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Multi-scale analysis of carbon mineralization in lime-treated soils considering soil mineralogy

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第6期16卷 2296-2309页

作者： Dhanalakshmi Padmaraj Chinchu Cherian dali Naidu Arnepalli Department of Civil Engineering Indian Institute of Technology MadrasChennai600036India University of Northern British Columbia Prince GeorgeBCV2N4Z9Canada

Mineral carbonation is emerging as a reliable CO_(2) capture technology that can mitigate climate *** lime-treated clayey soils,mineral carbonation occurs through the carbonation of free lime and cementitious products derived from pozzolanic *** kinetics of the reactions in lime-treated clayey soils are variable and depend primarily on soil *** present study demonstrates the role of soil mineralogy in CO_(2) capture and the subsequent changes caused by carbon mineralization in terms of the unconfined compressive strength(UCS)of lime-treated soils during their service *** clayey soils(kaolin,bentonite,and silty clay)with different mineralogical characteristics were treated with 4%lime content,and the samples were cured in a controlled environment for 7 d,90 d,1.0 d,and 365 *** the specified curing periods,the samples were exposed to CO_(2) in a carbonation cell for 7 *** non-carbonated samples purged with N2 gas were used as a benchmark to compare the mechanical,chemical-mineralogical,and microstructure changes caused by carbonation *** investigations indicated that exposure to CO_(2) resulted in an average increase of 1.%in the UCS of limetreated bentonite,whereas the strength of lime-treated kaolin and silty clay was reduced by an average of 35%.The chemical and microstructural analyses revealed that the precipitated carbonates effectively filled the macropores of the treated bentonite,compared to the inadequate cementation caused by pozzolanic reactions,resulting in strength *** contrast,strength loss in lime-treated kaolin and silty clay was attributed to the carbonation of cementitious phases and partly to the tensile stress induced by carbonate *** terms of carbon mineralization prospects,lime-treated kaolin exhibited maximum carbonation due to the higher availability of unreacted *** results suggest that,in addition to the increase in compressive strength,adequate calcium-b

关键词： Clays Mineralogy Carbon capture Lime Strength Pore structure

Coupled bio-chemo-hydro-mechanical modeling of microbially induced calcite precipitation process considering biomass encapsulation using a micro-scale relationship

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第7期16卷 2775-2789页

作者： Pavan Kumar Bhukya Nandini Adla dali Naidu Arnepalli Department of Civil Engineering Indian Institute of Technology MadrasChennai600036Tamil NaduIndia

Geomaterials with inferior hydraulic and strength characteristics often need improvement to enhance their engineering *** ground improvement techniques require enormous mechanical effort or synthetic *** stabilization technique such as microbially induced calcite precipitation(MICP)utilizes bacterial metabolic processes to precipitate cementitious calcium *** reactive transport of biochemical species in the soil mass initiates the precipitation of biocement during the MICP *** precipitated biocement alters the hydro-mechanical performance of the soil ***,the flow,deformation,and transport phenomena regulate the biocementation technique via coupled bio-chemo-hydro-mechanical(BCHM)*** all,one crucial phenomenon controlling the precipitation mechanism is the encapsulation of biomass by calcium *** encapsulation can potentially reduce the biochemical reaction rate and decelerate *** examination of the encapsulation process demands a thorough analysis of associated coupled *** this,a numerical model can assist in capturing the coupled processes influencing encapsulation during the MICP ***,most numerical models did not consider biochemical reaction rate kinetics accounting for the influence of bacterial *** this,the current study developed a coupled BCHM model to evaluate the effect of encapsulation on the precipitated calcite content using a micro-scale semiempirical ***,the developed BCHM model was verified and validated using numerical and experimental observations of soil column ***,the encapsulation phenomenon was investigated in the soil columns of variable maximum calcite crystal *** results depict altered reaction rates due to the encapsulation phenomenon and an observable change in the precipitated calcite content for each maximum crystal ***,the permeability and defor

关键词： Biocementation process Bio-chemo-hydro-mechanical(BCHM) model Reactive transport Encapsulation Micro-scale

Paleosalinity reconstruction in offshore lacustrine basins based on elemental geochemistry:a case study of Middle Upper Eocene Shahejie Formation,Zhanhua Sag,Bohai Bay Basin

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Journal of Oceanology and Limnology 2024年第4期42卷 1087-1105页

作者： Long SUN Shenghe WU dali YUE Wenfu CUI National Key Laboratory of Petroleum Resources and Engineering China University of Petroleum(Beijing)Beijing 102249China College of Geosciences China University of Petroleum(Beijing)Beijing 102249China Shengli Oil Production Plant Shengli Oilfield CompanySINOPECDongying 257400China

Salinity is a crucial property of water body and is essential for the restoration of paleoecology and ***,the theoretical method of application of elemental geochemical proxies to paleosalinity reconstruction is still ***,accurate determination and reconstruction of paleosalinity and its variation in an offshore lacustrine basin have been extremely challenging thus *** study presents detailed elemental geochemical investigations from the Zhanhua Sag in the southern Bohai Bay Basin to reconstruct the salinity variation in the Paleogene Eocene Shahejie Formation(50.8-33.9 Ma).Based on the variation of strontium barium ratio(Sr/Ba)and boron gallium ratio(B/Ga),we determined three typical salinity types of water body:salty water(Sr/Ba>0.5,B/Ga>6),brackish water(0.21.to 1..9,reflecting the overall characteristics of oligohaline(0.51.)brackish *** proxies yielded similar trends in paleosalinity variation,demonstrating a clear trend of rising and then declining from 50.8 Ma to 33.9 *** considered that the B/Ga ratio had the highest reliability and resolution in determining the salinity types of water body in the study *** environmental factors causing paleosalinity variation were also thoroughly analysed based on the temporal relationship among the salinity types of watermasses,paleoclimate characteristics from pollen records,and marine transgression events from marine *** research established a model of paleoclimatic and eustatic mechanisms to explain paleosalinity variation,providing reasonable and integral driving forces for the salinity variation of all offshore lacustrine basins.

关键词： paleosalinity paleoclimate Zhanhua Sag Middle-Upper Eocene Shahejie Formation

Coupled multiphysical model for investigation of influence factors in the application of microbially induced calcite precipitation

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第6期16卷 2232-2249页

作者： Xuerui Wang Pavan Kumar Bhukya dali Naidu Arnepalli Shuang Chen Gesellschaft für Anlagen-und Reaktorsicherheit(GRS)GGmbH Braunschweig38122Germany Department of Civil Engineering Indian Institute of Technology MadrasChennai600036India Federal Institute for Geosciences and Natural Resources(BGR) Hannover30655Germany

The study presents a comprehensive coupled thermo-bio-chemo-hydraulic(T-BCH)modeling framework for stabilizing soils using microbially induced calcite precipitation(MICP).The numerical model considers relevant multiphysics involved in MICP,such as bacterial ureolytic activities,biochemical reactions,multiphase and multicomponent transport,and alteration of the porosity and *** model incorporates multiphysical coupling effects through well-established constitutive relations that connect parameters and variables from different physical *** was implemented in the open-source finite element code OpenGeoSys(OGS),and a semi-staggered solution strategy was designed to solve the couplings,allowing for flexible model ***,the developed model can be easily adapted to simulate MICP applications in different *** numerical model was employed to analyze the effect of various factors,including temperature,injection strategies,and application ***,a TBCH modeling study was conducted on the laboratory-scale domain to analyze the effects of temperature on urease activity and precipitated calcium *** understand the scale dependency of MICP treatment,a large-scale heterogeneous domain was subjected to variable biochemical injection *** simulations conducted at the field-scale guided the selection of an injection strategy to achieve the desired type and amount of ***,the study emphasized the potential of numerical models as reliable tools for optimizing future developments in field-scale MICP *** present study demonstrates the potential of this numerical framework for designing and optimizing the MICP applications in laboratory-,prototype-,and field-scale scenarios.

关键词： Multiphysics Microbially induced calcite precipitation(MICP) Coupled thermo-bio-chemo-hydraulic(TBCH) model OpenGeoSys(OGS) Influence factors

WNT7A promotes tumorigenesis of head and neck squamous cell carcinoma via activating FZD7/JAK1.STAT3 signaling

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International Journal of Oral Science 2024年第1期16卷 85-96页

作者： Qingling Huang Yi Xiao Ting Lan Youguang Lu Li Huang dali Zheng Department of Biochemistry and Molecular Biology School of Basic Medical SciencesFujian Medical UniversityFuzhouChina Fujian Key Laboratory of Oral Diseases School and Hospital of StomatologyFujian Medical UniversityFuzhouChina Department of Preventive Dentistry School and Hospital of StomatologyFujian Medical UniversityFuzhouChina Department of Dentistry The First Affiliated Hospital of Fujian Medical UniversityFuzhouChina

Wnt signaling are critical pathway involved in organ development, tumorigenesis, and cancer progression. WNT7A, a member of the Wnt family, remains poorly understood in terms of its role and the underlying molecular mechanisms it entails in head and neck squamous cell carcinoma (HNSCC). According to the Cancer Genome Atlas (TCGA), transcriptome sequencing data of HNSCC, the expression level of WNT7A in tumors was found to be higher than in adjacent normal tissues, which was validated using Real-time RT-PCR and immunohistochemistry. Unexpectedly, overexpression of WNT7A did not activate the canonical Wnt-β-catenin pathway in HNSCC. Instead, our findings suggested that WNT7A potentially activated the FZD7/JAK1.STAT3 signaling pathway, leading to enhanced cell proliferation, self-renewal, and resistance to apoptosis. Furthermore, in a patient-derived xenograft (PDX) tumor model, high expression of WNT7A and phosphorylated STAT3 was observed, which positively correlated with tumor *** findings underscore the significance of WNT7A in HNSCC progression and propose the targeting of key molecules within the FZD7/JAK1.STAT3 pathway as a promising strategy for precise treatment of HNSCC.

关键词： WNT squamous tumorigenesis

Multi-Scale Pore Structure Heterogeneity in Tuff Reservoirs Investigated with Multi-Experimental Method and Fractal Dimensions in Chang 7 Formation,Southern Ordos Basin

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Journal of Earth Science 2024年第2期35卷 666-686页

作者： Hao Lu Qing Li dali Yue Dongdong Xia Shenghe Wu Lang Wen Yu He State Key Laboratory of Petroleum Resources and Prospecting China University of PetroleumBeijing102249China College of Geosciences China University of PetroleumBeijing102249China Petroleum Exploration and Development Institute of SINOPEC Beijing100083China

The tight tuff reservoir is an unusual type of unconventional reservoir with strong ***,there is a lack of research on the microscopic pore structure that causes the heterogeneity of tuff *** the Chang 7 Formation in Ordos Basin,China as a case study,carbon-dioxide gas adsorption,nitrogen gas adsorption and high-pressure mercury injection are integrated to investigate the multi-scale pore structure characteristics of tuff ***,the fractal dimension is introduced to characterize the complexity of pore structure in tuff *** this multi-experimental method,the quantitative characterizations of the full-range pore size distribution of four tuff types were obtained and compared in the size ranges of micropores,mesopores and *** dimension curves derived from full-range pores are divided into six segments as D1.D2,D3,D4,D5 and D6 corresponding to fractal characteristics of micropores,smaller mesopores,larger mesopores,smaller macropores,medium macropores and larger macropores,*** macropore volume,average macropore radius and fractal dimension D5 significantly control petrophysical *** larger macropore volume,average macropore radius and D5 correspond to favorable pore structure and good reservoir quality,which provides new indexes for the tuff reservoir *** study enriches the understanding of the heterogeneity of pore structures and contributes to unconventional oil and gas exploration and development.

关键词： tuff reservoir pore structure carbon-dioxide gas adsorption nitrogen gas adsorption high-pressure mercury injection fractal dimension petroleum geology

Putrescine Modulates Cadmium Fixation Ability of Cell Wall to Decrease Cadmium Accumulation in Rice,a Process Might Depend on Nitric Oxide

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Rice science 2024年第3期31卷 237-240,I0002-I0007页

作者： WANG Haoyu LI Su YANG Jibo HUANG Jing ZHU Xiaofang SHEN Renfang ZENG dali College of Advanced Agricultural Sciences Zhejiang A&F UniversityHangzhou 311300China State Key Laboratory of Soil and Sustainable Agriculture Institute of Soil ScienceChinese Academy of ScienceNanjing 210008China University of Chinese Academy of Sciences Beijing 100049China

Although putrescine(PUT)has been linked to plants'responses to cadmium(Cd)stress,the exact mechanism is still *** the current investigation,the endogenous PUT concentration in rice roots was enhanced by Cd *** PUT increased root cell wall hemicellulose levels,which in turn increased its Cd binding capacity,concurrently decreasing the transcription level of genes such as OsNRAMP1.and OsCd1.that are responsible for root Cd *** a result。

关键词： absorption roots cadmium

Study on Clogging Mechanism and Water Sediment Movement Mechanism of Patch-Type Drip Irrigation Emitters

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排灌机械工程学报 2024年

作者： ZHU Ximao YU Liming WANG Dan WANG Changman WU dali YCIC Ecological Environment Engineering Co.， LTD 4. Yanshan Manyue Berry Agriculture Co.， LTD Faculty of Modern Agriculture Engineering， Kunming University of Science and Technology Research Institute of Highway Ministry of Transport， Key Laboratory of Environmental Protection Technology on Road

As one of the key components of drip irrigation technology， the existence of sediment particles seriously affects the service life of emitters and restricts the popularization of drip irrigation technology. In this paper， two kinds of patch drip irrigation emitters are used as research object， and the anti-clogging performance experiment is carried out in the laboratory. The dynamic changes in emitters’ clogging characteristics (Dra， Cu) were statistically analyzed. The movement mechanism of emitter clogging and discharging sediment was studied. The effects of emitter structure and position factors on emitter clogging were analyzed. The results show that: (1. The pressure-compensated emitter has better anti-clogging performance， and its service life is 227.8% of the labyrinth channel emitter. (2) Single structural factor can not evaluate the anti-clogging performance of emitters. All factors causing emitter clogging should be considered comprehensively. (3) All emitters have sensitive clogging sediment inside， but only when sediment content is high can it easily cause blockage. The results show that when the sensitive sediment content is 5.46% and 5.54%， it does not affect the clogging characteristics of the emitters. (4) The discharge of sediment V90 from the emitter is affected by the accumulation effect of clogged sediment. The experimental results show that the emitter can discharge up to 50% of the accumulated clogged sediment without clogging. In comparison， the emitter with clogging can only discharge up to 25% of the accumulated clogged sediment. These results could provide references for the application and promotion of drip irrigation technology.

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Insights into Euphorbia diversity: Probing the contrasts between Euphorbia fischeriana Steud and Euphorbia ebracteolata Hayata

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Journal of Pharmaceutical Analysis 2024年第5期14卷 775-779页

作者： Kaicheng Du Yi Zhang Lei Sun Muke Tao Tiantian Zuo Yumeng Wang Zhengfeng Zhang dali Meng School of Traditional Chinese Materia Medica Shenyang Pharmaceutical UniversityShenyang110016China NMPA Key Laboratory for Quality Monitoring of Narcotic Drugs and Psychotropic Substances Chongqing Institute for Food and Drug ControlChongqing401121China National Institutes for Food and Drug Control Beijing100050China

In traditional Chinese medicine(TCM),Euphorbia fischeriana Steud(***)and Euphorbia ebracteolata Hayata(***),commonly referred to as“Langdu”,are widely extensively utilized for treating lymphatic tuberculosis and ringworm[1..Both plant species are perennial herbaceous plants mainly distributed in northeastern China,Mongolia,Russia(Siberia),and Republic of Korea[2].There have been many reports on the chemical constituents and pharmacological effects of the two plant species,which has made more and more researchers realize that there may be differences between *** and *** some cases,long-term improper use of herbal medicines can even lead to life-threatening conditions[3,4].Therefore,it is essential to employ an effective technology to differentiate between these two plants based on their chemical constituents and biological activities,so as to reduce the harm caused by the mixing and misuse of medicinal ***,the present paper describes a study of the differences between *** and ***,using untargeted plant metabolomics and biological activity *** study aims to provide valuable insight into their equivalence and potential interchangeability in TCM and clinical medication.

关键词： Euphorbia Siberia northeastern