74%,并呈现出良好的量效关系。获得的试验结果为开发真菌双糖抗肿瘤药物提供研究基础。

关键词：蒙古口蘑多糖紫蘑菇多糖抗肿瘤试验小鼠模型

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慢性肾脏病1~5期心肌肌钙蛋白T参考范围的确立

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华南国防医学杂志 2021年第9期35卷 642-646页

作者：潘德璋袁巧萌杨静逄玉涛赵明瑞刘志军任星峰中部战区总医院肾病内科湖北武汉430070 武汉科技大学医学院中部战区总医院核医学科湖北武汉430070

目的探讨慢性肾脏病(chronic kidney disease,CKD)1~5期患者心肌肌钙蛋白T(cardiac troponin T,cTnT)的参考范围。方法回顾性分析2014-01/2019-10月于作者医院住院的955例CKD患者临床资料。根据肾小球滤过率(glomerular filtration rate,GFR)将患者分为CKD1~5期;分组法按照正常组(CKD1~2期)、异常组(CKD3~5期)比较cTnT的差异性。建立各期、各组cTnT水平的参考范围。并检测分期法、分组法与原厂家cTnT水平参考范围的一致性。结果分组法中正常组与异常组的cTnT水平差异有统计学意义(P<0.01),参考范围为正常组≤0.02 ng/ml,异常组≤0.06 ng/ml;分期法中各期cTnT水平差异有统计学意义(P<0.01),cTnT水平随着CKD分期的升高而升高,参考范围为CKD1期≤0.02 ng/ml、CKD2期≤0.02 ng/ml、CKD3期≤0.03 ng/ml、CKD4期≤0.08 ng/ml、CKD5期≤0.10 ng/ml。CKD1~2期分期法、分组法与原厂家cTnT的参考范围一致。CKD3~5期分期法、分组法与原厂家的参考范围一致性均较差(Kappa=0.254、0.204);分期法与分组法的cTnT参考范围具有一致性(Kappa=0.581)。结论随着CKD分期的升高,CKD患者的cTnT水平呈逐渐上升趋势;建议使用分期法或分组法新建立的参考范围评价CKD3~5期患者的cTnT水平。

关键词：慢性肾脏病心肌肌钙蛋白T 参考范围肾小球滤过率

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