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Nucleophiles promotes the decomposition of electrophilic functional groups of tetracycline in ZVI/H_(2)O_(2) system: Efficiency and mechanism

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Chinese Chemical Letters 2024年第10期35卷 414-420页

作者： Xin Li Wanting Fu Ruiqing guan Yue Yuan Qinmei zhong Gang Yao Sheng-Tao Yang Liandong Jing Song Bai Key Laboratory of Pollution Control Chemistry and Environmental Functional Materials for Qinghai-Tibet Plateau of the National Ethnic Affairs Commission School of Chemistry and EnvironmentSouthwest Minzu UniversityChengdu 610041China Key Laboratory of General Chemistry of the National Ethnic Affairs Commission School of Chemistry and EnvironmentSouthwest Minzu University.Chengdu 610041China Institute of Environmental Engineering RWTH Aachen UniversityAachen 52062Germany

When zero-valent iron(ZVI)is prepared and applied under neutral conditions,it is easy to form oxides or hydroxides on its surface,which hinders the electron release of *** this end,a nucleophile was introduced into the ZVI system to inhibit the precipitation of iron ions,improve the conductivity of the solution,and promote the removal efficiency of electrophilic functional groups in organic *** this study,the addition of nucleophiles such as ethylenediamine,methylamine and dimethylamine to the ZVI/H_(2)O_(2)system resulted in an enhanced removal efficiency of tetracycline(TC)under neutral condition,while electrophiles such as EDTA-2Na and oxalic acid dihydrate impeded the removal of *** results demonstrated that the presence of nucleophiles could effectively promote the release of iron ions and increase the proportion of ferrous in both aqueous solution and solid surface of *** and theoretical calculation results revealed that the electrophilic functional group was eliminated in the TC molecule,and the toxicity of the treated solution was reduced ***,this work provides a selection of the conditions and pollutants applicable to ZVI under neutral pH conditions.

关键词： ZVI Nucleophiles Tetracycline Electrophilicfunctionalgroup Electronic transfer

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基于公平带宽估计的VCP协议的一种快速收敛方法

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系统仿真学报 2009年第20期21卷 6658-6661,6665页

作者：张慧翔戴冠中慕德俊戴航西北工业大学自动化学院西安710072

变结构控制协议(VCP)是一种高带宽时延网络环境下良好的拥塞控制机制,但其采用较大的乘减因子,公平性收敛时间较长。结合一种公平带宽估计算法在端系统估算公平带宽,有效地缩短了VCP协议的公平收敛时间。建立了改进算法的动态模型,分析... 详细信息

变结构控制协议(VCP)是一种高带宽时延网络环境下良好的拥塞控制机制,但其采用较大的乘减因子,公平性收敛时间较长。结合一种公平带宽估计算法在端系统估算公平带宽,有效地缩短了VCP协议的公平收敛时间。建立了改进算法的动态模型,分析了其稳定性和动态行为,以及其协议参数对动态性能的影响。最后利用ns2仿真实验验证了改进算法的有效性。

关键词：高带宽时延网络拥塞控制变结构控制协议公平带宽估计公平性收敛

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Single-celled metasurface for labeled vortex beam generator

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Journal of Materiomics 2024年第4期10卷 811-818页

作者： Congling Liang Qi dai Tian Huang Hong-Chao Liu Zhiqiang guan Rao Fu Jin Tao Zile Li Shaohua Yu Guoxing Zheng Electronic Information School and School of MicroelectronicsWuhan UniversityWuhan430072China Wuhan Institute of Quantum Technology Wuhan430206China Peng Cheng Laboratory Shenzhen518055China Suzhou Institute of Wuhan University Suzhou215123China Institute of Applied Physics and Materials Engineering University of MacaoAvenida da UniversidadeTaipaMacao SARMacao999078China State Key Laboratory of Optical Communication Technologies and Networks China Information Communication Technologies Group Corporation(CICT)Wuhan430074China

Vortex light is a unique beam characterized by a spiral phase as it propagates. A fundamental parameter of vortex light is the topological charge, which determines the amount of angular momentum and plays a crucial role in tailoring its behavior. However, conventional measurement methods for determining the topological charge, such as those based on interference and phase modulation, tend to be intricate and complex. In this regard, a labeled vortex beam generator is proposed, composed of a metasurface with a single-celled configuration. When the metasurface is illuminated by light of the designed wavelength, the outgoing light exhibits a vortex structure. Furthermore, the topological charge numbers can be directly observed with distinct labeled patterns when the metasurface is placed in an orthogonal-polarized optical path. With advantages such as ultra-compactness, high robustness, and exceptional precision, the proposed metasurface exhibits significant potential for applications in optical communication, light manipulation, optical sensing, etc.

关键词： Metasurface Vortex beam generator Topological charge

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A multi-objective optimization based on machine learning for dimension precision of wax pattern in turbine blade manufacturing

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Advances in Manufacturing 2024年第3期12卷 428-446页

作者： Jing dai Song-Zhe Xu Chao-Yue Chen Tao Hu San-San Shuai Wei-Dong Xuan Jiang Wang zhong-Ming Ren State Key Laboratory of Advanced Special Steels School of Materials Science and EngineeringShanghai UniversityShanghai200444People’s Republic of China

Wax pattern fabrication in the investment casting of hollow turbine blades directly determines the dimension accuracy of subsequent casting,and therefore significantly affects the quality of final *** this work,we develop a machine learning-based multi-objective optimization framework for improving dimension accuracy of wax pattern by optimizing its process *** consider two optimization objectives on the dimension of wax pattern,i.e.,the surface warpage and core *** active learning of Bayesian optimization is employed in data sampling to determine process parameters,and a validated numerical model of injection molding is used to compute objective results of dimension under varied process *** collected dataset is then leveraged to train different machine learning models,and it turns out that the Gaussian process regression model performs best in prediction accuracy,which is then used as the surrogate model in the optimization framework.A genetic algorithm is employed to produce a non-dominated Pareto front using the surrogate model in searching,followed by an entropy weight method to select the most optimal solution from the Pareto *** optimized set of process parameters is then compared to empirical parameters obtained from previous trial-and-error experiments,and it turns out that the maximum and average warpage results of the optimized solution decrease 26.0%and 20.2%,and the maximum and average errors of wall thickness compared to standard part decrease from 0.22 mm and 0.0517 mm using empirical parameters to 0.10 mm and 0.0356 mm using optimized parameters,*** framework is demonstrated capable of addressing the challenge of dimension control arising in the wax pattern production,and it can be reliably deployed in varied types of turbine blades to significantly reduce the manufacturing cost of turbine blades.

关键词： Hollow turbine blade Wax pattern fabrication Dimension control Multi-objective optimization Machine learning Numerical simulation

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网络蠕虫感染率的抗差估计法

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计算机工程与科学 2008年第1期30卷 1-3,11页

作者：邓妍戴冠中高逦西北工业大学自动化学院陕西西安710072

网络蠕虫对信息安全构成了威胁,检测和防范蠕虫成为网络安全的研究课题。本文提出了一种网络蠕虫感染率的估计方法,首先利用抗差估计原理构造了基于原始观测量的算法模型,然后根据权函数和残差区间给出了抗差等价权矩阵,分析了误差影响... 详细信息

网络蠕虫对信息安全构成了威胁,检测和防范蠕虫成为网络安全的研究课题。本文提出了一种网络蠕虫感染率的估计方法,首先利用抗差估计原理构造了基于原始观测量的算法模型,然后根据权函数和残差区间给出了抗差等价权矩阵,分析了误差影响及验后精度估计,最后进行了仿真实验。实验结果表明,这种方法具有良好的抗粗差能力,可靠且收敛速度快。

关键词：蠕虫网络安全抗差估计等价权矩阵

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网格计算与对等计算的比较研究

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小型微型计算机系统 2005年第10期26卷 1742-1748页

作者：邓智群戴冠中慕德俊罗红西北工业大学自动化学院陕西西安710072

对网格计算和对等计算从概念、目标、体系结构、组成团体、资源、安全需求、应用、基础架构和特征等方面进行了深入比较,总结了各自的特点,最后对二者的研究方向进行展望．

关键词：分布式计算网格计算对等计算比较

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Excitonic Instability in Ta2Pd3Te5 Monolayer

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Chinese Physics Letters 2024年第9期41卷 57-62页

作者： Jingyu Yao Haohao Sheng Ruihan Zhang Rongtian Pang Jin-Jian Zhou Quansheng Wu Hongming Weng Xi dai zhong Fang Zhijun Wang Beijing National Laboratory for Condensed Matter Physics and Institute of PhysicsChinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China Centre for Quantum Physics Key Laboratory of Advanced Optoelectronic Quantum Architecture and Measurement(MOE)School of PhysicsBeijing Institute of TechnologyBeijing 100081China Department of Physics Hong Kong University of Science and TechnologyHong Kong 999077China

By systematic theoretical calculations,we reveal an excitonic insulator(EI)in the Ta_(2)Pd_(3)Te_(5)*** bulk Ta_(2)Pd_(3)Te_(5)is a van der Waals(vdW)layered compound,whereas the vdW layer can be obtained through exfoliation or molecular-beam ***-principles calculations show that the monolayer is a nearly zero-gap semiconductor with the modified Becke–Johnson *** to the same symmetry of the band-edge states,the two-dimensional polarization 2D would be finite as the band gap goes to zero,allowing for an EI state in the *** the first-principles many-body perturbation theory,the GW plus Bethe–Salpeter equation calculation reveals that the exciton binding energy is larger than the single-particle band gap,indicating the excitonic *** computed phonon spectrum suggests that the monolayer is dynamically stable without lattice *** findings suggest that the Ta_(2)Pd_(3)Te_(5) monolayer is an excitonic insulator without structural distortion.

关键词： monolayer principles calculations

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Interfacial reaction between AZ91D magnesium alloy melt and mild steel under high temperature

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China Foundry 2024年第2期21卷 159-167页

作者： Jia-hong dai Jian-yue Zhang Bin Jiang Xiang-jun Xu zhong-tao Jiang Hong-mei Xie Qing-shan Yang Guo-qing Zhang College of Materials Science and Engineering Yangtze Normal UniversityChongqing 408100China National Engineering Research Center for Magnesium Alloys College of Materials Science and EngineeringChongqing UniversityChongqing 400044China Chongqing Jiulongyuan High-tech Industry Group Co. Ltd.Chongqing 400080China Loncin Industry Co. Ltd.Chongqing 400080China Department of Materials Science and Engineering The Ohio State UniversityColumbusOH 43210USA Chongqing Key Laboratory of Materials Surface&Interface Science Chongqing University of Arts and SciencesChongqing 402160China School of Metallurgy and Material Engineering Chongqing University of Science and TechnologyChongqing 401331China

The metallurgical quality control of magnesium(Mg)and Mg alloys in melting process is required to ensure a satisfied mechanical and corrosion performance,while the typical used steel crucible introduces impurities and interfacial interaction during melting ***,a systematic study about impurities diffusion and interfacial interaction between molten Mg and steel is *** the present study,the interfacial reaction between molten AZ91D Mg alloy and mild steel during melting process was investigated with the melting temperatures of 700℃,750℃ and 800℃.The results show that Al(Fe,Mn)intermetallic layer is the intermetallic primarily formed at the interfaces of AZ91D melt and mild ***,Al_(8)(Mn,Fe)5is indexed between Al(Fe,Mn)and ***_(3)C appears between the mild steel and Al(Fe,Mn)at 700℃ and 750℃,but absent at 800℃ due to the increased solubility of carbon in Mg *** is found that the growth of the intermetallic layer is controlled by diffusion mechanism,and Al and Mn are the dominant diffusing species in the whole interfacial reaction *** measuring the thickness of different layers,the growth constant was *** increases from 1.89(±0.03)×10^(-12)m^(2)·s^(-1)at 700℃ to 3.05(±0.05)×10^(-12)m^(2)·s^(-1)at 750℃,and 5.18(±0.05)×10^(-12)m^(2)·s^(-1)at 800℃.Meanwhile,the content of Fe is linearly increased in AZ91D with the increase of holding time at 700℃ and 750℃,while it shows a significantly increment after holding for 8 h at 800℃,indicating holding temperature is more crucial to determine the Fe content of AZ91D than holding time.

关键词： AZ91D mild steel interface reaction intermetallic growth kinetics

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Utilization of 3D printing technology in hepatopancreatobiliary surgery

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Journal of Zhejiang University-Science B(Biomedicine & Biotechnology) 2024年第2期25卷 123-134页

作者： Wujiang SHI Jiangang WANG Jianjun GAO Xinlei ZOU Qingfu DONG Ziyue HUANG Jialin SHENG Canghai guan Yi XU Yunfu CUI Xiangyu zhong Department of Hepatopancreatobiliary Surgery the Second Affiliated Hospital of Harbin Medical UniversityHarbin150086China Department of General Surgery Tangdu HospitalAir Force Medical UniversityXi’an710032China Key Laboratory of Basic Pharmacology of Ministry of Education Zunyi Medical UniversityZunyi563006China Key Laboratory of Functional and Clinical Translational Medicine Fujian Province UniversityXiamen Medical CollegeXiamen361000China Department of Pathology Li Ka Shing Faculty of MedicineThe University of Hong KongHong KongChina Jiangsu Province Engineering Research Center of Tumor Targeted Nano Diagnostic and Therapeutic Materials Yancheng Teachers UniversityYancheng224007China Key Laboratory of Biomarkers and In Vitro Diagnosis Translation of Zhejiang Province Hangzhou310053China Key Laboratory of Gastrointestinal Cancer(Fujian Medical University) Ministry of EducationSchool of Basic Medical SciencesFujian Medical UniversityFuzhou350122China Key Laboratory of Myocardial Ischemia Harbin Medical UniversityMinistry of EducationHarbin150086China

The technology of three-dimensional(3D)printing emerged in the late 1970s and has since undergone considerable development to find numerous applications in mechanical engineering,industrial design,and *** biomedical science,several studies have initially found that 3D printing technology can play an important role in the treatment of diseases in hepatopancreatobiliary *** example,3D printing technology has been applied to create detailed anatomical models of disease organs for preoperative personalized surgical strategies,surgical simulation,intraoperative navigation,medical training,and patient ***,cancer models have been created using 3D printing technology for the research and selection of chemotherapy *** the aim to clarify the development and application of 3D printing technology in hepatopancreatobiliary surgery,we introduce seven common types of 3D printing technology and review the status of research and application of 3D printing technology in the field of hepatopancreatobiliary surgery.

关键词： 3D printing Hepatopancreatobiliary surgery Organ model Cancer model

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VCP协议最大最小公平带宽分配的实现与仿真

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系统仿真学报 2010年第7期22卷 1716-1719,1723页

作者：张慧翔戴冠中姚磊周海瑞西北工业大学自动化学院西安710072

变结构控制协议(VCP)是一种高带宽时延乘积网络环境下良好的拥塞控制机制。然而在多瓶颈网络拓扑中,由于VCP采用基于负载因子编码的反馈控制机制,长距离数据流的过载响应受传输路径上多个节点的控制,从而系统达不到最大最小公平。通过分... 详细信息

变结构控制协议(VCP)是一种高带宽时延乘积网络环境下良好的拥塞控制机制。然而在多瓶颈网络拓扑中,由于VCP采用基于负载因子编码的反馈控制机制,长距离数据流的过载响应受传输路径上多个节点的控制,从而系统达不到最大最小公平。通过分析VCP的拥塞信息反馈方式,提出一种基于过载周期的反馈控制机制,使每个数据流的过载响应只受其瓶颈链路的控制,从而使系统达到最大最小公平。最后利用NS2仿真实验验证了基于过载周期的反馈控制机制的有效性。

关键词：高带宽时延网络拥塞控制变结构控制协议多瓶颈网络最大最小公平

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