Heterogeneous Cu_2O-mediated ethylene glycol production from dimethyl oxalate

作     者：Lu Li Dezhang Ren Jun Fu Yunjie Liu Fangming Jin Zhibao Huo 

作者机构：School of Environmental Science and Engineering the State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong University State Key Laboratory of Fine Chemicals Dalian University of Technology 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2016年第25卷第3期

页      面：507-511页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：financial support from the State Key Program of National Natural Science Foundation of China(No.21436007) Key Basic Research Projects of Science and Technology Commission of Shanghai(14JC1403100) the Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning(ZXDF160002) the Projectsponsored by SRF for ROCS,SEM(BG1600002) State Key Laboratory of Fine Chemicals(KF1411) 

主　　题：Dimethyl oxalate Ethylene glycol Cu_2O Hydrothermal reactions Chemicals 

摘      要：An efficient process for the conversion of dimethyl oxalateinto ethylene glycol with high selectivity and high yield over CuO was investigated. In situ formed Cu as a true catalytically active species showed a good catalytic performance for DMO conversion to produce EG in 95% yield.